US20080274928A1 - Water soluble magnesium compounds as cleaning agents and methods of using them - Google Patents

Water soluble magnesium compounds as cleaning agents and methods of using them Download PDF

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Publication number
US20080274928A1
US20080274928A1 US12/114,327 US11432708A US2008274928A1 US 20080274928 A1 US20080274928 A1 US 20080274928A1 US 11432708 A US11432708 A US 11432708A US 2008274928 A1 US2008274928 A1 US 2008274928A1
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United States
Prior art keywords
magnesium
water
salt
water soluble
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/114,327
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English (en)
Inventor
Kim R. Smith
Michael E. Besse
Brenda L. Tjelta
Lisa M. Sanders
Keith E. Olson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab USA Inc
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Ecolab Inc
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Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=39939966&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20080274928(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ecolab Inc filed Critical Ecolab Inc
Priority to US12/114,327 priority Critical patent/US20080274928A1/en
Assigned to ECOLAB INC. reassignment ECOLAB INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BESSE, MICHAEL E., SMITH, KIM R., OLSON, KEITH E., SANDERS, LISA M., TJELTA, BRENDA L.
Priority to US12/263,907 priority patent/US20090099054A1/en
Priority to US12/263,892 priority patent/US20090082245A1/en
Publication of US20080274928A1 publication Critical patent/US20080274928A1/en
Assigned to ECOLAB USA INC. reassignment ECOLAB USA INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ECOLAB, INC.
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02—Softening water by precipitation of the hardness
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/12—Oxygen-containing compounds
    • C23F11/124—Carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/18—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using inorganic inhibitors
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/20—Other heavy metals
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/22—Light metals
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/14—Maintenance of water treatment installations
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02—Softening water by precipitation of the hardness
    • C02F5/06—Softening water by precipitation of the hardness using calcium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • chelating agent and “sequestrant” refer to a compound that forms a complex (soluble or not) with water hardness ions (from the wash water, soil and substrates being washed) in a specific molar ratio.
  • Chelating agents that can form a water soluble complex include sodium tripolyphosphate, EDTA, DTPA, NTA, citrate, and the like.
  • Sequestrants that can form an insoluble complex include sodium triphosphate, zeolite A, and the like.
  • chelating agent and “sequestrant” are synonymous.
  • antiredeposition agent refers to a compound that helps keep suspended in water instead of redepositing onto the object being cleaned.
  • the composition can include magnesium compound at a predetermined ratio to the calcium in water.
  • the magnesium compound can be a water soluble magnesium salt including an anion that forms a water soluble salt with calcium.
  • Anions that form water soluble salts with both magnesium ion and calcium ion include chloride and acetate.
  • Sulfate form a water soluble salt with magnesium, but its calcium salt is water insoluble.
  • the composition can lack an effective amount or be substantially free of, for example, chelating agent, sequestrant, builder, threshold agent, surfactant, and sheeting agent.
  • the solid cleaning composition is provided in the form of a multiple-use solid, such as, a block or a plurality of pellets, and can be repeatedly used to generate aqueous detergent compositions for multiple washing cycles.
  • the solid cleaning composition is provided as a solid having a mass of about 5 g to 10 kg.
  • a multiple-use form of the solid cleaning composition has a mass of about 1 to 10 kg.
  • a multiple-use form of the solid cleaning composition has a mass of about 5 kg to about 8 kg.
  • a multiple-use form of the solid cleaning composition has a mass of about 5 g to about 1 kg, or about 5 g and to 500 g.
  • the present composition can be dispensed by immersing either intermittently or continuously in water.
  • the composition can then dissolve, for example, at a controlled or predetermined rate.
  • the rate can be effective to maintain a concentration of dissolved cleaning agent that is effective for cleaning.
  • FIG. 6 is illustrative of the invention.
  • FIG. 6 shows a plot of the performance of magnesium chloride in preventing precipitation in the presence of various levels of calcium, at various temperatures, and at a constant pH of 12.
  • a comparison of this graph with FIG. 5 shows that under very alkaline conditions a water soluble magnesium compound such as magnesium chloride is comparable to STPP in controlling water hardness
  • a magnesium compound such as magnesium chloride where the analogous calcium salt is water soluble was found to be more effective in preventing hard water scale than one where the analogous calcium salt is water insoluble.
  • FIG. 10 illustrates this at a 1:1 molar ratio of total magnesium ion to calcium ion for both salts.
  • the glass on the left, treated with a 1:1 molar ratio of MgCl 2 6H 2 O is substantially clear whereas the glass on the right, treated with a 1:1 molar ratio of MgSO 4 7H 2 O is completely cloudy.
  • the MgSO 4 treated glass (right) appears as if it has been dusted completely with an adherent powder.
  • a solid block was made by compressing about 50 grams of magnesium carbonate monohydrate for about 20 seconds at about 1000 psi.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Removal Of Specific Substances (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • ing And Chemical Polishing (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
US12/114,327 2007-05-04 2008-05-02 Water soluble magnesium compounds as cleaning agents and methods of using them Abandoned US20080274928A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/114,327 US20080274928A1 (en) 2007-05-04 2008-05-02 Water soluble magnesium compounds as cleaning agents and methods of using them
US12/263,907 US20090099054A1 (en) 2007-05-04 2008-11-03 Method for formulating a reduced phosphorus branded cleaning product or cleaning system
US12/263,892 US20090082245A1 (en) 2007-05-04 2008-11-03 Method for formulating a branded cleaning product

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US92757507P 2007-05-04 2007-05-04
US12/114,327 US20080274928A1 (en) 2007-05-04 2008-05-02 Water soluble magnesium compounds as cleaning agents and methods of using them

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/263,892 Continuation-In-Part US20090082245A1 (en) 2007-05-04 2008-11-03 Method for formulating a branded cleaning product
US12/263,907 Continuation-In-Part US20090099054A1 (en) 2007-05-04 2008-11-03 Method for formulating a reduced phosphorus branded cleaning product or cleaning system

Publications (1)

Publication Number Publication Date
US20080274928A1 true US20080274928A1 (en) 2008-11-06

Family

ID=39939966

Family Applications (15)

Application Number Title Priority Date Filing Date
US12/114,364 Active 2029-01-04 US8207102B2 (en) 2007-05-04 2008-05-02 Compositions including hardness ion and threshold agent and methods employing them to reduce corrosion and etch
US12/114,329 Active US7709434B2 (en) 2007-05-04 2008-05-02 Compositions including Ca and Mg ions and gluconate and methods employing them to reduce corrosion and etch
US12/114,355 Abandoned US20080274932A1 (en) 2007-05-04 2008-05-02 Composition for in situ manufacture of insoluble hydroxide when cleaning hard surfaces and for use in automatic warewashing machines and methods for manufacturing and using
US12/114,327 Abandoned US20080274928A1 (en) 2007-05-04 2008-05-02 Water soluble magnesium compounds as cleaning agents and methods of using them
US12/114,486 Active 2028-11-19 US8071528B2 (en) 2007-05-04 2008-05-02 Cleaning compositions with water insoluble conversion agents and methods of making and using them
US12/114,428 Active 2028-09-19 US8143204B2 (en) 2007-05-04 2008-05-02 Mg++ chemistry and method for fouling inhibition in heat processing of liquid foods and industrial processes
US12/114,342 Active 2029-08-02 US7960329B2 (en) 2007-05-04 2008-05-02 Compositions including magnesium ion, calcium ion, and silicate and methods employing them to reduce corrosion and etch
US12/114,513 Expired - Fee Related US7749329B2 (en) 2007-05-04 2008-05-02 Cleaning compositions containing water soluble magnesium compounds and methods of using them
US12/114,385 Active 2028-11-19 US8021493B2 (en) 2007-05-04 2008-05-02 Method of reducing corrosion using a warewashing composition
US12/114,448 Abandoned US20080274939A1 (en) 2007-05-04 2008-05-02 Water treatment system and downstream cleaning methods
US12/263,021 Expired - Fee Related US7741262B2 (en) 2007-05-04 2008-10-31 Compositions including hardness ions and gluconate and methods employing them to reduce corrosion and etch
US12/726,179 Active US7919448B2 (en) 2007-05-04 2010-03-17 Compositions including hardness ions and gluconate and methods employing them to reduce corrosion and etch
US12/785,867 Active US7922827B2 (en) 2007-05-04 2010-05-24 Cleaning compositions containing water soluble magnesium compounds and methods of using them
US13/039,968 Abandoned US20110160114A1 (en) 2007-05-04 2011-03-03 Cleaning compositions containing water soluble magnesium compounds and methods of using them
US13/209,719 Abandoned US20110301072A1 (en) 2007-05-04 2011-08-15 Method of reducing corrosion using a warewashing composition

Family Applications Before (3)

Application Number Title Priority Date Filing Date
US12/114,364 Active 2029-01-04 US8207102B2 (en) 2007-05-04 2008-05-02 Compositions including hardness ion and threshold agent and methods employing them to reduce corrosion and etch
US12/114,329 Active US7709434B2 (en) 2007-05-04 2008-05-02 Compositions including Ca and Mg ions and gluconate and methods employing them to reduce corrosion and etch
US12/114,355 Abandoned US20080274932A1 (en) 2007-05-04 2008-05-02 Composition for in situ manufacture of insoluble hydroxide when cleaning hard surfaces and for use in automatic warewashing machines and methods for manufacturing and using

Family Applications After (11)

Application Number Title Priority Date Filing Date
US12/114,486 Active 2028-11-19 US8071528B2 (en) 2007-05-04 2008-05-02 Cleaning compositions with water insoluble conversion agents and methods of making and using them
US12/114,428 Active 2028-09-19 US8143204B2 (en) 2007-05-04 2008-05-02 Mg++ chemistry and method for fouling inhibition in heat processing of liquid foods and industrial processes
US12/114,342 Active 2029-08-02 US7960329B2 (en) 2007-05-04 2008-05-02 Compositions including magnesium ion, calcium ion, and silicate and methods employing them to reduce corrosion and etch
US12/114,513 Expired - Fee Related US7749329B2 (en) 2007-05-04 2008-05-02 Cleaning compositions containing water soluble magnesium compounds and methods of using them
US12/114,385 Active 2028-11-19 US8021493B2 (en) 2007-05-04 2008-05-02 Method of reducing corrosion using a warewashing composition
US12/114,448 Abandoned US20080274939A1 (en) 2007-05-04 2008-05-02 Water treatment system and downstream cleaning methods
US12/263,021 Expired - Fee Related US7741262B2 (en) 2007-05-04 2008-10-31 Compositions including hardness ions and gluconate and methods employing them to reduce corrosion and etch
US12/726,179 Active US7919448B2 (en) 2007-05-04 2010-03-17 Compositions including hardness ions and gluconate and methods employing them to reduce corrosion and etch
US12/785,867 Active US7922827B2 (en) 2007-05-04 2010-05-24 Cleaning compositions containing water soluble magnesium compounds and methods of using them
US13/039,968 Abandoned US20110160114A1 (en) 2007-05-04 2011-03-03 Cleaning compositions containing water soluble magnesium compounds and methods of using them
US13/209,719 Abandoned US20110301072A1 (en) 2007-05-04 2011-08-15 Method of reducing corrosion using a warewashing composition

Country Status (12)

Country Link
US (15) US8207102B2 (enExample)
EP (5) EP2142628B1 (enExample)
JP (4) JP5592252B2 (enExample)
KR (1) KR101495135B1 (enExample)
CN (4) CN101688157B (enExample)
AU (4) AU2008247438B2 (enExample)
BR (4) BRPI0810513B1 (enExample)
CA (4) CA2681674C (enExample)
ES (2) ES2618291T3 (enExample)
MX (4) MX2009011624A (enExample)
NZ (1) NZ579857A (enExample)
WO (10) WO2008137800A1 (enExample)

Cited By (17)

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Publication number Priority date Publication date Assignee Title
US7709434B2 (en) 2007-05-04 2010-05-04 Ecolab Inc. Compositions including Ca and Mg ions and gluconate and methods employing them to reduce corrosion and etch
WO2010010526A3 (en) * 2008-07-22 2010-05-14 Ecolab Inc. Composition for enhanced removal of blood soils
US20100263689A1 (en) * 2009-04-21 2010-10-21 Ecolab Usa Inc. Methods and apparatus for controlling water hardness
CN101956200A (zh) * 2010-11-03 2011-01-26 大连三达奥克化学股份有限公司 无磷环保型粉状脱脂剂及制造方法
CN101956199A (zh) * 2010-11-03 2011-01-26 大连三达奥克化学股份有限公司 无磷环保型水基脱脂剂及制造方法
US20110021399A1 (en) * 2007-05-04 2011-01-27 Ecolab Usa Inc. Cleaning compositions containing water soluble magnesium compounds and methods of using them
CN102719841A (zh) * 2012-06-21 2012-10-10 大连三达奥克化学股份有限公司 飞机滤清器铝箔板网用槽浸超声波清洗剂及制备方法
CN102978634A (zh) * 2012-12-06 2013-03-20 三达奥克化学股份有限公司 环保喷淋型常温高效水基脱脂剂及制备方法
EP2700733A1 (en) 2012-08-20 2014-02-26 Pratt & Whitney Canada Corp. Oxidation-resistant coated superalloy
US9193610B2 (en) 2011-08-10 2015-11-24 Ecolab USA, Inc. Synergistic interaction of weak cation exchange resin and magnesium oxide
CN105839085A (zh) * 2016-06-06 2016-08-10 无锡伊佩克科技有限公司 快凝金属钝化剂及其制备方法
WO2019005720A1 (en) * 2017-06-26 2019-01-03 Ecolab Usa Inc. DISHWASHING METHOD COMPRISING DETERGENT COMPOSITIONS SUBSTANTIALLY FREE OF POLY (CARBOXYLIC ACID) POLYMERS
US11339354B2 (en) * 2013-11-11 2022-05-24 Ecolab Usa Inc. High alkaline warewash detergent with enhanced scale control and soil dispersion
US11440824B2 (en) * 2020-03-26 2022-09-13 Korea Institute Of Science And Technology Apparatus for inhibiting formation of calcium based crystal and apparatus for water treatment using the same
WO2022217134A1 (en) * 2021-04-09 2022-10-13 Garrison Minerals, Llc Dry powder mixture for total phosphorus removal within water and wastewater treatment
US11597893B2 (en) * 2019-06-28 2023-03-07 Ecolab Usa Inc. Solid laundry softener composition
US12486474B2 (en) 2022-04-15 2025-12-02 Ecolab Usa Inc. PPE-free tablet degreaser and multipurpose cleaner

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US8585906B2 (en) 2006-07-14 2013-11-19 Rayne Dealership Corporation Regeneration of ion exchange resin and recovery of regenerant solution
US7692041B2 (en) 2006-08-07 2010-04-06 The University Of Montana Method of oxidation using nitric acid
US20090250653A1 (en) 2006-08-07 2009-10-08 Kiely Donald E Hydroxycarboxylic Acids and Salts
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