WO2010082532A1 - 電気化学デバイスおよびその製造方法 - Google Patents
電気化学デバイスおよびその製造方法 Download PDFInfo
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- WO2010082532A1 WO2010082532A1 PCT/JP2010/050129 JP2010050129W WO2010082532A1 WO 2010082532 A1 WO2010082532 A1 WO 2010082532A1 JP 2010050129 W JP2010050129 W JP 2010050129W WO 2010082532 A1 WO2010082532 A1 WO 2010082532A1
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- film
- exterior film
- lead terminal
- melting point
- innermost layer
- Prior art date
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Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E60/13—Energy storage using capacitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Definitions
- the present invention relates to an electrochemical device applied to, for example, a lithium ion secondary battery or an electric double layer capacitor used for a power source of an electric vehicle or a mobile phone, and a manufacturing method thereof.
- packaging laminate materials widely used as packaging materials in the pharmaceutical and food fields can be used as exterior films for electrochemical devices such as batteries by encapsulating electrodes and electrolytes. It contributes greatly to the weight reduction and thinning of them.
- a power generation element including an electrode and an electrolyte is accommodated in an exterior film, and the power generation element is enclosed by heat-sealing the outer peripheral portion of the exterior film in a state where the lead terminals are pulled out and being fused.
- the structure which does is disclosed (for example, refer patent document 1).
- the packaging film made of such a packaging laminate material is composed of a plurality of layers, and the outermost layer is made of, for example, polyethylene terephthalate (PET) or nylon, while the innermost layer in contact with the electrolytic solution is a heat-weldable material (for example, high-density polyethylene, low-density polyethylene, linear low-density polyethylene, polyethylene-based ionomer, and polyolefin resin such as polypropylene).
- PET polyethylene terephthalate
- nylon nylon
- heat-weldable material for example, high-density polyethylene, low-density polyethylene, linear low-density polyethylene, polyethylene-based ionomer, and polyolefin resin such as polypropylene.
- the exterior film is provided with a metal foil such as an aluminum foil or a SUS foil as an intermediate layer in order to prevent moisture from entering the electrochemical device and evaporation of the electrolyte from the inside.
- a metal foil such as an aluminum foil or a SUS foil
- the outermost layer plays the role of protecting mechanical strength and protecting the intermediate layer metal foil from external force such as piercing.
- the packaging laminate material is cut into, for example, a rectangular shape to form an exterior film, and in such a state that an element containing an electrode, an electrolytic solution, or the like is accommodated, a peripheral portion of the exterior film, etc.
- the sealing portion is thermocompression bonded, whereby the electrochemical element such as the electrode or the electrolytic solution is enclosed in the exterior film.
- the pair of lead terminals in this electrochemical device is such that each outer end portion is pulled out from the seal portion in the exterior film, and the portion corresponding to the seal portion is heat-sealed in the innermost layer in the exterior film by heat sealing.
- the lead terminal may break through the innermost layer of the exterior film at the time of sealing, and may contact the metal foil of the intermediate layer to cause a short circuit.
- Patent Document 2 a technique for covering a lead terminal with a synthetic resin film corresponding to a seal portion in an exterior film has been proposed (for example, see Patent Document 2). Specifically, for example, a portion corresponding to the seal portion in the positive lead terminal or the negative lead terminal is previously coated with an insulating heat-sealable synthetic resin film.
- an adhesive synthetic resin layer having good adhesion to the metal is used as the innermost layer, and an insulating synthetic resin layer and an olefin resin layer are sequentially laminated on the outermost layer.
- a technique is disclosed (for example, see Patent Document 3).
- the present invention has been made in view of the above circumstances, and is capable of improving the durability by improving the adhesion between the lead terminal covering film and the exterior film, ensuring an appropriate sealing property, and improving the durability.
- An object of the present invention is to provide a device and a manufacturing method thereof.
- a laminated exterior film having at least an innermost layer made of a thermoadhesive synthetic resin; An electrochemical element housed in the exterior film; A lead terminal whose inner end is electrically connected to the electrochemical element and whose outer end is drawn out of the exterior film;
- the outermost layer is composed of a heat-adhesive synthetic resin that is compatible with the innermost layer of the exterior film, and includes a laminated lead terminal covering film provided corresponding to the seal portion by the exterior film, In a state where the lead terminal is sandwiched through the covering film, the seal portion by the exterior film is fused by heat sealing,
- the electrochemical device wherein the melting point of the outermost layer in the covering film for lead terminals is set to be lower than the melting point of the innermost layer of the exterior film.
- electrochemical device includes a battery power generation element including at least a positive electrode, a negative electrode, and an electrolyte interposed between positive and negative electrodes. device.
- thermoadhesive synthetic resin By a laminated adhesive film in which at least the innermost layer is made of a thermoadhesive synthetic resin, an electrochemical element, a lead terminal, and a thermoadhesive synthetic resin in which the outermost layer is compatible with the innermost layer of the outer film.
- the melting point of the outermost layer of the covering film for lead terminals is less than the melting point of the innermost layer of the outer film, when the sealing portion of the outer film is heat-sealed, Even if there is a temperature difference between the inner layer and the outermost layer of the coating film for lead terminals, the melting of the innermost layer of the outer film and the outermost layer of the coating film for lead terminals is almost parallel. Then proceed. For this reason, both the outermost layer of the covering film for lead terminals and the innermost layer of the exterior film are uniformly melted and hardened in the seal portion, and the sealing performance at the seal portion is effectively enhanced.
- the melting point difference between the outermost layer of the lead terminal covering film and the innermost layer of the exterior film is 9 ° C. or more, the lead terminal covering when the heat sealing is performed.
- the outermost layer of the film and the innermost layer of the exterior film are melted more uniformly, and the sealing state is further improved.
- the melting point of the innermost layer of the exterior film is 124 ° C. or higher, heat resistance as an electrochemical element is ensured.
- the thickness of the covering film for lead terminals is set to a predetermined thickness, the covering film can be covered and adhered to the lead terminals without any gap, and the sealing property can be improved. This can be further improved.
- the innermost layer in the exterior film and the outermost layer in the lead terminal covering film are olefin-based synthetic resins, and therefore, the compatibility of both at the time of heat sealing is further increased. In addition to being effectively exhibited, the chemical resistance to the electrolyte and the like is further improved.
- the thickness of the lead terminal is 0.2 to 0.5 mm, suppression of heat dissipation of the lead terminal at the time of heat sealing is effective in an electrochemical device that flows a large current.
- the processing time can be shortened.
- the electrochemical element includes a power generation element for a battery, it is possible to easily provide a thin battery having a high sealing property at a lead terminal drawing portion. .
- the electrochemical device of the present invention can be reliably manufactured.
- heat sealing is performed on the seal portion in the exterior film at a temperature of 20 ° C. or higher than the melting point of the innermost layer in the exterior film.
- FIG. 1 is a cross-sectional view showing, in a sealed state, a thin battery to which an electrochemical device according to an embodiment of the present invention is applied.
- FIG. 2 is an exploded perspective view showing the thin battery in a state before sealing.
- FIG. 3 is an exploded cross-sectional view showing the thin battery in a sealed state.
- 4 is an enlarged cross-sectional view of a portion A in FIG.
- FIG. 5 is a perspective view showing the vicinity of the seal portion in the lead terminal of the thin battery.
- FIG. 6 is a cross-sectional view showing a state where the vicinity of the seal portion of the lead terminal is sealed.
- FIG. 7 is a perspective view showing a state in which an electrochemical element is accommodated in an exterior film processed into a bag shape.
- FIG. 8 is a table showing the results of sealing performance evaluation in Examples and Comparative Examples.
- FIG. 1 is a sectional view showing a thin battery to which an electrochemical device according to an embodiment of the present invention is applied in a sealed state
- FIG. 2 is an exploded perspective view showing the thin battery in a state before sealing
- FIG. 3 is an exploded cross-sectional view showing the thin battery in a sealed state.
- this thin battery includes two exterior films 4 and 4 whose peripheral portions are welded and the inside is sealed, an electrochemical element 10 accommodated in the exterior films 4 and 4, one end A pair of lead terminals 5 and 6 in which inner end portions 5a and 6a as parts are connected to the electrochemical element 10 and outer end portions 5b and 6b as other ends are disposed outside the exterior films 4 and 4, Sealing films 7 and 7 are provided at positions corresponding to the lead-out portions (seal portions 4d) of the exterior films 4 and 4 in the lead terminals 5 and 6, respectively.
- the electrochemical element 10 is configured by laminating a positive electrode 1 and a negative electrode 2 with an electrolyte part 3 interposed therebetween.
- the electrolyte part 3 is composed of, for example, a combination of a separator and an electrolytic solution, a combination of a separator and a gel electrolyte, a combination of a gel electrolyte, a combination of a solid electrolyte, and the like. Needless to say, the electrolyte part 3 is not limited to the exemplified configuration.
- the positive electrode 1 and the negative electrode 2 are made of a metal conductive material such as an aluminum foil or a copper foil, and a positive electrode material such as LiCoO 2 or LiCoMn 2 O 4 and a negative electrode material such as LiC 6 Ti 5 O 12 are carbon conductive aids and binders. It becomes the composition applied with.
- the inner ends 5a and 5b of the pair of lead terminals 5 and 6 are respectively fixed to the positive electrode 1 and the negative electrode 2 of the electrochemical element 10 by welding or the like and electrically connected thereto.
- the exterior film 4 has a laminated structure, for example, a three-layer structure having an innermost layer 41, an intermediate layer 42, and an outermost layer 43 as shown in FIG.
- the innermost layer 41 is selected from a heat-adhesive (thermoplastic) synthetic resin, for example, high-density polyethylene, low-density polyethylene, linear low-density polyethylene, polyethylene ionomer, polyolefin resin such as polypropylene, and the like. It is configured.
- the outermost layer 43 is made of polyethylene terephthalate (PET) or nylon.
- the intermediate layer 42 in the exterior film 4 is made of a metal foil, for example, an aluminum foil or a SUS foil.
- the intermediate layer 42 effectively prevents moisture from entering from the outside and evaporation of the electrolyte from the inside.
- the outermost layer 43 has a role of securing mechanical strength and protecting the intermediate layer 42.
- the outer packaging film 4 in this example uses, as the innermost layer 41, a packaging laminate material obtained by dry lamination using a polypropylene unstretched film having a melting point of, for example, 168 ° C. into a bag shape.
- the positive electrode side and negative electrode side lead terminals 5 and 6 are made of a metal foil such as aluminum, copper, nickel, and stainless steel, and the thickness thereof is set to 0.2 to 0.5 mm.
- the thickness is preferably 0.2 mm or more, but is preferably 0.5 mm or less at the maximum. This is because when the thickness exceeds 0.5 mm, it is difficult to fill the both end edges in the width direction of the lead terminals 5 and 6 with a synthetic resin such as the covering film 7, which may cause a decrease in adhesion.
- both lead terminals 5 and 6 are previously coated with coating films 7 and 7 having a thickness of 0.08 to 0.25 mm.
- the covering film 7 has a three-layer structure having an innermost layer 71, an intermediate layer 72 and an outermost layer 73. The covering film 7 prevents the lead terminals 5 and 6 from coming into contact with the intermediate layer 42 of the exterior film 4 to cause a short circuit accident.
- the innermost layer 71 of the covering film 7 is made of an adhesive synthetic resin having good adhesion to the metal as the lead terminal constituent material.
- the intermediate layer 72 covering the innermost layer 71 is made of an insulating resin.
- the outermost layer 73 that contacts the innermost layer 41 of the outer film 4 is made of the same system and compatible synthetic resin as the innermost layer 41 of the outer film 4, for example, an olefin resin.
- the melting point of the outermost layer 73 in the covering film 7 is set to be lower than the melting point of the innermost layer 41 of the exterior film 4.
- the exterior film 4 has a melting point difference of 9 ° C. or more.
- the melting point of the outermost layer 73 in the coating film 7 is set to 134 ° C., for example, while the melting point of the innermost layer 41 is 168 ° C.
- the sealing portion 4 d in the exterior films 4 and 4 is sealed by heat sealing.
- the melting point of the innermost layer 41 in the exterior films 4 and 4 ( Here, heat sealing is performed at a temperature (188 ° C.) of 20 ° C. or higher than 168 ° C.
- the melting point of the outermost layer 73 of the covering film 7 in the lead terminals 5 and 6 is set to be lower than the melting point of the innermost layer 41 of the exterior film 4. For this reason, when the site
- the outermost layer 73 in the covering film 7 is uniformly melted with respect to the innermost layer 41 of the outer film 4 in the seal portion 4d, and both the layers 41 and 73 are well melted and solidified to be consolidated.
- the sealing performance in the seal portion 4a of the film 4 is effectively enhanced.
- the constituent material of the outermost layer 73 of the covering film 7 and the constituent material of the innermost layer 41 of the exterior film 4 can be arbitrarily selected and set from thermal adhesive (thermoplastic) synthetic resins.
- thermal adhesive thermoplastic
- both layers 73 and 41 are made of the same type of resin, for example, an olefin resin such as polyethylene (PE) or polypropylene (PP), the compatibility of both layers 73 and 41 is exhibited well.
- the olefin resin is excellent in chemical resistance and can be used positively considering contact with the electrolytic solution.
- the difference between the melting point of the outermost layer 73 of the covering film 7 and the melting point of the innermost layer 41 of the exterior film 4 can be arbitrarily set, but by setting the melting point difference to 9 ° C. or more as in this example, The melting of the innermost layer 41 of the exterior film 4 and the outermost layer 73 of the covering film 7 are effectively performed, and the sealing performance is further enhanced.
- the melting point of the outermost layer 73 of the coating film 7 with respect to the lead terminals 5 and 6 is less than 124 ° C., there is a concern about the influence on the heat resistance performance of the battery. If the melting point of the outer layer 73 is set to 124 ° C. or higher, the fear of a decrease in heat resistance is also eliminated.
- the heat sealing time should be set to 3 to 8 seconds, preferably 4 to 6 seconds. That is, when the heat seal time is too short, there is a risk that it is difficult to reliably seal due to insufficient heating. On the other hand, when the heat sealing time is too long, productivity is lowered, and it is difficult to obtain a good sealing state due to thermal deterioration due to excessive heating.
- the outermost layer 43 and the intermediate layer 42 of the outer packaging film 4 made of a packaging laminate material have the same material and thickness, and the thicknesses and widths of the lead terminals 5 and 6 are as follows. is there. “About the outermost layer 43 and the intermediate layer 42 of the exterior film 4”
- the outermost layer 43 made of nylon 25 ⁇ m and the intermediate layer 42 made of aluminum foil (AA standard 8079, O material) are dry laminated and used.
- Temperature Melting point of innermost layer 41 of exterior film 4 + 30 ° C. Pressure: 0.2MPa
- Example 1 As a constituent material of the innermost layer 41 in the outer film 4, a polypropylene unstretched film having a melting point of 168 ° C. of 30 ⁇ m is selected, and this is dry-laminated on nylon that becomes the outermost layer 43 and aluminum foil that becomes the intermediate layer 42. A packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape as shown in FIG.
- Example 2 As a constituent material of the innermost layer 41 in the outer film 4, a polypropylene unstretched film having a melting point of 168 ° C. of 30 ⁇ m is selected, and this is dry-laminated on nylon that becomes the outermost layer 43 and aluminum foil that becomes the intermediate layer 42. A packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape to obtain an exterior film 4.
- Example 3 As a constituent material of the innermost layer 41 in the outer film 4, a polypropylene unstretched film having a melting point of 143 ° C. of 30 ⁇ m is selected, and this is dry-laminated to nylon as the outermost layer 43 and aluminum foil as the intermediate layer 42. A packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape to obtain an exterior film 4.
- Example 4 As a constituent material of the innermost layer 41 in the outer film 4, a polypropylene unstretched film 30 ⁇ m having a melting point of 134 ° C. is selected, and this is dry-laminated to nylon as the outermost layer 43 and aluminum foil as the intermediate layer 42. A packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape to obtain an exterior film 4.
- Example 5 As a constituent material of the innermost layer 41 in the outer film 4, a polypropylene unstretched film 30 ⁇ m having a melting point of 134 ° C. is selected, and this is dry-laminated to nylon as the outermost layer 43 and aluminum foil as the intermediate layer 42. A packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape to obtain an exterior film 4.
- a constituent material of the innermost layer 41 in the outer film 4 a polypropylene unstretched film having a melting point of 168 ° C. of 30 ⁇ m is selected, and this is dry-laminated on nylon that becomes the outermost layer 43 and aluminum foil that becomes the intermediate layer 42.
- a packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape to obtain an exterior film 4.
- the outermost layer 73 is covered with the coating film 7 made of polypropylene having a melting point of 168 ° C. at the lead terminals 5 and 6. The part corresponding to the seal was covered. Thereafter, the seal portion 4d of the exterior film 4 was heat sealed for 5 seconds to obtain a sealed state.
- a constituent material of the innermost layer 41 in the outer film 4 a polypropylene unstretched film having a melting point of 143 ° C. of 30 ⁇ m is selected, and this is dry-laminated to nylon as the outermost layer 43 and aluminum foil as the intermediate layer 42.
- a packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape to obtain an exterior film 4.
- a constituent material of the innermost layer 41 in the outer film 4 a polypropylene unstretched film 30 ⁇ m having a melting point of 134 ° C. is selected, and this is dry-laminated to nylon as the outermost layer 43 and aluminum foil as the intermediate layer 42.
- a packaging laminate material was formed, the packaging laminate material was formed into a square shape, and processed into a bag shape to obtain an exterior film 4.
- the electrochemical device is described as an example applied to a thin battery.
- the present invention is not limited to a thin battery, and can be applied to various electrochemical devices such as an electric double capacitor. .
- the electrochemical device of the present invention can be used as a power source for electric vehicles, mobile phones and the like.
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Abstract
Description
前記外装フィルムに収容された電気化学素子と、
内端部が前記電気化学素子に電気的に接続されて、外端部が外装フィルムから外部に引き出されたリード端子と、
最外層が前記外装フィルムの最内層と相溶性を有する熱接着性合成樹脂で構成されて、前記外装フィルムによるシール部に対応して設けられた積層状のリード端子用被覆フィルムとを備え、
前記リード端子を前記被覆フィルムを介して挟んだ状態で前記外装フィルムによるシール部がヒートシールで融着され、
前記リード端子用被覆フィルムにおける最外層の融点が前記外装フィルムの最内層の融点未満に設定されていることを特徴とする電気化学デバイス。
前記リード端子の一部を前記被覆フィルムにて被覆する工程と、
前記外装フィルムに、電気化学素子を収容する工程と、
リード端子をその外端部を前記外装フィルムから引き出した状態で内端部を前記電気化学素子に電気的に接続する工程と、
前記リード端子を部分的に被覆した前記被覆フィルムに、前記外装フィルムによるシール部をヒートシールにて融着する工程と、を含むことを特徴とする電気化学デバイスの製造方法。
『外装フィルム4の最外層43と中間層42について』
ナイロン25μmからなる最外層43と、アルミニウム箔(AA規格8079、O材)からなる中間層42とをドライラミネートして使用する。
『リード端子について』
厚さ:0.2mm
幅:50mm
『ヒートシール条件について』
温度:外装フィルム4の最内層41の融点+30℃
圧力:0.2MPa
前記外装フィルム4における最内層41の構成材として、融点が168℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、図7に示すように袋状に加工して外装フィルム4とした。
前記外装フィルム4における最内層41の構成材として、融点が168℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、袋状に加工して外装フィルム4とした。
前記外装フィルム4における最内層41の構成材として、融点が143℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、袋状に加工して外装フィルム4とした。
前記外装フィルム4における最内層41の構成材として、融点が134℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、袋状に加工して外装フィルム4とした。
前記外装フィルム4における最内層41の構成材として、融点が134℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、袋状に加工して外装フィルム4とした。
前記外装フィルム4における最内層41の構成材として、融点が168℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、袋状に加工して外装フィルム4とした。
前記外装フィルム4における最内層41の構成材として、融点が143℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、袋状に加工して外装フィルム4とした。
前記外装フィルム4における最内層41の構成材として、融点が134℃であるポリプロピレン未延伸フィルム30μmを選択し、これを最外層43となるナイロンと中間層42となるアルミニウム箔とにドライラミネートして包装用ラミネート材料を形成し、この包装用ラミネート材料を方形に成形するとともに、袋状に加工して外装フィルム4とした。
比較例2と同条件であるが、ヒートシール時間を20secにて行った。
各検体にタブ部が下向きになるよう静置して85℃で1週間の保存テストを行い、その後各検体内部に注射針より圧力を計測しながら空気を送り込み、破裂するに至る圧力を測定した。その結果を図8に示す。
2・・・負極
3・・・電解質
4・・・外装フィルム
4d・・・外装フィルムのシール部
5・・・正極側リード端子
5a・・・正極側リード端子の内端部
5b・・・正極側リード端子の外端部
6・・・負極側リード端子
6a・・・負極側リード端子の内端部
6b・・・負極側リード端子の外端部
7・・・・リード端子用被覆フィルム
10・・・電気化学素子
41・・・外装フィルムの最内層
73・・・リード端子用被覆フィルムの最外層
Claims (12)
- 少なくとも最内層が熱接着性合成樹脂からなる積層状の外装フィルムと、
前記外装フィルムに収容された電気化学素子と、
内端部が前記電気化学素子に電気的に接続されて、外端部が外装フィルムから外部に引き出されたリード端子と、
最外層が前記外装フィルムの最内層と相溶性を有する熱接着性合成樹脂で構成されて、前記外装フィルムによるシール部に対応して設けられた積層状のリード端子用被覆フィルムとを備え、
前記リード端子を前記被覆フィルムを介して挟んだ状態で前記外装フィルムによるシール部がヒートシールで融着され、
前記リード端子用被覆フィルムにおける最外層の融点が前記外装フィルムの最内層の融点未満に設定されていることを特徴とする電気化学デバイス。 - 前記外装フィルムにおける最内層の融点と前記リード端子用被覆フィルムにおける最外層の融点との差が9℃以上である請求項1に記載の電気化学デバイス。
- 前記外装フィルムにおける最内層の融点が124℃以上である請求項1または2に記載の電気化学デバイス。
- 前記リード端子用被覆フィルムの厚みが、0.08~0.25mmである請求項1ないしは3のいずれか一つの項に記載の電気化学デバイス。
- リード端子用被覆フィルムにおける最外層の融点が168℃以下である請求項1ないしは4のいずれか一つの項に記載の電気化学デバイス。
- 前記外装フィルムにおける最内層と前記リード端子用被覆フィルムにおける最外層とが同系統の合成樹脂で構成されている請求項1ないしは5のいずれか一つの項に記載の電気化学デバイス。
- 前記外装フィルムにおける最内層と前記リード端子用被覆フィルムにおける最外層とは、オレフィン系の合成樹脂で構成されている請求項6に記載の電気化学デバイス。
- 前記リード端子の厚みが0.2~0.5mmである請求項1ないしは7のいずれか一つの項に記載の電気化学デバイス。
- 前記電気化学素子は、少なくとも正極、負極、および正負両極間に介在される電解質を含む電池用発電要素を備えたものである請求項1ないしは8のいずれか一つの項に記載の電気化学デバイス。
- 少なくとも最内層が熱接着性合成樹脂からなる積層状の外装フィルムと、電気化学素子と、リード端子と、最外層が前記外装フィルムの最内層と相溶性を有する熱接着性合成樹脂により構成され、かつその最外層の融点が前記外装フィルムの最内層の融点未満に設定された積層状のリード端子用被覆フィルムとを準備する工程と、
前記リード端子の一部を前記被覆フィルムにて被覆する工程と、
前記外装フィルムに、電気化学素子を収容する工程と、
前記リード端子をその外端部を前記外装フィルムから引き出した状態で内端部を前記電気化学素子に電気的に接続する工程と、
前記リード端子を部分的に被覆した前記被覆フィルムに、前記外装フィルムによるシール部をヒートシールにて融着する工程と、を含むことを特徴とする電気化学デバイスの製造方法。 - 前記外装フィルムにおけるシール部に対して、前記外装フィルムにおける最内層の融点よりも20℃以上の温度でヒートシールを施すようにした請求項10に記載の電気化学デバイスの製造方法。
- 前記外装フィルムにおけるシール部に対するヒートシール時間が、3~8secである請求項10または11に記載の電気化学デバイスの製造方法。
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- 2010-01-08 SG SG2011051612A patent/SG173025A1/en unknown
- 2010-01-08 WO PCT/JP2010/050129 patent/WO2010082532A1/ja active Application Filing
- 2010-01-08 US US13/144,127 patent/US20120082888A1/en not_active Abandoned
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Also Published As
Publication number | Publication date |
---|---|
CN102349174A (zh) | 2012-02-08 |
EP2383818A4 (en) | 2015-03-11 |
KR101280798B1 (ko) | 2013-07-05 |
EP2383818A1 (en) | 2011-11-02 |
KR20110105799A (ko) | 2011-09-27 |
US20120082888A1 (en) | 2012-04-05 |
JP2010165481A (ja) | 2010-07-29 |
JP5457040B2 (ja) | 2014-04-02 |
SG173025A1 (en) | 2011-08-29 |
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