TWI608650B - 製造鋰離子電池用正極活性材料的方法 - Google Patents
製造鋰離子電池用正極活性材料的方法 Download PDFInfo
- Publication number
- TWI608650B TWI608650B TW105133272A TW105133272A TWI608650B TW I608650 B TWI608650 B TW I608650B TW 105133272 A TW105133272 A TW 105133272A TW 105133272 A TW105133272 A TW 105133272A TW I608650 B TWI608650 B TW I608650B
- Authority
- TW
- Taiwan
- Prior art keywords
- active material
- positive electrode
- particles
- solution
- graphene oxide
- Prior art date
Links
- 239000007774 positive electrode material Substances 0.000 title claims description 63
- 238000004519 manufacturing process Methods 0.000 title claims description 38
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title description 57
- 229910001416 lithium ion Inorganic materials 0.000 title description 57
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 79
- 229910021389 graphene Inorganic materials 0.000 claims description 70
- 239000002245 particle Substances 0.000 claims description 62
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 48
- 229910052744 lithium Inorganic materials 0.000 claims description 48
- 229910052760 oxygen Inorganic materials 0.000 claims description 44
- 239000001301 oxygen Substances 0.000 claims description 43
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 42
- 239000007773 negative electrode material Substances 0.000 claims description 39
- 239000006183 anode active material Substances 0.000 claims description 24
- 239000011149 active material Substances 0.000 claims description 20
- 239000012752 auxiliary agent Substances 0.000 claims description 20
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 16
- 239000011230 binding agent Substances 0.000 claims description 16
- -1 polytetrafluoroethylene Polymers 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000002244 precipitate Substances 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 239000012298 atmosphere Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 239000003792 electrolyte Substances 0.000 claims description 7
- 229920002943 EPDM rubber Polymers 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- 229910011281 LiCoPO 4 Inorganic materials 0.000 claims description 4
- 229910013086 LiNiPO Inorganic materials 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000002033 PVDF binder Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 239000006230 acetylene black Substances 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000002134 carbon nanofiber Substances 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229920001973 fluoroelastomer Polymers 0.000 claims description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 2
- 239000004627 regenerated cellulose Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 239000010410 layer Substances 0.000 description 71
- 150000001875 compounds Chemical class 0.000 description 40
- 239000007864 aqueous solution Substances 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 17
- 239000007788 liquid Substances 0.000 description 16
- 239000013078 crystal Substances 0.000 description 14
- 239000008151 electrolyte solution Substances 0.000 description 11
- 239000002994 raw material Substances 0.000 description 10
- 239000010408 film Substances 0.000 description 8
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 3
- 229910018119 Li 3 PO 4 Inorganic materials 0.000 description 3
- 239000003990 capacitor Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000006182 cathode active material Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000001027 hydrothermal synthesis Methods 0.000 description 3
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 2
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- KKQAVHGECIBFRQ-UHFFFAOYSA-N methyl propyl carbonate Chemical compound CCCOC(=O)OC KKQAVHGECIBFRQ-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000009210 therapy by ultrasound Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- FMHNFHSEPBAWQN-UHFFFAOYSA-N C(OCCC(C)C)(O)=O.C(OCC(C)C)(OC)=O Chemical compound C(OCCC(C)C)(O)=O.C(OCC(C)C)(OC)=O FMHNFHSEPBAWQN-UHFFFAOYSA-N 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910013553 LiNO Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- 101100513612 Microdochium nivale MnCO gene Proteins 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- QQGWBRJQPRTJDA-UHFFFAOYSA-N [Li].CC(O)=O Chemical compound [Li].CC(O)=O QQGWBRJQPRTJDA-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- LEAMSPPOALICQN-UHFFFAOYSA-H iron(2+);diphosphate;octahydrate Chemical compound O.O.O.O.O.O.O.O.[Fe+2].[Fe+2].[Fe+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEAMSPPOALICQN-UHFFFAOYSA-H 0.000 description 1
- OWZIYWAUNZMLRT-UHFFFAOYSA-L iron(2+);oxalate Chemical compound [Fe+2].[O-]C(=O)C([O-])=O OWZIYWAUNZMLRT-UHFFFAOYSA-L 0.000 description 1
- LNOZJRCUHSPCDZ-UHFFFAOYSA-L iron(ii) acetate Chemical compound [Fe+2].CC([O-])=O.CC([O-])=O LNOZJRCUHSPCDZ-UHFFFAOYSA-L 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Inorganic materials [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 1
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 1
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- SBWRUMICILYTAT-UHFFFAOYSA-K lithium;cobalt(2+);phosphate Chemical compound [Li+].[Co+2].[O-]P([O-])([O-])=O SBWRUMICILYTAT-UHFFFAOYSA-K 0.000 description 1
- SNKMVYBWZDHJHE-UHFFFAOYSA-M lithium;dihydrogen phosphate Chemical compound [Li+].OP(O)([O-])=O SNKMVYBWZDHJHE-UHFFFAOYSA-M 0.000 description 1
- ILXAVRFGLBYNEJ-UHFFFAOYSA-K lithium;manganese(2+);phosphate Chemical compound [Li+].[Mn+2].[O-]P([O-])([O-])=O ILXAVRFGLBYNEJ-UHFFFAOYSA-K 0.000 description 1
- LRVBJNJRKRPPCI-UHFFFAOYSA-K lithium;nickel(2+);phosphate Chemical compound [Li+].[Ni+2].[O-]P([O-])([O-])=O LRVBJNJRKRPPCI-UHFFFAOYSA-K 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003214 poly(methacrylonitrile) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/042—Electrodes or formation of dielectric layers thereon characterised by the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Power Engineering (AREA)
- Composite Materials (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011186340 | 2011-08-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201705593A TW201705593A (zh) | 2017-02-01 |
| TWI608650B true TWI608650B (zh) | 2017-12-11 |
Family
ID=47741561
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105133272A TWI608650B (zh) | 2011-08-29 | 2012-08-28 | 製造鋰離子電池用正極活性材料的方法 |
| TW101131168A TWI566457B (zh) | 2011-08-29 | 2012-08-28 | 製造鋰離子電池用正極活性材料的方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW101131168A TWI566457B (zh) | 2011-08-29 | 2012-08-28 | 製造鋰離子電池用正極活性材料的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (4) | US8470477B2 (cg-RX-API-DMAC10.html) |
| JP (5) | JP6053115B2 (cg-RX-API-DMAC10.html) |
| KR (7) | KR102156726B1 (cg-RX-API-DMAC10.html) |
| CN (2) | CN106410192B (cg-RX-API-DMAC10.html) |
| TW (2) | TWI608650B (cg-RX-API-DMAC10.html) |
| WO (1) | WO2013031929A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8945498B2 (en) | 2011-03-18 | 2015-02-03 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing lithium-containing composite oxide |
| KR102156726B1 (ko) * | 2011-08-29 | 2020-09-16 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 리튬 이온 전지용 양극 활물질의 제작 방법 |
| JP2013093316A (ja) * | 2011-10-04 | 2013-05-16 | Semiconductor Energy Lab Co Ltd | 二次粒子の作製方法と蓄電装置の電極の作製方法 |
| CN103035922B (zh) | 2011-10-07 | 2019-02-19 | 株式会社半导体能源研究所 | 蓄电装置 |
| CN102683697B (zh) * | 2012-05-14 | 2014-12-17 | 国光电器股份有限公司 | 一种石墨烯基LiFePO4/C复合材料的制备方法 |
| US9225003B2 (en) | 2012-06-15 | 2015-12-29 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing storage battery electrode, storage battery electrode, storage battery, and electronic device |
| JP6207923B2 (ja) | 2012-08-27 | 2017-10-04 | 株式会社半導体エネルギー研究所 | 二次電池用正極の製造方法 |
| US9490472B2 (en) | 2013-03-28 | 2016-11-08 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing electrode for storage battery |
| CN103204486B (zh) * | 2013-04-16 | 2015-02-25 | 成都牧甫科技有限公司 | 复合多晶结构的石墨烯磷酸铁锂及其制备方法 |
| US9979013B2 (en) | 2013-04-30 | 2018-05-22 | Sumitomo Osaka Cement Co., Ltd. | Electrode material, paste, electrode plate, and lithium ion battery |
| KR102163376B1 (ko) | 2013-05-23 | 2020-10-08 | 도레이 카부시키가이샤 | 폴리 음이온계 정극 활물질 복합체 입자의 제조 방법 및 폴리 음이온계 정극 활물질 전구체-산화 그래파이트 복합 조립체 |
| CA2820227C (en) * | 2013-07-10 | 2020-10-20 | Grafoid, Inc. | Novel composite conductive material |
| JP2016013958A (ja) | 2013-12-02 | 2016-01-28 | 株式会社半導体エネルギー研究所 | 素子、膜の作製方法 |
| CN103928680A (zh) * | 2014-03-24 | 2014-07-16 | 上海大学 | 一种制备片状磷酸锰锂/石墨烯复合材料的喷雾干燥辅助合成方法 |
| US9666918B2 (en) | 2014-03-28 | 2017-05-30 | International Business Machines Corporation | Lithium oxygen battery and electrolyte composition |
| CN103928688B (zh) * | 2014-04-18 | 2016-03-30 | 西南大学 | 基于三维多孔石墨烯的氧析出电极的制备方法 |
| JP6745587B2 (ja) | 2014-05-29 | 2020-08-26 | 株式会社半導体エネルギー研究所 | 電極の製造方法 |
| CN104064739A (zh) * | 2014-07-02 | 2014-09-24 | 长沙国容新能源有限公司 | 锡钴合金/石墨烯复合材料及其制备方法 |
| CN104241646B (zh) * | 2014-08-28 | 2016-09-21 | 江苏容汇通用锂业股份有限公司 | 一种通过固液分离实现石墨烯对磷酸铁锂改性的方法 |
| CN104241606B (zh) * | 2014-09-09 | 2017-04-12 | 江苏容汇通用锂业股份有限公司 | 一种高倍率兼具优良低温性能的磷酸铁锂正极极片的制作方法 |
| JP6666107B2 (ja) | 2014-10-24 | 2020-03-13 | 株式会社半導体エネルギー研究所 | 蓄電池用電極の製造方法、及び蓄電池用電極 |
| KR20250152695A (ko) | 2014-10-27 | 2025-10-23 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 입자, 전극, 전력 저장 장치, 전자 장치, 및 전극의 제작 방법 |
| FI127782B (en) | 2014-12-02 | 2019-02-15 | Keliber Oy | Process for the production of lithium metal phosphate |
| WO2016178117A1 (en) | 2015-05-06 | 2016-11-10 | Semiconductor Energy Laboratory Co., Ltd. | Secondary battery and electronic device |
| JP2016222526A (ja) | 2015-05-29 | 2016-12-28 | 株式会社半導体エネルギー研究所 | 膜の作製方法および素子 |
| JP2017045726A (ja) | 2015-08-27 | 2017-03-02 | 株式会社半導体エネルギー研究所 | 電極、及びその製造方法、蓄電池、並びに電子機器 |
| CN105295193B (zh) * | 2015-10-22 | 2017-09-01 | 安徽大学 | 一种聚丙烯‑三元乙丙橡胶导电复合材料及其制备方法 |
| KR102465353B1 (ko) | 2015-12-02 | 2022-11-10 | 삼성전자주식회사 | 전계 효과 트랜지스터 및 이를 포함하는 반도체 소자 |
| CN105826524B (zh) * | 2016-03-18 | 2019-09-10 | 山东科技大学 | 一种石墨烯原位形核磷酸铁锂的合成方法 |
| US10680242B2 (en) * | 2016-05-18 | 2020-06-09 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing positive electrode active material, and lithium ion battery |
| FI128092B (en) | 2016-06-01 | 2019-09-13 | Keliber Oy | Method of Producing Non-Conductive Lithium Metal Phosphates |
| DE202017007628U1 (de) | 2016-07-05 | 2023-12-21 | Semiconductor Energy Laboratory Co., Ltd. | Positivelektrodenaktivmaterial und Sekundärbatterie |
| US20180013151A1 (en) | 2016-07-08 | 2018-01-11 | Semiconductor Energy Laboratory Co., Ltd. | Positive electrode active material, power storage device, electronic device, and method for manufacturing positive electrode active material |
| US12308421B2 (en) | 2016-09-12 | 2025-05-20 | Semiconductor Energy Laboratory Co., Ltd. | Electrode and power storage device comprising graphene compound |
| KR102702963B1 (ko) | 2016-10-12 | 2024-09-04 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질 입자 및 양극 활물질 입자의 제작 방법 |
| WO2018207049A1 (ja) | 2017-05-12 | 2018-11-15 | 株式会社半導体エネルギー研究所 | 正極活物質粒子 |
| KR102986927B1 (ko) | 2017-05-19 | 2026-07-03 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질, 양극 활물질의 제작 방법, 및 이차 전지 |
| KR102529616B1 (ko) | 2017-06-26 | 2023-05-04 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질의 제작 방법 및 이차 전지 |
| WO2019243952A1 (ja) | 2018-06-22 | 2019-12-26 | 株式会社半導体エネルギー研究所 | 正極活物質、正極、および二次電池、ならびに正極の作製方法 |
| CN109546151A (zh) * | 2018-09-21 | 2019-03-29 | 浙江工业大学 | 一种用于锂硫电池的粘结剂及其应用 |
| CN109775682B (zh) * | 2019-01-30 | 2021-01-29 | 鲍君杰 | 一种磷酸钴锂的制备方法 |
| CN110729460B (zh) * | 2019-09-30 | 2023-06-30 | 山东玉皇新能源科技有限公司 | 一种锂离子电池纳米硅复合补锂负极材料及其制备方法与应用 |
| CN111647863B (zh) * | 2020-07-02 | 2022-03-25 | 河北大学 | Li2FexSiO4正极薄膜的制备方法及应用 |
| KR102423486B1 (ko) * | 2020-08-24 | 2022-07-21 | (주)한국워터테크놀로지 | 전기 삼투 방식을 이용한 양극 활물질 탈수 장치 및 그 탈수 장치를 포함하는 탈수 설비 |
| KR20240035808A (ko) * | 2021-07-21 | 2024-03-18 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질의 제작 방법 |
| US20240079555A1 (en) * | 2022-09-06 | 2024-03-07 | GM Global Technology Operations LLC | Single-layered reference electrode |
| TWI827275B (zh) * | 2022-09-27 | 2023-12-21 | 台灣立凱電能科技股份有限公司 | 磷酸鋰鐵正極材料的製備方法 |
| CN115744850B (zh) * | 2022-12-15 | 2024-02-02 | 昆明川金诺化工股份有限公司 | 一种高品质磷酸二氢锂的制备方法 |
| CN119463536A (zh) * | 2023-12-07 | 2025-02-18 | 广州慧谷新材料科技股份有限公司 | 一种碳材料及制备方法、水性导电涂料及涂碳铝箔 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010103051A (ja) * | 2008-10-27 | 2010-05-06 | Nissan Motor Co Ltd | 蓄電デバイス用複合電極、その製造方法及び蓄電デバイス |
| US20100291438A1 (en) * | 2009-05-15 | 2010-11-18 | PDC Energy, LLC | Electrode material, lithium-ion battery and method thereof |
| US20110111299A1 (en) * | 2008-07-28 | 2011-05-12 | Jun Liu | Lithium ion batteries with titania/graphene anodes |
Family Cites Families (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2965450B2 (ja) * | 1993-01-14 | 1999-10-18 | 松下電器産業株式会社 | 非水電解質二次電池用電極 |
| US5474861A (en) | 1993-01-14 | 1995-12-12 | Matsushita Electric Industrial Co., Ltd. | Electrode for non-aqueous electrolyte secondary battery |
| JP4651960B2 (ja) | 2004-03-23 | 2011-03-16 | 住友大阪セメント株式会社 | リチウム電池用正極活物質の製造方法とリチウム電池用正極活物質及びリチウム電池用正極材料並びにリチウム電池 |
| US7842432B2 (en) | 2004-12-09 | 2010-11-30 | Nanosys, Inc. | Nanowire structures comprising carbon |
| US8278011B2 (en) | 2004-12-09 | 2012-10-02 | Nanosys, Inc. | Nanostructured catalyst supports |
| WO2006062947A2 (en) | 2004-12-09 | 2006-06-15 | Nanosys, Inc. | Nanowire-based membrane electrode assemblies for fuel cells |
| US7939218B2 (en) | 2004-12-09 | 2011-05-10 | Nanosys, Inc. | Nanowire structures comprising carbon |
| JP4536561B2 (ja) * | 2005-03-18 | 2010-09-01 | 住友大阪セメント株式会社 | 電極材料の製造方法 |
| JP3850427B2 (ja) | 2005-03-22 | 2006-11-29 | 株式会社物産ナノテク研究所 | 炭素繊維結合体およびこれを用いた複合材料 |
| JP2007018829A (ja) * | 2005-07-06 | 2007-01-25 | Matsushita Electric Ind Co Ltd | リチウム電池 |
| AU2006318658B2 (en) | 2005-11-21 | 2011-07-28 | Nanosys, Inc. | Nanowire structures comprising carbon |
| WO2007081945A1 (en) | 2006-01-09 | 2007-07-19 | The Dial Corporation | Dryer device with end of use indicator |
| KR101502184B1 (ko) | 2007-03-19 | 2015-03-12 | 유미코르 | Ｌｉ계 배터리에 사용하기 위한 상온 단상 Ｌｉ 삽입／추출 물질 |
| JP5153189B2 (ja) | 2007-03-30 | 2013-02-27 | 三井造船株式会社 | リチウムイオン二次電池正極材料の製造方法 |
| US7745047B2 (en) | 2007-11-05 | 2010-06-29 | Nanotek Instruments, Inc. | Nano graphene platelet-base composite anode compositions for lithium ion batteries |
| CN101919089B (zh) | 2007-12-25 | 2014-04-16 | 花王株式会社 | 锂电池正极用复合材料 |
| JP5377946B2 (ja) | 2007-12-25 | 2013-12-25 | 花王株式会社 | リチウム電池正極用複合材料 |
| JP5082833B2 (ja) * | 2007-12-27 | 2012-11-28 | セイコーエプソン株式会社 | 文書画像処理プログラム、文書画像処理装置、および文書画像処理方法 |
| EP2276698A1 (en) | 2008-04-14 | 2011-01-26 | Dow Global Technologies Inc. | Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries |
| WO2009131095A1 (ja) * | 2008-04-25 | 2009-10-29 | 住友大阪セメント株式会社 | リチウムイオン電池用正極活物質の製造方法、該製造方法で得られたリチウムイオン電池用正極活物質、リチウムイオン電池用電極、及びリチウムイオン電池 |
| JP5462445B2 (ja) * | 2008-04-30 | 2014-04-02 | 三菱マテリアル株式会社 | リチウムイオン二次電池 |
| JP5164260B2 (ja) * | 2008-06-12 | 2013-03-21 | テイカ株式会社 | 炭素−オリビン型リン酸鉄リチウム複合体の製造方法、およびリチウムイオン電池用正極材料 |
| KR101628416B1 (ko) * | 2008-08-05 | 2016-06-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 재충전가능한 리튬 배터리용 캐쏘드 활성 물질로서의 리튬 금속 포스페이트/탄소 나노복합체 |
| JP2010049873A (ja) * | 2008-08-20 | 2010-03-04 | Toyo Ink Mfg Co Ltd | 電池用組成物 |
| KR101286935B1 (ko) | 2008-10-27 | 2013-07-16 | 어 스쿨 코포레이션 칸사이 유니버시티 | 축전 디바이스용 복합 전극, 그의 제조 방법 및 축전 디바이스 |
| JP5381024B2 (ja) | 2008-11-06 | 2014-01-08 | 株式会社Ｇｓユアサ | リチウム二次電池用正極及びリチウム二次電池 |
| US8580432B2 (en) | 2008-12-04 | 2013-11-12 | Nanotek Instruments, Inc. | Nano graphene reinforced nanocomposite particles for lithium battery electrodes |
| CA2747728C (en) | 2008-12-19 | 2017-11-28 | Clive P. Bosnyak | Exfoliated carbon nanotubes, methods for production thereof and products obtained therefrom |
| US9093693B2 (en) | 2009-01-13 | 2015-07-28 | Samsung Electronics Co., Ltd. | Process for producing nano graphene reinforced composite particles for lithium battery electrodes |
| EP2228855B1 (en) | 2009-03-12 | 2014-02-26 | Belenos Clean Power Holding AG | Open porous electrically conductive nanocomposite material |
| JP5381192B2 (ja) | 2009-03-16 | 2014-01-08 | Ｔｄｋ株式会社 | リチウムイオン二次電池用活物質の製造方法 |
| JP5509918B2 (ja) | 2009-03-27 | 2014-06-04 | 住友大阪セメント株式会社 | リチウムイオン電池用正極活物質の製造方法とリチウムイオン電池用正極活物質及びリチウムイオン電池用電極並びにリチウムイオン電池 |
| US20140370380A9 (en) | 2009-05-07 | 2014-12-18 | Yi Cui | Core-shell high capacity nanowires for battery electrodes |
| EP3865454A3 (en) * | 2009-05-26 | 2021-11-24 | Belenos Clean Power Holding AG | Stable dispersions of single and multiple graphene layers in solution |
| JP2011032156A (ja) | 2009-07-06 | 2011-02-17 | Kaneka Corp | グラフェンまたは薄膜グラファイトの製造方法 |
| US20110008233A1 (en) * | 2009-07-10 | 2011-01-13 | Semiconductor Energy Laboratory Co., Ltd. | Positive electrode active material |
| JP2013502045A (ja) * | 2009-08-14 | 2013-01-17 | ザ リージェンツ オブ ザ ユニバーシティ オブ ミシガン | Ｌｉイオン電池コンポネントの直接熱スプレー合成 |
| JP5531532B2 (ja) * | 2009-09-28 | 2014-06-25 | 住友大阪セメント株式会社 | リチウムイオン電池正極活物質の製造方法 |
| JP5594656B2 (ja) * | 2009-09-30 | 2014-09-24 | 国立大学法人名古屋大学 | リチウムイオン二次電池の正極材の製造方法 |
| US8778538B2 (en) | 2009-11-06 | 2014-07-15 | Northwestern University | Electrode material comprising graphene-composite materials in a graphite network |
| US9431649B2 (en) * | 2009-11-23 | 2016-08-30 | Uchicago Argonne, Llc | Coated electroactive materials |
| CN101752561B (zh) * | 2009-12-11 | 2012-08-22 | 宁波艾能锂电材料科技股份有限公司 | 石墨烯改性磷酸铁锂正极活性材料及其制备方法以及锂离子二次电池 |
| US9912009B2 (en) | 2009-12-18 | 2018-03-06 | Molecular Rebar Design, Llc | Binders, electrolytes and separator films for energy storage and collection devices using discrete carbon nanotubes |
| JP6093570B2 (ja) | 2009-12-18 | 2017-03-08 | モレキュラー レバー デザイン エルエルシー | 剥離マイクロチューブならびに空間制御された付着ナノスケール粒子および層を含有する高性能エネルギー貯蔵および収集装置 |
| US8652687B2 (en) | 2009-12-24 | 2014-02-18 | Nanotek Instruments, Inc. | Conductive graphene polymer binder for electrochemical cell electrodes |
| CN101777648B (zh) * | 2010-01-26 | 2012-08-22 | 中国科学院宁波材料技术与工程研究所 | 单分散磷酸铁锂纳米材料的制备方法及其锂离子二次电池 |
| CN103189308A (zh) | 2010-06-22 | 2013-07-03 | 设计纳米管有限责任公司 | 改性碳纳米管、其生产方法以及由此获得的产品 |
| US8795899B2 (en) | 2010-08-19 | 2014-08-05 | Nanotek Instruments, Inc. | Lithium super-battery with a functionalized nano graphene cathode |
| US8691441B2 (en) | 2010-09-07 | 2014-04-08 | Nanotek Instruments, Inc. | Graphene-enhanced cathode materials for lithium batteries |
| CN106229475B (zh) | 2010-10-08 | 2019-12-17 | 株式会社半导体能源研究所 | 储能装置用正极活性材料的制造方法及储能装置 |
| EP2445049B1 (en) | 2010-10-22 | 2018-06-20 | Belenos Clean Power Holding AG | Electrode (anode and cathode) performance enhancement by composite formation with graphene oxide |
| CN102044666B (zh) * | 2010-11-19 | 2013-03-13 | 杭州电子科技大学 | 一种锂电池用磷酸铁锂复合材料的制备方法 |
| US20170226363A1 (en) | 2010-12-14 | 2017-08-10 | Molecular Rebar Design, Llc | Printing ink dispersions comprising discrete carbon nanotubes |
| EP2651819A1 (en) | 2010-12-14 | 2013-10-23 | Styron Europe GmbH | Improved elastomer formulations |
| JP2012204150A (ja) * | 2011-03-25 | 2012-10-22 | Sumitomo Osaka Cement Co Ltd | 電極活物質の製造方法と電極活物質及び電極並びに電池 |
| ES2548549T3 (es) | 2011-06-23 | 2015-10-19 | Molecular Rebar Design, Llc | Formulaciones de baterías de plomo y ácido que contienen nanotubos de carbono discretos |
| EP2724403B1 (en) | 2011-06-23 | 2016-10-05 | Molecular Rebar Design, LLC | Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom |
| KR102156726B1 (ko) * | 2011-08-29 | 2020-09-16 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 리튬 이온 전지용 양극 활물질의 제작 방법 |
| JP6294873B2 (ja) | 2012-06-21 | 2018-03-14 | モレキュラー レバー デザイン，エルエルシー | 不連続カーボンナノチューブを使用した、エネルギー蓄積および回収装置のためのバインダ、電解質およびセパレータフィルム |
| CN104755545A (zh) | 2012-07-08 | 2015-07-01 | 分子钢筋设计有限责任公司 | 使用离散的碳纳米管分子钢筋制成的聚氨酯聚合物和组合物 |
-
2012
- 2012-08-24 KR KR1020207010059A patent/KR102156726B1/ko active Active
- 2012-08-24 CN CN201610986520.3A patent/CN106410192B/zh active Active
- 2012-08-24 CN CN201280041901.4A patent/CN103765641B/zh active Active
- 2012-08-24 WO PCT/JP2012/072090 patent/WO2013031929A1/en not_active Ceased
- 2012-08-24 KR KR1020217003213A patent/KR102344325B1/ko active Active
- 2012-08-24 KR KR1020147007978A patent/KR101972795B1/ko active Active
- 2012-08-24 KR KR1020207026190A patent/KR102212898B1/ko active Active
- 2012-08-24 KR KR1020197011308A patent/KR102100352B1/ko active Active
- 2012-08-24 KR KR1020237009465A patent/KR20230042411A/ko not_active Abandoned
- 2012-08-24 KR KR1020217042239A patent/KR102513118B1/ko active Active
- 2012-08-27 US US13/595,024 patent/US8470477B2/en active Active
- 2012-08-27 JP JP2012186537A patent/JP6053115B2/ja active Active
- 2012-08-28 TW TW105133272A patent/TWI608650B/zh not_active IP Right Cessation
- 2012-08-28 TW TW101131168A patent/TWI566457B/zh not_active IP Right Cessation
-
2013
- 2013-06-21 US US13/923,428 patent/US8685570B2/en active Active
-
2014
- 2014-02-12 US US14/178,535 patent/US9711292B2/en active Active
-
2016
- 2016-11-28 JP JP2016229750A patent/JP6352371B2/ja active Active
-
2017
- 2017-06-14 US US15/622,995 patent/US10096428B2/en not_active Expired - Fee Related
-
2018
- 2018-06-06 JP JP2018108348A patent/JP6797864B2/ja active Active
-
2020
- 2020-11-18 JP JP2020191418A patent/JP2021036539A/ja not_active Withdrawn
-
2022
- 2022-07-22 JP JP2022117211A patent/JP7305855B2/ja active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110111299A1 (en) * | 2008-07-28 | 2011-05-12 | Jun Liu | Lithium ion batteries with titania/graphene anodes |
| JP2010103051A (ja) * | 2008-10-27 | 2010-05-06 | Nissan Motor Co Ltd | 蓄電デバイス用複合電極、その製造方法及び蓄電デバイス |
| US20100291438A1 (en) * | 2009-05-15 | 2010-11-18 | PDC Energy, LLC | Electrode material, lithium-ion battery and method thereof |
Non-Patent Citations (1)
| Title |
|---|
| Chutchamon Sirisopanaporn, Christian Masquelier, Peter G. Bruce, A. Robert Armstrong, Robert Dominko, "Dependence of Li2FeSiO4 Electrochemistry on Structure", 2010/12/30 * |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI566457B (zh) | 製造鋰離子電池用正極活性材料的方法 | |
| JP6247713B2 (ja) | 蓄電装置の作製方法 | |
| TWI626782B (zh) | 電極材料以及製造電力貯存裝置的方法 | |
| JP2021193674A (ja) | 蓄電装置の製造方法 | |
| JP2012221716A (ja) | 二次電池用の正極活物質およびその作製方法、ならびに二次電池 | |
| JP6363647B2 (ja) | 二次電池用の正極活物質 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |