WO2008105306A1 - コーティング組成物およびフォトクロミック光学品 - Google Patents

コーティング組成物およびフォトクロミック光学品 Download PDF

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Publication number
WO2008105306A1
WO2008105306A1 PCT/JP2008/052953 JP2008052953W WO2008105306A1 WO 2008105306 A1 WO2008105306 A1 WO 2008105306A1 JP 2008052953 W JP2008052953 W JP 2008052953W WO 2008105306 A1 WO2008105306 A1 WO 2008105306A1
Authority
WO
WIPO (PCT)
Prior art keywords
coating composition
mass
parts
organosilicon compound
silica fine
Prior art date
Application number
PCT/JP2008/052953
Other languages
English (en)
French (fr)
Inventor
Ikumi Kawaguchi
Hironobu Nagoh
Katsuhiro Mori
Original Assignee
Tokuyama Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokuyama Corporation filed Critical Tokuyama Corporation
Priority to JP2009501202A priority Critical patent/JP5247673B2/ja
Priority to CN2008800014312A priority patent/CN101578343B/zh
Priority to EP08720784A priority patent/EP2113542A4/en
Priority to AU2008220162A priority patent/AU2008220162B2/en
Priority to BRPI0806453-9A priority patent/BRPI0806453A2/pt
Priority to US12/519,113 priority patent/US8852737B2/en
Priority to MX2009006432A priority patent/MX2009006432A/es
Publication of WO2008105306A1 publication Critical patent/WO2008105306A1/ja

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/22Absorbing filters
    • G02B5/23Photochromic filters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/06Polysiloxanes containing silicon bound to oxygen-containing groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5435Silicon-containing compounds containing oxygen containing oxygen in a ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259Silicic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Optical Filters (AREA)
  • Eyeglasses (AREA)

Abstract

【課題】プラスチックレンズのような光学基材の表面に、高い密着性を有し、透明性及び耐擦傷性に優れたハードコート層を形成し得るコーティング組成物を提供する。 【解決手段】このコーティング組成物は、(a)30nm以下の粒径のシリカ微粒子;(b)エポキシ基含有有機ケイ素化合物(b1)とテトラアルコキシシラン(b2)とを、0.25乃至4.0の質量比(b1/b2)で含む有機ケイ素化合物成分;(c)水;及び(d)アルミニウムを中心金属とする錯体からなる硬化触媒;から成り、前記シリカ微粒子(a)と有機ケイ素化合物成分(b)との合計量を100質量部として、前記シリカ微粒子(a)を15乃至55質量部、前記水(c)を30乃至200質量部、及び前記硬化触媒(d)を0.1乃至5.0質量部の量で含有している。
PCT/JP2008/052953 2007-02-22 2008-02-21 コーティング組成物およびフォトクロミック光学品 WO2008105306A1 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2009501202A JP5247673B2 (ja) 2007-02-22 2008-02-21 コーティング組成物およびフォトクロミック光学品
CN2008800014312A CN101578343B (zh) 2007-02-22 2008-02-21 涂层组合物及光致变色光学品
EP08720784A EP2113542A4 (en) 2007-02-22 2008-02-21 COATING COMPOSITION AND PHOTOCHROMIC OPTICAL ARTICLE
AU2008220162A AU2008220162B2 (en) 2007-02-22 2008-02-21 Coating composition and photochromic optical article
BRPI0806453-9A BRPI0806453A2 (pt) 2007-02-22 2008-02-21 composição de revestimento, artigo óptico fotocrÈmico, e, método de produção do mesmo
US12/519,113 US8852737B2 (en) 2007-02-22 2008-02-21 Coating composition and photochromic optical article
MX2009006432A MX2009006432A (es) 2007-02-22 2008-02-21 Composicion de recubrimiento y articulo optico fotocromico.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007042007 2007-02-22
JP2007-042007 2007-02-22
JP2007-306243 2007-11-27
JP2007306243 2007-11-27

Publications (1)

Publication Number Publication Date
WO2008105306A1 true WO2008105306A1 (ja) 2008-09-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/052953 WO2008105306A1 (ja) 2007-02-22 2008-02-21 コーティング組成物およびフォトクロミック光学品

Country Status (9)

Country Link
US (1) US8852737B2 (ja)
EP (1) EP2113542A4 (ja)
JP (1) JP5247673B2 (ja)
CN (1) CN101578343B (ja)
AU (1) AU2008220162B2 (ja)
BR (1) BRPI0806453A2 (ja)
MX (1) MX2009006432A (ja)
SG (1) SG178745A1 (ja)
WO (1) WO2008105306A1 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009067754A (ja) * 2007-09-14 2009-04-02 Tokuyama Corp クロメン化合物
WO2010082566A1 (ja) * 2009-01-13 2010-07-22 株式会社トクヤマ コーティング組成物、該組成物の製造方法、およびハードコート層を有する積層体
WO2011055667A1 (ja) * 2009-11-06 2011-05-12 株式会社トクヤマ コーティング組成物および光学物品
JP2014161766A (ja) * 2013-02-22 2014-09-08 Asahi Glass Co Ltd 被膜付き基板の製造方法
JP2015137259A (ja) * 2014-01-23 2015-07-30 二朗 阿部 ベンゾクロメン化合物、フォトクロミック剤及びフォトクロミック光学材料
WO2015129312A1 (ja) * 2014-02-28 2015-09-03 富士フイルム株式会社 水性組成物、ハードコートフィルム、積層フィルム、透明導電性フィルム、およびタッチパネル
WO2015163467A1 (ja) * 2014-04-24 2015-10-29 ホヤ レンズ タイランド リミテッド 眼鏡レンズ
EP2423281A4 (en) * 2009-04-20 2017-01-25 Tokuyama Corporation Coating composition
WO2023145963A1 (ja) * 2022-01-31 2023-08-03 ホヤ レンズ タイランド リミテッド フォトクロミック化合物、フォトクロミック組成物、フォトクロミック物品及び眼鏡

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IT1402988B1 (it) * 2010-10-20 2013-09-27 Bridgestone Corp Metodo per la realizzazione di porzioni colorate su di un pneumatico
KR101336206B1 (ko) * 2012-05-07 2013-12-05 서울대학교산학협력단 능동형 인공 홍채 및 그 제조 방법
EP2938753B1 (en) * 2012-12-25 2019-02-27 Akzo Nobel Coatings International B.V. A coating composition, a preparation method therefore, and use thereof
CN103265884A (zh) * 2013-06-06 2013-08-28 苏州禾川化工新材料科技有限公司 一种镜片加硬增透液
TWI546559B (zh) * 2015-05-19 2016-08-21 長興材料工業股份有限公司 增光穿透塗料組合物及由其所形成之塗層
WO2017154515A1 (ja) * 2016-03-11 2017-09-14 パナソニックIpマネジメント株式会社 帯電防止材料、その製造方法および帯電防止膜
KR102198801B1 (ko) 2017-12-07 2021-01-05 삼성에스디아이 주식회사 색 변환 패널 및 색 변환 패널의 제조 방법
CN108641599A (zh) * 2018-05-14 2018-10-12 苏州东辉光学有限公司 一种光学保护漆
CN111647332A (zh) * 2019-03-04 2020-09-11 中核华兴达丰机械工程有限公司 一种塔机用水性漆及其制备方法
JP2021148814A (ja) * 2020-03-16 2021-09-27 株式会社トクヤマ フォトクロミック積層体、フォトクロミック硬化性組成物、および該組成物の製造方法

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MX2009006432A (es) 2009-07-03
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BRPI0806453A2 (pt) 2011-09-06

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