TWI324047B - - Google Patents
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- TWI324047B TWI324047B TW092120654A TW92120654A TWI324047B TW I324047 B TWI324047 B TW I324047B TW 092120654 A TW092120654 A TW 092120654A TW 92120654 A TW92120654 A TW 92120654A TW I324047 B TWI324047 B TW I324047B
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- 239000000203 mixture Substances 0.000 claims abstract description 96
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- 230000009261 transgenic effect Effects 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 150000003648 triterpenes Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- RMRCNWBMXRMIRW-WYVZQNDMSA-L vitamin b12 Chemical compound N([C@@H]([C@@]1(C)[C@@](C)(CC(N)=O)[C@H](CCC(N)=O)\C(N1[Co+]C#N)=C(/C)\C1=N\C([C@H]([C@@]1(CC(N)=O)C)CCC(N)=O)=C\C1=N\C([C@H](C1(C)C)CCC(N)=O)=C/1C)[C@@H]2CC(N)=O)=C\1[C@]2(C)CCC(=O)NCC(C)OP([O-])(=O)O[C@H]1[C@@H](O)[C@@H](N2C3=CC(C)=C(C)C=C3N=C2)O[C@@H]1CO RMRCNWBMXRMIRW-WYVZQNDMSA-L 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 235000008939 whole milk Nutrition 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/68—Acidifying substances
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/256—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/17—Amino acids, peptides or proteins
- A23L33/18—Peptides; Protein hydrolysates
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/40—Complete food formulations for specific consumer groups or specific purposes, e.g. infant formula
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Mycology (AREA)
- Pediatric Medicine (AREA)
- Molecular Biology (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Dispersion Chemistry (AREA)
- Non-Alcoholic Beverages (AREA)
- Jellies, Jams, And Syrups (AREA)
Description
疚、發明說明: ί:發明所屬之技術領域3 技術領域 本發明係有關於一種綜合營養補給用膠狀飲料組成 物,更詳而言之,係有關於一種含有醣類、脂質及蛋白質 三大營養素且平衡良好並具有柔和之膠狀形態,且具有清 涼感之味道之膠狀飲料組成物。 C先前技術:j 背景技術 從以往就有人研究開發各種液劑形態及固劑形態之各 種營養補給用飲食品(營養食品)製品。這些營養食品製品摻 合有日常生活所需之各種營養素,並利用來作為用以補充 飲食或迅速地補給因運動、工作等所消耗之能量之營養食 品。 發明人先刖亦開發出推合有主要營養素且平衡良好之 南黏性液劑形態之細合營養組成物(參照日本專利公開公 報特公平06-83653號公報),藉由攝取該綜合營養組成物, 可改善不平衡之飲食生活,且適當地補給日常生活所需之 能量及營養素,進而預防及治療(防止惡化)起因於攝取過量 卡洛里(肥胖等)之各種疾病,例如糖尿病、高血壓、心臟病 等’然而’該综合營養組成物為具有在中性附近之阳之高 黏性液劑形g,作為飲料飲㈣因其嗜好性而不易為現代 人所喜愛。 最近,數種束膠形式之飲料在一般清涼飲料市場上市 而成為新的飲食品形態。這些飲料係於藉由震盪等將凝結 之凍膠震潰後飲食,其特有之飲用感覺、吞藥感'食感之 樂趣等符合現代人之嗜好而受到注目。這些康膠形式之飲 料係調整為仿照一般清涼飲料之酸性pH且保存性佳,然而 卻幾乎未含有蛋白質、脂質等,未構成綜合營養補給用之 組成’即,未構成摻合各營養素且平衡良好之組成。 又,WO99/34690號公報中揭示有適於吞嚥困難者之營 養補給用膠狀食品及其製造方法,該膠狀食品係含有蛋白 質、脂質等營養素且平衡良好,並調整為具有清涼感之酸 性pH,且為具有飲料合適性(可吞嚥性)之膠狀食品。然而, 該食品本身必須為蛋白質之等電點凝膠(由蛋白質形成之 凝膠)與如果膠、三仙膠等膠凝劑(增稠劑)之凝膠之複合凝 膠’故具有如下述之缺點’即’由於該凝膠在凝結(凝膠化) 蛋白質後均質化且藉由膠凝劑將所得到之乳化液凝膠化, 因此,依照均質化程度之不同,蛋白質之凝膠會對味覺造 成不良影響。且,該食品因長期保存而在經過一段時間後 製品p Η會降低,凝膠隨之在經過一段時間後品質變差(強度 降低、一部分衰變、脫水等),且無法維持具有製造最初之 飲食合適性(容易咀嚼之適當硬度與黏度)之均質凝膠狀形 態。 H 明内 3 發明之揭示 本發明之目的係提供一種綜合營養補給用膠狀飲料組 成物,該綜合營養補給用膠狀飲料組成物係含有各營養素 且平衡良好,並具有具清涼感之低PH與適合飲食(飲用)之 柔和之膠狀形態,且該形態可長期安定地保存者。 發明人構想若可將先前開發之综合營養組成物(參照 特公平06-83653號公報)作成凍膠形式夂飲料形態,則可^ 到飲食合適性優異且可補給综合營養之飲料而反覆研究= 然而,若將以較高濃度含有蛋白質、脂質等且適合補給综 合營養之營養組成物調整為如公知凍膠形式飲料般具有清 涼感之酸性pH,則確認蛋白質會凝結而無法構成均勻之膠 狀形態’且產生粗糙表面而損害食感,又,亦確認了脂質 成分亦會分離而無法得到均質組織。 發明人進而反覆研究之結果,發現如下所示在特定量 範圍内利用特定成分時,可得到符合前述目的之综合營養 補給用膠狀飲料組成物。本發明係以該見識為基礎進而反 覆檢討而完成。 本發明係提供如下述第1至7項之膠狀飲料組成物及第 8、9項之膠狀飲料組成物之製造方法。 第1項·一種綜合營養補給用膠狀飲料組成物,係具有3 〜4範圍之pH之膠狀物,且相對於組成物全重量,包含有: 醣類5〜20重量% ;脂質0.1〜5重量% ;於?1^3〜4不凝結之 蛋白質素材2.5〜6重量% ;檸檬酸ο]〜3重量% ;選自於由 抗壞血酸、酒石酸、琥站醆、蘋果酸、葡萄糖酸、磷酸、 植酸及檸檬酸.3Na所構成之群中之至少丨種之酸成分〇 2〜 1.5重量!% ;乳化劑0.01〜〇·5重量% ;瓊脂〇丨〜丨重量% ; 及水65〜90重量%。 棒樣酸〇·2〜3重量% ;選自於由抗壞血酸、酒石酸、琥珀 酸、頻果酸、葡萄糖酸、磷酸、植酸、乳酸及檸檬酸· 3Na 所構成之群中之至少1種之酸成分0.2〜1·5重量% ;乳化劑 〇·01〜〇.5重量% ;瓊脂0.1〜1重量% ;及水65〜90重量% » 第9項.如前述第8項之膠狀飲料組成物之製造方法,其 中前述冷卻係於將混合物填充於容器後進行。 本說明書中,只要「%」沒有特別聲明,則表示「重 量%」。 本發明之綜合營養補給用膠狀飲料組成物係具有特別 適合飲用之柔和膠狀形態與清爽之食感,且具有可長期安 定地保持該膠狀形態及食感之優異保存安定性。本發明膠 狀飲料組成物中所謂「柔和之膠狀形態」係指具有如將本 發明組成物填充於具有吸口之容器時可輕易地從該吸口飲 食之流動性,且具有在該飲食時可得到適當之味覺與吞嚥 感之適度硬度及黏度。本發明膠狀飲料組成物中所謂「清 爽之食感」特別是藉由組合利用檸檬酸與其他特定酸成分 並將pH調整為3〜4,較佳者為3 5〜4之酸性領域來賦予。 本發明膠狀飲料組成物中所謂「保存安定性」係指例如於 37°C放置1個月實質上亦維持與製造最初相同ipH及膠狀 形態之性質。 本發明組成物雖然具有酸性,但卻不會感覺因蛋白 質凝結乃至凝固所造成之不均、味覺之粗糙表面,且飲用 合適性及食感優異’外觀上亦為平滑且均質者。 又,如前所述,由於本發明膠狀飲料組成物係豐富地 1324047 摻合有醣類、脂質、蛋白質等人體所需之營養素且平衡良 好,因此藉由飲用該膠狀飲料組成物,可得到綜合營養補 給效果。 以下詳細說明構成本發明膠狀飲料組成物之各成分, 5 再詳細說明本發明組成物之製造方法。 醣類 醣類可從一般此種營養補給用組成物所慣用者中適當 地選擇。該醣類為三大營養素之一,且以肝糖儲存於肝臟 或肌肉中,並於運動時等作為能量源消耗,其具體例可列 10 舉如:葡萄糖、果糖等單糖類;麥芽糖、蔗糖、乳糖等二 糖類;木糖醇、山梨糖醇、丙三醇、赤藻糖醇等糖醇類; 糊精、環糊精等多糖類;果寡糖、乳寡等寡糖類等。這些 醣類可單獨使用其1種,亦可併用2種以上。2種以上之併用 當然亦包含使用市售之如異構糖、精製白糖等之醣類混合 15 物者。 於這些醣類中,舉例言之,包含有如蔗糖般不僅作為 營養源且亦作為甜味料之機能者。由於具有此種甜味料機 能之醣類會賦予所得到之膠狀飲料組成物甜味,因此通常 宜加以利用。 20 於本發明膠狀飲料組成物中,醣類之摻合量宜設為5 〜20% ,且以10〜20%為佳,尤以13〜18%為佳。藉由於 前述範圍内來利用,本發明組成物可構成為避免作為營養 源之醣類之過與不足且其摻合平衡良好。特別是具有甜味 料機能之醣類可於5〜15%之範圍内摻合,且以8〜13%尤 10 佳。 脂質 月旨質可從此種營養補給用組成物中所廣泛使用之各種 物質中適當地選擇。該脂質在例如長時間運動時等取代前 述黯類成分而作為能量源请耗,該脂質之代表例首先可列 舉如作為必須脂肪酸源之長鏈脂肪酸三酸甘油酯(LCT)。該 LCT包含如:大豆油、錦籽油、紅花油、玉米油、米油、 椰子油、紫蘇油、芝麻油、亞麻仁油等植物油;沙丁魚油、 鳕魚肝油等魚油;蛤模油等。又,腊質之其他代表例可列 10 舉如故數8〜10之中鍵脂肪自文二酸甘油自旨(mct)。該MCT之 特徵係具有易吸收性、易燃燒性、難蓄積性。LCT及MCT 可單獨使用其1種,亦可由相同或相異之群中併用2種以上。 於本發明膠狀飲料組成物中,脂質可於〇1〜5%之範 圍内添加摻合,且以0.1〜3%為佳,尤以〇5〜3%為佳。藉 Μ由於該範圍内來掺合’可滿足作為平衡營養補給組成物之 原則。 乳化劑 由於脂質為油性且不容易溶解於水中’因此通常以水 中油型乳膠形態利用在本發明中。故,在調製本發明組成 20物時,必須利用用以使該脂質乳化之乳化劑。該乳化劑可 適當地選擇使用各種迄今飲食品領域中所利用者。若考慮 將本發料組餘為敢紐,_乳化劑雜 自於具有耐酸性者。 其代表例可列舉如甘油月旨肪酸_。甘油___ 11 1324047 可使用各種於此種食品領域中已知利用來作為乳化劑之物 質,例如可利用分類為高純度一酸甘油酯、高純度二甘油 單脂肪酸酯、聚甘油酯等各種物質之任一者。其具體例可 列舉如:市售之「太陽軟體」(註冊商標’太陽化學公司製 5 造)、「耶摩爾齊(工7少^一)」(註冊商標,理研維生素公 司製造)、「料特(口3一卜一)」(註冊商標,三菱化學公司 製造)等。 於本發明中’除了甘油脂肪酸酯類以外,亦可使用於 此種食品領域中所利用之乳化劑。其例子包含有:如卵黃 10 即填脂、氣化印男·卵鱗脂、大丑印填脂、氮化大豆印填脂 等磷脂;聚氧乙烯單油酸醋(例如以「吐溫8〇」(註冊商標, AMR公司製造)市售者)等之合成界面活性劑;蔗糖脂肪酸 酯;脫水山梨糖醇脂肪酸酯;丙二醇脂肪酸酯等。 乳化劑無須僅單獨使用其1種,可併用2種以上,通常 15宜併用2種以上。於本發明膠狀飲料組成物中,乳化劑可以 〇·01〜〇·5%之比例摻合’且以0.01〜0.3%為佳。又,於製 ^本發明膠狀飲料組成物時,在預先混合蛋白質、檸檬酸 及其他酸成分而調製乳化液乃至分散液時,於該液中乳化 劑之摻合比例宜設為1〜5%,且以3〜5%之濃度之比例為 20 佳〇 蛋白質素材 蛋白質與前述醣類及脂質同為三大營養素之一。於本 發月中蛋白質素材係選擇使用於本發明膠狀飲料組成物 所八有之Ρίϊ,即,於3〜4之pH不凝結者◎該蛋白質素材可 12 1324047 列舉如.乳清蛋白濃縮物(WPC,Whey Protein Concentrate)、乳清蛋白單離物(wpi ’ Whey Protein Isolate)、脫鹽乳清等之蛋白質及數量平均分子量通常約在 500〜10000,較佳者為2〇〇〇〜8000之範圍内之蛋白質水解 5物(亦可包含肽類、一部分之胺基酸),其中宜為WPC及WPI。 WPC及WPI係將為乾酪及酪蛋白製造過程中所得到之 乳製品副產品之乳清液體作為原料,而藉由進行過濾、離 子交換、結晶、沉澱、逆滲透等操作而得之乳清製品。市 售之 WPC 有 WPC-34、WPC-50、WPC-60、WPC-75 及 10 WPC-80。雖然依製造業者之不同而有些許差異,不過, WPC及WPI之蛋白質含量(重量% )'構成該蛋白質之主要成 分之組成(相對於全蛋白質之重量% )及蛋白質以外成分之 含量(重量% )係如下述表1所示(參照New Food Industry, 25(3) , 33(1983)等)。 15 表1 WPC-34 WPC-50 WPC-60 WPC-75 WPC-80 WPI 蛋白質 34-36 50-52 60-62 75-78 80-82 90-92 α -乳球蛋白 6.5 9.5 11 14 15 21 冷-乳球蛋白 16 24 29 36 38 47 ώ·清白蛋白 1.7 2.5 3.0 3.8 4.0 1.5 免疫球蛋白 2.7 4.0 4.8 6.0 6.4 2.4 乳糖 48-52 33-37 25-30 10-15 4-8 0.5-1 脂肪 3-4.5 5-6 1-7 4-9 4-8 0.5-1 灰分 6.5-8·0 4.5-5.5 4-6 4-6 3-4 2-3 水分 3.0-4.5 3.5-4.5 3-5 3-5 3.5-4.5 4.5 PH 6-6.7 6-6.7 6-6.7 6-6.7 6-6.7 6-6.7 脫鹽乳清可從低溫殺菌過之乳清依照沉澱、過濾、透 析等分離技術並除去無機物而得。通常其醣類含量為79 13 % ’脂質含量為2%,蛋白 7%。 * 3篁马13<,灰分含量則小於 數1平均分子量位於約5⑼〜⑽⑻ 解物可列舉如:_料 内之蛋白質水 5 I白曹㈣f 言酸4將於PH3〜4範圍不凝結之 蛋質或後述路蛋白、明耀、大豆蛋白、 之:峨作成前述預定分子量之肽,其通常= 之胺基酸狀鍵合後之肽所構成。前述蛋白質水解
物亦可含有胺基酸。較佳之蛋白質水解物之數量平均分子 量約為2000〜8000。 1〇 _3〜4不凝結之蛋白質素材可單獨使用其增,或者 昆合2種以上制。其摻合於本购·飲料組成物中之換 合量宜設為2.5〜6%,且以3〜5%之範圍為佳。藉由於該 範圍内摻合,可構成適當之蛋白質源之營養平衡,且可滿 足作為綜合營養飲料組成物之原則。 15 於本發明組成物中,亦可依需要與於PH3〜4不凝結之
蛋白質同時地來併用於酸性領域中凝結之蛋白質素材。其 具體例可列舉如:路蛋白、大豆蛋白、小麥蛋白等;該等 之鹽類,則述各種蛋白之發酵產物;前述各種蛋白之萃取 物,刖述各種蛋白之濃縮物;其他全脂乳粉、脫脂乳粉等。 20該等可單獨使用1種,亦可混合2種以上使用。藉由將該等 蛋白質與前述於pH3〜4不凝結之蛋白質併用,可調整蛋白 質成分之平衡、改善呈味性。該等於酸性領域中凝結之蛋 白質素材中,係以為發酵產物之乳果、乾酪較為理想,然 而’於酸性領域中凝結之蛋白質素材摻合於本發明組成物 14 I之摻合|必須設為不會損害本發明組成物之雜形態、 e &味覺)等特徵之量,該量宜設為在本發明膠狀飲料組成 物中小於1%之量。 檸樣酸及酸成分 5 於本發明膠狀飲料組成物中, 為了將其pH調整為3〜 ’較佳者為3.5〜4,併用檸檬酸與選自於由抗壞血酸、酒 石酸、琥珀酸、蘋果酸、葡萄糖酸、磷酸、植酸、乳酸及 才宁樣酸· 3Na所構成之群中之至少丨種之酸成分是重要的。 於本發明膠狀飲料組成物中,檸檬酸係於0.2〜3%, 10較佳者為〇.2〜2%之範圍摻合,且以用以將組成物之pHs 為3〜4之足夠量來摻合。若利用於該摻合量範圍之檸檬 酸’則所得到之組成物之酸味變得過酸且不會有阻礙食物 味道之虞。 作為酸成分之選自於由抗壞血酸、酒石酸、琥珀酸、 15 蘋果酸、葡萄糖酸、磷酸、植酸、乳酸及檸檬酸.3Na所構 成之群中之至少1種係不會損害組成物之食感並可構成更 清爽之食感,且具有PH調節作用乃至緩衝作用,其中特別 是以葡萄糖酸及乳酸為佳。又,抗壞血酸係具有可得到作 為維生素C之營養補給效果之優點,故以摻合為佳。於本發 20明膠狀飲料組成物中’該等酸成分係於0.2〜1.5%之範圍内 摻合,且以0.2〜I·0%為佳,依此,可改善期望之食感及得 到pH調節作用乃至缓衝作用。 又,於本説明書中’凝膠之pH係藉由利用玻璃電極之 測定法來求得。 15 本發明膠狀飲料組成物係利用瓊脂來作為其必須膠凝 劑成分。瓊脂可使用各種以石花菜、龍鬚菜、雞毛菜、伊 谷草等紅藻類為原料且進行熱水萃取並凝固後使其乾燥之 物質中之任一者。該瓊脂包含有絲瓊脂、棒瓊脂、片瓊脂、 粉末瓊脂等。於組成物中,其摻合比例宜從0.1〜1% ,較 佳者為0.2〜0.5%之範圍中選擇。藉由於該範圍内來利用瓊 脂’可得到本發明期望之均質之飲食合適性優異之膠狀物。 水 本發明膠狀飲料組成物,又,相對於組成物全量係含 有65-90%之水’且以含有70_85%為佳。 其他膠凝劑或增稠劑 於本發明組成物中’更可依需要將以往在食品頜威中 作為膠凝劑乃至增稠劑廣泛利用之各種物質與前述缓脂併 用。該膠凝劑可列舉如:結冷膠 '鹿角菜膠、果膠、明膠 等。又,增稠劑可列舉如:富塞蘭藻膠、刺槐豆膠、瓜爾 豆膠、阿拉伯膠、三仙膠等。其中,宜為選自於結冷膠、 鹿角菜膠、果膠、明膠之膠凝劑,及選自於刺槐豆膠、泰 爾豆膠及三仙膠之增稠劑。這些膠凝劑及増網劑可分別單 獨使用1種’亦可併用2種以上,特別是以併用膠凝劑與增 稠劑為佳。膠凝劑及/或增稠劑係藉由其摻合來發揮適度之 凝膠化能與凝膠安定化能,且有助於調整所得到之膠狀物 之凝膠強度,又,藉由與瓊脂併用,可改善脫水性、食感 等。 1324047 本發明膠狀飲料組成物中,通常膠凝劑及增鲷劑可分 別於0.05〜0.3%之範圍内摻合。 其他添加劑 於本發明膠狀飲料組成物中,除了前述各成分之外, 更可依期望摻合適當之添加劑成分。 該成分可列舉如:天然甜味料(醣類除外)、合成甜味料 等甜味料、維生素類及無機物類(電解質及微量元素)、天然 香料、合成香料等香料、著色料、風味物質(巧克力等)、保 存料、天然果汁、天然果肉等。 10 天然甜味料(不屬於醣類之甜味料)可列舉如:索門丁 甜菊萃取物(類配St體A等)、甘草甜素等。合成甜味劑可列 舉如.糖精、天冬醯苯丙胺酸曱酯等。 維生素_各種轉性讀祕維生素類, 15 =維_(網關 '維__素)、維生 二 素)、維生桃⑽醇)、維生素伽維生素)、峰生: ^觀醇等 >、維生针(生細)、祕 ' 祕:、泛、生㈣、酒石錢膽驗等胺、 如.务儿 里兀常)係一般之物質,可列舉 .虱化鈉、醋酸鈉、硫酸鎂、 20 酸鈣、《V, Μ 、虱化鎂、氣化鈣、葡萄糖 酸鈣礼酸鈣、席夫鈣、磷醆二飼、伙Μ ,. 巧碟酸一鈉、甘油碟酸 ,丐、卵喊鈣、牛骨粉、牛奶鈣 隹瑞酴雜^ 払檬酸鐵'焦磷酸亞鐵、 I酸錳、硫酸銅、硫酸辞、 蛾化鈉、山細、鋅、盆、銅、碟、銘等。 天然香料、嫩吻料可_心親、柳橙 17 1324047 味、葡萄柚味、檸檬味等。 著色料可列舉如:紅色2號、紅色3號、綠色3號、藍色 1號、藍色2號、黃色4號、黃色5號、紅甘藍色素、柳橙色 素、樓子花色素、葉綠素、紫蘇色素、蕃茄色素、紅花色 5素等。 風味物質可列舉如巧克力等。
保存料可列舉如:丁羥基苯甲醚(BHA)、二丁羥基曱 苯(BHT)、硝酸鈉、亞硝酸鈉、乙二胺四醋酸二鈉(EDTA · 2Na)、tert-丁基氫醌(TBHQ)、安息香酸、安息香樹萃取物、 10 茵陳蒿萃取物、日柏酚萃取物、果膠分解物、朴木萃取物、 連翹萃取物等。 天然果汁、天然果肉可列舉如:蘋果、青蘋果、柳橙、 橘子、葡萄柚、桃子、草莓、麝香葡萄、葡萄、鳳梨、檸 檬、西洋梨、荔枝、藍莓、芒果、香蕉等。 15 於該等之中,維生素類及無機物類之添加係合乎綜合
營養補給之目的且較為理想。特別是維生素類可列舉如下 述組成(於本發明組成物200g中所摻合之各維生素類組 成,更含有1〜500mg之維生素C)之综合維生素類。
維生素A 10〜2000IU 維生素B! 0.01 〜3.0mg 維生素b2 0.01 ~ 3.1 mg 維生素b6 0.01 〜3.2mg 維生素b12 0.卜 ^30pg 維生素D 1〜: 300IU 20 18
維生素E 1〜100IU 於酿胺 0.1〜30mg 泛酸ί弓 0.1〜31mg 葉酸 〇.〇1〜lOmg 5 該等添加劑成分可單獨利用1種,亦可組合2種以上。 該等成分之摻合比例並無特殊之限制,然而,一般而言, 天然果汁及天然果肉以外之添加劑成分通常係由合計^相 對於本發明膠狀飲料組成物1〇〇重量份為小於2重量份之量 中選擇。又,天然果汁及天然果肉可於合計量相對於本發 10明膠狀飲料組成物100重量份為50重量份為止之量來摻合。 本發明組成物之製造 本發明組成物係藉由首先於加溫下將前述各成分之預 定量與預定量之水混合後乳化,接著進行冷卻來調製。前 述乳化可藉㈣全部成分同時投人水中後加上㈣摔等些 許機械操作來崎。又,料藉_切水雜成分調製 為水溶液形態,且於其中加人油溶性成分與乳化劑或該等 之混合物’並同樣地進行攪拌等之方法來進行。為了得到 更均質之乳化混合液,財讀用後者之方法為佳。 15 20 前述各成分之混合操作(乳化操作)可於常溫下實施但 宜採用加溫條件來實施。又,前魏化操作係依照-般之 方法’可利用適當之乳化機如高速乳化機、高壓均化器等 而藉由完全通過方錢藉㈣環方式來實施。 士本發明組絲特別理想之製造方法之—具體例係,舉 例&之’於蛋白f成分、檸檬酸及水之混合液(分散液)中添 19 1324047 加並混合脂質、乳化劑、醣類及其他添加劑成分,且將所 得到之乳化物加溫至6〇t左右,並混合該乳化物以及使瓊 脂、其他膠凝劑乃至增稠劑加熱溶解於預先加溫至8〇。〇左 右之水中所調製之液體之方法。 5 期望膠狀飲料製品可藉由將依上述所得到之乳化液冷 卻來取得,更為理想的是藉由將乳化液填充於適當容器並 殺菌後冷卻來取得。適當之容器可為作為此種飲料之收納 容器使用之各種塑膠製容器之任一者,其材質可列舉如: 積層聚乙烯、聚丙烯、延伸聚醯胺、聚對苯二甲酸乙二酯、 10愛柏爾(工八-少)(註冊商標,乙_ .乙稀醇共聚合樹脂, 倉雷(夕^)股份有限公司製造)及該等樹脂與紹、紙等之 複合材料等。市售具體之容器可列舉如:軟盒(例如富士密 封股份有限公司製造)、瓶裝盒(註冊商標,凸版印刷股份有 限公司製造)、素盒(只只夕于)(註冊商標,大日本印刷股份 15有限公司製造)、茶包(于r 一只 '少夕)(註冊商標,細川洋行 公司製造)等。殺菌可依照慣用方法並藉由加熱殺菌等來實 施’此時’由於兼具加溫操作之功能,因此無須該殺菌操 作前之加溫操作。 依此調製之本發明膠狀飲料製品係具有良好飲食合適 20性且可安全飲用者,且藉由飲用該膠狀飲料製品,可充分 得到取得平衡之營養源之補給效果。 C實施方式2 發明之較佳實施形態 又,於 以下舉出實施例以進一步詳細地說明本發明。 20 1324047 各例中,只要份及%沒有特別標記則表示重量份及重量%。 實施例1-4 將下述表2所示各成分之預定量及作為其他成分之適 量無機物、維生素及香料投入水中,混合攪拌並使其乳化 5 後昇溫至80°C,且將其200g填充於素盒(註冊商標,大曰本 印刷股份有限公司製造),並以80°C加熱殺菌10分鐘後冷 卻,得到裝入盒子之本發明膠狀飲料製品。又,無機物係 使用葡萄糖酸鈣,維生素係使用前述列舉之維生素類,香 料則使用蘋果味。 10 依前述所得到之本發明膠狀飲料於外觀上皆具有均一 且平滑之表面狀態,且呈現柔和之凝膠狀。 15 20 21 表2 ^—_ 珉分 她 -------- 實施例 1 2 3 I 4 嗯類 砂糖 果糖 -_____事糖 10.0 10.0 5.0 5.0 15.0 脂質 一- 米油 玉米油 油 2.0 2.0 2.0 1.0 1.0 货白賀素材 wpi WPC 分解明勝 6.0 4.0 4.0 1.0 4.0 1.0 知檬餐 一 Γ7 X —— 0.8 0.7 1.0 0.8 竣成分 蘋果酸 抗壤血酸 ^糖酸 0.4 0.4 0.6 0.6 乳化劑 甘油脂肪酸酯 蔗糖脂肪酸酯 卵磷脂 0.2 0.2 0.2 0.1 0.1 瓊脂 0.6 0.5 0.5 0.5 增稠劑 瓜爾豆膠 刺槐豆膠 三仙膠 - 0.1 0.1 0.1 水 80.0 82.1 80.6 75.8 能量(Kcal/lOOg) 79.6 70.8 76.0 94.4 pH 3.9 Γ 3.7 3.7 3.9 表2中所使用之各成分係如下述,於後述表3中亦相同〇 WPI :使用表1所示之WPI。
WPC :使用表1所示之WPC-80 » 酵素分解明膠:將明膠酵素分解者,數量平均分子量 22 約為8000以下。 又’能量係以(4χ醣類含量)+(9χ脂質含量)+ (4x蛋白 質si)來汁异,然而表示每i〇〇g試料之Kcal。 實施例5-10 混合下述表3所示之蛋白質素材、檸檬酸與其他酸成分 及—部分之水(構成50%之量)並調製分散液《接著,將表3 所示之脂質、醣類、乳化劑及增稠劑之預定量及作為其他 成分之適量無機物、維生素及香料投入前述分散液中,混 合攪拌後使該混合物昇溫至6〇eC並調製A液。另一方面,使 剩餘之水昇溫至80 C以上,且於其中加入各表所示之環脂 及其他膠凝劑成分’攪拌溶解後調製B液。 混合刖述A液與B液,將其2〇〇g填充於素盒,並以 加熱殺菌10分鐘後冷卻,得到裝入盒子之本發明膠狀飲料 製品。 依前述所得到之本發明膠狀飲料於外觀上皆具有均一 且平滑之表面狀態,且呈現柔和之凝膠狀。 1324047 試驗例1 該試驗係藉由官能試驗來調查本發明所利用之酸對所 得到之膠狀飲料之酸味之影響。 將下述各成分投入水中,與實施例1相同地調製本發明 5 膠狀飲料試料1〜7及比較飲料試料1〜3。 作為醣類之砂糖及糊精(7 : 3混合物) 16.1% 作為脂質之玉米油 0.6% 0.02% 0.3% 0.1°/〇 表4所示之量(% ) 表4所示之量(% ) 於pH3〜4不凝結之蛋白質素材之WPC(表1所示者)6.1% 作為乳化劑之甘油脂肪酸酯 10 瓊脂 作為增稠劑之瓜爾豆膠 檸檬酸 酸成分 使10名小組討論參加者飲用所得到之各試料,並藉由 15 下述基準官能評價其酸味。 3:具有理想之酸味 2:感覺有些許酸味 1 :過酸 所得到之結果併計於表4,然而,官能試驗評價係以10 20 名小組討論參加者之合計分數來表示。 又,各試料基於其pH為3.7-4.0而皆具有清爽之食感。 25 1324047 表4 試料No. 所使用之酸及使用量(% ) pH 官能評價 本發明1 檸檬酸0.5 抗壞血酸1.0 — 4.0 23 本發明2 檸檬酸1.0 擰檬酸3Na0.5 — 3.9 20 本發明3 檸檬酸0.5 葡萄糖酸0.5 — 3.9 23 本發明4 檸檬酸0.5 磷酸0.5 — 3.9 21 本發明5 檸檬酸0.5 乳酸0.5 — 3.9 28 本發明6 檸檬酸0.5 磷酸0.5 葡萄糖酸0.5 3.8 28 本發明7 檸檬酸0.5 乳酸0.5 磷酸0.5 3.7 26 比較1 檸檬酸1.0 — — 3.5 15 比較2 酒石酸1.0 — — 3.9 12 比較3 蘋果酸1.0 — — 4.0 13 如表4所示,組合利用檸檬酸與其他酸成分之1種或2 種而得到之本發明膠狀飲料試料於官能試驗中係評價為感 覺有些許酸味或具有理想之酸味,相對於此,單獨利用檸 5 檬酸或其他酸而得到之比較飲料則皆被評價為過酸之食 感。 試驗例2 該試驗係用以調查本發明膠狀飲料組成物及比較飲料 組成物於經過一段時間之pH變化(降低)及凝膠硬度變化(降 10 低)而進行者。 利用表5所示之各成分,與試驗例丨所示之方法相同地 調製本發明膠狀飲料試料(本發明品)及比較飲料試料(比較 品)〇 26 1324047 表5 組成(% ) 本發明品 比較品 醣類(砂糖+糊精=7 : 3) 16.0 16.0 脂質(玉米油) 2.1 2.1 於pH3〜4不凝結之蛋白質素材(WPI) 2.9 2.9 乳化劑(甘油脂肪酸酯) 0.1 0.1 瓊脂 0.3 0.3 增稠劑(瓜爾豆膠) 0.1 0.1 擰檬酸 0.42 0.21 乳酸 0.09 - 水 78.0 78.3 將所得到之各試料保存於室溫(25°C)-1個月、37°C-1個 月或50°C-1週之各條件下,且於製造後不久及保存後之各 時期調查其pH及凝膠狀態。凝膠狀態係藉由利用10名小組 5 討論參加者之官能試驗來評價,且藉由下述評價分數之合 計分數來表示。於該合計分數為20分以上時判斷為凝膠強 度良好,15〜19分時判斷為凝膠強度弱,14分以下時則判 斷為凝膠強度不佳。 3:口味佳且為柔軟之凝膠狀態 10 2 :柔軟之凝膠狀態稍弱(口味之良好度減少) 1 :凝膠之形成狀態非常弱(無定型性且為液狀) 下述表6顯示所得到之結果。 表6 試料 本發明品 比較品 pH 凝膠強 度 專門小 組測試 pH 凝膠強 度 專門小 組測試 室 試驗開始時 3.78 良好 28 3.99 良好 25 溫 1個月後 3.77 良好 28 3.99 良好 23 37 試驗開始時 3.78 良好 28 3.99 良好 25 °C 1個月後 3.78 良好 23 3.80 不佳 14 50 試驗開始時 3.78 良好 28 3.99 良好 25 °C 1週後 3.77 良好 21 3.95 弱 16 27 1324047 由表6所示之結果可知,若為本發明膠狀飲料試料(本 發明品)’則於37 C、保存1個月後及5〇。〇、保存丨週後亦幾 乎沒有pH變化及凝膠硬度之降低,相對於此,若為比較試 料(比較品)’則顯然於37。(:、保存1個月後pH大幅降低且凝 5膠無法保持凝膠狀態而成為接近溶膠之狀態,又,於50eC、 保存1週後則雖然pH降低少但凝膠狀態變弱。 試驗例3 該試驗係將本發明膠狀飲料組成物放置於高溫且藉由 官能評價試驗其安定性(凝膠之耐熱性)。 利用表7所示之各成分之預定量,與試驗例丨同樣地來 調製本發明膠狀飲料試料(本發明品)及比較飲料試料(比較 品)〇 表7
一 組成(% ) 本發明品 比較品 ^^醣類(砂糖+糊精=7 : 3) 16.1 16.1 -- 脂質(玉米油) 0.6 0.6 〜4不凝結之蛋白質素材(WPI) 6.1 6.1 __乳化劑(甘油脂肪酸酯) 0.02 0.02 ^瓊脂 0.3 0.3 〜_ 增稠劑(瓜爾豆膠) 0.1 0.1 --- 檸檬酸 0.39 0.83 ----葡萄糖酸_ 0.352 . __ 磷酸 0.085 - 〜水 76.0 76.0 將所得到之各試料於65。(:、70°C ' 75〇C ' 80°C 或 85°C 15分別放置1分、2分、3分、5分、10分、20分、30分、40分、 50分或60分後冷卻,使1〇名小組討論參加者飲用並藉由下 述基準來評價各凝膠之狀態。 28 A:口味佳且為柔軟之凝膠狀態 B:柔軟之凝膠狀態稍弱(口味之良好度減少) C :凝膠之形成狀態非常弱(無定型性且為液狀) 下述表8顯示所得到之結果。 表8 放置時間(分) 1 2 3 5 10 20 30 40 ' 65〇C 本發明品 A A A A A A A 比較品 A A A A A A A 70°C 本發明品 A A A A A A A 比較品 A A A A A A B C 75 °C 本發明品 A A A A A A A A 比較品 A A A A A B C - 80°C 本發明品 A A A A C - - 比較品 A A C - - - - ~syc\ 本發明品 A A A - - 比較品 B C - - B 由表8所示之結果可知,構成本發明膠狀飲料試料(本 發明品)之凝膠係具有即使利用高溫亦不易劣化之耐熱性
B 如前所述,本發明膠狀飲料製品係具有良好飲食合適 性且可安全飲用,且藉由飲用該膠狀飲料製品,可充分得 到取得平衡之營養源之補給效果。又,本發明膠狀飲料製 品亦適合用在例如運動選手等在運動中於短時間内欲進行 營養補給時等。 產業上之可利用性 本發明之目的係提供一種综合營養補給用膠狀飲料組 成物,該綜合營養補給用膠狀飲料組成物係含有各營養素 且平衡良好,並具有具清涼感之低pH與適合飲食(飲用)之 柔和之膠狀形態,且該形態可長期安定地保持者。藉由攝 1324047 取該組成物,可改善不平衡之飲食生活,且適當地補給活 動所需之能量及營養素,進而預防及治療(防止惡化)起因於 攝取過量卡洛里(肥胖等)之各種疾病,例如糖尿病、高血 壓、心臟病等。又,本發明综合營養補給用膠狀飲料組成 物對於隨著高齡者之人口增加而逐漸増加之吞嚥困難者而 I亦可作為有用之營養補給食品,特別是該組成物不用擔 。攝取時@該組成物誤人氣管而彳丨起喘不過氣地咳漱、 吸入性肺炎之發病等’且亦沒有因該組成物啥住而窒息之 危險性等,故可安心且美味地食用。 鲁 I闺式簡單說明】 (無) 30
Claims (1)
1324047 第92120654號專利申諳案申譆糞利範圍替換本 99年2月 告本¥、申請專利範圍:日修正本 ί_L—5----- 1. 一種综合營養補給用膠狀飲料組成物,係具有3〜4範圍 之pH之膠狀物,且相對於組成物全重量,包含有:醣類 5〜20重量% ;脂質0.1〜5重量% 〜4不凝結之 5 蛋白質素材2.5〜6重量% ,係選自於由乳清蛋白濃縮 物、乳清蛋白分離物、脫鹽乳清及數平均分子量 500~1〇〇〇〇之明膠水解物所構成之群中之至少1種;檸檬 酸0_2〜3重量% ;葡萄糖酸及磷酸0.2〜1·5重量% ;乳 化劑0.01〜0.5重量% ;瓊脂0.1〜1重量% ;及水65〜90 10 重量% 。 2·如申請專利範圍第1項之膠狀飲料組成物,更包含有 - 0·05〜0.3重量%之選自於由結冷膠、鹿角菜膠、果膠及 - 明膠所構成之群中之至少1種之膠凝劑。 3. 如申請專利範圍第1項之膠狀飲料組成物,更包含有 15 0·05〜0‘3重量%之選自於由瓜爾豆膠、刺槐豆膠及三仙 膠所構成之群中之炱少1種之增稠劑。 4. 如申請專利範圍第1項之膠狀飲料組成物,更包含有 〇·05〜0·3重量%之選自於由結冷膠、鹿角菜膠、果膠及 明膠所構成之群中之至少1種之膠凝劑,與0.05〜0.3重 里%之選自於由瓜爾豆膠、刺槐豆膠及三仙膠所構成之 群中之至少1種之增稠劑。 •一種如申請專利範園第1項之膠狀飲料組成物之製造方 法’係於加溫下混合並乳化下述各成分,接著將所得到 5物予以冷卻者,且前述各成分包含有: 31 1324047 醣類5〜20重量% ; 脂質0.1〜5重量% ; 於pH3〜4不凝結之蛋白質素材2.5〜6重量%,係選 自於由乳清蛋白濃縮物、乳清蛋白分離物、脫鹽乳清及 5 數平均分子量500〜10000之明膠水解物所構成之群中之 至少1種; 擰檬酸0.2〜3重量% ; 葡萄糖酸及磷酸0.2〜1.5重量% ; 乳化劑0.01〜〇·5重量% ; 10 瓊脂0·1〜1重量% ;及 水65〜90重量%。 6.如申請專利範圍第5項之膠狀飲料組成物之製造方法, 其中前述冷卻係於將混合物填充於容器後進行。 32
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US (1) | US20050260322A1 (zh) |
EP (1) | EP1541042B1 (zh) |
JP (1) | JPWO2004010796A1 (zh) |
KR (1) | KR100950143B1 (zh) |
CN (1) | CN1326477C (zh) |
AT (1) | ATE326149T1 (zh) |
CA (1) | CA2489566C (zh) |
DE (1) | DE60305331T8 (zh) |
ES (1) | ES2261983T3 (zh) |
TW (1) | TW200403971A (zh) |
WO (1) | WO2004010796A1 (zh) |
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- 2003-07-29 JP JP2004524176A patent/JPWO2004010796A1/ja active Pending
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Also Published As
Publication number | Publication date |
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ATE326149T1 (de) | 2006-06-15 |
EP1541042A4 (en) | 2005-08-10 |
DE60305331D1 (de) | 2006-06-22 |
KR20050033635A (ko) | 2005-04-12 |
CN1671300A (zh) | 2005-09-21 |
KR100950143B1 (ko) | 2010-03-30 |
EP1541042B1 (en) | 2006-05-17 |
CA2489566C (en) | 2009-12-22 |
WO2004010796A1 (ja) | 2004-02-05 |
EP1541042A1 (en) | 2005-06-15 |
US20050260322A1 (en) | 2005-11-24 |
ES2261983T3 (es) | 2006-11-16 |
JPWO2004010796A1 (ja) | 2005-12-02 |
CN1326477C (zh) | 2007-07-18 |
DE60305331T8 (de) | 2009-07-16 |
TW200403971A (en) | 2004-03-16 |
DE60305331T2 (de) | 2007-02-01 |
CA2489566A1 (en) | 2004-02-05 |
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