WO2006057331A1 - 熱可塑性重合体組成物 - Google Patents
熱可塑性重合体組成物 Download PDFInfo
- Publication number
- WO2006057331A1 WO2006057331A1 PCT/JP2005/021666 JP2005021666W WO2006057331A1 WO 2006057331 A1 WO2006057331 A1 WO 2006057331A1 JP 2005021666 W JP2005021666 W JP 2005021666W WO 2006057331 A1 WO2006057331 A1 WO 2006057331A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fluorine
- polymer composition
- thermoplastic polymer
- thermoplastic
- fluororubber
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 80
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 116
- 239000011737 fluorine Substances 0.000 claims abstract description 109
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 107
- 229920000642 polymer Polymers 0.000 claims abstract description 87
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- 239000003431 cross linking reagent Substances 0.000 claims abstract description 31
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- 239000010410 layer Substances 0.000 claims description 31
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- 239000005977 Ethylene Substances 0.000 claims description 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
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- 238000000034 method Methods 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 14
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- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 8
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- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
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- QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1386—Natural or synthetic rubber or rubber-like compound containing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
Definitions
- the present invention relates to a thermoplastic polymer composition that also has fluororesin and cross-linked fluororubber power, and a molded product, a sealing material, a fuel peripheral part, a fuel hose, and a fuel comprising the thermoplastic polymer composition. Concerning the container.
- Cross-linked rubber is widely used in the fields of automobile parts, household parts, electric wire coverings, medical parts and the like because of its excellent heat resistance, chemical resistance and flexibility.
- a crosslinked rubber for example, (1) a step of kneading uncrosslinked rubber with a crosslinking agent, an acid acceptor, a filler, etc., (2) an extruder or an injection molding machine. (3) It is generally a complicated process such as a step of crosslinking using a press or an oven, and it takes a long time to obtain a molded product.
- the crosslinked rubber does not melt after crosslinking, it cannot be post-processed such as fusing and cannot be recycled.
- thermoplastic resin composition in which crosslinked rubber particles are dispersed in a thermoplastic resin such as polypropylene-based resin
- the thermoplastic resin composition is a thermoplastic resin. It is said that it can be melt-molded and recycled, and is close to cross-linked rubber and can exhibit performance.
- dynamically crosslinked rubber include those having a structure in which crosslinked ethylene propylene rubber (EPDM) is dispersed in a polypropylene resin (for example, JP-A-6-287368, JP-A-6- No. 256571 or JP-A-11 228750) has been extensively studied, and some have been put into practical use.
- the TPV composed of the above-mentioned polypropylene-based resin and crosslinked EPDM has a heat resistance above the melting point of the polypropylene-based resin because the matrix is a polypropylene-based resin. In fact, it has no chemical resistance.
- a structure using a polyester-based resin or 4-methyl-1-pentene-based resin as a matrix and having a crosslinked rubber dispersed therein are known (for example, see JP-A-10-212392 and JP-A-11-269330).
- these TPVs have slightly improved heat resistance and chemical resistance compared to TPVs composed of polypropylene-based resin and cross-linked EPDM! There is a problem that it is inferior in performance and mechanical performance.
- TPVs having a structure in which a fluorinated rubber is used as a matrix and a crosslinked fluorinated rubber is dispersed as a crosslinked rubber have been studied (for example, Japanese Patent Laid-Open Nos. 61-57641 and 5-5). 140401 or JP-A-6-228397).
- TPV has excellent heat resistance and chemical resistance due to the fluorine resin of the matrix, it has poor physical properties such as flexibility and compression set due to non-uniform dispersion of the cross-linked fluororubber. In addition, it cannot be said that the molding strength is sufficient.
- An object of the present invention is to provide a thermoplastic polymer composition that has excellent heat resistance, chemical resistance, oil resistance, and fuel barrier properties, is flexible, and has excellent moldability. is there.
- the present invention provides a fluorine ⁇ (A) 10 to 95 weight 0/0 and crosslinked fluororubber (B) thermoplastic polymer composition comprising 90 to 5 wt%,
- Fluororesin (A) is composed of a fluorinated ethylenic polymer (a) having a melting point of 120 to 330 ° C, and the bridging fluororubber (B) is present in the presence of the fluororesin (A) and the crosslinking agent (C).
- the present invention also relates to a thermoplastic polymer composition obtained by dynamically crosslinking at least one fluororubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) under melting conditions.
- the melting point of the fluorinated ethylenic polymer (a) is preferably 150 to 310 ° C.
- CF CF-R 1 (1) (In the formula, R 1 represents —CF or —OR 2. R 2 represents 1 carbon atom.
- R 1 represents —CF or —OR 2.
- R 2 represents carbon number 1.
- the polymer is one or more polymers selected.
- the cross-linking agent (C) is preferably at least one selected from the group consisting of organic peroxides, polyamine compounds, and polyhydroxy compounds.
- the fluorine resin (A) forms a continuous phase and the crosslinked fluororubber (B) forms a dispersed phase.
- the average dispersed particle diameter of the crosslinked fluororubber (B) is preferably 0.01 to 30 / ⁇ ⁇ .
- the specific force of the melt viscosity of the fluorinated resin ( ⁇ ) and the fluorinated rubber (b-1) or the fluorinated thermoplastic elastomer (b-2) is 0.1 to 1.5.
- the melt flow rate of the thermoplastic polymer composition is preferably 1 to 30 gZlOmin.
- the fuel permeability of the thermoplastic polymer composition is preferably 0.1 to 20 g'mm / m 2 'day.
- the present invention also relates to a molded article, a sealing material, a fuel peripheral part, a single-layer fuel hose, and a single-layer fuel container comprising the thermoplastic polymer composition.
- the present invention relates to a multilayer fuel hose or multilayer fuel container including a layer comprising the thermoplastic polymer composition.
- thermoplastic polymer composition that is also powerful
- Fluororesin (A) is composed of a fluorinated ethylenic polymer (a) having a melting point of 120 to 330 ° C, and the bridging fluororubber (B) is present in the presence of the fluororesin (A) and the crosslinking agent (C).
- the present invention also relates to a thermoplastic polymer composition obtained by dynamically crosslinking at least one fluororubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) under melting conditions.
- Fluorine resin (A) is not particularly limited, and at least one fluorine-containing ethylene polymer (a) Fluorine-containing ethylenic polymer (a) may be used as long as it also has a fluorinated resin. a) may have any structural unit derived from at least one fluorine-containing ethylenic monomer. Examples of the fluorine-containing ethylenic monomer include tetrafluoroethylene, general formula (1):
- R 1 is —CF or —OR 2
- R 2 is a perfluoroalkyl having 3 to 5 carbon atoms, f 3 ff
- Perfluoroethylenically unsaturated compounds such as perfluoroethylenically unsaturated compounds represented by the following formulas), chlorofluoroethylene, trifluoroethylene, hexafluoroisobutene, bi-lidene fluoride, fluoride Bulle, general formula (2):
- X 1 is a hydrogen atom or a fluorine atom
- X 2 is a hydrogen atom, a fluorine atom or a chlorine atom
- n is an integer of 1 to 10
- the fluorine-containing ethylenic polymer (a) may have a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer.
- Non-fluorinated ethylenic monomers other than the above-mentioned fluororefin and perfluororefin can be mentioned.
- Examples of the non-fluorinated ethylenic monomer include ethylene, propylene, and alkyl butyl ethers.
- the alkyl bulle ether is an alkyl bur ether having an alkyl group having 1 to 5 carbon atoms.
- the fluorine-containing ethylenic polymer (a) is preferable because the thermoplastic polymer composition obtained has excellent heat resistance, chemical resistance, oil resistance, and ease of molding processability.
- R 1 is —CF or OR 2
- R 2 is a perfluoroalkyl having 3 to 5 carbon atoms, f 3 ff
- Tetrafluoroethylene perfluoro (alkyl butyl ether) copolymer (PFA) or tetrafluoroethylene monohexafluoropropylene copolymer (FEP) composed of perfluoroethylenically unsaturated compounds represented by
- R 1 is —CF or OR 2
- R 2 is a perfluoroalkyl having 3 to 5 carbon atoms, f 3 ff
- Ethylene-tetrafluoroethylene monohexafluoropropylene copolymer consisting of perfluoroethylenically unsaturated compounds represented by
- PVDF Polyvinylidene fluoride
- the molar ratio of the tetrafluoroethylene unit to the ethylene unit is preferably 20:80 to 90: 1, more preferably 62:38 to 90:10, and particularly preferably 63:37 to 80:20. better ⁇ 0
- the type is not limited as long as tetrafluoropropoxy O b ethylene and E Ji Ren and copolymerizable as Yogu third component also contain a third component.
- the third component is usually T3 self
- R 3 monomers having 1 to 8 carbon atoms are particularly preferred.
- the content of the third component is 0. 1 to the fluorine-containing ethylenic polymer (a): L0 mol% are preferred, 0.1 to 5 mole 0/0, more preferably tool 0. 2 to 4 mol 0/0 are particularly preferred.
- Tetorafu Ruoroechiren units 90 to 99 mole 0/0 and it is the general formula (1) is also par full O b ethylenically unsaturated compound unit 1 to 10 mol% Ca represented by fluorine-containing ethylenic polymer (a) Is more preferable.
- the fluorine-containing ethylenic polymer (a) having tetrafluoroethylene and the perfluoroethylenically unsaturated compound represented by the general formula (1) may contain a third component. As long as it is copolymerizable with tetrafluoroethylene and the perfluoroethylenically unsaturated compound represented by the formula (1), the kind thereof is not limited.
- Et-TFE-HFP copolymer is preferable in terms of low fuel permeability and flexibility in addition to the above-described effects.
- Tetrafluoropropoxy O b ethylene units 19-90 mole 0/0, ethylene units of 9-80 mole 0/0, and PA full O b ethylenically unsaturated compound unit 1-72 mole represented by the general formula (1) % force becomes the fluorine-containing ethylenic polymer, more preferably from (a), more preferably tetrafluoropropoxy O b ethylene units 20 to 70 mole 0/0, an ethylene unit of 20 to 60 mol%, and the general formula (1) is in represented by Per full O b ethylenically unsaturated compound unit through 603 mole 0/0 force becomes the fluorine-containing ethylenic polymer (a).
- the fluorine-containing ethylenic polymer (a) having the power of tetrafluoroethylene, ethylene and the perfluoroethylenically unsaturated compound represented by the general formula (1) may contain an additional component.
- the content of the additional component is preferably 0.1 to 3 mol% with respect to the fluorine-containing ethylenic polymer (a).
- the melting point of the fluorine-containing ethylenic polymer (a) is 120 to 330 ° C, preferably 150 to 310 ° C, more preferably 150 to 290 ° C. It is more preferably 170 to 250 ° C.
- the melting point power of the fluorine-containing ethylenic polymer (a) is less than 120 ° C, the heat resistance of the resulting thermoplastic polymer composition tends to decrease, and when it exceeds 330 ° C, ) And a crosslinking agent (C), in the case where the fluororubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2) is dynamically crosslinked under melting conditions, the fluorine-containing ethylenic polymer ( Although it is necessary to set the melting temperature above the melting point of a), the fluororubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2) may be thermally deteriorated.
- cross-linked fluororubber (B) used in the present invention at least one fluororubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) is dynamically added under melting conditions. If it is cross-linked, it is not particularly limited! /.
- Examples of the fluororubber (b-1) include perfluorofluororubber and non-perfluorofluororubber.
- Perfluorofluororubber includes tetrafluoroethylene (hereinafter referred to as TFE) Z perfluoro (alkyl butyl ether) (hereinafter referred to as PAVE) copolymer, TFEZ hexafluoropropylene. (Hereinafter referred to as HFP) ZPAVE copolymer and the like.
- TFE tetrafluoroethylene
- PAVE alkyl butyl ether
- HFP TFEZ hexafluoropropylene
- non-perfluorofluororubber examples include bi-lidene fluoride (hereinafter referred to as VdF) polymer, TFEZ propylene copolymer, and the like. It can be used in any combination within the range without impairing the effects of the invention. wear.
- VdF bi-lidene fluoride
- TFEZ propylene copolymer examples include TFEZ propylene copolymer, and the like. It can be used in any combination within the range without impairing the effects of the invention. wear.
- those exemplified as the perfluoro fluorororubber and the non-perfluorofluorororubber have a constitution of a main monomer, and those obtained by copolymerizing a crosslinking monomer, a modified monomer, etc. can be suitably used.
- a crosslinking monomer or the modifying monomer a known crosslinking monomer such as an iodine atom, bromine atom or double bond-containing monomer, a transfer agent, a modified monomer such as a known ethylenically unsaturated compound, or the like can be used. .
- VdF polymer examples include a VdFZHFP copolymer, a VdF / TFE ZHFP copolymer, a VdFZTFEZ propylene copolymer, a VdFZ ethylene ZHFP copolymer, and a VdFZTFEZPAVE copolymer.
- VdFZPAVE copolymer examples include VdFZPAVE copolymer, VdF Z chlorofluoroethylene (hereinafter referred to as CTFE) copolymer, and the like.
- a fluorine-containing copolymer having a strength of 25 to 85 mol% of VdF and 75 to 15 mol% of at least one other monomer copolymerizable with VdF is more preferable to use.
- At least one other monomer copolymerizable with VdF for example, TFE, CTFE, trifluoroethylene, HFP, trifluoropropylene, tetrafluoropropylene, penta
- fluorine-containing monomers such as fluoropropylene, trifluorobutene, tetrafluoroisobutene, PAVE, and fluorinated butyl
- non-fluorine monomers such as ethylene, propylene, and alkyl butyl ether.
- fluororubber from the viewpoint of heat resistance, compression set, workability, and cost, it is preferable to use a fluororubber containing VdF units. From the viewpoint of good compression set, VdF units and HFP More preferred is a fluororubber having a unit.
- the rubber is at least one rubber selected from the group consisting of VdFZHFP-based fluororubber, VdFZTFEZHFP-based fluororubber, and TFEZ propylene-based fluororubber power.
- V dFZTFEZHFP-based fluororubber is more preferable. .
- the fluorine-containing thermoplastic elastomer (b-2) includes at least one elastomeric polymer segment (S1) and at least one non-elastomeric polymer segment (S2).
- the elastomeric polymer segment (S1) and the non-elastomeric polymer segment (S2) are not particularly limited as long as they are compatible with the fluororesin (A).
- at least one is preferably a fluorine-containing polymer segment, and both of them are preferably fluorine-containing polymer segments.
- improvement of the moldability of the thermoplastic polymer composition of the present invention can be expected, and the molded product obtained therefrom can be expected to have excellent tensile breaking strength and tensile breaking elongation.
- the elastomeric polymer segment (S1) imparts flexibility to the polymer and has a glass transition point of S25 ° C or lower, preferably 0 ° C or lower.
- R 4 has 1 carbon
- a perfluoroalkyl group such as perfluorobule ether represented by f to 5 perfluoroalkyl group, p is an integer of 0 to 5 and q is an integer of 0 to 5; -Fluorine-containing monomers such as redenefluoride, trifluoroethylene, trifluoropropylene, tetrafluoropropylene, pentafluoropropylene, triphenololeobutene, tetrafluoroisobutene, fluorinated butyl; ethylene, propylene, Examples thereof include non-fluorine monomers such as alkyl butyl ether.
- Examples of monomers that give a crosslinking site include, for example, the general formula (4):
- R 5 is a fluoroalkylene group
- R 1 is a hydrogen atom or CH
- X 6 is an iodine atom or a bromine atom), an iodine or bromine-containing monomer represented by the general formula (5):
- n is an integer of 1 to 3
- X 7 is a cyano group, a carboxyl group, an alkoxycarbonyl group, or a bromine atom
- X 9 is a hydrogen atom or a fluorine atom, s is an integer of 1 to 10
- non-fluorine monomers such as butyl ether, carboxylic acid butyl ester and acrylic acid.
- the elastomeric polymer segment (S1) is a copolymer of tetrafluoroethylene, bi-lidene fluoride, and hexafluoropropylene, and is a powerful non-elastomer polymer.
- the fluorine-containing thermoplastic elastomer (b-2) contains an elastomeric polymer segment (S1) and a non-elastomeric polymer segment (S2) in the form of a block graft in one molecule. It is important that the polymer is a fluorine multi-segmented polymer, and the fluorine-containing thermoplastic elastomer (b-2)
- a triblock polymer consisting of one elastomeric polymer segment (S1) and two non-elastomeric polymer segments (S2), at least one of which is a fluoropolymer segment It is more preferable to be powerful
- the fluorine-containing thermoplastic elastomer (b-2) As the fluorine-containing thermoplastic elastomer (b-2), the elastomeric polymer segment (S1) and the non-elastomeric polymer segment (S2) are connected in the form of a block graft or the like.
- Various known methods for forming segmented polymers can be used. Among them, the method for producing block type fluorine-containing multi-segmented polymers described in JP-B-58-4728 and the like, and JP-A-62-34324
- the method of producing a graft-type fluorine-containing multi-segmented polymer disclosed in Japanese Patent Publication No. 1 can be preferably used.
- a preferred production method of the fluorine-containing thermoplastic elastomer (b-2) is a known iodine transfer polymerization method as a production method of the fluororubber.
- the perhaloolefin and, if necessary, a monomer that provides a curing site are stirred under pressure in an aqueous medium in the presence of an iodine compound, preferably a diiodine compound, in a substantially oxygen-free manner.
- an iodine compound preferably a diiodine compound
- diiodine compounds used include, for example, the general formula (8)
- R 2 is a saturated or unsaturated fluorohydrocarbon group having 1 to 16 carbon atoms.
- R 2 is a chlorofluoro hydrocarbon group or a hydrocarbon group having 1 to 3 carbon atoms, which contains an oxygen atom, and is obtained by the presence of a compound represented by Introduced in this way Iodine or bromine functions as a crosslinking point.
- Examples of the compound represented by the general formula (8) include 1,3 jodo perfluoropropan, 1,3 jodo 2 black mouth perfluoropropane, 1,4 jodo perfluoro Butane, 1, 5 Jodo 2, 4 Dichro mouth perfluoropentane, 1, 6 Jodhpur fluor mouth hexane, 1, 8 Jodh per fluoroctane, 1, 12 Jodh per fluor decane, 1, 16 Jodh per ful Hexadecane, Jodomethane, 1, 2 Jodoethane, 1, 3 Jodo, n-propane, CF Br, BrCF CF Br ⁇ CF CFBrCF
- the radical polymerization initiator used in the present invention may be the same as that conventionally used for the polymerization of a fluorine-containing elastomer.
- These initiators include organic and inorganic peroxides and azo compounds.
- Typical initiators include persulfates, peroxidative power carbonates, peroxyesters, and the like.
- Preferred initiators include ammonium persulfate (APS). APS can be used alone or in combination with a reducing agent such as sulfite or sulfite.
- a wide range of emulsifiers can be used for the emulsion polymerization. From the viewpoint of suppressing the chain transfer reaction to the emulsifier molecule that occurs during the polymerization, a fluorocarbon chain or a fluoropolyether chain is used. Desirable salts of carboxylic acids.
- the amount of emulsifier used is preferably about 0.05 to 2% by weight of the added water, and more preferably 0.2 to 1.5% by weight.
- the polymerization pressure can be varied within a wide range. Generally, it is in the range of 0.5-5 MPa. The higher the polymerization pressure, the higher the polymerization rate. Therefore, from the viewpoint of improving productivity, the polymerization pressure is preferably 0.8 MPa or more.
- the elastomeric polymer segment (S1) of the fluorine-containing thermoplastic elastomer (b-2) is produced by the iodine transfer polymerization method, the number-average molecular weight of the fluorine-containing multi-segmented polymer is obtained as a whole. From the viewpoint of imparting flexibility, imparting elasticity, and imparting mechanical properties, a force S of 3,000 to 750,000 is preferable, and a force S of 5,000 to 300,000 is preferable.
- the terminal part of the elastomeric polymer segment (S1) obtained in this way has a permeation type, and the iodine atom that is the starting point for block copolymerization of the non-elastomeric polymer segment (S2) is determined. Have.
- the block copolymerization of the non-elastomeric polymer segment (S2) to the elastomeric polymer segment (S1) continues with the emulsion polymerization of the elastomeric polymer segment (S1). This can be done by changing the monomer for the non-elastomeric polymer segment (S2).
- the number average molecular weight of the non-elastomeric polymer segment (S2) is determined from the viewpoint of imparting heat resistance and mechanical properties to the thermoplastic polymer composition of the present invention. , 000 force is better than a child, ⁇ is 3,000 to 600,000.
- the non-elastomer polymer segment (S2) is bonded to the fluorine-containing thermoplastic elastomer (b-2), and the polymer molecule of only the elastomer polymer segment (S1) is It is preferably 20% by weight or less, more preferably 10% by weight or less, based on the total amount of segments and polymer molecules in the fluorine-containing thermoplastic elastomer (b-2).
- Fluoro rubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) force in view of the possibility of cross-linking using organic peroxides. Iodine atom or bromine atom in the molecule It is preferable to have
- the weight ratio of the fluorine resin (A) to the fluorine rubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) added to the fluorine resin (A) is 10Z90. It is in the range of ⁇ 95Z5, more preferably in the range of 20 ⁇ 80 to 80 ⁇ 20. Weight of fluororubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) added to fluorocarbon resin (b) If the ratio is less than 5% by weight, the flexibility of the resulting thermoplastic polymer composition tends to be reduced, and if it exceeds 90% by weight, the fluidity of the resulting thermoplastic polymer composition is poor. However, molding processability tends to be reduced.
- the thermoplastic polymer composition of the present invention comprises at least one fluororubber (b-1) or a fluorine-containing thermoplastic elastomer (b) in the presence of a fluorocarbon resin (A) and a crosslinking agent (C). — Obtained by dynamically crosslinking 2) under melting conditions.
- the dynamic cross-linking treatment means that the fluororubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2) is used by using a bunnery mixer, a pressure-feeder, an extruder or the like. Is dynamically cross-linked simultaneously with melt kneading.
- an extruder such as a twin screw extruder is preferable because a high shear force can be applied.
- an extruder such as a twin screw extruder is preferable because a high shear force can be applied.
- dynamically crosslinking the phase structure of the fluorocarbon resin (A) and the crosslinked fluororubber (B) can be controlled.
- the crosslinking agent (C) can be appropriately selected depending on the type of the fluororubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2) and the melt-kneading conditions.
- the cross-linking system used in the present invention is a type of cure site when the fluoro rubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2) contains a crosslinkable group (cure site). Therefore, it may be appropriately selected depending on the use of the obtained molded article or the like.
- the crosslinking system any of a polyol crosslinking system, an organic peroxide crosslinking system, and a polyamine crosslinking system can be employed.
- Crosslinking by polyamine crosslinking has a carbon-nitrogen double bond at the crosslinking point and is characterized by excellent dynamic mechanical properties.
- crosslinking using a polyol crosslinking system or an organic peroxide crosslinking system crosslinking agent There is a tendency for permanent set to increase.
- a polyol crosslinking type or organic peroxide crosslinking type crosslinking agent it is preferable to use a polyol crosslinking type or organic peroxide crosslinking type crosslinking agent.
- a polyol crosslinking type crosslinking agent is used because of its excellent sealing properties. More preferred ,.
- crosslinking agent in the present invention polyamine-based, polyol-based, and organic peroxide-based crosslinking agents can be used.
- polyamine crosslinking agent examples include hexamethylenediamine amine carbamate, N, N, monocincinamylidene 1, 6 hexamethylenediamine, 4, 4'-bis (aminocyclohexenole) methane power rubamate And polyamine compounds.
- N, N'-dicinnamylidene 1, 6 hexamethylenediamine is preferred!
- the polyol cross-linking agent a compound conventionally known as a fluororubber cross-linking agent can be used.
- a polyhydroxy compound particularly, a polyhydroxy aromatic compound having excellent heat resistance.
- a compound is preferably used.
- the polyhydroxy aromatic compound is not particularly limited.
- 2, 2 bis (4 hydroxyphenol) propane hereinafter referred to as bisphenol A
- Perfluoropropane hereinafter referred to as bisphenol AF
- resorcinol 1,3 dihydroxybenzene, 1,7 dihydroxynaphthalene, 2,7 dihydroxynaphthalene, 1,6 dihydroxynaphthalene, 4,4, -dihydroxydiphenol Ninole, 4, 4, 1-dihydroxystilbene, 2, 6 dihydroxyanthracene, hydroquinone, catechol, 2, 2-bis (4-hydroxyphenol) butane (hereinafter referred to as bisphenol B), 4, 4-bis (4-hydroxyphenol) valeric acid, 2,2 bis (4hydroxyphenyl) tetrafluorodioxypropane, 4,4, -dihydroxy Diphenylenoleshonone, 4, 4, Dihydroxydiphenyl ketone, Tri (4-hydroxyphenol) methane, 3, 3
- the organic peroxide cross-linking agent may be an organic peroxide compound that can easily generate a peroxide radical in the presence of heat or a redox system.
- organic peroxide compound that can easily generate a peroxide radical in the presence of heat or a redox system.
- the heat resistance that is preferred by the polyhydroxy compound is excellent from the viewpoint of excellent molding properties, such as a molded article that has a small compression set and good moldability.
- Bisphenol AF which is more preferred for polyhydroxy aromatic compounds, is more preferred.
- a crosslinking accelerator is usually used in combination with the polyol crosslinking agent.
- the crosslinking reaction can be promoted by promoting the formation of an intramolecular double bond in the dehydrofluorination reaction of the fluororubber main chain.
- an oxime compound is generally used as the crosslinking accelerator for the polyol crosslinking system.
- the onium compound is not particularly limited, and examples thereof include an ammonium compound such as a quaternary ammonium salt, a phosphonium compound such as a quaternary phosphonium salt, an oxonium compound, a sulfoneum compound, a cyclic amine, Examples include monofunctional amine compounds, among which quaternary ammonium salts and quaternary phosphonium salts are preferred.
- the quaternary ammonium salt is not particularly limited.
- 8-methyl-1,8 diazabicyclo [5, 4, 0] -7 undecese-um chloride 8-methyl-1,8 diazabicyclo [ 5, 4, 0] — 7 Hundestheum iodide
- 8—Methyl-1,8 diazabicyclo [5, 4, 0] —7 Hundesse-um hydroxide 8-methyl 1,8 diazabicyclo [5,
- the quaternary phospho-um salt is not particularly limited, and examples thereof include tetrabutyl phospho-um chloride, benzyl triphenyl phospho-um chloride (hereinafter referred to as BTPPC), benzyl trimethyl phospho-um chloride, Examples thereof include benzyltributylphosphomethylene chloride, tributylarylphosphonium chloride, tributyl-2-methoxypropylphosphonium chloride, and benzylphenol (dimethylamino) phosphonium chloride.
- BTPPC benzyltriphenylphospho-muchloride
- a crosslinking accelerator a quaternary ammonium salt, a solid solution of a quaternary phosphonium salt and bisphenol AF, a chlorine-free crosslinking disclosed in JP-A-11-147891 Accelerators can also be used.
- organic peroxide crosslinking accelerator examples include triallyl cyanurate, triallyl isocyanurate (TAIC), triacryl formal, triallyl trimellitate, N, N'm-phenol bismaleimide, di-acid.
- the amount of the crosslinking agent (C) is 0.1 to 10 parts by weight with respect to 100 parts by weight of the fluororubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2). Is more preferably 0.3 to 5 parts by weight.
- the crosslinking agent (C) is less than 0.1 part by weight, the crosslinking of the fluororubber (b 1) or the fluorine-containing thermoplastic elastomer (b-2) does not proceed sufficiently and the resulting thermoplastic weight
- the heat resistance and oil resistance of the coalesced composition tend to be reduced, and if it exceeds 10 parts by weight, the molding processability of the resulting thermoplastic polymer composition tends to be lowered.
- the melting condition means a temperature at which the fluororesin (A), the fluororubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2) is melted.
- the melting temperature depends on the glass transition temperature and Z or melting point of fluorine resin (A) and fluororubber (b-1) or fluorine-containing thermoplastic elastomer (b-2). It is preferable that the temperature is 130 to 320 ° C.
- the temperature is lower than 120 ° C, the dispersion between the fluorocarbon resin (A) and the fluororubber (b-1) or the fluorine-containing thermoplastic elastomer (b-2) tends to be coarsened. Above 330 ° C, fluororubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) tends to thermally deteriorate.
- the obtained thermoplastic polymer composition has a structure in which the fluorine resin (A) forms a continuous phase and the crosslinked fluorine rubber (B) forms a dispersed phase, or the fluorine resin (A). And the cross-linked fluororubber (B) can form a co-continuous structure. Among them, the fluorocarbon resin (A) forms a continuous phase and the cross-linked fluororubber (B) forms a dispersed phase. It is preferable to have a structure.
- Fluoro rubber (b-1) or fluorinated thermoplastic elastomer (b-2) force Even when the initial dispersion matrix was formed, the fluororubber (b-1) or When the fluorine-containing thermoplastic elastomer (b-2) becomes a crosslinked fluororubber (B), the melt viscosity increases, and the crosslinked fluororubber (B) becomes a dispersed phase, or with the fluororesin (A). It forms a co-continuous phase.
- thermoplastic polymer composition of the present invention has excellent heat resistance, In addition to showing chemical resistance and oil resistance, it has good moldability. that time
- the average dispersed particle size of the crosslinked fluororubber (B) is preferably 0.01 to 30 / ⁇ ⁇ , more preferably 0.1 to LO m. If the average dispersed particle size is less than 0.01 m, the fluidity tends to decrease, and if it exceeds 30 m, the strength of the resulting thermoplastic polymer composition tends to decrease.
- the average dispersed particle size of the cross-linked fluororubber (B) in the thermoplastic polymer composition of the present invention can be confirmed by using any one of AFM, SEM, TEM, or a combination thereof.
- AFM the difference in surface information between the continuous phase fluorocarbon resin (A) and the dispersed phase bridge fluororubber (B) is obtained as a light / dark image, and the light / dark is divided into gradations. This makes binary values possible.
- the binarization position is the central level that is divided into gradations, whereby an image with a clear contrast is obtained, and the crosslinked rubber particle diameter of the dispersed phase can be read.
- the image should be emphasized so that the cross-linked fluororubber (B) in the dispersed phase is clear from the image obtained by the backscattered electron image, or the brightness or darkness adjustment or both adjustments should be applied to the image.
- the crosslinked rubber particle diameter of the dispersed phase can be read.
- the cross-linked rubber particle size of the dispersed phase can be read as in AFM and SEM by adjusting the contrast of the image obtained and / or adjusting the contrast of the image as in SEM. These may be selected more easily for each thermoplastic polymer composition.
- the thermoplastic polymer composition of the present invention has a ratio of melt viscosity of fluorine resin (A) and fluorine rubber (b-1) or fluorine-containing thermoplastic elastomer (b-2) ( [Melting viscosity of rosin (A)] Z [Melt viscosity of rubber (b-1) or elastomer (b-2)]) Force 0.1 to 1.5 Is 0.2 to 1.2, particularly preferably 0.3 to 1.1. Even if the ratio of the melt viscosity is less than 0.1 or more than 1.5, the average dispersed particle size of the crosslinked fluororubber (B) tends to become coarse and the dispersion becomes nonuniform.
- melt viscosity of the fluorinated resin (A) to the fluorinated rubber (b-1) or the fluorinated thermoplastic elastomer (b-2) is 0.1 to 1.5, the crosslinked fluorinated rubber Since the average dispersed particle size of (B) is reduced and the dispersion becomes uniform, a thermoplastic polymer composition excellent in flexibility, compression set and molding processability can be obtained.
- melt viscosity is 297 ° C under the condition of 5000g load. The measured melt flow rate value.
- thermoplastic polymer composition of the present invention is preferred! /,
- the form of fluororesin (A) forms a continuous phase
- the crosslinked fluororubber (B) forms a dispersed phase. It is also possible to include a co-continuous structure of fluorine resin (A) and cross-linked fluororubber (B) as part of the structure.
- thermoplastic polymer composition of the present invention fluorine ⁇ (A) 10 to 95 wt%, crosslinking fluorororubber (B) 90 to 5 is made of weight 0/0 force, fluorine ⁇ (A ) 20-80 0/0, crosslinked fluorine rubber (B) 80 to 20 is preferably a weight 0/0 device fluorine ⁇ (a) 30 to 70 weight 0/0, cross-linking the fluororubber (B ) 70-30 and more preferably by weight 0/0. If the fluororesin (A) is less than 10% by weight, the flowability of the resulting thermoplastic polymer composition tends to deteriorate and the molding processability tends to deteriorate. The flexibility of the plastic polymer composition tends to decrease.
- the melt flow rate (MFR) of the thermoplastic polymer composition of the present invention is preferably 0.5 to 30 gZlO min, more preferably 1 to 25 gZlO min.
- MFR was measured using a melt flow rate measuring device manufactured by Toyo Seiki Seisakusho under the conditions of 297 ° C. and 50 OOg load.
- the thermoplastic polymer composition of the present invention preferably has a fuel permeability of 0.1 to 20 g'mmZm 2 'day in consideration of use in fuel peripheral parts. more preferably 2 ⁇ 18g'm mZm 2 'day.
- thermoplastic polymer composition of the present invention includes other polymers such as polyethylene, polypropylene, polyamide, polyester and polyurethane, calcium carbonate, talc, clay, titanium oxide, carbon black, barium sulfate and the like.
- the thermoplastic polymer composition of the present invention comprises a general molding processing method and molding processing apparatus. Can be used for molding.
- the molding method for example, any method such as injection molding, extrusion molding, compression molding, blow molding, calender molding, vacuum molding and the like can be adopted, and the thermoplastic polymer composition of the present invention is intended for use. Depending on the shape, it is formed into a compact of any shape.
- the present invention includes a force relating to a molded article obtained by using the thermoplastic polymer composition of the present invention.
- the molded article includes a molded article of a sheet or a film, and It includes a laminated structure having a layer made of the thermoplastic polymer composition of the present invention and a layer made of another material.
- the other material is expected to have the required properties. What is necessary is just to select an appropriate thing according to a use.
- the other material examples include polyolefin (eg, high density polyethylene, medium density polyethylene, low density polyethylene, linear low density polyethylene, ethylene propylene copolymer, polypropylene, etc.), nylon, polyester, salt Thermoplastic polymers such as bur resin (PVC) and salt vinylidene resin (PVDC), crosslinked rubber such as ethylene-propylene-gen rubber, butyl rubber, nitrile rubber, silicone rubber, acrylic rubber, metal, glass, wood, For example, ceramic.
- polyolefin eg, high density polyethylene, medium density polyethylene, low density polyethylene, linear low density polyethylene, ethylene propylene copolymer, polypropylene, etc.
- nylon polyester
- Thermoplastic polymers such as bur resin (PVC) and salt vinylidene resin (PVDC)
- crosslinked rubber such as ethylene-propylene-gen rubber, butyl rubber, nitrile rubber, silicone rubber, acrylic rubber, metal, glass, wood, For example, ceramic
- an adhesive layer may be interposed between the layer made of the thermoplastic polymer composition of the present invention and the base material layer made of another material! .
- the adhesive used in the adhesive layer includes an acid anhydride modified product of a gen-based polymer; an acid anhydride modified product of polyolefin; a polymer polyol (for example, a glycol or a mixture of glycols such as ethylene glycol and propylene glycol).
- a known method such as coextrusion, co-injection, or extrusion coating can be used.
- the present invention includes a fuel hose or a fuel container comprising a single layer of the thermoplastic polymer composition of the present invention.
- the use of the fuel hose is not particularly limited, and examples thereof include a filler hose for automobiles, an evaporation hose, and a breather hose.
- the use of the fuel container is not particularly limited, and examples thereof include a fuel container for an automobile, a fuel container for a motorcycle, a fuel container for a small generator, and a fuel container for a lawn mower.
- the present invention includes a multilayer fuel hose or a multilayer fuel container including a layer comprising the thermoplastic polymer composition of the present invention.
- the multi-layer fuel hose or multi-layer fuel container comprises a layer made of the thermoplastic polymer composition of the present invention and at least one layer made of another material, and these layers do not interpose an adhesive layer. In other words, they are bonded to each other with or between them.
- Examples of other material strength layers include layers made of rubber other than the thermoplastic polymer composition of the present invention and layers made of thermoplastic resin.
- the rubber may be acrylonitrile-butadiene rubber or hydrogenated rubber thereof, acrylonitrile-butadiene rubber and polyvinyl chloride-polyethylene rubber, fluoro rubber, epoxy Chlorohydrin rubber and acrylic rubber selected from the group consisting of at least one kind of rubber.
- Acrylonitrile butadiene rubber or its hydrogenated rubber, rubber blended with acrylonitrile-butadiene rubber and polysilene rubber, and fluorine rubber are preferred. More preferably, it also has at least one rubber force selected from the group that also has strength.
- thermoplastic resin from the viewpoint of fuel barrier properties, fluorine resin, polyamide-based resin, polyolefin resin, polyester-based resin, polybulualcohol-based resin, polysalt resin At least selected from the group consisting of bulle-based greaves and poly-ferresulfide-based greaves
- thermoplastic resin consisting of at least one selected from the group consisting of a fluoro resin, a polyamide-based resin, a polybulal alcohol-based resin, a poly-phenylene sulfide-based resin, and a thermoplastic resin that has one kind of strength. I like it.
- thermoplastic polymer composition obtained by the present invention shown above, and others there are no particular limitations on the fuel hose or fuel container comprising a layer of rubber or other thermoplastic resin, such as a fuel hose such as a filler hose for automobiles, an evaporative hose, or a breather hose; a fuel for automobiles Examples include containers, motorcycle fuel containers, small generator fuel containers, and lawn mower fuel containers.
- a fuel hose such as a filler hose for automobiles, an evaporative hose, or a breather hose
- a fuel for automobiles Examples include containers, motorcycle fuel containers, small generator fuel containers, and lawn mower fuel containers.
- a fuel hose comprising a layer made of the thermoplastic polymer composition of the present invention and a layer made of other rubber includes acrylonitrile monobutadiene rubber or hydrogenated rubber thereof or acrylonitrile monobutadiene rubber and polyhedron.
- a fuel hose composed of two layers, an outer layer that also has a rubber strength and an inner layer made of the thermoplastic polymer composition of the present invention, has excellent fuel barrier properties. 'Flexible' is preferable in view of chemical resistance.
- thermoplastic polymer composition of the present invention and the molded article made of the composition can be suitably used in the following fields.
- semiconductor-related fields such as semiconductor manufacturing equipment, liquid crystal panel manufacturing equipment, plasma panel manufacturing equipment, plasma addressed liquid crystal panels, field emission display panels, solar cell substrates, o (square) rings, packings, sealing materials, tubes Rolls, coatings, linings, gaskets, diaphragms, hoses, etc., which are CVD equipment, dry etching equipment, wet etching equipment, oxidation diffusion equipment, sputtering equipment, ashing equipment, cleaning equipment, ion implantation equipment, exhaust equipment It can be used for chemical piping and gas piping.
- a gate valve O-ring and seal material as a quartz window O-ring and seal material, as a chamber O-ring and seal material, as a gate O-ring and as a seal material, a bell jar O-ring and seal Coupling O-rings, seal materials, pump O-rings, sealing materials, diaphragms, semiconductor gas control device O-rings, sealing materials, resist developer, stripping solution O-rings
- a sealing material as a wafer cleaning solution hose, as a tube, as a wafer transfer roll, as a resist developer tank, as a coating for a stripping liquid tank, as a coating, as a coating, as a coating for a wafer cleaning liquid tank It can be used as a lining or coating, or as a lining or coating in a wet etching bath.
- sealing materials In addition, sealing materials' sealing agent, optical fiber quartz coating material, electronic parts for insulation, vibration proofing, waterproofing, moisture proofing, circuit board potting, coating, adhesive seals, gaskets for magnetic storage devices, It is used as a modifier for sealing materials such as epoxy, sealant for clean rooms and clean rooms.
- gaskets, shaft seals, valve stem seals, sealing materials and hoses can be used for engines and peripheral devices, and hoses and sealing materials can be used for AT devices. Rings, tubes, packings, valve cores, hoses, seals and diaphragms can be used in fuel systems and peripheral devices.
- On-seal, universal joint gasket, speedometer pinion seal, foot brake piston cup, torque transmission O-ring, oil seal, exhaust gas re-burning unit scenery, bearing Shinore, EGR tubes, twin key bush tube for sensors Daiafuramu carburetor, rubber vibration isolator (engine mount, exhaust part, etc.), afterburners hoses, can be used as an oxygen sensor bush.
- the printing field such as a printing machine
- the coating field such as a coating facility, rolls and the like
- a developing roll of a film developing machine / coiled film image forming machine a gravure roll of a printing roll, a guide roll, a gravure roll of a magnetic tape manufacturing coating line of a coating tool, and a magnetic tape manufacturing coating It can be used as a line guide roll, various coating rolls, and the like.
- dry copying machine seals printing equipment printing rolls, scrapers, tubes, valve parts, coating, coating equipment coating rolls, scrapers, tubes, valve parts, printer ink tubes, rolls, belts, dry copying machine belts It can be used as a roll, a roll for a printing press, a belt, or the like.
- the tube can also be used in the field of analysis and physics and chemistry.
- a sealing material between the electrode and the separator is used as a seal for hydrogen 'oxygen' product water piping.
- the molded article of the present invention can be suitably used for the various applications described above, and is particularly suitable as a fuel peripheral part.
- the molded article of the present invention is particularly useful as a sealing material, knock, roller, tube or hose.
- thermoplastic polymer composition produced in the examples and comparative examples, compression molding was carried out under the conditions of 260 ° C and 5 MPa with a hot press machine to produce sheet-like test pieces having a thickness of 2 mm.
- a hot press machine was used to measure the A hardness according to JIS-K6301.
- melt flow rate was measured under the conditions of a load of 297 ° C. and 5000 g using a melt point measuring device.
- thermoplastic polymer composition pellets produced in the examples and comparative examples compression molding was performed at 260 ° C and 5 MPa using a hot press machine, and sheet-like test pieces having a thickness of 2 mm and 0.7 mm were obtained. Produced. The sheet specimens are overlapped to form a cylindrical shape with a diameter of 29. Omm and a thickness of 12.7 mm, and left for 22 hours under conditions of a temperature of 150 ° C and a compression deformation of 25% according to JIS K6301 The compression set after the measurement was measured.
- the pellets of the thermoplastic polymer composition produced in the examples and comparative examples were compression-molded by a hot press machine at 260 ° C and 5 MPa, and a sheet-like specimen having a thickness of 2 mm was obtained.
- a dumbbell-shaped specimen having a thickness of 2 mm and a width of 5 mm was punched out.
- the obtained dumbbell-shaped test piece using an autograph (manufactured by Shimadzu Corporation), the tensile breaking strength and tensile strength at 23 ° C under the condition of 50 mmZ according to JIS-K6301 The elongation at break was measured.
- Tetrafluoroethylene Ratio of tetrafluoroethylene to ethylene in the ethylene copolymer segment 50: 50 mol%
- VdF Bi-Ridene Fluoride
- TFE Tetrafluoroethylene
- HFP Hexafluoro-Propylene
- VdF: TFE: HFP 50: 20: 30 mol%, at 121 ° C
- 1-viscosity 88
- Polyol crosslinking agent 2, 2 Bis (4-hydroxyphenol) perfluoropropane (Daikin Industries “Bisphenol AF”)
- Organic peroxide crosslinking agent 2, 5 To dimethyl-2,5 bis (t-butylperoxy) Toxin-3 (Nippon Yushi “Perhexine 25B-40J”)
- thermoplastic polymer composition pellets The above-mentioned fluorine-containing ethylenic polymer (a), fluorine-containing thermoplastic elastomer (b-2) and crosslinking agent (C-2) were premixed in the proportions shown in Table 1, and then placed in a twin-screw extruder. Then, the mixture was melt-kneaded under conditions of a cylinder temperature of 250 ° C. and a screw rotation speed of 300 rpm to produce thermoplastic polymer composition pellets.
- Table 1 shows the results of measurement of hardness, fluidity, compression set, tensile strength, tensile elongation, and fuel permeability using the obtained thermoplastic polymer composition pellets by the methods described above. .
- a compound of the above-described fluorine-containing ethylenic polymer (a) and fluororubber (b-1) was prepared. Is pre-mixed in the proportions shown in Table 1, and then, with respect to 100 parts by weight of the fluororubber (b — 1 13) in the compound, an acid acceptor (acid magnesium “MA150” manufactured by Kyowa Chemical Industry Co., Ltd.) 3 parts by weight, accelerator (Calcium hydroxide “Caldick 2000” manufactured by Omi Chemical Co., Ltd.) 6 parts by weight are mixed and fed to a twin-screw extruder. The cylinder temperature is 250 ° C and the screw speed is 300 rpm.
- thermoplastic polymer composition pellets The mixture was melt-kneaded under the conditions described above to produce thermoplastic polymer composition pellets.
- Table 1 shows the results of measurement of hardness, fluidity, compression set, tensile strength, tensile elongation and fuel permeability using the obtained thermoplastic polymer composition pellets by the methods described above. .
- thermoplastic polymer compositions obtained in Examples 1 to 8 were scanned with an electron microscope (JEOL).
- the fluororesin (A) had a structure in which a continuous phase was formed and the bridged fluororubber (B) had a dispersed phase.
- Table 1 shows the results of measurements of hardness, fluidity, compression set, tensile strength, tensile elongation, and fuel permeability using the pellets of fluorine resin (A) alone by the methods described above.
- crosslinking agent (C 1) with respect to 100 parts by weight of the above-mentioned fluororubber (b-la), crosslinking accelerator (benzyl triphenylphospho-um chloride; ⁇ -ZC manufactured by Hokuko Chemical Co., Ltd.)) 43 parts by weight, 3 parts by weight of acid acceptor (Kyowa Kagaku Kogyo "MA150"), 6 parts by weight of accelerator (Calcium hydroxide "Caldick 2000" by Omi Chemical) 2 rolls And kneaded at 160 ° C for 10 minutes, followed by oven crosslinking at 180 ° C for 4 hours to produce a crosslinked fluororubber (b-1a).
- crosslinking agent (C 1) with respect to 100 parts by weight of the above-mentioned fluororubber (b-la), crosslinking accelerator (benzyl triphenylphospho-um chloride; ⁇ -ZC manufactured by Hokuko Chemical Co., Ltd.)) 43 parts by weight, 3 parts by weight of acid acceptor
- test piece was prepared from the obtained cross-linked fluororubber (bl) sheet according to the method described above, and the hardness, tensile rupture strength, tensile rupture elongation, and compression set were measured by the method described above, and Table 1 shows the results of chemical resistance evaluation.
- thermoplastic polymer composition of the present invention comprises a fluorocarbon resin and a cross-linked fluoro rubber, and the cross-linked fluoro rubber is dynamically mixed with at least one fluoro rubber or fluorine-containing thermoplastic elastomer under melting conditions.
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Abstract
Description
Claims
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US11/658,866 US20090011164A1 (en) | 2004-11-26 | 2005-11-25 | Thermoplastic Polymer Composition |
CN200580040551XA CN101065440B (zh) | 2004-11-26 | 2005-11-25 | 热塑性聚合物组合物 |
JP2006547846A JP4910704B2 (ja) | 2004-11-26 | 2005-11-25 | 熱可塑性重合体組成物 |
EP20050809652 EP1816162B1 (en) | 2004-11-26 | 2005-11-25 | Thermoplastic polymer composition |
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CN110087878A (zh) | 2016-12-27 | 2019-08-02 | 大金工业株式会社 | 层积体 |
EP3649193B1 (en) * | 2017-07-05 | 2022-04-20 | Solvay Specialty Polymers Italy S.p.A. | Composition containing fluorinated thermoplastic elastomers and vulcanizates |
US20210135109A1 (en) * | 2017-07-31 | 2021-05-06 | Corning Incorporated | Accelerated thermal crosslinking of pvdf-hfp via addition of organic bases, and the usage of crosslinked pvdf-hfp as gate dielectric material for otft devices |
JP6493616B1 (ja) * | 2017-11-02 | 2019-04-03 | ダイキン工業株式会社 | 放熱材料用含フッ素エラストマー組成物及びシート |
DE102017223546A1 (de) * | 2017-12-21 | 2019-06-27 | Contitech Ag | Barriereschicht für Schläuche |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6157641A (ja) * | 1984-07-09 | 1986-03-24 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | フツ素化熱可塑性エラストマ−組成物 |
JPH04108845A (ja) * | 1989-12-06 | 1992-04-09 | E I Du Pont De Nemours & Co | 重合体性添加剤を含有する改良されたフツ素化熱可塑性エラストマーおよびこの種のエラストマーの製造方法 |
JPH05140401A (ja) * | 1991-11-20 | 1993-06-08 | Asahi Glass Co Ltd | 含フツ素熱可塑性エラストマー組成物及びその製造方法 |
JPH0688001A (ja) * | 1992-09-08 | 1994-03-29 | Daikin Ind Ltd | フッ素ゴム加硫用組成物および加硫フッ素ゴム |
JPH06228397A (ja) * | 1993-01-29 | 1994-08-16 | Asahi Glass Co Ltd | 柔軟性を有するフッ素樹脂組成物及びその製造方法 |
JPH10101880A (ja) * | 1996-09-27 | 1998-04-21 | Nichias Corp | 熱可塑性エラストマー組成物、その製造法および成形品 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995019880A1 (fr) * | 1994-01-24 | 1995-07-27 | Nippon Zeon Co., Ltd. | Stratifie de couches de composition de caoutchouc vulcanisable, procede de production du stratifie de caoutchouc et stratifie de caoutchouc |
JP3340932B2 (ja) * | 1997-02-06 | 2002-11-05 | ニチアス株式会社 | 熱可塑性エラストマー組成物、その製造法および成形品 |
US6203873B1 (en) * | 1998-05-22 | 2001-03-20 | Dayco Products, Inc. | Blends of fluoroelastomer interpolymers with thermo fluoroplastic interpolymers and the use of such blends in hoses |
AU2631100A (en) * | 1999-03-02 | 2000-09-21 | 3M Innovative Properties Company | Compositions for fluoropolymer bonding to non-fluorinated polymers |
ATE527288T1 (de) * | 1999-11-09 | 2011-10-15 | Daikin Ind Ltd | Vulkanisierbare fluorhaltige elastomer- zusammensetzung |
US6624251B1 (en) * | 1999-12-01 | 2003-09-23 | Freudenberg-Nok General Partnership | Highly chemically resistant thermoplastic vulcanizates based on fluorocarbon polymers and seal-gasket products made with same |
US6310141B1 (en) * | 2000-06-27 | 2001-10-30 | Dyneon Llc | Fluoropolymer-containing compositions |
GB0027188D0 (en) * | 2000-11-07 | 2000-12-27 | Zeon Corp | Laminates of thermoplastic fluororesins and their manufacture |
JP2002276862A (ja) * | 2001-01-12 | 2002-09-25 | Tokai Rubber Ind Ltd | 低透過燃料系ホース |
JP4096291B2 (ja) * | 2002-02-13 | 2008-06-04 | 旭硝子株式会社 | 含フッ素共重合体 |
JP2003278958A (ja) * | 2002-03-25 | 2003-10-02 | Tokai Rubber Ind Ltd | 燃料電池車用水素燃料輸送ホース |
JP2004090405A (ja) * | 2002-08-30 | 2004-03-25 | Tokai Rubber Ind Ltd | 自動車用燃料系ホース |
US20050155690A1 (en) * | 2004-01-16 | 2005-07-21 | Park Edward H. | Bonding of dynamic vulcanizates of fluorocarbon elastomers |
US7135527B2 (en) * | 2004-03-30 | 2006-11-14 | Freudenberg-Nok General Partnership | Elastomeric compositions containing fluoropolymer blends |
US7413697B2 (en) * | 2004-06-21 | 2008-08-19 | Freudenberg-Nok General Partnership | Pre-molding heat treatment of dynamic vulcanizates of fluorocarbon elastomers |
US20090226654A1 (en) * | 2004-11-26 | 2009-09-10 | Daikin Industries, Ltd | Thermoplastic polymer composition and process for preparing thermoplastic polymer composition |
CN101065441A (zh) * | 2004-11-26 | 2007-10-31 | 大金工业株式会社 | 热塑性聚合物组合物 |
-
2005
- 2005-11-25 US US11/658,807 patent/US20090226654A1/en not_active Abandoned
- 2005-11-25 KR KR1020077014488A patent/KR20070086648A/ko active IP Right Grant
- 2005-11-25 EP EP05809645A patent/EP1826238A4/en not_active Withdrawn
- 2005-11-25 US US11/658,866 patent/US20090011164A1/en not_active Abandoned
- 2005-11-25 WO PCT/JP2005/021666 patent/WO2006057331A1/ja active Application Filing
- 2005-11-25 JP JP2006547846A patent/JP4910704B2/ja active Active
- 2005-11-25 EP EP20050809652 patent/EP1816162B1/en active Active
- 2005-11-25 KR KR1020077014485A patent/KR100898213B1/ko active IP Right Grant
- 2005-11-25 WO PCT/JP2005/021668 patent/WO2006057333A1/ja active Application Filing
-
2010
- 2010-12-10 US US12/965,746 patent/US20110086983A1/en not_active Abandoned
-
2011
- 2011-08-08 US US13/205,554 patent/US20110290363A1/en not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6157641A (ja) * | 1984-07-09 | 1986-03-24 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | フツ素化熱可塑性エラストマ−組成物 |
JPH04108845A (ja) * | 1989-12-06 | 1992-04-09 | E I Du Pont De Nemours & Co | 重合体性添加剤を含有する改良されたフツ素化熱可塑性エラストマーおよびこの種のエラストマーの製造方法 |
JPH05140401A (ja) * | 1991-11-20 | 1993-06-08 | Asahi Glass Co Ltd | 含フツ素熱可塑性エラストマー組成物及びその製造方法 |
JPH0688001A (ja) * | 1992-09-08 | 1994-03-29 | Daikin Ind Ltd | フッ素ゴム加硫用組成物および加硫フッ素ゴム |
JPH06228397A (ja) * | 1993-01-29 | 1994-08-16 | Asahi Glass Co Ltd | 柔軟性を有するフッ素樹脂組成物及びその製造方法 |
JPH10101880A (ja) * | 1996-09-27 | 1998-04-21 | Nichias Corp | 熱可塑性エラストマー組成物、その製造法および成形品 |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007137994A (ja) * | 2005-11-17 | 2007-06-07 | Yunimatekku Kk | 含フッ素アロイ化共重合体 |
WO2009009361A3 (en) * | 2007-07-11 | 2009-03-26 | 3M Innovative Properties Co | Methods for melt-processing thermoplastic fluoropolymers |
JP5481671B2 (ja) * | 2009-03-31 | 2014-04-23 | ダイキン工業株式会社 | 高分子アクチュエータ素子用電極膜及びそれを有する高分子アクチュエータ素子 |
CN101921510A (zh) * | 2010-09-10 | 2010-12-22 | 英利能源(中国)有限公司 | 含氟烯烃-乙烯基醚共聚物的油墨组合物及光伏组件边框 |
WO2013141253A1 (ja) * | 2012-03-19 | 2013-09-26 | ダイキン工業株式会社 | フッ素ゴム組成物 |
KR20180012782A (ko) | 2015-05-27 | 2018-02-06 | 닛폰 바루카 고교 가부시키가이샤 | 열가소성 불소 수지 조성물, 및 가교체의 제조 방법 |
JP2017019263A (ja) * | 2015-07-07 | 2017-01-26 | 上海交通大学 | フッ素樹脂複合体の製造方法および成形体の製造方法 |
WO2017138642A1 (ja) * | 2016-02-12 | 2017-08-17 | 古河電気工業株式会社 | 耐熱性架橋フッ素ゴム成形体及びその製造方法、シランマスターバッチ、マスターバッチ混合物及びその成形体、並びに、耐熱性製品 |
JPWO2017138642A1 (ja) * | 2016-02-12 | 2018-12-06 | 古河電気工業株式会社 | 耐熱性架橋フッ素ゴム成形体及びその製造方法、シランマスターバッチ、マスターバッチ混合物及びその成形体、並びに、耐熱性製品 |
US11192984B2 (en) | 2016-02-12 | 2021-12-07 | Furukawa Electric Co., Ltd. | Heat-resistant crosslinked fluorocarbon rubber formed body and method for producing the same, silane master batch, master batch mixture and formed body thereof, and heat-resistant product |
WO2019167954A1 (ja) * | 2018-02-28 | 2019-09-06 | ダイキン工業株式会社 | 熱可塑性樹脂組成物およびその製造方法 |
JP2019151833A (ja) * | 2018-02-28 | 2019-09-12 | ダイキン工業株式会社 | 熱可塑性樹脂組成物およびその製造方法 |
WO2020013314A1 (ja) * | 2018-07-13 | 2020-01-16 | ダイキン工業株式会社 | 熱可塑性樹脂組成物およびその製造方法 |
JP2020015908A (ja) * | 2018-07-13 | 2020-01-30 | ダイキン工業株式会社 | 熱可塑性樹脂組成物およびその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1816162B1 (en) | 2015-01-07 |
KR100898213B1 (ko) | 2009-05-18 |
US20090011164A1 (en) | 2009-01-08 |
JP4910704B2 (ja) | 2012-04-04 |
EP1816162A4 (en) | 2009-08-12 |
US20110290363A1 (en) | 2011-12-01 |
EP1826238A1 (en) | 2007-08-29 |
JPWO2006057331A1 (ja) | 2008-06-05 |
KR20070086648A (ko) | 2007-08-27 |
EP1826238A4 (en) | 2009-08-12 |
US20090226654A1 (en) | 2009-09-10 |
WO2006057333A1 (ja) | 2006-06-01 |
US20110086983A1 (en) | 2011-04-14 |
EP1816162A1 (en) | 2007-08-08 |
KR20070089203A (ko) | 2007-08-30 |
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