BRPI0513813B1 - Artigo compreendendo filme óptico, substrato e camada adesiva sensível a pressão - Google Patents
Artigo compreendendo filme óptico, substrato e camada adesiva sensível a pressão Download PDFInfo
- Publication number
- BRPI0513813B1 BRPI0513813B1 BRPI0513813-2A BRPI0513813A BRPI0513813B1 BR PI0513813 B1 BRPI0513813 B1 BR PI0513813B1 BR PI0513813 A BRPI0513813 A BR PI0513813A BR PI0513813 B1 BRPI0513813 B1 BR PI0513813B1
- Authority
- BR
- Brazil
- Prior art keywords
- block
- meth
- acrylate
- substrate
- methacrylate
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 104
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 90
- 239000010410 layer Substances 0.000 title claims abstract description 86
- 239000012788 optical film Substances 0.000 title claims abstract description 66
- 229920001400 block copolymer Polymers 0.000 claims abstract description 94
- 239000000178 monomer Substances 0.000 claims abstract description 74
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 65
- -1 alkyl methacrylate Chemical compound 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 25
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 24
- 125000004404 heteroalkyl group Chemical group 0.000 claims abstract description 13
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 claims description 36
- 239000000853 adhesive Substances 0.000 claims description 35
- 229920000642 polymer Polymers 0.000 claims description 20
- 239000004417 polycarbonate Substances 0.000 claims description 16
- 238000003860 storage Methods 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229920000515 polycarbonate Polymers 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 2
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 claims description 2
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims 1
- 230000003287 optical effect Effects 0.000 abstract description 28
- 230000003667 anti-reflective effect Effects 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 239000010408 film Substances 0.000 description 83
- 230000015572 biosynthetic process Effects 0.000 description 47
- 238000000034 method Methods 0.000 description 41
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- 238000002360 preparation method Methods 0.000 description 32
- 239000007789 gas Substances 0.000 description 29
- 238000000576 coating method Methods 0.000 description 26
- 238000006116 polymerization reaction Methods 0.000 description 23
- 239000000243 solution Substances 0.000 description 19
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 18
- 239000004926 polymethyl methacrylate Substances 0.000 description 17
- 238000010998 test method Methods 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 12
- 239000003999 initiator Substances 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 230000003750 conditioning effect Effects 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 230000009477 glass transition Effects 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
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- 238000010526 radical polymerization reaction Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000002411 adverse Effects 0.000 description 5
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 150000003926 acrylamides Chemical class 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
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- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 238000010551 living anionic polymerization reaction Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
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- 239000003701 inert diluent Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
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- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 239000012815 thermoplastic material Substances 0.000 description 3
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 2
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 101710141544 Allatotropin-related peptide Proteins 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
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- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
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- 150000002576 ketones Chemical class 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
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- YVWBWDZQFGXBOT-UHFFFAOYSA-N 1,3-bis(1-phenylethenyl)benzene Chemical compound C=1C=CC(C(=C)C=2C=CC=CC=2)=CC=1C(=C)C1=CC=CC=C1 YVWBWDZQFGXBOT-UHFFFAOYSA-N 0.000 description 1
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 1
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- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- ILLHORFDXDLILE-UHFFFAOYSA-N 2-bromopropanoyl bromide Chemical compound CC(Br)C(Br)=O ILLHORFDXDLILE-UHFFFAOYSA-N 0.000 description 1
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- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
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- ZVYGIPWYVVJFRW-UHFFFAOYSA-N 3-methylbutyl prop-2-enoate Chemical compound CC(C)CCOC(=O)C=C ZVYGIPWYVVJFRW-UHFFFAOYSA-N 0.000 description 1
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 1
- BVDBXCXQMHBGQM-UHFFFAOYSA-N 4-methylpentan-2-yl prop-2-enoate Chemical compound CC(C)CC(C)OC(=O)C=C BVDBXCXQMHBGQM-UHFFFAOYSA-N 0.000 description 1
- OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 1
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- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
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- LVGFPWDANALGOY-UHFFFAOYSA-N 8-methylnonyl prop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C=C LVGFPWDANALGOY-UHFFFAOYSA-N 0.000 description 1
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- Polymers & Plastics (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Laminated Bodies (AREA)
- Graft Or Block Polymers (AREA)
- Polarising Elements (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/901629 | 2004-07-29 | ||
| US10/901,629 US7255920B2 (en) | 2004-07-29 | 2004-07-29 | (Meth)acrylate block copolymer pressure sensitive adhesives |
| PCT/US2005/024093 WO2006023143A1 (en) | 2004-07-29 | 2005-07-07 | (meth)acrylate block copolymer pressure sensitive adhesives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0513813A BRPI0513813A (pt) | 2008-05-13 |
| BRPI0513813B1 true BRPI0513813B1 (pt) | 2015-06-09 |
Family
ID=35385621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0513813-2A BRPI0513813B1 (pt) | 2004-07-29 | 2005-07-07 | Artigo compreendendo filme óptico, substrato e camada adesiva sensível a pressão |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US7255920B2 (enExample) |
| EP (3) | EP2108687B1 (enExample) |
| JP (2) | JP5096143B2 (enExample) |
| KR (1) | KR101126371B1 (enExample) |
| CN (1) | CN1989216B (enExample) |
| AT (1) | ATE448283T1 (enExample) |
| BR (1) | BRPI0513813B1 (enExample) |
| DE (1) | DE602005017634D1 (enExample) |
| MX (1) | MX2007000860A (enExample) |
| WO (1) | WO2006023143A1 (enExample) |
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| CN119731221A (zh) | 2022-03-17 | 2025-03-28 | 科学把手粘合剂公司 | 可自主固化且可发泡的双组分丙烯酸类胶粘剂 |
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-
2004
- 2004-07-29 US US10/901,629 patent/US7255920B2/en not_active Expired - Lifetime
-
2005
- 2005-07-07 KR KR1020077001978A patent/KR101126371B1/ko not_active Expired - Fee Related
- 2005-07-07 EP EP20090165271 patent/EP2108687B1/en not_active Expired - Lifetime
- 2005-07-07 EP EP10184025.4A patent/EP2287266B1/en not_active Expired - Lifetime
- 2005-07-07 BR BRPI0513813-2A patent/BRPI0513813B1/pt not_active IP Right Cessation
- 2005-07-07 EP EP20050772413 patent/EP1773961B1/en not_active Expired - Lifetime
- 2005-07-07 DE DE200560017634 patent/DE602005017634D1/de not_active Expired - Lifetime
- 2005-07-07 JP JP2007523588A patent/JP5096143B2/ja not_active Expired - Fee Related
- 2005-07-07 CN CN2005800252849A patent/CN1989216B/zh not_active Expired - Fee Related
- 2005-07-07 AT AT05772413T patent/ATE448283T1/de not_active IP Right Cessation
- 2005-07-07 WO PCT/US2005/024093 patent/WO2006023143A1/en not_active Ceased
- 2005-07-07 MX MX2007000860A patent/MX2007000860A/es not_active Application Discontinuation
-
2007
- 2007-07-10 US US11/775,420 patent/US8039104B2/en not_active Expired - Fee Related
- 2007-10-16 US US11/872,979 patent/US7494708B2/en not_active Expired - Fee Related
-
2012
- 2012-01-12 JP JP2012004098A patent/JP5453465B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0513813A (pt) | 2008-05-13 |
| DE602005017634D1 (en) | 2009-12-24 |
| US7255920B2 (en) | 2007-08-14 |
| KR101126371B1 (ko) | 2012-03-28 |
| US20060024521A1 (en) | 2006-02-02 |
| EP1773961A1 (en) | 2007-04-18 |
| ATE448283T1 (de) | 2009-11-15 |
| JP2008508394A (ja) | 2008-03-21 |
| JP5453465B2 (ja) | 2014-03-26 |
| JP5096143B2 (ja) | 2012-12-12 |
| EP2108687A1 (en) | 2009-10-14 |
| US20080138557A1 (en) | 2008-06-12 |
| CN1989216A (zh) | 2007-06-27 |
| US7494708B2 (en) | 2009-02-24 |
| MX2007000860A (es) | 2007-04-18 |
| CN1989216B (zh) | 2010-12-22 |
| WO2006023143A1 (en) | 2006-03-02 |
| EP2108687B1 (en) | 2014-06-18 |
| EP2287266B1 (en) | 2015-09-02 |
| US8039104B2 (en) | 2011-10-18 |
| US20080011419A1 (en) | 2008-01-17 |
| EP2287266A1 (en) | 2011-02-23 |
| KR20070040803A (ko) | 2007-04-17 |
| EP1773961B1 (en) | 2009-11-11 |
| JP2012117071A (ja) | 2012-06-21 |
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