WO1997027229A1 - Procede pour la polymerisation en suspension du chlorure de vinyle - Google Patents
Procede pour la polymerisation en suspension du chlorure de vinyle Download PDFInfo
- Publication number
- WO1997027229A1 WO1997027229A1 PCT/EP1997/000164 EP9700164W WO9727229A1 WO 1997027229 A1 WO1997027229 A1 WO 1997027229A1 EP 9700164 W EP9700164 W EP 9700164W WO 9727229 A1 WO9727229 A1 WO 9727229A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dialkyl
- polymerization
- solution
- peroxydicarbonate
- vinyl chloride
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/32—Peroxy compounds the —O—O— group being bound between two >C=O groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
Definitions
- the present invention relates to a process for the aqueous suspension polymerization of vinyl chloride using dialkyl peroxydicarbonates. It more particularly relates to such a process in which dialkyl peroxydicarbonates with short alkyl chains are used in the form of a solution
- the invention also relates to a process for the manufacture of a dialkyl peroxydicarbonate solution with short alkyl chains
- dialkyl peroxydicarbonates it is known to use dialkyl peroxydicarbonates to initiate the polymerization in aqueous suspension of vinyl chloride.
- Dialkyl peroxydicarbonates with short alkyl chains such as diethyl and diisopropyl peroxydicarbonates, constitute initiators which are particularly appreciated because of their activity.
- high at the usual polymerization temperatures of vinyl chloride However, they have the disadvantage of being unstable, so that their storage in the pure state presents very serious risks
- This preparation is carried out by reaction of an alkyl haloformate with a peroxy compound in the presence of water and of a volatile solvent immiscible with water. preferably having a boiling temperature below 100 ° C, such as pentane or hexane.
- the initiator solution thus obtained is then introduced in toto (organic phase and aqueous phase) into the polymerization reactor which is then loaded with a view to polymerization (British patent 1,484,675 in the name of SOLVAY & Cie). This process makes it possible to automate the supply of initiator to the reactors but always requires producing the just sufficient quantity of initiator immediately before the polymerization.
- the object of the present invention is to provide a process for the aqueous suspension polymerization of vinyl chloride by means of dialkyl peroxydicarbonates with short alkyl chains which does not have any of the above-mentioned drawbacks. It also aims to provide an improved process for the manufacture of a solution of dialkyl peroxydicarbonates which is particularly suitable for use in the aqueous suspension polymerization of vinyl chloride.
- the invention relates to a process for the polymerization in aqueous suspension of vinyl chloride with the intervention of dialkyl peroxydicarbonates with short alkyl chains, characterized in that the dialkyl peroxydicarbonate is used in the form of a solution in a liquid and water-insoluble dialkyl alkanedicarboxylate
- the dialkyl peroxydicarbonate solution with short alkyl chains used according to the process of the present invention consists essentially of dialkyl peroxydicarbonate and of solvent (dialkyl alkanedicarboxylate). It is therefore free from other ingredients of the polymerization, such as for example from monomer.
- dialkyl alkanedicarboxylate (hereinafter briefly designated by the term “ester”) liquid and insoluble in water, is meant to designate the esters liquid and insoluble in water under normal conditions, that is to say at room temperature and at atmospheric pressure
- insoluble in water is meant more particularly a solubility in water at room temperature less than 0.5 g / l.
- the solubility in water of the esters serving as solvent for the peroxydicarbonate in the process of the invention does not exceed 0.3 g / l.
- liquid and water-insoluble esters used in the process of the invention generally have boiling temperatures (under normal conditions) well above 100 ° C. Most often they are above 150 ° C.
- C2 to C12 there may be mentioned for example diethyl and dibutyl butanedicarboxylates (succinates), diethyl, dipropyl, dibutyl hexanedicarboxylates (adipates), diisobutyl and diethylhexyl, octanedicarboxylates (suberates) diethyl and dibutyl and dibutyl, diethylbutyl and diethylhexyl decanedicarboxylates (sebacates).
- Esters which are very suitable for carrying out the process of the invention are the alkanedicarboxylates derived from C4 to C8 alkanedicarboxylic acids and from C6 to C10 alkanols. Very particularly preferred esters are chosen from hexanedicarboxylates (adipates) derived from adipic acid and C 6 -C 10 alkanols An ester very particularly preferred in the process of the invention is diethylhexyl adipate
- the concentration of dialkyl peroxydicarbonate in the solutions used in the polymerization process according to the invention generally amounts to approximately 15 to 40% by weight.
- the use in the polymerization of dilute solutions of peroxydicarbonate, for example of solutions containing approximately 10% by weight (or less) of dialkyl peroxydicarbonate presents the risk of leading to vinyl chloride polymers whose glass transition temperature and therefore the heat resistance is reduced. Generally, it does not exceed about 40% by weight, because too high a concentration reduces the accuracy of the measurement when the reactor is supplied with the initiator. Good results are obtained with solutions in which the concentration of dialkyl peroxydicarbonate is approximately 25 to 35% by weight.
- dialkyl peroxydicarbonates with short alkyl chains used in the polymerization process according to the invention can be stored safely at low temperature (below 10 ° C) and this, for many hours, without loss of notable activity. They can therefore be prepared in advance in sufficient quantity to supply several reactors of polymerization or to feed several polymerization cycles in the same reactor
- dialkyl peroxydicarbonates with short alkyl chains is intended to denote for the purposes of the present invention, peroxydicarbonates whose alkyl radicals contain 2 or 3 carbon atoms and represent the ethyl, propyl or isopropyl radicals, more particularly the ethyl and isopropyl radicals
- a particularly preferred peroxydicarbonate is diethyl peroxydicarbonate
- a diethyl or diisopropyl peroxydicarbonate is therefore used in the form of a solution in a hexanedicarboxylate (adipate) derived from adipic acid and an alkanol in C6 to CIO
- dialkyl peroxydicarbonates with short alkyl chains other usual initiators can be used jointly in the polymerization process of the invention.
- other initiators mention may be made of peroxides dilauroyl and dibenzoyl, azo compounds or dialkyl peroxydicarbonates with long alkyl chains, such as diketyl peroxydicarbonate
- it is preferred to initiate polymerization with the exclusive intervention of dialkyl peroxydicarbonates with short alkyl chains Unlike other peroxide mentioned above , these have the advantage that their residues or excess possibly present in the polymerization medium at the end of the polymerization cycle (and which could affect the thermal stability of the vinyl chloride polymers resulting from the process) are easily destroyed by simple alkalinization of the medium at the end of the cycle e of polymerization
- dialkyl peroxydicarbonates in organic solution can be introduced, in whole or in part after the start of the polymerization (delayed)
- the delayed processing of part of the dialkyl peroxydicarbonate with short alkyl chains is advantageous for improving the kinetics of the polymerization or also for producing resins with a low K number (produced at high temperature) exhibiting good thermal stability
- the total amount of initiator used generally ranges from approximately 0.15 to 0.90 , and more particularly still from approximately 0.20 to 0.35% by weight approximately relative to the monomer (s) used
- the general conditions for polymerization are those usually used for the batch polymerization of vinyl chloride in aqueous suspension
- polymerization of vinyl chloride is intended to denote, for the purposes of the present invention, both the homopolymerization of vinyl chloride and its copolymerization with other ethylenically unsaturated monomers which can be polymerized by the radical route.
- vinyl chloride comonomers which can be used in the process of the invention, mention may be made of olefins, halogenated olefins, vinyl ethers, vinyl esters such as, for example, acetate of vinyl, as well as acrylic esters, nitriles and amides
- the comonomers are used in amounts not exceeding 50 mol%, most often 35 mol% of the mixture of comonomers used in the copolymerization
- the process according to the invention is well suited for the homopolymerization of vinyl chloride.
- Polymerization in aqueous suspension means polymerization with the intervention of oil-soluble initiators, in this case in particular dialkyl peroxydicarbonates with short alkyl chains, in the presence of dispersing agents, such as, for example, water-soluble cellulosic ethers, partially saponified polyvinyl acetates (also called polyvinyl alcohols) and t their mixtures It is also possible, at the same time as the dispersing agents, to use surfactants The amount of dispersing agent used generally varies between 0.7 and 2.0% by weight relative to the (x) monomer (s)
- the polymerization temperature is usually between about 40 and 80 ° C
- the vinyl chloride polymers produced according to the process of the invention are conventionally isolated from their polymerization medium, generally after having been subjected to a purification in residual monomer (s).
- polymerization of the invention allows automation of the feed to the reactors II leads to an improvement in the reproducibility of the polymerization cycles
- dialkyl peroxydicarbonates in the form of a solution in an ester according to the The invention does not significantly affect the kinetics of the polymerization, nor the general properties (such as K number, density and particle size) of the vinyl chloride polymers produced.
- these provide by melt processing of shaped articles with a very small number of fish-eyes
- the present invention also relates to an improved process for the production in two stages of a dialkyl peroxydicarbonate solution with short alkyl chains which can be used in (and particularly suitable for) the polymerization in aqueous suspension of vinyl chloride.
- a dialkyl peroxydicarbonate with short alkyl chains (as defined above) is produced, in a first step, by reacting in water appropriate quantities of alkyl haloformate with an inorganic peroxide in the presence an inorganic salt in an amount sufficient to increase the density of the aqueous reaction medium and, in a second step, the dialkyl peroxydicarbonate produced is extracted by extraction using a water-insoluble solvent, to produce a solution of dialkyl peroxydicarbonate in this solvent
- the inorganic salt is used in an amount sufficient to bring the density of the aqueous reaction medium to a value at least equal to 1.05 and more particularly still to a value at least equal to 1, 10.
- the quantity of inorganic salt should be adjusted so that it does not exceed the saturation concentration of millet salt u aqueous reaction
- any inorganic salt which does not interfere with the formation reaction of dialkyl peroxydicarbonate and which does not precipitate under the conditions of reaction is appropriate.
- any inorganic salt which does not interfere with the formation reaction of dialkyl peroxydicarbonate and which does not precipitate under the conditions of reaction is appropriate.
- chlorides of alkali metals are used.
- chloride is used. sodium.
- reaction temperature most often rises to a value located O 97/27229 PC17EP97 / 00164
- peroxydicarbonate is complete after a few minutes of reaction; generally the reaction time does not exceed 10 minutes and most often 5 minutes.
- the alkyl haloformate is most often and advantageously a chloroformate.
- Inorganic peroxide is most often calcium or sodium peroxide or even hydrogen peroxide.
- a base such as calcium hydroxide or sodium hydroxide, should also be introduced into the aqueous reaction medium.
- This procedure has the double advantage of substantially reducing the consumption of inorganic salt to densify the aqueous phase and of reducing or even eliminating the environmental problems linked to the evacuation of the saline aqueous phase after the manufacture of dialkyl peroxydicarbonate.
- solvent insoluble in water is meant a solvent insoluble in water at room temperature and at atmospheric pressure and, more particularly a solvent whose solubility in water under these conditions is less than 0.5 g / and more particularly still at 0.3 g / l
- solvents which can be used for the extraction of dialkyl peroxydicarbonate
- water-insoluble organic compounds chosen from the usual plasticizers for polyvinyl chloride.
- esters of aromatic polycarboxylic acids such as dibutyl or diethylhexyl phthalates
- alkyl epoxycarboxylates such as octyl epoxy stearate
- oils epoxidized such as epoxidized soybean oil
- dialkyl alkanedicarboxylates the definition of which is given earlier in the context of the description of the dialkyl peroxydicarbonate solutions used * "n used in the polymerization in aqueous suspension of vinyl chlourure
- a solvent which also has a density of less than 1, and preferably less than 0.95.
- Particularly preferred solvents are chosen from dialkyl alkanedicarboxylates derived from C4 to C8 alkanedicarboxylic acids and from alkanols in C6 to CIO
- Very particularly preferred solvents are chosen from hexanedicarboxylates (adipates) derived from adipic acid and alkanols in C6 to CIO Excellent results are obtained with diethylhexyl adipate (boiling temperature under atmospheric pressure 214 ° C, solubility in water at room temperature ⁇ 0.2 g / l, density 0.922)
- the amount of solvent used for the extraction is not critical. It goes without saying that it will depend in particular on the degree of solubility of the dialkyl peroxydicarbonate in the solvent chosen. Advantageously, this amount will be such that the final concentration of the peroxydicarbonate solution.
- dialkyl amounts from about 15 to about 40% by weight and more particularly still from 25 to 35% by weight
- the second stage of production of the dialkyl peroxydicarbonate solutions namely the separation by extraction of the dialkyl peroxydicarbonate produced in the first stage, is carried out in any known and appropriate manner.
- the solvent extraction solvent is added to the aqueous reaction medium after completion of the reaction for the manufacture of dialkyl peroxydicarbonate, the phases are allowed to settle and the organic supernatant phase is separated from the aqueous reaction phase to collect a pure solution. of peroxydicarbonate.
- a solution of dialkyl peroxydicarbonate with short alkyl chains (such as diethyl, dipropyl or diisopropyl) containing 15 to 40% by weight of dialkyl peroxydicarbonate is produced.
- work, at the first stage of the manufacturing process of sodium chloride as salt inorganic to increase the density of the aqueous phase and, in the second step, of adipates of C6 to C10 alkanols, in particular of diethylhexyl adipate, as extraction solvent to produce a solution of dialkyl peroxydicarbonate.
- the process for manufacturing solutions of dialkyl peroxydicarbonates according to the invention provides pure solutions which are stable on storage with high yields. These solutions can be transported without danger and do not lead to problems of deposits in the conduits.
- Example 1 The following example is intended to illustrate the invention.
- diethylhexyl adipate precooled to 5 ° C.
- the stirring is stopped.
- the aqueous phase is then separated by decantation (dense phase) and the organic phase is recovered.
- the solution of diethyl peroxydicarbonate in diethylhexyl adipate thus produced is stored at 5 ° C for later use. Its diethyl peroxydicarbonate content (evaluated by analysis) is 287 g / kg. Polymerization of vinyl chloride.
- the medium is heated to 53 ° C., after which cold water is circulated. in the double jacket
- time to
- the pressure in the reactor has dropped by l, 5 kg / cm 2
- the polymerization is stopped by successively carrying out an introduction of 0.35 kg of ammonia, degassing of the unconverted vinyl chloride and cooling.
- the polyvinyl chloride produced is conventionally isolated from the aqueous suspension.
- the polymerization of vinyl chloride was reproduced under the same conditions as in Example 1, except that the appropriate quantity of diethyl peroxydicarbonate was first synthesized in situ in the reaction reactor. polymerization by reaction at room temperature and with stirring of 0.734 kg of ethyl chloroformate and 0.109 kg of hydrogen peroxide in the presence of the total amount of water (basified by addition of 0.284 kg of sodium hydroxide) and of the total quantity of polyvinyl alcohols intended for the polymerization (cf.
- Example 1 ie 1860 kg of water and in total 1.335 kg of polyvinyl alcohols
- the reactor is closed , we stop the agitation, we put the reactor under vacuum! (60mm absolute Hg) for 5 minutes and introduced with stirring (1 lt / min) 1335 kg of vinyl chloride
- the heating and polymerization were carried out as in Example 1
- the pressure in the reactor dropped by 1.5 kg / cm 3 and the polymerization was stopped. 1092 kg of PVC were collected, the K number (measured under the same conditions) being 71.3.
- the table below also summarizes the properties evaluated on the PVC produced according to Comparative Example 2.
Abstract
Description
Claims
Priority Applications (21)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69701855T DE69701855T3 (de) | 1996-01-25 | 1997-01-10 | Verfahren zur wässrigen Suspensionspolymerisation von Vinyl Chlorid mittels Dialkylperoxidicarbonate in Lösung und Verfahren zur Herstellung einer Lösung aus Dialkylperoxydicarbonat |
PL97328268A PL186797B1 (pl) | 1996-01-25 | 1997-01-10 | Sposób polimeryzacji w zawiesinie wodnej chlorku winylu i sposób wytwarzania roztworu nadtlenodiwęglanu dialkilu |
IL12539697A IL125396A (en) | 1996-01-25 | 1997-01-10 | Process for the aqueous suspension polymerization of vinyl chloride |
AU14424/97A AU723766B2 (en) | 1996-01-25 | 1997-01-10 | Process for the aqueous suspension polymerization of vinyl chloride with the use of dialkyl peroxydicarbonates in solution and process for the manufacture of a solution of dialkyl peroxydicarbonate |
HU9900981A HU229149B1 (en) | 1996-01-25 | 1997-01-10 | Process for the suspension polymerisation of vinyl chloride and solutions of dialkyl peroxydicarbonate |
BR9707080A BR9707080A (pt) | 1996-01-25 | 1997-01-10 | Processos para a polimerização em suspens o aquosa de cloreto de vinila e fabricação de uma solução de peroxidicarbonato de dialquila com curtas cadeias alquilas |
CA002244154A CA2244154C (fr) | 1996-01-25 | 1997-01-10 | Procede pour la polymerisation en suspension du chlorure de vinyle |
AT97901036T ATE192460T1 (de) | 1996-01-25 | 1997-01-10 | Verfahren zur wässrigen suspensionspolymerisation von vinyl chlorid mittels dialkylperoxidicarbonate in lösung und verfahren zur herstellung einer lösung aus dialkylperoxydicarbonat |
SK988-98A SK284350B6 (sk) | 1996-01-25 | 1997-01-10 | Spôsob výroby roztoku dialkylperoxydiuhličitanu a použitie tohto roztoku na polymerizáciu vinylchloridu |
US09/117,098 US6258906B1 (en) | 1996-01-25 | 1997-01-10 | Process for manufacture of a solution of dialkyl peroxydicarbonate |
RO98-01217A RO119887B1 (ro) | 1996-01-25 | 1997-01-10 | Procedeu de polimerizare, în suspensie apoasă, a clorurii de vinil şi obţinerea unei soluţii de peroxidicarbonat de dialchil |
JP52648697A JP4889837B2 (ja) | 1996-01-25 | 1997-01-10 | ジアルキルパーオキシジカーボネート溶液を用いた塩化ビニルの水性縣濁重合方法及びジアルキルパーオキシジカーボネート溶液の製造方法 |
EA199800653A EA000881B1 (ru) | 1996-01-25 | 1997-01-10 | Способ полимеризации хлористого винила в водной суспензии с помощью раствора пероксидикарбонатов диалкила и способ получения раствора пероксидикарбоната диалкила |
IL13705597A IL137055A (en) | 1996-01-25 | 1997-01-10 | Process for preparing a dialkyl peroxydicarbonate solution |
KR10-2004-7010890A KR20040091624A (ko) | 1996-01-25 | 1997-01-10 | 퍼옥시이탄산 디알킬 용액의 제조방법 |
EP97901036A EP0876410B2 (fr) | 1996-01-25 | 1997-01-10 | Procédé de polymérisation en suspension aqueuse du chlorure de vinyle à l'aide de peroxydicarbonates de dialkyle en solution et procédé de fabrication d'une solution de peroxydicarbonate de dialkyle |
UA98084552A UA63900C2 (uk) | 1996-01-25 | 1997-10-01 | Спосіб полімеризації у водній суспензії хлористого вінілу за допомогою розчину пероксидикарбонатів діалкілу та спосіб одержання розчину пероксидикарбонату діалкілу (варіанти) |
NO19983430A NO318952B1 (no) | 1996-01-25 | 1998-07-24 | Fremgangsmate for suspensjonspolymerisasjon av vinylklorid |
BG102649A BG63396B1 (bg) | 1996-01-25 | 1998-07-24 | Метод за полимеризиране във водна суспензия на винилхлорид с помощта на диалкилови пероксидикарбонати в разтвор и метод за получаване на разтвор на диалкилов пероксидикарбонат |
US09/866,026 US6617408B2 (en) | 1996-01-25 | 2001-05-25 | Process for polymerization of vinyl chloride |
NO20035017A NO328156B1 (no) | 1996-01-25 | 2003-11-12 | Fremgangsmate for fremstilling av en opplosning av dialkylperoksydikarbonat |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9600070 | 1996-01-25 | ||
BE9600070A BE1009969A3 (fr) | 1996-01-25 | 1996-01-25 | Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle. |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/117,098 A-371-Of-International US6258906B1 (en) | 1996-01-25 | 1997-01-10 | Process for manufacture of a solution of dialkyl peroxydicarbonate |
US09117098 A-371-Of-International | 1997-01-10 | ||
US09/866,026 Division US6617408B2 (en) | 1996-01-25 | 2001-05-25 | Process for polymerization of vinyl chloride |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997027229A1 true WO1997027229A1 (fr) | 1997-07-31 |
Family
ID=3889493
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/000164 WO1997027229A1 (fr) | 1996-01-25 | 1997-01-10 | Procede pour la polymerisation en suspension du chlorure de vinyle |
Country Status (32)
Country | Link |
---|---|
US (3) | US6258906B1 (fr) |
EP (1) | EP0876410B2 (fr) |
JP (3) | JP4889837B2 (fr) |
KR (2) | KR100476175B1 (fr) |
CN (2) | CN1132859C (fr) |
AR (2) | AR006753A1 (fr) |
AT (1) | ATE192460T1 (fr) |
AU (1) | AU723766B2 (fr) |
BE (1) | BE1009969A3 (fr) |
BG (1) | BG63396B1 (fr) |
BR (1) | BR9707080A (fr) |
CA (1) | CA2244154C (fr) |
CZ (1) | CZ292259B6 (fr) |
DE (1) | DE69701855T3 (fr) |
DZ (1) | DZ2170A1 (fr) |
EA (1) | EA000881B1 (fr) |
ES (1) | ES2148924T5 (fr) |
HR (1) | HRP970047B1 (fr) |
HU (1) | HU229149B1 (fr) |
IL (2) | IL125396A (fr) |
MY (1) | MY116847A (fr) |
NO (2) | NO318952B1 (fr) |
PL (1) | PL186797B1 (fr) |
PT (1) | PT876410E (fr) |
RO (1) | RO119887B1 (fr) |
SK (1) | SK284350B6 (fr) |
TR (1) | TR199801423T2 (fr) |
TW (1) | TW326048B (fr) |
UA (1) | UA63900C2 (fr) |
WO (1) | WO1997027229A1 (fr) |
YU (1) | YU49136B (fr) |
ZA (1) | ZA97449B (fr) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999005102A1 (fr) * | 1997-07-22 | 1999-02-04 | Solvay (Societe Anonyme) | Solution organique de peroxydicarbonate de dialkyle, procede pourl'obtenir, et preparation de polymeres halogenes a l'intervention de celle-ci |
WO2001032613A1 (fr) * | 1999-11-04 | 2001-05-10 | Oxy Vinyls, Lp | Procede de production de peroxydicarbonates et leur utilisation dans la polymerisation radicalaire des monomeres |
EP1593695A1 (fr) * | 2004-05-05 | 2005-11-09 | VESTOLIT GmbH & Co. KG | Procédé de préparation de polymères et copolymères |
US7214329B2 (en) | 2001-03-23 | 2007-05-08 | Akzo Nobel N.V. | Storage stable aqueous organic peroxide emulsions |
FR2968660A1 (fr) * | 2010-12-14 | 2012-06-15 | Solvay | Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle |
FR2984331A1 (fr) * | 2011-12-15 | 2013-06-21 | Solvay | Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1009969A3 (fr) * | 1996-01-25 | 1997-11-04 | Solvay | Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle. |
US6995221B2 (en) * | 1999-11-04 | 2006-02-07 | Oxy Vinyls, L.P. | Method for producing organic peroxides and their use in the radical polymerization of monomers |
US6846888B2 (en) * | 2001-02-01 | 2005-01-25 | Atofina Chemicals, Inc. | Stabilized organic peroxydicarbonate compositions |
EP1852418A1 (fr) | 2006-04-27 | 2007-11-07 | Arkema France | Procédé de synthèse de peroxydes organiques sélectionnés |
EP1849804A1 (fr) * | 2006-04-27 | 2007-10-31 | Arkema France | Procede de polymerisation ou reticulation radicalaire en presence d'un peroxyde organique selon un procede ex situ |
CN101230770B (zh) * | 2007-01-22 | 2010-12-01 | 优护国际企业股份有限公司 | 具寻码功能的两用号码锁 |
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FR2352839A1 (fr) * | 1976-05-25 | 1977-12-23 | Kureha Chemical Ind Co Ltd | Polymerisation en suspension de chlorure de vinyle et de composants monomeres en contenant des quantites predominantes |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999005102A1 (fr) * | 1997-07-22 | 1999-02-04 | Solvay (Societe Anonyme) | Solution organique de peroxydicarbonate de dialkyle, procede pourl'obtenir, et preparation de polymeres halogenes a l'intervention de celle-ci |
BE1011295A3 (fr) * | 1997-07-22 | 1999-07-06 | Solvay | Solution organique de peroxydicarbonate de dialkyle, procede pour l'obtenir, preparation de polymeres halogenes a l'intervention de celle-ci et polymeres halogenes obtenus. |
WO2001032613A1 (fr) * | 1999-11-04 | 2001-05-10 | Oxy Vinyls, Lp | Procede de production de peroxydicarbonates et leur utilisation dans la polymerisation radicalaire des monomeres |
KR100732660B1 (ko) * | 1999-11-04 | 2007-06-27 | 옥시 비닐스, 엘.피. | 퍼옥시디카보네이트를 제조하는 방법 및 이를 단량체의라디칼 중합에 사용하는 용도 |
CZ302981B6 (cs) * | 1999-11-04 | 2012-02-01 | Oxy Vinyls, Lp | Zpusob výroby peroxodikarbonátu a jejich využití pri radikálové polymerizaci monomeru |
US7214329B2 (en) | 2001-03-23 | 2007-05-08 | Akzo Nobel N.V. | Storage stable aqueous organic peroxide emulsions |
EP1593695A1 (fr) * | 2004-05-05 | 2005-11-09 | VESTOLIT GmbH & Co. KG | Procédé de préparation de polymères et copolymères |
FR2968660A1 (fr) * | 2010-12-14 | 2012-06-15 | Solvay | Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle |
WO2012080124A1 (fr) * | 2010-12-14 | 2012-06-21 | Solvay Sa | Procédé pour la préparation d'une solution organique d'un peroxydicarbonate de dialkyle |
FR2984331A1 (fr) * | 2011-12-15 | 2013-06-21 | Solvay | Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle |
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