WO2016136533A1 - 重合性化合物及び光学異方体 - Google Patents
重合性化合物及び光学異方体 Download PDFInfo
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- WO2016136533A1 WO2016136533A1 PCT/JP2016/054399 JP2016054399W WO2016136533A1 WO 2016136533 A1 WO2016136533 A1 WO 2016136533A1 JP 2016054399 W JP2016054399 W JP 2016054399W WO 2016136533 A1 WO2016136533 A1 WO 2016136533A1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D277/82—Nitrogen atoms
-
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
- C07C243/10—Hydrazines
- C07C243/20—Hydrazines having nitrogen atoms of hydrazine groups bound to carbon atoms of rings other than six-membered aromatic rings
-
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
- C07C243/10—Hydrazines
- C07C243/22—Hydrazines having nitrogen atoms of hydrazine groups bound to carbon atoms of six-membered aromatic rings
-
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
- C07C251/86—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to carbon atoms of six-membered aromatic rings
-
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
- C07C251/88—Hydrazones having also the other nitrogen atom doubly-bound to a carbon atom, e.g. azines
-
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
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- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/56—Ring systems containing three or more rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
- C07D241/38—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with only hydrogen or carbon atoms directly attached to the ring nitrogen atoms
- C07D241/40—Benzopyrazines
- C07D241/42—Benzopyrazines with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/54—Benzoxazoles; Hydrogenated benzoxazoles
- C07D263/58—Benzoxazoles; Hydrogenated benzoxazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
-
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- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/84—Naphthothiazoles
-
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
- C07D303/27—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds having all hydroxyl radicals etherified with oxirane containing compounds
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
- C07D333/54—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
- C07D333/58—Radicals substituted by nitrogen atoms
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- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
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- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
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Definitions
- the present invention relates to a compound having a polymerizable group, a polymerizable composition containing the compound, a polymerizable liquid crystal composition, and an optical anisotropic body using the polymerizable liquid crystal composition.
- a compound having a polymerizable group is used in various optical materials.
- a polymer having a uniform orientation by aligning a polymerizable composition containing a polymerizable compound in a liquid crystal state and then polymerizing it.
- Such a polymer can be used for polarizing plates, retardation plates and the like necessary for displays.
- two or more types of polymerization are used to satisfy the required optical properties, polymerization rate, solubility, melting point, glass transition temperature, polymer transparency, mechanical strength, surface hardness, heat resistance and light resistance.
- a polymerizable composition containing a functional compound is used. In that case, the polymerizable compound to be used is required to bring good physical properties to the polymerizable composition without adversely affecting other properties.
- the brightness of the screen may be uneven, the color may be unnatural, or the desired optical characteristics may not be obtained.
- the quality of the product is greatly reduced. Therefore, development of a polymerizable liquid crystal compound having reverse wavelength dispersion or low wavelength dispersion capable of solving such a problem has been demanded.
- the problem to be solved by the present invention is to provide a polymerizable compound having a high storage stability without causing precipitation of crystals when added to the polymerizable composition, and a polymerizable compound containing the polymerizable compound
- An object of the present invention is to provide a polymerizable composition in which discoloration or peeling from a substrate does not easily occur when a film-like polymer obtained by polymerizing the composition is irradiated with ultraviolet light. Furthermore, it is providing the polymer obtained by polymerizing the said polymeric composition, and the optical anisotropic body using the said polymer.
- R 1 and R 2 each independently represents a hydrogen atom or a hydrocarbon group having 1 to 80 carbon atoms, the group may have a substituent, and any carbon atom is An atom may be substituted, but at least one of R 1 and R 2 represents a group containing a polymerizable group;
- a 1 , A 2 and A 3 are each independently 1,4-phenylene group, 1,4-cyclohexylene group, pyridine-2,5-diyl group, pyrimidine-2,5-diyl group, naphthalene-2, Represents a 6-diyl group, a naphthalene-1,4-diyl group, a tetrahydronaphthalene-2,6-diyl group, a decahydronaphthalene-2,6-diyl group, or a 1,3-dioxane-2,5-diyl group.
- Z 1 , Z 2 and Z 3 are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—.
- W 1 represents an optionally substituted aromatic group having 1 to 80 carbon atoms and / or a non-aromatic group, and the aromatic group is a hydrocarbon ring or a heterocyclic ring.
- the non-aromatic group may be a hydrocarbon group or a group in which any carbon atom of the hydrocarbon group is substituted with a hetero atom (however, oxygen atoms are not directly bonded to each other).
- the group may be unsubstituted or substituted by one or more substituents L W ;
- W 2 is a hydrogen atom, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO—, — OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—.
- —COO—CH ⁇ CH—, —OCO—CH ⁇ CH—, —CH ⁇ CH—, —CF ⁇ CF— or —C ⁇ C— which may be substituted by a straight chain having 1 to 20 carbon atoms Or a branched alkyl group, wherein any hydrogen atom in the alkyl group may be substituted with a fluorine atom, or W 2 is an optionally substituted aromatic group having 1 to 80 carbon atoms and / Or represents a group containing a non-aromatic group, the aromatic group may be a hydrocarbon ring or a heterocyclic ring, The aromatic group may be a hydrocarbon group or a group in which any carbon atom of the hydrocarbon group is substituted with a hetero atom (however, oxygen atoms are not directly bonded to each other), and the group is unsubstituted.
- W 2 may represent a group represented by P W — (Sp W —X W ) kW —, where P 2 W represents a polymerizable group, and Sp W represents a spacer group or a single bond, but when there are a plurality of Sp W, they may be the same or different, and X W represents —O—, —S—.
- LW is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, cyano group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group , A diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO.
- X LW is —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—.
- kLW represents an integer of 0 to 10
- Y is a hydrogen atom, fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, cyano group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, A diethylamino group, a diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group or one —CH 2
- atom represents a linear or branched alkyl group of 1 to 20, wherein any hydrogen atom in the alkyl group may be substituted with a fluorine atom, or Y is P Y- (S Y -X Y ) kY -Y may represent a group represented by-, P Y represents a polymerizable group, Sp Y represents a spacer group or a single bond, and when a plurality of Sp Y are present, they may be the same or different.
- Represents a group selected from L is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, cyano group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group, A diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, — CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—.
- Number 1 20 represents a linear or branched alkyl group, and any hydrogen atom in the alkyl group may be substituted with a fluorine atom, or L is P L- (Sp L -X L ) kL-. Wherein P L represents a polymerizable group, and Sp L represents a spacer group or a single bond, but when there are a plurality of Sp L, they may be the same or different.
- X L may be —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ C H—, —COO—CH 2 CH 2 —, —OCO—CH 2 CH 2 —, —CH 2 CH 2 —COO—, —CH 2 CH 2 —OCO—, —COO—CH 2 —, —OCO—CH 2 CH 2 —, —CH 2 CH 2 —COO—, —CH
- KL represents an integer of 0 to 10, but when a plurality of L are present in the compound, they may be the same or different, and the group connecting TM is a single bond. Or a double bond.
- the present invention provides a polymerizable liquid crystal composition, a polymer obtained by polymerizing the polymerizable liquid crystal composition, and an optical anisotropic body using the polymer.
- the compound of the present invention has high storage stability when constituting a polymerizable composition, and is useful as a constituent member of the polymerizable composition.
- the optical anisotropic body using the polymerizable liquid crystal composition containing the compound of the present invention is difficult to cause discoloration or peeling from the substrate when irradiated with ultraviolet light. Useful for material applications.
- the present invention provides a reverse dispersible compound represented by the general formula (I), together with a polymerizable composition containing the compound, a resin, a resin additive, an oil, a filter, an adhesive using the compound, Adhesives, oils and fats, inks, pharmaceuticals, cosmetics, detergents, building materials, packaging materials, liquid crystal materials, organic EL materials, organic semiconductor materials, electronic materials, display elements, electronic devices, communication equipment, automobile parts, aircraft parts, mechanical parts
- the present invention provides a pesticide and food, a product using them, a polymerizable liquid crystal composition, a polymer obtained by polymerizing the polymerizable liquid crystal composition, and an optical anisotropic body using the polymer.
- the film indicates “reverse wavelength dispersion.
- "Or” reverse dispersibility is commonly referred to by those skilled in the art.
- a compound constituting a retardation film exhibiting reverse dispersion is called a reverse dispersion compound.
- R 1 and R 2 may each independently have a hydrogen atom or a substituent, and an arbitrary carbon atom may be substituted with a heteroatom having 1 to 80 carbon atoms Although it represents a hydrocarbon group, it is preferable that at least one of R 1 and R 2 represents a group containing a polymerizable group from the viewpoint of mechanical strength when the film is formed. From the viewpoint of mechanical strength and liquid crystallinity.
- the groups represented by R 1 and R 2 are each independently represented by the following general formula (IR)
- P represents a polymerizable group
- Sp represents a spacer group or a single bond, and when a plurality of Sp are present, they may be the same or different
- X represents —O—, —S. —, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—.
- these polymerizable groups are polymerized by radical polymerization, radical addition polymerization, cationic polymerization and anionic polymerization.
- the formula (P-1), formula (P-2), formula (P-3), formula (P-4), formula (P-5), formula (P ⁇ 7), formula (P-11), formula (P-13), formula (P-15) or formula (P-18) are preferred, and formula (P-1), formula (P-2), formula (P-18) P-7), formula (P-11) or formula (P-13) is more preferred, formula (P-1), formula (P-2) or formula (P-3) is more preferred, and formula (P- Particular preference is given to 1) or formula (P-2).
- Sp represents a spacer group or a single bond, and when a plurality of Sp are present, they may be the same or different.
- the spacer group may be unsubstituted or may be substituted with one or more of the following substituents L.
- the spacer group, one -CH 2 - or nonadjacent two or more -CH 2 - are each independently -O -, - COO -, - OCO -, - OCO-O -, - CO It preferably represents an alkylene group having 1 to 20 carbon atoms which may be replaced by —NH—, —NH—CO—, —CH ⁇ CH— or —C ⁇ C—.
- a plurality of Sps are present from the viewpoint of easy availability of raw materials and ease of synthesis, they may be the same or different from each other, and each independently represents one —CH 2 — or not adjacent 2 It is more preferable that two or more —CH 2 — each independently represents an alkylene group having 1 to 10 carbon atoms or a single bond that may be independently replaced by —O—, —COO—, or —OCO—, each independently And more preferably an alkylene group having 1 to 10 carbon atoms or a single bond, and when there are a plurality of alkylene groups, they may be the same or different and each independently an alkylene group having 1 to 8 carbon atoms. Is particularly preferred.
- X represents —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S. —CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S —, —SCF 2 —, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ CH—, —COO—CH 2 CH 2 —, —OCO -CH 2 CH 2 -, - CH 2 CH 2 -COO -, - CH 2 CH 2 -OCO -, - COO-CH 2 -, - OCO-CH 2 -, - CH 2 -COO
- k represents an integer of 0 to 10, preferably represents an integer of 0 to 5, more preferably represents an integer of 0 to 2, and particularly preferably represents 1. preferable.
- R 1 and R 2 may each independently have a hydrogen atom or a substituent, and from 1 carbon atom in which any carbon atom may be substituted with a heteroatom.
- 80 represents a hydrocarbon group, and at least one of R 1 and R 2 represents a group containing a polymerizable group.
- R 1 or R 2 represents a group that does not contain a polymerizable group
- R 1 or R 2 are each independently a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, iodine from the viewpoint of liquid crystallinity and ease of synthesis.
- atom, pentafluorosulfuranyl group, a cyano group, a nitro group, an isocyano group, Chioisoshiano group, or any hydrogen atom in the group may be substituted by a fluorine atom, one -CH 2 - or adjacent
- Two or more —CH 2 — are each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—.
- R 1 and R 2 are each independently a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, or one —CH 2 — or two or more non-adjacent —CH 2 —. And more preferably represents a straight-chain or branched alkyl group having 1 to 12 carbon atoms which may be substituted by —O—, —COO—, —OCO—, —O—CO—O—, a hydrogen atom, fluorine It is more preferable to represent an atom, a chlorine atom, a cyano group, or a linear alkyl group having 1 to 12 carbon atoms or a linear alkoxy group, and a linear alkyl group or linear alkoxy group having 1 to 12 carbon atoms. It is particularly preferred to represent.
- a 1 , A 2 and A 3 are each independently unsubstituted or substituted by one or more of the following substituents L, 1,4-phenylene group, 1,4- Cyclohexylene group, pyridine-2,5-diyl group, pyrimidine-2,5-diyl group, naphthalene-2,6-diyl group, naphthalene-1,4-diyl group, tetrahydronaphthalene-2,6-diyl group, It represents a decahydronaphthalene-2,6-diyl group or a 1,3-dioxane-2,5-diyl group.
- Substituent L is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, cyano group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino Group, diisopropylamino group, trimethylsilyl group, dimethylsilyl group, thioisocyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—.
- Carbon atom Represents a linear or branched alkyl group of 1 to 20, wherein any hydrogen atom in the alkyl group may be substituted with a fluorine atom, or L is P L- (Sp L -X L ).
- kL - may represent a group represented by wherein P L represents a polymerizable group, Sp L each represents a spacer group or a single bond, even they are the same if the Sp L there are multiple X L is —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO.
- L is a fluorine atom, chlorine atom, pentafluorosulfuranyl group, nitro group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino group, or any hydrogen atom May be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — may each independently represent —O—, —S—, —CO—, —COO—.
- a straight chain having 1 to 20 carbon atoms which may be substituted by a group selected from: —OCO—, —O—CO—O—, —CH ⁇ CH—, —CF ⁇ CF— or —C ⁇ C—
- a fluorine atom, a chlorine atom, or an arbitrary hydrogen atom may be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent ones may be substituted.
- -CH 2 - are each independently - More preferably, it represents a linear or branched alkyl group having 1 to 12 carbon atoms which may be substituted with a group selected from-, -COO- or -OCO-, and is a fluorine atom, a chlorine atom, or It is more preferable that an arbitrary hydrogen atom represents a linear or branched alkyl group or alkoxy group having 1 to 12 carbon atoms that may be substituted with a fluorine atom, and includes a fluorine atom, a chlorine atom, or 1 carbon atom. To 8 linear alkyl groups or linear alkoxy groups are particularly preferred.
- a 1 , A 2 and A 3 are each independently unsubstituted or optionally substituted by one or more substituents L It preferably represents a phenylene group, 1,4-cyclohexylene group or naphthalene-2,6-diyl group, and each independently represents the following formulas (A-1) to (A-11):
- each group independently represents a group selected from formula (A-1) to formula (A-8), and each independently represents a group selected from formula (A-1). It is particularly preferable to represent a group selected from the formula (A-4).
- Z 1 , Z 2 and Z 3 are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, — COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —OCO—NH—, —NH—COO—.
- CH 2 -, - COO -, - OCO -, - COO-CH 2 CH 2 -, - OCO-CH 2 CH 2 -, - CH 2 CH 2 -COO -, - CH 2 CH 2 -OCO- or a single bond are more preferable, and it is particularly preferable that each independently represents —COO—, —OCO—, or a single bond.
- Z 2 is —OCH 2 —, —CH 2 O—, —COO—, —OCO— from the viewpoint of difficulty in peeling from the substrate.
- M represents a trivalent aromatic group which may be substituted. From the viewpoint of liquid crystallinity of the compound, availability of raw materials, and ease of synthesis, M represents the following formula (M- 1) or formula (M-2)
- a bond may be present at any position, and any —CH ⁇ may be independently replaced by —N ⁇ .
- a bond may be present at any position.
- L M is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluoro sul Furanyl group, nitro group, cyano group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino group, trimethylsilyl group, dimethylsilyl group, thioisocyano group, or
- One -CH 2 - or nonadjacent two or more -CH 2 - are each independently -O -, - S -, - CO -, - COO -, - OCO -, - CO-S —, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—,
- any hydrogen atom in the alkyl group may be substituted by a fluorine atom, but, L M is those when there are a plurality of preferably a group selected from may be the same or different.).
- Examples of the group represented by the above formula (M-1) include the following formula (M-1-1) or formula (M-1-2)
- M is unsubstituted or one or more of the above-described substituents L M from the viewpoint of difficulty in discoloration and difficulty in peeling from the substrate.
- a group selected from the above formula (M-1-1), formula (M-1-2), formula (M-2-3), and formula (M-2-4), which may be substituted by And M is an unsubstituted group selected from the above formulas (M-1-1), (M-1-2), (M-2-3), and (M-2-4). It is more preferable that M represents a group selected from the above-mentioned formulas (M-1-1) and (M-1-2) which are unsubstituted.
- T is the following formula (T-1) or formula (T-2)
- W 1 represents an optionally substituted aromatic group having 1 to 80 carbon atoms and / or a non-aromatic group, and the aromatic group is a hydrocarbon ring or a heterocyclic ring.
- the non-aromatic group may be a hydrocarbon group or a group in which any carbon atom of the hydrocarbon group is substituted with a hetero atom (however, oxygen atoms are not directly bonded to each other).
- the group may be unsubstituted or substituted by one or more substituents L W , where W 2 is a hydrogen atom, or one —CH 2 — or two or more non-adjacent — CH 2 — is independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO.
- the aromatic group may be a hydrocarbon ring or a heterocyclic ring
- the non-aromatic group may be a hydrocarbon group or a group in which any carbon atom of the hydrocarbon group is substituted with a hetero atom.
- the group may be unsubstituted or substituted by one or more substituents L W , or W 2 may be P W- ( sp W -X W) kW - it may represent a group represented by, this
- P W represents a polymerizable group
- Sp W each represents a spacer group or a single bond, they if Sp W there are a plurality may be different even in the same
- X W is -O -, - S-, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH —, —
- KW represents an integer of 0 to 10, but W 1 and W 2 may be combined to form a ring structure
- LW is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, cyano group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group , A diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH
- X LW is —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—.
- Y is a hydrogen atom, Fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfurani Group, a nitro group, a cyano group, isocyano group, an amino group, a hydroxyl group, a mercapto group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino group, trimethylsilyl group, dimethylsilyl group, Chioisoshiano group or one -CH 2 or
- any hydrogen atom May be substituted by a fluorine atom, or Y is P Y - (Sp Y -X Y ) kY - may represent a group represented by, P Y represents a polymerizable group, Sp Y is a spacer group or When a plurality of Sp Y are present, they may be the same or different, and XY represents —O—, —S—, —OCH 2 —, —CH 2 O—, —CO -, -COO-, -OCO-, -CO-S-, -S-CO-, -O-CO-O-, -CO-NH-, -NH-CO-, -SCH 2- , -CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, — O
- Y is a hydrogen atom, a fluorine atom, a chlorine atom, a nitro group, a cyano group, or any hydrogen in the group from the viewpoint of liquid crystallinity and ease of synthesis.
- the atom may be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — may each independently represent —O—, —S—, —CO—, —COO.
- Y may be any hydrogen atoms in the hydrogen atom or a group substituted by fluorine atoms, one -CH 2 - or nonadjacent two or more -CH 2 - are each independently - More preferably, it represents a linear or branched alkyl group having 1 to 12 carbon atoms which may be substituted by O—, —COO— or —OCO—, and Y represents a hydrogen atom or any hydrogen atom in the group Is more preferably a linear or branched alkyl group having 1 to 12 carbon atoms which may be substituted with a fluorine atom, and Y represents a hydrogen atom or a linear alkyl group having 1 to 12 carbon atoms. More preferably, Y particularly preferably represents a hydrogen atom.
- W 1 represents an optionally substituted aromatic group having 1 to 80 carbon atoms and / or a non-aromatic group, and the aromatic group may be a hydrocarbon ring or a heterocyclic ring,
- the non-aromatic group may be a hydrocarbon group or a group in which any carbon atom of the hydrocarbon group is substituted with a hetero atom (however, oxygen atoms are not directly bonded to each other). it may be substituted by unsubstituted or substituted with one or more substituents L W.
- the aromatic group contained in W 1 is unsubstituted or substituted by one or more of the above-described substituents L W from the viewpoint of availability of raw materials and ease of synthesis. -1) to formula (W-20)
- the ring structure may have a bond at an arbitrary position, and may form a group in which two or more aromatic groups selected from these groups are linked by a single bond.
- CH ⁇ may each independently be replaced by —N ⁇
- —CH 2 — each independently represents —O—, —S—, —NR T — (wherein R T represents a hydrogen atom or a carbon atom) Represents an alkyl group of the number 1 to 20, and may be replaced by —CS— or —CO—, but does not contain an —O—O— bond, and these groups are unsubstituted or include one or more the substituents L W may be substituted.
- the group represented by the above formula (W-1) is a group represented by the following formula (W-1-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-1-7)
- the group represented by the above formula (W-2) is a group represented by the following formula (W-2-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-2-8)
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by the above formula (W-3) is unsubstituted. Or may be substituted by one or more of the above-described substituents L W (Formula (W-3-1) to Formula (W-3-6))
- the group represented by the above formula (W-4) is a group represented by the following formula (W-4-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-4-9)
- the group represented by the above formula (W-5) is a group represented by the following formula (W-5-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-5-13)
- these groups may have a bond at an arbitrary position, and RT represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- RT represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- Examples of the group represented by the above formula (W-6) include those represented by the following formula (W-6-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-6-12)
- the group represented by the above formula (W-7) is a group represented by the following formula (W-7-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-7-8)
- these groups may have a bond at an arbitrary position, and RT represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- RT represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- Examples of the group represented by the above formula (W-8) include those represented by the following formula (W-8-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-8-19)
- the group represented by the above formula (W-9) is a group represented by the following formula (W-9-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-9-7)
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by the above formula (W-10) is unsubstituted. Or may be substituted by one or more of the above-described substituents L W below (W-10-1) to (W-10-16)
- the group represented by the above formula (W-11) is a group represented by the following formula (W-11-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-11-10)
- the group represented by the above formula (W-12) is a group represented by the following formula (W-12-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-12-4)
- the group represented by the above formula (W-13) is a group represented by the following formula (W-13-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-13-8)
- the group represented by the above formula (W-14) is a group represented by the following formula (W-14-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-14-8)
- the group represented by the above formula (W-15) is a group represented by the following formula (W-15-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-15-10)
- the group represented by the above formula (W-16) is a group represented by the following formula (W-16-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-16-8)
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by the above formula (W-17) is unsubstituted. Or may be substituted by one or more of the above-described substituents L W below (W-17-1) to (W-17-4)
- the group represented by the above formula (W-18) is a group represented by the following formula (W-18-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-18-4)
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by the above formula (W-19) is unsubstituted. Or may be substituted by one or more of the above-described substituents L W below (W-19-1) to (W-19-16)
- the group represented by the above formula (W-20) is a group represented by the following formula (W-20-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-20-4)
- W 1 is represented by the following formulas (W-7-7-1) to (W-14-7-1):
- L W1 is a fluorine atom, a chlorine atom, a nitro group, a cyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—
- s represents an integer of 0 to 4
- t represents an integer of 0 to 3. It is more preferable that u represents a group selected from 0 to 2, and W 1 represents the following formula (W-7-7-1) to formula (W-14-7- 1-1)
- W 1 represents a group selected from the above formula (W-7-7-1-1).
- W 2 may be a hydrogen atom, or any hydrogen atom in the group may be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — may each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO —, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ CH—, —CH ⁇ CH—, —CF ⁇ CF— or —C ⁇ C Represents a linear or branched alkyl group having 1 to 20 carbon atoms which may be substituted by-, or W 2 is an aromatic group having 1 to 80 carbon atoms which may be substituted and / or non-substituted Represents a group containing an aromatic group
- W 2 is preferably a hydrogen atom.
- W 2 may be any hydrogen atom in the group substituted by a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—,
- a linear or branched alkyl group having 1 to 20 carbon atoms which may be substituted by —CO—, —COO— or —OCO—, or represented by P W — (Sp W —X W ) kW — Preferably represents a group.
- W 2 has 1 to 12 carbon atoms in which one —CH 2 — or two or more non-adjacent —CH 2 — may be each independently substituted by —O—. It is even more preferable to represent a linear alkyl group or a group represented by P W — (Sp W —X W ) kW —.
- P W (Sp W —X W ) kW —.
- a preferable structure of P W is the same as that described for P.
- Sp W preferably represents a spacer group, and from the viewpoint of liquid crystallinity, availability of raw materials, and ease of synthesis, when there are a plurality of them, they may be the same or different, and each independently One —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO.
- Each may independently represent one —CH 2 — or two or more non-adjacent —CH 2 — each independently —O—, —COO—, —OCO—, — More preferably, it represents a linear alkylene group having 1 to 20 carbon atoms which may be replaced by OCO-O-, and when there are a plurality of them, they may be the same or different, and each independently Te one -CH 2 - or two or more -C nonadjacent 2 - It is further preferred that represent are each independently -O- from good 1 -C be replaced in 12 linear alkylene group.
- Sp W is a carbon in which one —CH 2 — or two or more non-adjacent —CH 2 — may be independently replaced with —O—. It is particularly preferable to represent a linear alkylene group having 1 to 12 atoms.
- kw preferably represents an integer of 1 to 3 from the viewpoints of liquid crystallinity and availability of raw materials, and particularly preferably 1 from the viewpoint of curing shrinkage when formed into a film.
- the group directly bonded to the N atom in the group represented by P W — (Sp W —X W ) kW — is preferably —CH 2 — from the viewpoint of ease of synthesis.
- the group represented by P W- (Sp W -X W ) kW- is from the viewpoint of the stability over time of phase difference and reverse wavelength dispersion and peeling from the substrate when irradiated with ultraviolet light for a long time.
- kwa represents an integer of 0 to 20 and kwb represents an integer of 1 to 10
- kwa is more preferably an integer of 2 to 12 and particularly preferably an integer of 2 to 8 from the viewpoint of liquid crystallinity.
- kwb is more preferably an integer of 1 to 3, and particularly preferably 1 or 2, from the viewpoint of liquid crystallinity.
- W 2 represents an optionally substituted aromatic group having 1 to 80 carbon atoms and / or a non-aromatic group
- the preferred structure of W 2 is the same as described for W 1 .
- W 1 and W 2 may be combined to form a ring structure, in which case the cyclic group represented by —NW 1 W 2 is unsubstituted or substituted with one or more of the above-described substituents.
- any —CH ⁇ may be independently replaced by —N ⁇ , and —CH 2 — may be independently —O—, —S—, —NR T — (where R T represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms.), May be replaced by —CS— or —CO—, but does not contain an —O—O— bond, and these groups are may be substituted by unsubstituted or one or more of the aforementioned substituents L W.) preferably represents a group selected from.
- the group represented by the above formula (W-21) is a group represented by the following formula (W-21-1), which may be unsubstituted or substituted by one or more of the above-described substituents L W (W-21-3)
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-23 represents a group represented by the above formula (W-23).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a group represented by the above formula (W-24).
- W-24-1 to (W-24-4) which may be substituted or substituted by one or more of the above-described substituents L W
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-27 preferably represents a group represented by the above formula (W-27).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-28 represents a group represented by the above formula (W-28).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-29 preferably represents a group represented by the above formula (W-29).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a group represented by the above formula (W-30).
- W-30 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-30-6 which are substituted or optionally substituted by one or more of the above-mentioned substituents L W
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-31 represents a group represented by the above formula (W-31).
- the group represented by the above formula (W-32) is preferably unsubstituted or substituted with one or more of the above-described substituents L W as described below. From formula (W-32-1) to formula (W-32-3)
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-34 represents a group represented by the above formula (W-34).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-35 represents a group represented by the above formula (W-35).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-37 represents a group represented by the above formula (W-37).
- W-37-1 which may be substituted or substituted by one or more of the above-described substituents L W
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a group represented by the above formula (W-39).
- W-39-1) to (W-39-3) which may be substituted or optionally substituted by one or more of the above-described substituents L W
- the group represented by the above formula (W-40) is unsubstituted or substituted by one or more of the above-described substituents L W as described below.
- Formula (W-40-1) to Formula (W-40-4) is unsubstituted or substituted by one or more of the above-described substituents L W as described below.
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-41 represents a group represented by the above formula (W-41).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-42-1 represents a group represented by the above formula (W-42).
- W-42-1 which may be substituted or substituted by one or more of the above-mentioned substituents L W
- the cyclic group represented by —NW 1 W 2 may be unsubstituted or substituted with one or more of the above-described substituents L W ( W-21-1), Formula (W-23-2), Formula (W-23-3), Formula (W-23-4), Formula (W-25-2), Formula (W-25-3) ), Formula (W-27-1), Formula (W-27-2), Formula (W-27-3), Formula (W-32-2), Formula (W-32-3), Formula (W -37-1), a formula (W-38-2), a formula (W-38-3), a formula (W-38-4), and a group selected from formula (W-42-1) preferable.
- W 1 and W 2 may be combined to form a ring structure, in which case the cyclic group represented by ⁇ CW 1 W 2 is unsubstituted or contains one or more of the above-mentioned substituents
- any —CH ⁇ may be independently replaced by —N ⁇ , and —CH 2 — may be independently —O—, —S—, —NR T — (where R T represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms.), May be replaced by —CS— or —CO—, but does not contain an —O—O— bond, and these groups are may be substituted by unsubstituted or one or more of the aforementioned substituents L W.) preferably represents a group selected from.
- the group represented by the above formula (W-43) is a group represented by the following formula (W-43-1) which may be unsubstituted or substituted by one or more of the above-described substituents L W. (W-43-3)
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-45 represents a group represented by the above formula (W-45).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-46 represents a group represented by the above formula (W-46).
- the group represented by the above formula (W-47) is unsubstituted or substituted by one or more of the above-described substituents L W as described below.
- Formula (W-47-1) to Formula (W-47-4) is unsubstituted or substituted by one or more of the above-described substituents L W as described below.
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-48 represents a group represented by the above formula (W-48).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-49 represents a group represented by the above formula (W-49).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a group represented by the above formula (W-50).
- W-50-7 which are substituted or optionally substituted by one or more of the above-mentioned substituents L W
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-51 represents a group represented by the above formula (W-51).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-52 represents a group represented by the above formula (W-52).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-53 represents a group represented by the above formula (W-53).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-56 represents a group represented by the above formula (W-56).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a group represented by the above formula (W-57).
- W-57 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-57-3 which are substituted or optionally substituted by one or more of the above-mentioned substituents L W
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-59 represents a group represented by the above formula (W-59).
- W-59-1 which may be substituted or substituted by one or more of the above-mentioned substituents L W
- the group represented by the above formula (W-60) is preferably a group represented by the following formula (W—) which may be unsubstituted or substituted by one or more of the above-described substituents L W. 60-1) to formula (W-60-6)
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-61 represents a group represented by the above formula (W-61).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-63 represents a group represented by the above formula (W-63).
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R T represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- W-64 represents a group represented by the above formula (W-64).
- W-64-1 which may be substituted or substituted by one or more of the above-mentioned substituents L W
- LW is a fluorine atom, a chlorine atom, a nitro group, a cyano group, a methylamino group, a dimethylamino group, a diethylamino group, a diisopropylamino group, or a group from the viewpoint of ease of synthesis, availability of raw materials, and liquid crystallinity.
- Any hydrogen atom therein may be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, 1 to 20 carbon atoms which may be substituted by —CO—, —COO—, —OCO—, —O—CO—O—, —CH ⁇ CH—, —CF ⁇ CF— or —C ⁇ C—.
- It preferably represents a linear or branched alkyl group, and a fluorine atom, a chlorine atom, a nitro group, a cyano group, a methylamino group, a dimethylamino group, or any hydrogen atom in the group is substituted with a fluorine atom.
- One -CH 2 -Or two or more non-adjacent —CH 2 — may be each independently substituted by —O—, —S— or —CO—, linear or branched alkyl having 1 to 20 carbon atoms
- —CH 2 — or two or more non-adjacent —CH 2 — each independently represents a linear alkyl group having 1 to 10 carbon atoms which may be substituted by —O—, Fluorine atom, chlorine atom, nitro group, cyano group, dimethylamino group, or any hydrogen atom in the group may be substituted with fluorine atom, one —CH 2 — or two not adjacent
- —CH 2 — or two or more non-adjacent —CH 2 — each independently represents a linear alkyl group having 1 to 10 carbon atoms which may be substituted by —O—, Fluorine atom, chlorine atom, nitro group, cyano group, dimethylamino group, or any hydrogen atom in the group may be substituted with fluorine atom, one —CH 2 — or two not adjacent
- Each of the above -CH 2 - is independent Even more preferably, it represents a linear alkyl group having 1 or 2 carbon atoms which may
- the total number of ⁇ electrons contained in W 1 and W 2 is preferably 4 to 24 from the viewpoints of wavelength dispersion characteristics, storage stability, liquid crystallinity, and ease of synthesis.
- R 11 and R 21 are each independently A hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, or a straight-chain alkyl group or straight-chain alkoxy group having 1 to 12 carbon atoms).
- the compound represented by the general formula (IA) or (IB) is preferable, and the orientation is further improved.
- a compound represented by the general formula (IA) is preferable, and when importance is placed on reverse wavelength dispersion, a compound represented by the general formula (IB) is preferable.
- the compound represented by the general formula (IC) is preferable.
- a 12 represents a group selected from the above formula (A-1), formula (A-3) or formula (A-4), and A 22 and A 32 represent Represents a group represented by the formula (A-2), Z 12 represents —OCH 2 —, —CH 2 O—, —COO— or —OCO—, and R 22 represents a hydrogen atom, a fluorine atom, or a carbon atom.
- a compound represented by a straight-chain alkyl group or straight-chain alkoxy group having 1 to 12 atoms is more preferred.
- a 13 and A 23 represent a group represented by the above formula (A-2), and A 33 represents the above formula (A-1) or (A-3). Or a group selected from formula (A-4), Z 23 and Z 33 each represent —OCH 2 —, —CH 2 O—, —COO— or —OCO—, and R 13 represents a hydrogen atom, a fluorine atom, Or a straight-chain alkyl group having 1 to 12 carbon atoms or a straight-chain alkoxy group).
- a 14 and A 34 represent groups selected from the above formula (A-1), formula (A-3) or formula (A-4), and A 24 represents the above-mentioned groups.
- a group selected from formulas (A-1) to (A-4), and Z 14 and Z 34 represent —OCH 2 —, —CH 2 O—, —COO—, or —OCO—. More preferred is a compound.
- the compound of this invention can be manufactured with the following manufacturing methods.
- (Production method 1) Production of a compound represented by the following formula (S-14)
- P, Sp, X, L, W 1 and W 2 each independently represent the same as defined in the general formula (I) and the general formula (IR); Independently represents an integer of 0 to 4, t represents an integer of 0 to 3, PG represents a protecting group, and halogen represents a halogen atom or a halogen equivalent.
- the hydroxyl group of the compound represented by the formula (S-1) is protected by a protecting group (PG).
- the protecting group (PG) is not particularly limited as long as it can be stably protected until the deprotection step.
- Specific examples of the protecting group include a tetrahydropyranyl group.
- a compound represented by the formula (S-4) can be obtained by reacting a compound represented by the formula (S-2) with a compound represented by the formula (S-3).
- Examples of the reaction include a method of cross-coupling in the presence of a metal catalyst and a base.
- the metal catalyst include [1,1′-bis (diphenylphosphino) ferrocene] palladium (II) dichloride, palladium (II) acetate, and tetrakis (triphenylphosphine) palladium (0).
- the base include triethylamine.
- Reaction conditions include, for example, Metal-Catalyzed Cross-Coupling Reactions (Co-authored by Armin de Meijere, Francois Diedrich, Wiley-VCH), Palladium Reagents and Catalysts: New Persent: 21 Cross-Coupling Reactions: A Practical Guide (Topics in Current Chemistry) (SL Buchwald, K. Fugami, T. Hiyama, M. Kosumi, M. Miura, M. Miura. R.Muci, M.Nomura, E.Shirakawa, K.Tamao al, include the methods described in literature Springer) and the like.
- the compound represented by the formula (S-6) can be obtained by reacting the compound represented by the formula (S-4) with the compound represented by the formula (S-5).
- the reaction conditions for example, a method using a condensing agent or a compound represented by the formula (S-5) is converted to an acid chloride, mixed acid anhydride or carboxylic acid anhydride and then represented by the general formula (S-4). The method of making it react with a compound in base presence is mentioned.
- examples of the condensing agent include N, N′-dicyclohexylcarbodiimide, N, N′-diisopropylcarbodiimide, and 1-ethyl-3- (3-dimethylaminopropyl) carbodiimide hydrochloride.
- examples of the base include triethylamine and diisopropylethylamine.
- the compound represented by the formula (S-9) can be obtained by reacting the compound represented by the formula (S-7) with the compound represented by the formula (S-8).
- Examples of the reaction conditions include the above-mentioned conditions.
- the compound represented by the formula (S-11) can be obtained by reacting the compound represented by the formula (S-10) with, for example, hydrazine monohydrate.
- the compound represented by the formula (S-13) can be obtained by reacting the compound represented by the formula (S-11) with a compound represented by the formula (S-12) in the presence of a base.
- a base include potassium carbonate and cesium carbonate.
- the compound represented by the formula (S-14) can be obtained by reacting the compound represented by the formula (S-13) with a compound represented by the formula (S-9) in the presence of an acid catalyst.
- the acid include p-toluenesulfonic acid, pyridinium p-toluenesulfonate, 10-camphorsulfonic acid and the like.
- P, Sp, X, L, W 1 and W 2 each independently represent the same as defined in the general formula (I) and the general formula (IR); Independently represents an integer of 0 to 4, t represents an integer of 0 to 3, and PG represents a protecting group.
- the hydroxyl group of the compound represented by the formula (S-15) is protected with a protecting group (PG).
- the protecting group (PG) is not particularly limited as long as it can be stably protected until the deprotection step.
- GREEN'S PROTECTIVE GROUPS IN ORGANIC SYNTHESIS (Fourth Edition), PETER GM.
- Protecting groups (PG) mentioned in WUTS, THEODORA W. GREENE, John Wiley & Sons, Inc., Publication) and the like are preferred.
- Specific examples of the protecting group include a tetrahydropyranyl group.
- the compound represented by the formula (S-17) can be obtained by formylating the compound represented by the formula (S-16).
- Examples of the reaction conditions include a method of reacting with magnesium chloride and paraformaldehyde in the presence of a base.
- An example of the base is triethylamine.
- the compound represented by the formula (S-19) can be obtained by reacting the compound represented by the formula (S-17) with the compound represented by the formula (S-18).
- Examples of the reaction conditions include the conditions described in Production Method 1.
- a compound represented by the formula (S-22) can be obtained by reacting a compound represented by the formula (S-20) with a compound represented by the formula (S-21).
- Examples of the reaction conditions include the conditions described in Production Method 1.
- the compound represented by the formula (S-25) can be obtained by reacting the compound represented by the formula (S-23) with the compound represented by the formula (S-24).
- Examples of the reaction conditions include the conditions described in Production Method 1.
- the compound represented by the formula (S-27) can be obtained by reacting the compound represented by the formula (S-26) with, for example, hydrazine monohydrate.
- the compound represented by the formula (S-28) can be obtained by reacting the compound represented by the formula (S-27) with the compound represented by the formula (S-25).
- Examples of the reaction conditions include the conditions described in Production Method 1.
- Reaction conditions other than those described in each step of production method 1 and production method 2 include, for example, an experimental chemistry course (edited by the Chemical Society of Japan, published by Maruzen Co., Ltd.), Organic Synthesis (John Wiley & Sons, Inc., Publication), and Bielstein Handbook of. Organic Chemistry (Beilstein-Institut futer Literatur der Organischen Chemie, & J Wr.Berlin and Heidelberg GmbH & Co.K), Springer-Verlag Berlin and Heidelberg GmbH & Cos. Or SciFinder (Chemical Abstracts Service, American Chemical Society) or Reaxys conditions provided from the online search services (Elsevier Ltd.) and the like.
- a reaction solvent can be appropriately used in each step.
- the solvent is not particularly limited as long as it gives the target compound.
- phase transfer catalyst When the reaction is carried out in an organic solvent and water two-phase system, a phase transfer catalyst can be added.
- the phase transfer catalyst include benzyltrimethylammonium chloride, polyoxyethylene (20) sorbitan monolaurate [Tween 20], sorbitan monooleate [Span 80], and the like.
- purification can be performed as necessary in each step.
- the purification method include chromatography, recrystallization, distillation, sublimation, reprecipitation, adsorption, and liquid separation treatment.
- a purification agent silica gel, alumina, activated carbon, activated clay, celite, zeolite, mesoporous silica, carbon nanotube, carbon nanohorn, Bincho charcoal, charcoal, graphene, ion exchange resin, acid clay, silicon dioxide, diatomaceous earth, Examples include perlite, cellulose, organic polymer, and porous gel.
- the compound of the present invention is preferably used in a nematic liquid crystal composition, a smectic liquid crystal composition, a chiral smectic liquid crystal composition, and a cholesteric liquid crystal composition.
- a compound other than the present invention may be added.
- polymerizable compounds used by mixing with the polymerizable compound of the present invention include those represented by the general formula (X-11)
- P 11 , P 12 and P 13 each independently represent a polymerizable group
- Sp 11 , Sp 12 and Sp 13 each independently represent a single bond or an alkylene group having 1 to 20 carbon atoms.
- X 11, X 12 and X 13 are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO.
- W 11 and W 12 each independently represent a hydrogen atom or a methyl group
- Sp 14 and Sp 15 each independently represent an alkylene group having 2 to 18 carbon atoms
- X 14 and X 15 each independently -O-, -COO-, -OCO- or a single bond
- Z 13 and Z 14 each independently represent -COO- or -OCO-
- a 15 , A 16 and A 17 each independently And may be unsubstituted or substituted by a fluorine atom, a chlorine atom, a linear or branched alkyl group having 1 to 4 carbon atoms, or a linear or branched alkoxy group having 1 to 4 carbon atoms.
- 4-phenylene group is preferred, and the following formulas (X-11a-1) to (X-11a-4)
- W 13 and W 14 each independently represent a hydrogen atom or a methyl group
- Sp 16 and Sp 17 each independently represent an alkylene group having 2 to 18 carbon atoms. Is mentioned.
- compounds in which Sp 16 and Sp 17 are each independently an alkylene group having 2 to 8 carbon atoms are particularly preferred.
- P 14 represents a polymerizable group
- Sp 18 represents a single bond or an alkylene group having 1 to 20 carbon atoms, but one —CH 2 — or two or more non-adjacent — CH 2 — may be replaced by —O—, —COO—, —OCO—, —O—CO—O—
- X 16 represents a single bond, —O—, —COO—, or —OCO—.
- Z 15 represents a single bond, —COO— or —OCO—
- L 11 is independently a fluorine atom, a chlorine atom, one —CH 2 — or two or more non-adjacent —CH 2 —.
- —O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ CH—, —CH ⁇ CH—, —CF ⁇ CF— or —C ⁇ C— represents a linear or branched alkyl group having 1 to 20 carbon atoms which may be substituted.
- a polymerizable compound that does not exhibit liquid crystallinity can be added to the extent that the liquid crystallinity of the composition is not significantly impaired.
- any compound that is recognized as a polymer-forming monomer or polymer-forming oligomer in this technical field can be used without particular limitation. Specific examples include those described in “Photocuring Technology Data Book, Materials (Monomer, Oligomer, Photopolymerization Initiator)” (supervised by Kunihiro Ichimura, Kiyosuke Kato, Technonet).
- the compound of the present invention can be polymerized without using a photopolymerization initiator, but a photopolymerization initiator may be added depending on the purpose.
- concentration of the photopolymerization initiator is preferably 0.1% by mass to 15% by mass, more preferably 0.2% by mass to 10% by mass, and 0.4% by mass to 8% by mass with respect to the compound of the present invention. % Is more preferable.
- the photopolymerization initiator include benzoin ethers, benzophenones, acetophenones, benzyl ketals, and acylphosphine oxides.
- the photopolymerization initiator examples include 2-methyl-1- (4-methylthiophenyl) -2-morpholinopropan-1-one (IRGACURE 907), benzoic acid [1- [4- (phenylthio) benzoyl] heptylidene] Amino (IRGACURE OXE 01) etc. are mentioned.
- the thermal polymerization initiator examples include azo compounds and peroxides.
- Specific examples of the thermal polymerization initiator include 2,2'-azobis (4-methoxy-2,4-dimethylvaleronitrile), 2,2'-azobis (isobutyronitrile) and the like.
- One type of polymerization initiator may be used, or two or more types of polymerization initiators may be used in combination.
- a stabilizer can be added to the liquid crystal composition of the present invention in order to improve its storage stability.
- the stabilizer examples include hydroquinones, hydroquinone monoalkyl ethers, tert-butylcatechols, pyrogallols, thiophenols, nitro compounds, ⁇ -naphthylamines, ⁇ -naphthols, nitroso compounds, and the like. It is done.
- the addition amount is preferably in the range of 0.005% by mass to 1% by mass, more preferably 0.02% by mass to 0.8% by mass, and 0.03% by mass with respect to the composition. To 0.5% by mass is more preferable.
- One kind of stabilizer may be used, or two or more kinds of stabilizers may be used in combination. Specific examples of the stabilizer include those represented by formulas (X-13-1) to (X-13-35).
- n represents an integer of 0 to 20
- the polymerizable liquid crystal composition containing the compound of the present invention is used for applications such as films, optical elements, functional pigments, pharmaceuticals, cosmetics, coating agents, synthetic resins, Depending on the purpose, metals, metal complexes, dyes, pigments, dyes, fluorescent materials, phosphorescent materials, surfactants, leveling agents, thixotropic agents, gelling agents, polysaccharides, ultraviolet absorbers, infrared absorbers, antioxidants Further, metal oxides such as ion exchange resin and titanium oxide can be added.
- the polymer obtained by polymerizing the polymerizable liquid crystal composition containing the compound of the present invention can be used for various applications.
- a polymer obtained by polymerizing a polymerizable liquid crystal composition containing the compound of the present invention without orientation can be used as a light scattering plate, a depolarizing plate, and a moire fringe prevention plate.
- polymerizing after orientating has optical anisotropy, and is useful.
- Such an optical anisotropic body includes, for example, a substrate obtained by rubbing a polymerizable liquid crystal composition containing the compound of the present invention with a cloth, a substrate on which an organic thin film is formed, or an alignment film on which SiO 2 is obliquely deposited. It can be produced by polymerizing the polymerizable liquid crystal composition after it is supported on a substrate having it or sandwiched between substrates.
- Examples of the method for supporting the polymerizable liquid crystal composition on the substrate include spin coating, die coating, extrusion coating, roll coating, wire bar coating, gravure coating, spray coating, dipping, and printing.
- an organic solvent may be added to the polymerizable liquid crystal composition during coating.
- the organic solvent hydrocarbon solvents, halogenated hydrocarbon solvents, ether solvents, alcohol solvents, ketone solvents, ester solvents, aprotic solvents and the like can be used.
- Toluene or hexane as the solvent methylene chloride as the halogenated hydrocarbon solvent, tetrahydrofuran, acetoxy-2-ethoxyethane or propylene glycol monomethyl ether acetate as the ether solvent, methanol, ethanol or alcohol as the alcohol solvent Isopropanol, acetone, methyl ethyl ketone, cyclohexanone, ⁇ -butyl lactone or N-methyl pyrrolidinone as the ketone solvent, ethyl acetate or cellosolve as the ester solvent, and dimethyl as the aprotic solvent It can be mentioned formamide or acetonitrile.
- the polymerizable liquid crystal composition may be used alone or in combination, and may be appropriately selected in consideration of the vapor pressure and the solubility of the polymerizable liquid crystal composition.
- a method for volatilizing the added organic solvent natural drying, heat drying, reduced pressure drying, or reduced pressure heat drying can be used.
- it is also effective to provide an intermediate layer such as a polyimide thin film on the substrate or to add a leveling agent to the polymerizable liquid crystal material.
- the method of providing an intermediate layer such as a polyimide thin film on a substrate is effective for improving the adhesion between a polymer obtained by polymerizing a polymerizable liquid crystal material and the substrate.
- Examples of the alignment treatment other than the above include use of flow alignment of liquid crystal material, use of electric field or magnetic field. These orientation means may be used alone or in combination. Furthermore, a photo-alignment method can be used as an alignment treatment method instead of rubbing. As a shape of the substrate, in addition to a flat plate, a curved surface may be included as a constituent part.
- substrate can be used regardless of an organic material and an inorganic material.
- organic material used as the substrate material examples include polyethylene terephthalate, polycarbonate, polyimide, polyamide, polymethyl methacrylate, polystyrene, polyvinyl chloride, polytetrafluoroethylene, polychlorotrifluoroethylene, polyarylate, polysulfone, and triacetyl.
- Cellulose, cellulose, polyetheretherketone and the like can be mentioned, and examples of the inorganic material include silicon, glass and calcite.
- the polymerizable liquid crystal composition containing the compound of the present invention When the polymerizable liquid crystal composition containing the compound of the present invention is polymerized, it is desirable that the polymerization proceeds rapidly. Therefore, a method of polymerizing by irradiating active energy rays such as ultraviolet rays or electron beams is preferable. When ultraviolet rays are used, a polarized light source or a non-polarized light source may be used. Further, when the polymerization is carried out with the liquid crystal composition sandwiched between two substrates, at least the substrate on the irradiation surface side must have appropriate transparency to the active energy rays.
- the orientation state of the unpolymerized part is changed by changing conditions such as an electric field, a magnetic field, or temperature, and further irradiation with active energy rays is performed. Then, it is possible to use a means for polymerization. Moreover, it is preferable that the temperature at the time of irradiation exists in the temperature range by which the liquid crystal state of the polymeric liquid crystal composition of this invention is hold
- the polymerization is carried out at a temperature as close to room temperature as possible from the viewpoint of avoiding unintentional induction of thermal polymerization, that is, typically at a temperature of 25 ° C. It is preferable to make it.
- the intensity of the active energy ray is preferably 0.1 mW / cm 2 to 2 W / cm 2 . When the intensity is 0.1 mW / cm 2 or less, a great amount of time is required to complete the photopolymerization and the productivity is deteriorated. When the intensity is 2 W / cm 2 or more, the polymerizable liquid crystal compound or the polymerizable liquid crystal is used. There is a risk that the composition will deteriorate.
- the optical anisotropic body obtained by polymerization can be subjected to heat treatment for the purpose of reducing initial characteristic changes and achieving stable characteristic expression.
- the heat treatment temperature is preferably in the range of 50 to 250 ° C.
- the heat treatment time is preferably in the range of 30 seconds to 12 hours.
- optical anisotropic body manufactured by such a method may be peeled off from the substrate and used alone or without peeling. Further, the obtained optical anisotropic bodies may be laminated or bonded to another substrate for use.
- a compound represented by the formula (I-5-1) was obtained by the method described in Bioorganic & Medicinal Chemistry Letters, 2005, Vol. 15, No. 6, pp. 1675-1681.
- To the reaction vessel 2.0 g of the compound represented by the formula (I-5-1) and 20 mL of dichloromethane were added.
- the reaction vessel was cooled to ⁇ 78 ° C., and 8.2 g of boron tribromide was added dropwise and stirred. After pouring into water, it was diluted with ethyl acetate and washed with brine. Purification was performed by column chromatography (dichloromethane / methanol) to obtain 1.6 g of a compound represented by the formula (I-5-2).
- a compound represented by the formula (I-6-9) was obtained by the method described in JP2011-207765A. To the reaction vessel, 2.0 g of the compound represented by the formula (I-6-9) and 30 mL of dichloromethane were added. While cooling with ice, 2.1 g of bromine was added and stirred. After usual post-treatment, purification was performed by column chromatography to obtain 2.4 g of a compound represented by the formula (I-6-10).
- a compound represented by the formula (I-7-2) was obtained by the method described in Macromolecular Chemistry and Physics, 2009, Vol. 210, No. 7, pages 531-541. Under a nitrogen atmosphere, 5.0 g of the compound represented by the formula (I-7-1), 7.1 g of the compound represented by the formula (I-7-2), 9.5 g of triphenylphosphine, and 60 mL of tetrahydrofuran were added. . While cooling with ice, 7.3 g of diisopropyl azodicarboxylate was added and stirred. After usual post-treatment, purification was performed by column chromatography to obtain 8.1 g of a compound represented by the formula (I-7-3).
- a compound represented by the formula (I-7-16) was obtained by the method described in Synthetic Communications, 2011, Vol. 41, No. 9, pp. 1381-1393. Under a nitrogen atmosphere, 2.0 g of the compound represented by the formula (I-7-16), 2.5 g of the compound represented by the formula (I-7-15), 0.03 g of copper (I) iodide in a reaction vessel. , 30 mL of triethylamine, 90 mL of N, N-dimethylformamide, and 0.1 g of tetrakis (triphenylphosphine) palladium (0) were added and stirred. After usual post-treatment, purification was performed by column chromatography to obtain 2.7 g of a compound represented by the formula (I-7-17).
- a compound represented by the formula (I-7-21) was obtained by the method described in WO2012-141245A1.
- a reaction vessel 2.7 g of a compound represented by the formula (I-7-20), 0.5 g of a compound represented by the formula (I-7-21), 0.3 g of ( ⁇ ) -10-camphorsulfonic acid, Tetrahydrofuran 30mL and ethanol 20mL were added and stirred.
- purification was performed by column chromatography and recrystallization to obtain 2.2 g of a compound represented by the formula (I-7).
- reaction solution 5.0 g of methyl 6-hydroxy-2-naphthalenecarboxylate, 3.0 g of paraformaldehyde, 20 mL of triethylamine, 3.5 g of magnesium chloride, and 30 mL of acetonitrile were added and stirred.
- the reaction solution was poured into hydrochloric acid and subjected to usual post-treatment, followed by purification by column chromatography to obtain 4.5 g of a compound represented by the formula (I-8-10).
- a compound represented by the formula (I-8-17) was obtained by the method described in WO2012-141245A1.
- a reaction vessel 2.8 g of a compound represented by the formula (I-8-16), 0.7 g of a compound represented by the formula (I-8-17), 0.3 g of ( ⁇ ) -10-camphorsulfonic acid, Tetrahydrofuran 30mL and ethanol 20mL were added and stirred.
- purification was performed by column chromatography and recrystallization to obtain 2.4 g of a compound represented by the formula (I-8).
- a compound represented by the formula (I-9-3) was obtained by the method described in European Journal of Organic Chemistry, 2008, No. 10, pages 1797-1801. Under a nitrogen atmosphere, 2.0 g of the compound represented by the formula (I-9-2), 3.0 g of the compound represented by the formula (I-9-3), 2.0 g of potassium carbonate, 20 mL of tetrahydrofuran, Water (20 mL) and tetrakis (triphenylphosphine) palladium (0) (0.1 g) were added and the mixture was heated and stirred. After usual post-treatment, purification was performed by column chromatography to obtain 2.3 g of a compound represented by the formula (I-9-4).
- a compound represented by the formula (I-9-5) was obtained by the method described in JP2012-240945A. To the reaction vessel were added 2.0 g of the compound represented by the formula (I-9-5), 0.8 g of 3-chloropropanol, 3.7 g of cesium carbonate, and 30 mL of dimethyl sulfoxide, and the mixture was heated and stirred. After usual post-treatment, purification was performed by column chromatography and recrystallization to obtain 1.9 g of a compound represented by the formula (I-9-6).
- a compound represented by the formula (I-10-1) was obtained by the method described in Organic Letters, 2014, Vol. 16, No. 13, pages 3544-3547. Under a nitrogen atmosphere, 5.0 g of the compound represented by the formula (I-10-1), 2.3 g of pyridine, and 50 mL of dichloromethane were added to the reaction vessel. While cooling with ice, 8.3 g of trifluoromethanesulfonic anhydride was added and stirred. After usual post-treatment, purification was performed by column chromatography to obtain 7.7 g of a compound represented by the formula (I-10-2).
- a compound represented by the formula (I-10-12) was obtained by the method described in WO2008-010985. Under a nitrogen atmosphere, 3.0 g of the compound represented by the formula (I-10-12), 3.5 g of N-ethyldiisopropylamine, and 30 mL of dichloromethane were added to the reaction vessel. While cooling with ice, 2.1 g of acryloyl chloride was added and stirred. After usual post-treatment, purification was performed by column chromatography to obtain 3.4 g of a compound represented by the formula (I-10-13).
- a compound represented by the formula (I-112-2) was produced by the method described in JP2010-31223A.
- a reaction vessel 2.0 g of the compound represented by the formula (I-112-1), 3.4 g of the compound represented by the formula (I-112-2), 0.4 g of N, N-dimethylaminopyridine, 30 mL of dichloromethane was added.
- 1.3 g of diisopropylcarbodiimide was added dropwise and stirred at room temperature. After the precipitate was filtered, the filtrate was washed with hydrochloric acid, water and brine. Purification was performed by column chromatography (silica gel) and recrystallization to obtain 3.7 g of a compound represented by the formula (I-112-3).
- Transition temperature (temperature rise 5 ° C./min): C 117 N 220 I 1 H NMR (CDCl 3 ) ⁇ 0.92 (t, 3H), 1.07 (q, 2H), 1.24 to 2.06 (m, 27H), 2.35 (m, 2H), 2.
- a compound represented by formula (I-113) was obtained in the same manner as described above. Transition temperature (temperature rise 5 ° C./min): C 90 S 156 N 1 H NMR (CDCl 3 ) ⁇ 0.92 (t, 3H), 1.09 (m, 2H), 1.31 (m, 13H), 1.48 (m, 6H), 1.74 (t, 3H), 1.81 (t, 3H), 1.93 (m, 6H), 2.54 (t, 1H), 2.72 (t, 1H), 3.94 (t, 2H), 4.
- Transition temperature (temperature rise 5 ° C./min): C 64-77 N> 220
- Transition temperature (temperature rise 5 ° C./min): C 147-156 N 173 I 1 H NMR (CDCl 3 ) ⁇ 0.92 (t, 3H), 1.11 (q, 2H), 1.25 (m, 2H), 1.37-1.55 (m, 9H), 71 (m, 6H), 1.78 (m, 2H), 1.94 (m, 4H), 2.33 (m, 4H), 2.56 (m, 2H), 2.70 (m, 1H) ), 3.72 (s, 3H), 3.94 (t, 2H), 4.17 (t, 2H), 5.82 (dd, 1H), 6.13 (dd, 1H), 6.40.
- reaction vessel 166.5 g of a compound represented by the formula (I-118-3), 77.4 g of triethylamine, and 830 mL of dichloromethane were added. 55.4 g of acryloyl chloride was added dropwise while cooling with ice, followed by stirring at room temperature for 4 hours. The reaction solution was washed with brine and purified by column chromatography (alumina) to obtain an oily substance. To this was added 35 mL of 10% hydrochloric acid, 580 mL of methanol, and 580 mL of tetrahydrofuran, and the mixture was stirred at room temperature for 2 hours.
- alumina column chromatography
- reaction solution was washed with a saturated aqueous sodium hydrogen carbonate solution, water and brine in this order, and the solvent was distilled off. Purification was performed by column chromatography (silica gel) to obtain 116.8 g of a compound represented by the formula (I-118-5).
- Transition temperature (temperature increase 5 ° C./min, temperature decrease 5 ° C./min): C 101-105 (N 82) I 1 H NMR (CDCl 3 ) ⁇ 0.92 (t, 3H), 1.08-1.91 (m, 26H), 2.06 (d, 2H), 2.24 (d, 2H), 2.
- the stable storage concentration of the compound to be evaluated was measured.
- the stable storage concentration was determined by preparing a composition in which the compound to be evaluated was added to the base liquid crystal in 5% increments from 5% to 25%, and after leaving the prepared composition at 17.5 ° C. for 10 weeks, Is defined as the maximum concentration of the compound at which no precipitation occurs.
- Is defined as the maximum concentration of the compound at which no precipitation occurs.
- a compound having a large maximum addition concentration has a high stable storage concentration, meaning that no crystal precipitation occurs even after long-term storage.
- a 120 J sun test was performed at 60 mW / cm 2 and 26 ° C. using a xenon lamp irradiation tester (Sun Test XLS manufactured by Atlas Co., Ltd.) on the 10 films produced. About each obtained film, external appearance, such as discoloration and peeling by visual observation, was evaluated. ⁇ discoloration> The yellow index (YI) was measured for each of the ten films subjected to the sun test. The difference ( ⁇ YI) between the 10 YI average values before the sun test and the 10 YI average values after the sun test was calculated.
- the yellow index (YI) was calculated by measuring the absorption spectrum of the polymer with JASCO UV / VIS Spectrophotometer V-560 and using the attached color diagnostic program.
- ⁇ Peeling> The film was divided into an area of 10 squares ⁇ 10 squares, for a total of 100 squares. For each of the 10 films on which the sun test was performed, the squares where peeling occurred were counted, and the ratio (%) of the squares where peeling occurred among all squares (100 squares / 10 sheets). evaluated. The results are shown in the table below.
- any of the films produced using the compounds of the present invention of Example 45 to Example 66 hardly undergoes discoloration or peeling from the substrate when irradiated with ultraviolet light. Therefore, the compound of the present invention is useful as a constituent member of the polymerizable composition. Moreover, the optical anisotropic body using the polymeric liquid crystal composition containing the compound of this invention is useful for uses, such as an optical film.
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Abstract
Description
A1、A2及びA3は各々独立して1,4-フェニレン基、1,4-シクロヘキシレン基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ナフタレン-2,6-ジイル基、ナフタレン-1,4-ジイル基、テトラヒドロナフタレン-2,6-ジイル基、デカヒドロナフタレン-2,6-ジイル基又は1,3-ジオキサン-2,5-ジイル基を表すが、これらの基は無置換であるか又は1つ以上の置換基Lによって置換されても良く、
Z1、Z2及びZ3は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CH2CH2-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-OCO-NH-、-NH-COO-、-NH-CO-NH-、-NH-O-、-O-NH-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-、-N=CH-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表し、
Mは置換されていても良い3価の芳香族基を表し、
Tは下記の式(T-1)又は式(T-2)
W2は水素原子、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくは、W2は置換されていても良い炭素原子数1から80の芳香族基及び/又は非芳香族基を含む基を表すが、当該芳香族基は炭化水素環又は複素環であっても良く、当該非芳香族基は炭化水素基又は炭化水素基の任意の炭素原子がヘテロ原子に置換された基であっても良く(但し、酸素原子同士が直接結合することは無い。)、当該基は無置換であるか又は1つ以上の置換基LWによって置換されても良く、若しくは、W2はPW-(SpW-XW)kW-で表される基を表しても良く、ここでPWは重合性基を表し、SpWはスペーサー基又は単結合を表すが、SpWが複数存在する場合それらは同一であっても異なっていても良く、XWは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XWが複数存在する場合それらは同一であっても異なっていても良く(ただし、PW-(SpW-XW)kW-には-O-O-結合を含まない。)、kWは0から10の整数を表すが、W1及びW2は一緒になって環構造を形成しても良く、
LWはフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくは、LWはPLW-(SpLW-XLW)kLW-で表される基を表しても良く、ここでPLWは重合性基を表し、SpLWはスペーサー基又は単結合を表すが、SpLWが複数存在する場合それらは同一であっても異なっていても良く、XLWは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XLWが複数存在する場合それらは同一であっても異なっていても良く(ただし、PLW-(SpLW-XLW)kLW-には-O-O-結合を含まない。)、kLWは0から10の整数を表すが、化合物内にLWが複数存在する場合それらは同一であっても異なっていても良く、
Yは水素原子、フッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基又は1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくはYはPY-(SY-XY)kY-で表される基を表しても良く、PYは重合性基を表し、SpYはスペーサー基又は単結合を表すが、SpYが複数存在する場合それらは同一であっても異なっていても良く、XYは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XYが複数存在する場合それらは同一であっても異なっていても良く(ただし、PY-(SpY-XY)kY-には-O-O-結合を含まない。)、kYは0から10の整数を表す。)から選ばれる基を表し、
Lはフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくは、LはPL-(SpL-XL)kL-で表される基を表しても良く、ここでPLは重合性基を表し、SpLはスペーサー基又は単結合を表すが、SpLが複数存在する場合それらは同一であっても異なっていても良く、XLは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XLが複数存在する場合それらは同一であっても異なっていても良く(ただし、PL-(SpL-XL)kL-には-O-O-結合を含まない。)、kLは0から10の整数を表すが、化合物内にLが複数存在する場合それらは同一であっても異なっていても良く、T-Mを連結する基は単結合であっても二重結合であっても良い。)で表される化合物を提供し、併せて当該化合物を含有する重合性組成物、当該化合物を用いた樹脂、樹脂添加剤、オイル、フィルター、接着剤、粘着剤、油脂、インキ、医薬品、化粧品、洗剤、建築材料、包装材、液晶材料、有機EL材料、有機半導体材料、電子材料、表示素子、電子デバイス、通信機器、自動車部品、航空機部品、機械部品、農薬及び食品並びにそれらを使用した製品、重合性液晶組成物、当該重合性液晶組成物を重合させることにより得られる重合体及び当該重合体を用いた光学異方体を提供する。
LWはフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくは、LWはPLW-(SpLW-XLW)kLW-で表される基を表しても良く、ここでPLWは重合性基を表し、SpLWはスペーサー基又は単結合を表すが、SpLWが複数存在する場合それらは同一であっても異なっていても良く、XLWは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XLWが複数存在する場合それらは同一であっても異なっていても良く(ただし、PLW-(SpLW-XLW)kLW-には-O-O-結合を含まない。)、kLWは0から10の整数を表すが、化合物内にLWが複数存在する場合それらは同一であっても異なっていても良く、Yは水素原子、フッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基又は1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくはYはPY-(SpY-XY)kY-で表される基を表しても良く、PYは重合性基を表し、SpYはスペーサー基又は単結合を表すが、SpYが複数存在する場合それらは同一であっても異なっていても良く、XYは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XYが複数存在する場合それらは同一であっても異なっていても良く(ただし、PY-(SpY-XY)kY-には-O-O-結合を含まない。)、kYは0から10の整数を表す。)から選ばれる基を表す。
(製法1)下記式(S-14)で表される化合物の製造
式(S-1)で表される化合物のヒドロキシル基を保護基(PG)によって保護する。保護基(PG)としては、脱保護工程に至るまで安定に保護しうるものであれば特に制限は無いが、例えば、GREENE’S PROTECTIVE GROUPS IN ORGANIC SYNTHESIS((Fourth Edition)、PETER G.M.WUTS、THEODORA W.GREENE共著、John Wiley & Sons,Inc.,Publication)等に挙げられている保護基(PG)が好ましい。保護基の具体例としてはテトラヒドロピラニル基が挙げられる。
(製法2)下記式(S-28)で表される化合物の製造
式(S-15)で表される化合物のヒドロキシル基を保護基(PG)によって保護する。保護基(PG)としては、脱保護工程に至るまで安定に保護しうるものであれば特に制限は無いが、例えば、GREENE’S PROTECTIVE GROUPS IN ORGANIC SYNTHESIS((Fourth Edition)、PETER G.M.WUTS、THEODORA W.GREENE共著、John Wiley & Sons,Inc.,Publication)等に挙げられている保護基(PG)が好ましい。保護基の具体例としてはテトラヒドロピラニル基が挙げられる。
(実施例1)式(I-1)で表される化合物の製造
相転移温度(昇温過程):C 107 N 217 I
1H NMR (CDCl3):1.52(m,8H),1.74(quin,4H),1.86(quin,4H),4.07(td,4H),4.20(td,4H),5.84(d,2H),6.14(dd,2H),6.42(d,2H),6.99(d,4H),7.11(t,1H),7.21-7.40(m,8H),7.62(d,1H),7.93(m,2H),8.19(dd,4H)ppm.
(実施例2)式(I-2)で表される化合物の製造
相転移温度(昇温過程):C 113 N 171 I
1H NMR (CDCl3):1.48-1.59(m,8H),1.74(m,4H),1.85(m,4H), 4.07(q,4H),4.19(td,4H),5.84(d,2H),6.14(ddd,2H),6.42(dt,2H),7.00(q,4H),7.30(m,4H),7.39-7.46(m,5H),7.51(d,1H),7.61(dd,2H),7.85(d,1H),6.17(d,2H),8.22-8.25(m,3H),8.39(d,1H),8.57(s,1H)ppm.
(実施例3)式(I-3)で表される化合物の製造
相転移温度(昇温過程):C 180 N >220 I
1H NMR (CDCl3):1.42-1.60(m,8H), 1.68-1.91(m,8H),3.95(m,2H),4.07(t,2H),4.16-4.22(m,4H),5.83(dd,2H),6.09-6.18(m,2H),6.42(dd,2H),6.82(br,2H),7.00(d,2H),7.09(br,1H),7.21(br,1H),7.33(m,3H),7.45(br,1H),7.62(m,2H),7.70(d,2H),8.02(br,2H),8.19(d,3H),8.25(br,1H)ppm.
(実施例4)式(I-4)で表される化合物の製造
相転移温度(昇温過程):C 60-80 N 206 I
1H NMR (CDCl3):1.44-1.60(m,9H),1.66-1.90(m,13H),2.07(m,2H),2.29(m,2H),2.68(m,1H),4.03(td,4H),4.19(td,4H),5.07(m,1H),5.84(dt,2H),6.13(dd,2H),6.42(dd,2H),6.86(d,2H),6.93(d,2H),7.06-7.22(m,3H),7.30(dd,1H),7.45(d,1H),7.63(d,1H),7.90(s,1H),8.04(m,4H),8.11(s,1H)ppm.
(実施例5)式(I-5)で表される化合物の製造
LCMS:1023[M+1]
(実施例6)式(I-6)で表される化合物の製造
LCMS:1129[M+1]
(実施例7)式(I-7)で表される化合物の製造
LCMS:1121[M+1]
(実施例8)式(I-8)で表される化合物の製造
LCMS:1115[M+1]
(実施例9)式(I-9)で表される化合物の製造
LCMS:826[M+1]
(実施例10)式(I-10)で表される化合物の製造
LCMS:951[M+1]
(実施例11)式(I-111)で表される化合物の製造
転移温度(昇温5℃/分):C 159 N 167 I
MS(m/z):794[M++1]
(実施例12)式(I-112)で表される化合物の製造
転移温度(昇温5℃/分):C 117 N 220 I
1H NMR(CDCl3)δ 0.92(t,3H),1.07(q,2H),1.24-2.06(m,27H),2.35(m,2H),2.55(t,1H),3.95(t,2H),4.18(t,2H),5.83(dd,1H),6.13(dd,1H),6.42(dd,1H),6.88(d,2H),6.98(m,3H),7.19-7.26(m,2H),7.35(m,1H),7.51(m,1H),7.68(m,1H),7.89(m,1H),8.08(m,1H)ppm.
MS(m/z):794[M++1]
(実施例13)式(I-113)で表される化合物の製造
転移温度(昇温5℃/分):C 90 S 156 N
1H NMR(CDCl3)δ 0.92(t,3H),1.09(m,2H),1.31(m,13H),1.48(m,6H),1.74(t,3H),1.81(t,3H),1.93(m,6H),2.54(t,1H),2.72(t,1H),3.94(t,2H),4.18(t,2H),5.81(d,1H),6.13(q,1H),6.41(d,1H),6.41(d,1H),6.88(d,2H),6.96(d,2H),7.20(t,1H),7.26(d,1H),7.45(d,1H),7.57(d,1H),7.84(s,1H),8.07(d,3H)ppm.
MS(m/z):822[M++1]
(実施例14)式(I-114)で表される化合物の製造
転移温度(昇温5℃/分):C 64-77 N >220 I
1H NMR(CDCl3)δ 0.92(t,3H),1.07(q,2H),1.23(m,2H),1.37(m,3H),1.48-1.60(m,6H),1.74(quin,2H),1.83-1.90(m,4H),1.97(d,2H),2.56(tt,1H),4.07(t,2H),4.19(t,2H),5.83(dd,1H),6.13(dd,1H),6.42(dd,1H),7.00(d,2H),7.11(q,1H),7.12(d,1H),7.19-7.31(m,4H),7.46(d,1H),7.61(d,1H),7.85(d,1H),8.09(s,1H),8.17(m,4H)ppm.
MS(m/z):788[M++1]
(実施例15)式(I-115)で表される化合物の製造
転移温度(昇温5℃/分):C 190 N 260 I
1H NMR(CDCl3)δ 0.89(t,1H),1.05(t,2H),1.31(q,2H),1.50(m,6H),1.74,(m,15H),2.54(t,1H),4.03(t,2H),4.19(t,2H),5.81(d,1H),6.13(q,1H),6.41(d,1H),6.43(d,1H),7.09(d,2H),7.11(d,2H),7.20(t,1H),7.26(d,1H),7.45(d,1H),7.57(d,1H),7.84(s,1H),8.07(d,3H)ppm.
MS(m/z):750[M++1]
(実施例16)式(I-116)で表される化合物の製造
転移温度(昇温5℃/分):C 147-156 N 173 I
1H NMR(CDCl3)δ 0.92(t,3H),1.11(q,2H),1.25(m,2H),1.37-1.55(m,9H),1.71(m,6H),1.78(m,2H),1.94(m,4H),2.33(m,4H),2.56(m,2H),2.70(m,1H),3.72(s,3H),3.94(t,2H),4.17(t,2H),5.82(dd,1H),6.13(dd,1H),6.40(dd,1H),6.88(d,2H),6.98(m,3H),7.17(t,1H),7.24(dd,1H),7.35(t,1H),7.66-7.72(m,3H),7.88(d,1H)ppm.
MS(m/z):808[M++1]
(実施例17)式(I-117)で表される化合物の製造
転移温度(昇温5℃/分):C 117-122 N 146 I
1H NMR(CDCl3)δ 0.91(m,6H),1.10(q,2H),1.23-1.56(m,18H),1.68-1.81(m,9H),1.94(t,4H),2.32(m,4H),2.56-2.70(m,3H),3.94(t,2H),4.18(t,2H),4.29(t,2H),5.82(dd,1H),6.13(dd,1H),6.40(dd,1H),6.89(d,2H),6.99(m,3H),7.16(t,1H),7.23(dd,1H),7.34(t,1H),7.66-7.72(m,3H),7.90(d,1H)ppm.
MS(m/z):878[M++1]
(実施例18)式(I-118)で表される化合物の製造
転移温度(昇温5℃/分):C 75-108 N 180 I
1H NMR(CDCl3)δ 0.94(t,3H),1.10(m,2H),1.25(m,2H),1.29-1.57(m,11H),1.80-2.08(m,6H),2.30(m,2H),2.54(m,1H),3.67-3.78(m,6H),3.85(t,2H),4.11(t,2H),4.32(t,2H),5.84(dd,1H),6.15(dd,1H),6.40(dd,1H),6.82-7.00(m,4H),7.08-7.60(m,4H),7.65-8.10(m,3H)、8.40(s,1H)、11.6(s,1H)ppm.
LCMS:826[M+1]
(実施例19)式(I-119)で表される化合物の製造
転移温度(昇温5℃/分):C 106 N 125 I
1H NMR(CDCl3)δ 0.92(t,3H),1.05-1.83(m,22H),1.93(t,5H),2.33(m,4H),2.55(m,2H),2.71(m、1H),3.30(s,3H),3.62(m,2H),3.85(t,2H),3.94(t,2H),4.17(t,2H),4.48(t,2H),5.82(dd,1H),6.12(dd,1H),6.40(dd,1H),6.88(d,2H),6.99(m,3H),7.17(t,1H),7.23(dd,1H),7.34(t,1H),7.66(d,1H),7.71(d,1H),7.89(d,1H),8.02(s,1H)ppm.
(実施例20)式(I-120)で表される化合物の製造
転移温度(昇温5℃/分):C 131 I
1H NMR(CDCl3)δ 0.88-0.94(m,6H),1.10(m,2H),1.22-1.52(m,13H),1.72(m,6H),1.94(t,4H),2.32(m,4H),2.53-2.62(m,3H),3.69-3.77(m,6H),3.86(t,2H),4.12(t,2H),4.27-4.34(m,4H),5.83(dd,1H),6.16(dd,1H),6.43(dd,1H),6.91(d,2H),6.97-7.02(m,3H),7.16(t,1H),7.23(dd,1H),7.33(t,1H),6.66-7.72(m,3H),7.90(d,1H)ppm.
LCMS:910[M+1]
(実施例21)式(I-121)で表される化合物の製造
転移温度(昇温5℃/分、降温5℃/分):C 101-105(N 82)I
1H NMR(CDCl3)δ 0.92(t,3H),1.08-1.91(m,26H),2.06(d,2H),2.24(d,2H),2.51(m,2H),3.30(s,3H),3.51(dd,2H),3.67(dd,2H),3.87(quin,4H),3.94(t,2H),4.17(t,2H),4.54(t,2H),5.82(dd,1H),6.12(dd,1H),6.40(dd,1H),6.86(m,3H),6.97(m,2H),7.16(m,2H),7.32(t,1H),7.65(d,1H),7.70(d,1H),7.82(d,1H),8.36(s,1H)ppm.
(実施例22)式(I-122)で表される化合物の製造
1H NMR(CDCl3)δ 1.00(t,3H),1.28(m,2H),1.45-1.81(m,12H),1.97(br,1H),2.13(m,2H),2.26(m,2H),2.57(tt,1H),2.65(t,2H),3.27(s,3H),3.37(m,2H),3.50(m,2H),3.70(t,2H),3.95(q,4H),4.17(t,2H),4.33(t,2H),5.82(dd,1H),6.12(dd,1H),6.40(dd,1H),6.87(d,2H),6.98(m,3H),7.15(t,1H),7.25(m,5H),7.32(t,1H),7.64(m,2H),7.69(d,1H),7.91(s,1H)ppm.
実施例1から実施例22と同様の方法、公知の方法と同様の方法を用いて、式(I-11)から式(I-110)、式(I-123)から式(I-133)で表される化合物を製造した。
(実施例23~44、比較例1~3)
実施例1から実施例22記載の式(I-1)から式(I-10)、式(I-111)から式(I-122)で表される化合物及び特許文献1記載の化合物(R-1)、特許文献2記載の化合物(R-2)、特許文献3記載の化合物(R-3)を評価対象の化合物とした。
(実施例45~66、比較例4~6)
配向膜用ポリイミド溶液を厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、100℃で10分乾燥した後、200℃で60分焼成することにより塗膜を得た。得られた塗膜をラビング処理した。ラビング処理は、市販のラビング装置を用いて行った。
〈変色〉
サンテストを行った10枚の各フィルムについて、各々イエローインデックス(YI)を測定した。サンテスト実施前の10枚のYI平均値と、サンテスト実施後の10枚のYI平均値との差(ΔYI)を算出した。イエローインデックス(YI)はJASCO UV/VIS Spectrophotometer V-560で重合体の吸収スペクトルを測定し、付属のカラー診断プログラムを使用し計算した。計算式は、
YI=100(1.28X-1.06Z)/Y (JIS K7373)
(X、Y、ZはXYZ表色系における3刺激値を表す。)である。ΔYI値が大きいほど、サンテスト実施後の変色が強く見られることを意味する。
〈剥離〉
フィルムを縦10マス×横10マス、計100マスの領域に区分した。サンテストを行った10枚の各フィルムについて、剥離の生じたマス目をカウントし、全マス目1000マス(100マス/枚×10枚)中、剥離の生じたマス目の割合(%)を評価した。
結果を下表に示す。
Claims (9)
- 一般式(I)
A1、A2及びA3は各々独立して1,4-フェニレン基、1,4-シクロヘキシレン基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ナフタレン-2,6-ジイル基、ナフタレン-1,4-ジイル基、テトラヒドロナフタレン-2,6-ジイル基、デカヒドロナフタレン-2,6-ジイル基又は1,3-ジオキサン-2,5-ジイル基を表すが、これらの基は無置換であるか又は1つ以上の置換基Lによって置換されても良く、
Z1、Z2及びZ3は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CH2CH2-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-OCO-NH-、-NH-COO-、-NH-CO-NH-、-NH-O-、-O-NH-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-、-N=CH-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表し、
Mは置換されていても良い3価の芳香族基を表し、
Tは下記の式(T-1)又は式(T-2)
W2は水素原子、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくは、W2は置換されていても良い炭素原子数1から80の芳香族基及び/又は非芳香族基を含む基を表すが、当該芳香族基は炭化水素環又は複素環であっても良く、当該非芳香族基は炭化水素基又は炭化水素基の任意の炭素原子がヘテロ原子に置換された基であっても良く(但し、酸素原子同士が直接結合することは無い。)、当該基は無置換であるか又は1つ以上の置換基LWによって置換されても良く、若しくは、W2はPW-(SpW-XW)kW-で表される基を表しても良く、ここでPWは重合性基を表し、SpWはスペーサー基又は単結合を表すが、SpWが複数存在する場合それらは同一であっても異なっていても良く、XWは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XWが複数存在する場合それらは同一であっても異なっていても良く(ただし、PW-(SpW-XW)kW-には-O-O-結合を含まない。)、kWは0から10の整数を表すが、W1及びW2は一緒になって環構造を形成しても良く、
LWはフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくは、LWはPLW-(SpLW-XLW)kLW-で表される基を表しても良く、ここでPLWは重合性基を表し、SpLWはスペーサー基又は単結合を表すが、SpLWが複数存在する場合それらは同一であっても異なっていても良く、XLWは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XLWが複数存在する場合それらは同一であっても異なっていても良く(ただし、PLW-(SpLW-XLW)kLW-には-O-O-結合を含まない。)、kLWは0から10の整数を表すが、化合物内にLWが複数存在する場合それらは同一であっても異なっていても良く、
Yは水素原子、フッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基又は1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくはYはPY-(SpY-XY)kY-で表される基を表しても良く、PYは重合性基を表し、SpYはスペーサー基又は単結合を表すが、SpYが複数存在する場合それらは同一であっても異なっていても良く、XYは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XYが複数存在する場合それらは同一であっても異なっていても良く(ただし、PY-(SpY-XY)kY-には-O-O-結合を含まない。)、kYは0から10の整数を表す。)から選ばれる基を表し、
Lはフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、シアノ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、若しくは、LはPL-(SpL-XL)kL-で表される基を表しても良く、ここでPLは重合性基を表し、SpLはスペーサー基又は単結合を表すが、SpLが複数存在する場合それらは同一であっても異なっていても良く、XLは-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、XLが複数存在する場合それらは同一であっても異なっていても良く(ただし、PL-(SpL-XL)kL-には-O-O-結合を含まない。)、kLは0から10の整数を表すが、化合物内にLが複数存在する場合それらは同一であっても異なっていても良く、T-Mを連結する基は単結合であっても二重結合であっても良い。)で表される化合物。 - 一般式(I)において、R1及びR2のうち少なくとも1つが下記一般式(I-R)
- 式(I-R)において、Spが各々独立して、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-COO-、-OCO-、-OCO-O-、-CO-NH-、-NH-CO-、-CH=CH-又は-C≡C-に置き換えられても良い炭素原子数1から20のアルキレン基を表す、請求項2又は請求項3に記載の化合物。
- 請求項1から請求項4のいずれか一項に記載の化合物を含有する組成物。
- 請求項1から請求項4のいずれか一項に記載の化合物を含有する液晶組成物。
- 請求項5又は請求項6に記載の組成物を重合することにより得られる重合体。
- 請求項7記載の重合体を用いた光学異方体。
- 請求項1から請求項4のいずれか一項に記載の化合物を用いた樹脂、樹脂添加剤、オイル、フィルター、接着剤、粘着剤、油脂、インキ、医薬品、化粧品、洗剤、建築材料、包装材、液晶材料、有機EL材料、有機半導体材料、電子材料、表示素子、電子デバイス、通信機器、自動車部品、航空機部品、機械部品、農薬及び食品並びにそれらを使用した製品。
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- 2016-02-16 US US15/547,949 patent/US10597371B2/en active Active
- 2016-02-16 CN CN201680009332.3A patent/CN107207419B/zh active Active
- 2016-02-16 KR KR1020177022782A patent/KR20170121174A/ko not_active Application Discontinuation
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Also Published As
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US10597371B2 (en) | 2020-03-24 |
US20180022716A1 (en) | 2018-01-25 |
JPWO2016136533A1 (ja) | 2017-04-27 |
JP6164509B2 (ja) | 2017-07-19 |
KR20170121174A (ko) | 2017-11-01 |
CN107207419A (zh) | 2017-09-26 |
CN107207419B (zh) | 2021-03-09 |
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