TW201016730A - Grafted polyethylene - Google Patents
Grafted polyethylene Download PDFInfo
- Publication number
- TW201016730A TW201016730A TW098122707A TW98122707A TW201016730A TW 201016730 A TW201016730 A TW 201016730A TW 098122707 A TW098122707 A TW 098122707A TW 98122707 A TW98122707 A TW 98122707A TW 201016730 A TW201016730 A TW 201016730A
- Authority
- TW
- Taiwan
- Prior art keywords
- decane
- polyethylene
- examples
- group
- ατμ
- Prior art date
Links
- -1 polyethylene Polymers 0.000 title claims abstract description 201
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 145
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 139
- 238000000034 method Methods 0.000 claims abstract description 80
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 56
- 150000001875 compounds Chemical class 0.000 claims abstract description 33
- 150000003254 radicals Chemical class 0.000 claims abstract description 19
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 104
- 239000003054 catalyst Substances 0.000 claims description 68
- 238000004132 cross linking Methods 0.000 claims description 57
- 239000000203 mixture Substances 0.000 claims description 55
- 230000000052 comparative effect Effects 0.000 claims description 54
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical class CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 claims description 46
- 238000006243 chemical reaction Methods 0.000 claims description 40
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 37
- 229920005989 resin Polymers 0.000 claims description 35
- 239000011347 resin Substances 0.000 claims description 35
- 229920001903 high density polyethylene Polymers 0.000 claims description 34
- 239000004700 high-density polyethylene Substances 0.000 claims description 34
- 238000009833 condensation Methods 0.000 claims description 31
- 230000005494 condensation Effects 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 28
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 20
- 229920003020 cross-linked polyethylene Polymers 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 18
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims description 17
- 239000003963 antioxidant agent Substances 0.000 claims description 17
- 239000004703 cross-linked polyethylene Substances 0.000 claims description 17
- 230000000694 effects Effects 0.000 claims description 15
- 150000002978 peroxides Chemical class 0.000 claims description 15
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 230000003078 antioxidant effect Effects 0.000 claims description 13
- 230000004913 activation Effects 0.000 claims description 12
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 11
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 9
- 239000008188 pellet Substances 0.000 claims description 9
- 229920001179 medium density polyethylene Polymers 0.000 claims description 8
- 239000004701 medium-density polyethylene Substances 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- 125000004429 atom Chemical group 0.000 claims description 7
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 6
- KVWLLOIEGKLBPA-UHFFFAOYSA-N 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexaoxonane Chemical compound CCC1(C)OOC(C)(CC)OOC(C)(CC)OO1 KVWLLOIEGKLBPA-UHFFFAOYSA-N 0.000 claims description 6
- OAWZPHCPLADLAD-UHFFFAOYSA-N 4-(trimethoxymethyl)dodecyl prop-2-enoate Chemical compound C(C=C)(=O)OCCCC(C(OC)(OC)OC)CCCCCCCC OAWZPHCPLADLAD-UHFFFAOYSA-N 0.000 claims description 6
- 230000008901 benefit Effects 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
- PVXLNYCCPHJLIA-UHFFFAOYSA-N C(CCCCCCCCC)OCCCCCCCCCC.C=CC Chemical compound C(CCCCCCCCC)OCCCCCCCCCC.C=CC PVXLNYCCPHJLIA-UHFFFAOYSA-N 0.000 claims description 4
- 125000006575 electron-withdrawing group Chemical group 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 150000002430 hydrocarbons Chemical group 0.000 claims description 4
- 150000001451 organic peroxides Chemical class 0.000 claims description 4
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 claims description 3
- JZHKIUBMQMDQRG-UHFFFAOYSA-N C(=C)C(C(OC)(OC)OC)CCCCCCCC Chemical compound C(=C)C(C(OC)(OC)OC)CCCCCCCC JZHKIUBMQMDQRG-UHFFFAOYSA-N 0.000 claims description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 3
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- OWCFCPLYQPPJPH-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC.CCCCCCCCCC OWCFCPLYQPPJPH-UHFFFAOYSA-N 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 229920003299 Eltex® Polymers 0.000 claims description 2
- 239000013065 commercial product Substances 0.000 claims description 2
- 231100000584 environmental toxicity Toxicity 0.000 claims description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002923 oximes Chemical class 0.000 claims description 2
- 238000010561 standard procedure Methods 0.000 claims description 2
- 150000001454 anthracenes Chemical class 0.000 claims 6
- 229920002098 polyfluorene Polymers 0.000 claims 2
- ADZSJBRALCSBAF-UHFFFAOYSA-N COC(C(OC)(OC)OC)(CCCCCCCC)CCC.C=CC Chemical compound COC(C(OC)(OC)OC)(CCCCCCCC)CCC.C=CC ADZSJBRALCSBAF-UHFFFAOYSA-N 0.000 claims 1
- IGLYOBYYLYQAES-UHFFFAOYSA-N COCCCC(C(OC)(OC)OC)CCCCCCCC.C=CC Chemical compound COCCCC(C(OC)(OC)OC)CCCCCCCC.C=CC IGLYOBYYLYQAES-UHFFFAOYSA-N 0.000 claims 1
- NUPSHWCALHZGOV-UHFFFAOYSA-N Decyl acetate Chemical compound CCCCCCCCCCOC(C)=O NUPSHWCALHZGOV-UHFFFAOYSA-N 0.000 claims 1
- 239000006057 Non-nutritive feed additive Substances 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 150000004756 silanes Chemical class 0.000 abstract 1
- 229940063583 high-density polyethylene Drugs 0.000 description 29
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 16
- 239000000463 material Substances 0.000 description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 15
- 239000005977 Ethylene Substances 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 13
- 229960000583 acetic acid Drugs 0.000 description 13
- 239000002253 acid Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- 239000003651 drinking water Substances 0.000 description 5
- 235000020188 drinking water Nutrition 0.000 description 5
- 239000001530 fumaric acid Substances 0.000 description 5
- 235000011087 fumaric acid Nutrition 0.000 description 5
- 229920001684 low density polyethylene Polymers 0.000 description 5
- 239000004702 low-density polyethylene Substances 0.000 description 5
- 239000011976 maleic acid Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- 239000001117 sulphuric acid Substances 0.000 description 5
- 235000011149 sulphuric acid Nutrition 0.000 description 5
- 239000000052 vinegar Substances 0.000 description 5
- 235000021419 vinegar Nutrition 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 101150019273 GATM gene Proteins 0.000 description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000004611 light stabiliser Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 229920001112 grafted polyolefin Polymers 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229940095064 tartrate Drugs 0.000 description 3
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 3
- CWZQYRJRRHYJOI-UHFFFAOYSA-N 1,1,1-trimethoxydecane Chemical compound CCCCCCCCCC(OC)(OC)OC CWZQYRJRRHYJOI-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 2
- SDVVCEXZGFHIER-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)OCCCCCCCC.C(CCCCCCCCCCC)(=O)OCCCCCCCC Chemical compound C(CCCCCCCCCCC)(=O)OCCCCCCCC.C(CCCCCCCCCCC)(=O)OCCCCCCCC SDVVCEXZGFHIER-UHFFFAOYSA-N 0.000 description 2
- FVUSVCOGYDHBFA-UHFFFAOYSA-N COCC(C(OC)(OC)OC)CCCCCCCC.C=CC Chemical compound COCC(C(OC)(OC)OC)CCCCCCCC.C=CC FVUSVCOGYDHBFA-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 229930182558 Sterol Natural products 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 2
- 125000006612 decyloxy group Chemical group 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010559 graft polymerization reaction Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002198 insoluble material Substances 0.000 description 2
- 150000002688 maleic acid derivatives Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 125000005429 oxyalkyl group Chemical group 0.000 description 2
- 239000003444 phase transfer catalyst Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000004334 sorbic acid Substances 0.000 description 2
- 235000010199 sorbic acid Nutrition 0.000 description 2
- 229940075582 sorbic acid Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 235000003702 sterols Nutrition 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
- QMTFKWDCWOTPGJ-KVVVOXFISA-N (z)-octadec-9-enoic acid;tin Chemical compound [Sn].CCCCCCCC\C=C/CCCCCCCC(O)=O QMTFKWDCWOTPGJ-KVVVOXFISA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- ZKEUVTROUPQVTM-UHFFFAOYSA-N 1-pentylperoxypentane Chemical compound CCCCCOOCCCCC ZKEUVTROUPQVTM-UHFFFAOYSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- CAUIZLLMSGBIJK-UHFFFAOYSA-N 2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(C(O)=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 CAUIZLLMSGBIJK-UHFFFAOYSA-N 0.000 description 1
- UPZFLZYXYGBAPL-UHFFFAOYSA-N 2-ethyl-2-methyl-1,3-dioxolane Chemical compound CCC1(C)OCCO1 UPZFLZYXYGBAPL-UHFFFAOYSA-N 0.000 description 1
- QARLTYSAFQGMMB-UHFFFAOYSA-N 2-ethylbutanenitrile Chemical compound CCC(CC)C#N QARLTYSAFQGMMB-UHFFFAOYSA-N 0.000 description 1
- BWLBGMIXKSTLSX-UHFFFAOYSA-N 2-hydroxyisobutyric acid Chemical compound CC(C)(O)C(O)=O BWLBGMIXKSTLSX-UHFFFAOYSA-N 0.000 description 1
- WQHMEGBWNFRWDH-UHFFFAOYSA-N 2-methoxy-2-methylundecane Chemical compound CCCCCCCCCC(C)(C)OC WQHMEGBWNFRWDH-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- KUQVFOOAIOMQOT-UHFFFAOYSA-N 2-methylpropyltin Chemical compound CC(C)C[Sn] KUQVFOOAIOMQOT-UHFFFAOYSA-N 0.000 description 1
- NFPBWZOKGZKYRE-UHFFFAOYSA-N 2-propan-2-ylperoxypropane Chemical compound CC(C)OOC(C)C NFPBWZOKGZKYRE-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- WIUUTPUGGXEVBH-UHFFFAOYSA-N 3-hydroxybutan-2-one 3-oxobutanoic acid Chemical compound C(CC(=O)C)(=O)O.OC(C(C)=O)C WIUUTPUGGXEVBH-UHFFFAOYSA-N 0.000 description 1
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 1
- OWXXKGVQBCBSFJ-UHFFFAOYSA-N 6-n-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[2-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]ami Chemical compound N=1C(NCCCN(CCN(CCCNC=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC(N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)N(C)C(C)(C)C1 OWXXKGVQBCBSFJ-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- BMTAFVWTTFSTOG-UHFFFAOYSA-N Butylate Chemical compound CCSC(=O)N(CC(C)C)CC(C)C BMTAFVWTTFSTOG-UHFFFAOYSA-N 0.000 description 1
- QBSZKOXEASPZRG-UHFFFAOYSA-N C(=CC)OCCCC(C(OC)(OC)OC)CCCCCCCC Chemical compound C(=CC)OCCCC(C(OC)(OC)OC)CCCCCCCC QBSZKOXEASPZRG-UHFFFAOYSA-N 0.000 description 1
- LERMQUULPSCGHK-UHFFFAOYSA-N C(C)(=O)OCCCC.C(C)(=O)OCCCC.[Sn] Chemical compound C(C)(=O)OCCCC.C(C)(=O)OCCCC.[Sn] LERMQUULPSCGHK-UHFFFAOYSA-N 0.000 description 1
- NXVBTEFXMHHCBG-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)OCCCC.C(C1=CC=CC=C1)(=O)OCCCC.[Sn] Chemical compound C(C1=CC=CC=C1)(=O)OCCCC.C(C1=CC=CC=C1)(=O)OCCCC.[Sn] NXVBTEFXMHHCBG-UHFFFAOYSA-N 0.000 description 1
- YBQXVIHXNPTURF-UHFFFAOYSA-N C(C=C)#N.SC(C(=O)O)=C Chemical compound C(C=C)#N.SC(C(=O)O)=C YBQXVIHXNPTURF-UHFFFAOYSA-N 0.000 description 1
- SDEJOFWFZCMBFX-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)OCCCCCCCC.C(CCCCCCCCCCC)(=O)OCCCCCCCC.[Sn] Chemical compound C(CCCCCCCCCCC)(=O)OCCCCCCCC.C(CCCCCCCCCCC)(=O)OCCCCCCCC.[Sn] SDEJOFWFZCMBFX-UHFFFAOYSA-N 0.000 description 1
- JBOXTBMWKSSCOW-UHFFFAOYSA-N C1(=CC=CC=2C3=CC=CC=C3CC12)C(C(OC)(OC)OC)CCCCCCCC.C=CC Chemical compound C1(=CC=CC=2C3=CC=CC=C3CC12)C(C(OC)(OC)OC)CCCCCCCC.C=CC JBOXTBMWKSSCOW-UHFFFAOYSA-N 0.000 description 1
- IMSKPPWXLVXKAY-UHFFFAOYSA-N CC(C(OC)(OC)OC)(CCCCCCCC)C Chemical compound CC(C(OC)(OC)OC)(CCCCCCCC)C IMSKPPWXLVXKAY-UHFFFAOYSA-N 0.000 description 1
- YJOBGXITWVSGQV-UHFFFAOYSA-N CC(C)(C)OOC(C)(CCC(C)(OOC(C)(C)C)S)S Chemical compound CC(C)(C)OOC(C)(CCC(C)(OOC(C)(C)C)S)S YJOBGXITWVSGQV-UHFFFAOYSA-N 0.000 description 1
- GIBYOBNLCWRAQM-UHFFFAOYSA-N COCC(C(OC)(OC)C)CCCCCCCC.C=CC Chemical compound COCC(C(OC)(OC)C)CCCCCCCC.C=CC GIBYOBNLCWRAQM-UHFFFAOYSA-N 0.000 description 1
- HCULCJNSZJLXBW-UHFFFAOYSA-N COCCCCCCCCCC.C=CC Chemical compound COCCCCCCCCCC.C=CC HCULCJNSZJLXBW-UHFFFAOYSA-N 0.000 description 1
- CQOKGSNIYCCTLH-UHFFFAOYSA-N C[S](C)OC Chemical compound C[S](C)OC CQOKGSNIYCCTLH-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- DQOGYOHFTLDMBV-UHFFFAOYSA-N ClC1=CC=C(C(C2=CC=C(C=C2)Cl)OOC(C2=CC=C(C=C2)Cl)C2=CC=C(C=C2)Cl)C=C1 Chemical compound ClC1=CC=C(C(C2=CC=C(C=C2)Cl)OOC(C2=CC=C(C=C2)Cl)C2=CC=C(C=C2)Cl)C=C1 DQOGYOHFTLDMBV-UHFFFAOYSA-N 0.000 description 1
- PYBOUZPCXWOMJC-UHFFFAOYSA-N ClCC(C(OC)(OC)OC)CCCCCCCC Chemical compound ClCC(C(OC)(OC)OC)CCCCCCCC PYBOUZPCXWOMJC-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 208000033962 Fontaine progeroid syndrome Diseases 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 101000801643 Homo sapiens Retinal-specific phospholipid-transporting ATPase ABCA4 Proteins 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- CFWFJIRDZVFKJB-GRZKGYEASA-N Montanol Chemical compound CC(C)C(\C)=C\C(=O)[C@H](C)CCC[C@]1(C)OC\C(=C\CO)CC[C@H]1O CFWFJIRDZVFKJB-GRZKGYEASA-N 0.000 description 1
- CFWFJIRDZVFKJB-UHFFFAOYSA-N Montanol Natural products CC(C)C(C)=CC(=O)C(C)CCCC1(C)OCC(=CCO)CCC1O CFWFJIRDZVFKJB-UHFFFAOYSA-N 0.000 description 1
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 108091034117 Oligonucleotide Proteins 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002675 Polyoxyl Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Chemical group 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 102100033617 Retinal-specific phospholipid-transporting ATPase ABCA4 Human genes 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical group O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229910009257 Y—Si Inorganic materials 0.000 description 1
- GGQMVXCTMDYLJU-UHFFFAOYSA-N [CH2-]C(C=CC)=O Chemical compound [CH2-]C(C=CC)=O GGQMVXCTMDYLJU-UHFFFAOYSA-N 0.000 description 1
- ZGGGFLCIYHJOBB-UHFFFAOYSA-N [Sn].C(CCCCCC(C)(C)C)(=O)OC.C(CCCCCC(C)(C)C)(=O)OC Chemical compound [Sn].C(CCCCCC(C)(C)C)(=O)OC.C(CCCCCC(C)(C)C)(=O)OC ZGGGFLCIYHJOBB-UHFFFAOYSA-N 0.000 description 1
- MBYNTKPBDYZMAQ-UHFFFAOYSA-N [benzhydrylperoxy(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)OOC(C=1C=CC=CC=1)C1=CC=CC=C1 MBYNTKPBDYZMAQ-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003302 alkenyloxy group Chemical group 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- GVFOJDIFWSDNOY-UHFFFAOYSA-N antimony tin Chemical compound [Sn].[Sb] GVFOJDIFWSDNOY-UHFFFAOYSA-N 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- YUZCJIHIKDVFLP-UHFFFAOYSA-N butyl 2-hydroxy-2-phenylpropanoate Chemical compound C(CCC)OC(C(C)(C1=CC=CC=C1)O)=O YUZCJIHIKDVFLP-UHFFFAOYSA-N 0.000 description 1
- BXIQXYOPGBXIEM-UHFFFAOYSA-N butyl 4,4-bis(tert-butylperoxy)pentanoate Chemical compound CCCCOC(=O)CCC(C)(OOC(C)(C)C)OOC(C)(C)C BXIQXYOPGBXIEM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000012969 di-tertiary-butyl peroxide Substances 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000011978 dissolution method Methods 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- JDVIRCVIXCMTPU-UHFFFAOYSA-N ethanamine;trifluoroborane Chemical compound CCN.FB(F)F JDVIRCVIXCMTPU-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 125000006289 hydroxybenzyl group Chemical group 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011968 lewis acid catalyst Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- UISUQHKSYTZXSF-UHFFFAOYSA-N methanolate;tin(2+) Chemical compound [Sn+2].[O-]C.[O-]C UISUQHKSYTZXSF-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- WUNHQSWYDYWRIF-UHFFFAOYSA-N methyl 7,7-dimethyloctanoate Chemical compound COC(=O)CCCCCC(C)(C)C.COC(=O)CCCCCC(C)(C)C WUNHQSWYDYWRIF-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- ZUZLIXGTXQBUDC-UHFFFAOYSA-N methyltrioctylammonium Chemical compound CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC ZUZLIXGTXQBUDC-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000003544 oxime group Chemical group 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000570 polyether Chemical group 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QVKOLZOAOSNSHQ-UHFFFAOYSA-N prop-1-ene;prop-2-enoic acid Chemical compound CC=C.OC(=O)C=C QVKOLZOAOSNSHQ-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- UORVCLMRJXCDCP-UHFFFAOYSA-N propynoic acid Chemical compound OC(=O)C#C UORVCLMRJXCDCP-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical group [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- SEEPANYCNGTZFQ-UHFFFAOYSA-N sulfadiazine Chemical group C1=CC(N)=CC=C1S(=O)(=O)NC1=NC=CC=N1 SEEPANYCNGTZFQ-UHFFFAOYSA-N 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 125000004963 sulfonylalkyl group Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 150000003527 tetrahydropyrans Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- CPRPKIMXLHBUGA-UHFFFAOYSA-N triethyltin Chemical compound CC[Sn](CC)CC CPRPKIMXLHBUGA-UHFFFAOYSA-N 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- JABYJIQOLGWMQW-UHFFFAOYSA-N undec-4-ene Chemical compound CCCCCCC=CCCC JABYJIQOLGWMQW-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004457 water analysis Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0812187.3A GB0812187D0 (en) | 2008-07-03 | 2008-07-03 | Modified polyethylene |
| US16238009P | 2009-03-23 | 2009-03-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201016730A true TW201016730A (en) | 2010-05-01 |
Family
ID=39717911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW098122707A TW201016730A (en) | 2008-07-03 | 2009-07-03 | Grafted polyethylene |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20110172367A1 (enExample) |
| EP (1) | EP2318447A1 (enExample) |
| JP (1) | JP5552484B2 (enExample) |
| KR (1) | KR20110052546A (enExample) |
| CN (1) | CN102083875B (enExample) |
| BR (1) | BRPI0913927A2 (enExample) |
| CA (1) | CA2729885A1 (enExample) |
| GB (1) | GB0812187D0 (enExample) |
| MX (1) | MX2010013751A (enExample) |
| RU (1) | RU2489449C2 (enExample) |
| TW (1) | TW201016730A (enExample) |
| UA (1) | UA105637C2 (enExample) |
| WO (1) | WO2010000477A1 (enExample) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0812185D0 (en) * | 2008-07-03 | 2008-08-13 | Dow Corning | Polymers modified by silanes |
| GB0812186D0 (en) * | 2008-07-03 | 2008-08-13 | Dow Corning | Modified polyolefins |
| GB201000121D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Modified polyolefins |
| GB201000117D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Organopolysiloxanes containing an unsaturated group |
| GB201000120D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Process for forming crosslinked and branched polymers |
| CN102985468B (zh) * | 2010-06-21 | 2015-11-25 | 北欧化工股份公司 | 硅烷可交联聚合物组合物 |
| EP2407506A1 (en) * | 2010-07-13 | 2012-01-18 | Borealis AG | Pipes made from a polyethylene copolymer with slow crack growth |
| EP2635446A1 (en) | 2010-11-03 | 2013-09-11 | Dow Corning Corporation | Epoxidised elastomer compositions modified by silanes |
| JP5614376B2 (ja) * | 2011-06-09 | 2014-10-29 | 日立金属株式会社 | シラン架橋ポリオレフィン絶縁電線 |
| JP5614375B2 (ja) * | 2011-06-09 | 2014-10-29 | 日立金属株式会社 | シラン架橋ポリオレフィン絶縁電線 |
| ES2787508T3 (es) | 2011-08-26 | 2020-10-16 | Borealis Ag | Composición de polímero reticulable en silano |
| GB201121124D0 (en) | 2011-12-08 | 2012-01-18 | Dow Corning | Hydrolysable silanes |
| GB201121122D0 (en) | 2011-12-08 | 2012-01-18 | Dow Corning | Hydrolysable silanes and elastomer compositions containing them |
| GB201121127D0 (en) | 2011-12-08 | 2012-01-18 | Dow Corning | Treatment of filler with silane |
| GB201121133D0 (en) | 2011-12-08 | 2012-01-18 | Dow Corning | Hydrolysable silanes |
| GB201121128D0 (en) | 2011-12-08 | 2012-01-18 | Dow Corning | Treatment of filler with silane |
| EP2690115B1 (en) * | 2012-07-24 | 2018-02-21 | Borealis AG | Slow partial cross-linking polyolefin composition for improving disinfectant resistance of an article |
| CN105209002A (zh) * | 2013-05-10 | 2015-12-30 | 宝洁公司 | 包含硅烷改性的油的消费产品 |
| US10040888B1 (en) | 2013-06-14 | 2018-08-07 | Cooper-Standard Automotive Inc. | Composition including silane-grafted polyolefin |
| US10100139B2 (en) * | 2013-08-01 | 2018-10-16 | Cooper-Standard Automotive Inc. | Hose, composition including silane-grafted polyolefin, and process of making a hose |
| DE102013216502A1 (de) * | 2013-08-21 | 2015-02-26 | Evonik Industries Ag | Zinn-freie Zusammensetzung für die Vernetzung von thermoplastischen Polyolefinen |
| DE102013216504A1 (de) * | 2013-08-21 | 2015-02-26 | Evonik Industries Ag | Zinn-freie Katalysator-haltige Zusammensetzung für einen Monosil-Prozess mit optimierter Prozesscharakteristik |
| EP3164633B1 (en) | 2014-07-02 | 2020-01-29 | Cooper-Standard Automotive, Inc. | Hose, abrasion resistant composition, and process of making a hose |
| CA2989407C (en) | 2015-06-17 | 2023-09-19 | Dow Global Technologies Llc | Process for making crosslinked cable insulation using high melt strength ethylene-based polymer made in a tubular reactor and optionally modified with a branching agent |
| MX2019006664A (es) | 2016-12-10 | 2019-10-09 | Cooper Standard Automotive Inc | Composiciones de elastomero de poliolefina y metodos para la fabricacion de las mismas. |
| EP3551714A1 (en) | 2016-12-10 | 2019-10-16 | Cooper-Standard Automotive, Inc. | Dynamic seals, compositions, and methods of making the same |
| JP7256169B2 (ja) | 2017-07-25 | 2023-04-11 | ダウ シリコーンズ コーポレーション | ポリオレフィン主鎖とポリオルガノシロキサンペンダント基とを有する、グラフトコポリマーを調製するための方法 |
| EP3470442A1 (en) | 2017-10-11 | 2019-04-17 | Borealis AG | Sealing material comprising terpolymers |
| JP6795481B2 (ja) * | 2017-11-07 | 2020-12-02 | 日立金属株式会社 | 絶縁電線 |
| JP6756693B2 (ja) | 2017-11-07 | 2020-09-16 | 日立金属株式会社 | 絶縁電線 |
| JP6756692B2 (ja) | 2017-11-07 | 2020-09-16 | 日立金属株式会社 | 絶縁電線 |
| CA3101628A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Hot melt adhesive composition containing a polyolefin - polydiorganoosiloxane copolymer and methods for the preparation and use thereof |
| US12037462B2 (en) | 2018-03-19 | 2024-07-16 | Dow Global Technologies Llc | Polyolefin-polydiorganosiloxane block copolymer and method for the synthesis thereof |
| EP3768765B1 (en) | 2018-03-19 | 2023-05-17 | Dow Silicones Corporation | Polyolefin-polydiorganosiloxane block copolymer and hydrosilylaton reaction method for the synthesis thereof |
| US11814555B2 (en) | 2018-03-19 | 2023-11-14 | Dow Silicones Corporation | Hot melt adhesive compositions containing polyolefin-polydiorganosiloxane copolymers and methods for the preparation and use thereof |
| AU2019300199B2 (en) * | 2018-07-13 | 2024-09-05 | Akzo Nobel Coatings International B.V. | Tie-coat composition |
| JP7334195B2 (ja) | 2018-07-17 | 2023-08-28 | ダウ シリコーンズ コーポレーション | ポリシロキサン樹脂－ポリオレフィンコポリマー並びにその調製方法及び使用方法 |
| TW202010783A (zh) * | 2018-09-13 | 2020-03-16 | 美商陶氏全球科技有限責任公司 | 含有三有機膦的基於乙烯之聚合物組合物 |
| CN112390912A (zh) * | 2020-11-04 | 2021-02-23 | 广州鹿山新材料股份有限公司 | 吹膜级马来酸酐接枝聚乙烯及其制备方法 |
| CN112457447A (zh) * | 2020-11-25 | 2021-03-09 | 郑州中原思蓝德高科股份有限公司 | 一种改性聚烯烃助剂 |
| PL447686A1 (pl) * | 2024-02-01 | 2024-06-03 | Politechnika Warszawska | Kompozycja polimerowa, sposób wytwarzania i zastosowanie tej kompozycji do wytwarzania materiałów przewodzących ciepło |
Family Cites Families (92)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3873642A (en) * | 1961-02-20 | 1975-03-25 | Avisun Corp | Crystalline olefin block polymers and their preparation |
| US3075948A (en) * | 1959-10-23 | 1963-01-29 | Owens Illinois Glass Co | Method for preparing graft copolymers of polyolefin and silanes and a graft copolymer thereof |
| US3179612A (en) * | 1962-02-02 | 1965-04-20 | Dow Corning | alpha, beta-unsaturated carboxylicester-substituted organosilicon compounds |
| US3258477A (en) * | 1963-07-19 | 1966-06-28 | Dow Corning | Acryloxyalkylsilanes and compositions thereof |
| US3414551A (en) * | 1965-06-24 | 1968-12-03 | Hercules Inc | Modification of crystalline propylene polymers |
| US3503943A (en) * | 1965-10-21 | 1970-03-31 | Exxon Research Engineering Co | Silane modified ethylene-propylene terpolymer |
| US3458460A (en) * | 1967-11-27 | 1969-07-29 | Hooker Chemical Corp | Unsaturated polyesters cross-linked by diels-alder reaction |
| BE794718Q (fr) * | 1968-12-20 | 1973-05-16 | Dow Corning Ltd | Procede de reticulation d'olefines |
| US3873643A (en) * | 1972-12-18 | 1975-03-25 | Chemplex Co | Graft copolymers of polyolefins and cyclic acid and acid anhydride monomers |
| US4303763A (en) * | 1980-01-17 | 1981-12-01 | Resdev, Inc. | Unsaturated ethylene polymers and processes for preparing and for using same |
| JPS5893704A (ja) * | 1981-11-30 | 1983-06-03 | Sekisui Chem Co Ltd | シラン変性ポリオレフイン系樹脂の製造方法 |
| US4481322A (en) * | 1983-03-30 | 1984-11-06 | Union Carbide Corporation | Novel reinforcing additive and method of reinforcing thermoplastic polymer therewith |
| IT1209510B (it) * | 1984-03-09 | 1989-08-30 | Franco Gimpel | Composizioni poliolefiniche reticolabili, contenenti zeoliti cristalline. |
| US4857250A (en) * | 1984-04-13 | 1989-08-15 | Union Carbide Corporation | One-extrusion method of making a shaped crosslinkable extruded polymeric product |
| EP0189174B1 (en) * | 1985-01-23 | 1990-04-25 | Nissan Chemical Industries Ltd. | Polymers of substituted 1,3-butadiene compounds and process for their preparation |
| GB8502928D0 (en) * | 1985-02-05 | 1985-03-06 | Bicc Plc | Cross-linkable compositions |
| US4709084A (en) * | 1985-09-23 | 1987-11-24 | Union Camp Corporation | Terpene-based ester tackifiers |
| JPS62275168A (ja) * | 1985-12-03 | 1987-11-30 | Hitachi Chem Co Ltd | 塗料用樹脂組成物 |
| JPH0635495B2 (ja) * | 1985-12-10 | 1994-05-11 | 三菱油化株式会社 | シラン架橋が可能なエチレン共重合体 |
| FI80853C (sv) * | 1988-06-07 | 1990-08-10 | Neste Oy | Plastbelagt stålrör |
| US4702868A (en) * | 1987-02-24 | 1987-10-27 | Valcour Incorporated | Moldable silane-crosslinked polyolefin foam beads |
| GB8704673D0 (en) * | 1987-02-27 | 1987-04-01 | Bicc Plc | Control of grafting processes |
| JPH0832693B2 (ja) * | 1987-04-13 | 1996-03-29 | 大阪有機化学工業株式会社 | アクリル酸グリシジルまたはメタクリル酸グリシジルの精製方法 |
| US4946977A (en) * | 1987-09-25 | 1990-08-07 | Huels Troisdorf Ag | Method for the preparation of organosilanes containing methacryloxy or acryloxy groups |
| GB8818880D0 (en) * | 1988-08-09 | 1988-09-14 | Research Corp Ltd | Modified polymers |
| DE4011044A1 (de) * | 1990-04-05 | 1991-10-10 | Fraunhofer Ges Forschung | Silane, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polymerisaten und polykondensaten |
| US5326824A (en) * | 1990-05-18 | 1994-07-05 | Mitsui Toatsu Chemicals, Incorporated | Syndiotactic propylene copolymer, method for preparing same, and its use |
| US5918641A (en) * | 1990-06-18 | 1999-07-06 | Hardy; Jean | Flexible tubular conduit comprising a jacket made of crosslinked polyethylene device and process for manufacturing such a conduit |
| FR2663401B1 (fr) * | 1990-06-18 | 1992-09-18 | Coflexip | Conduite tubulaire flexible comportant une gaine en polyethylene reticule, dispositif et procede pour la fabrication d'une telle conduite. |
| ES2125895T3 (es) * | 1991-03-22 | 1999-03-16 | Phillips Petroleum Co | Alfa-olefinas superiores ramificadas, injertadas, reforzadas con vidrio. |
| JP2953277B2 (ja) * | 1993-11-05 | 1999-09-27 | 信越化学工業株式会社 | コーティング用常温硬化性樹脂組成物 |
| ES2191050T3 (es) * | 1994-04-18 | 2003-09-01 | Yasuhiro Koike | Resina de uso optico del tipo de distribucion de indice de refraccion y el procedimiento de produccion de esta resina. |
| US6028146A (en) * | 1994-08-26 | 2000-02-22 | Borealis A/S | Free radical grafting of monomers onto polypropylene resins |
| FR2732351B1 (fr) * | 1995-03-29 | 1998-08-21 | Michelin & Cie | Composition de caoutchouc pour enveloppe de pneumatique renfermant de la silice dopee aluminium a titre de charge renforcante |
| US5824718A (en) * | 1995-04-20 | 1998-10-20 | The Dow Chemical Company | Silane-crosslinkable, substantially linear ethylene polymers and their uses |
| US5684171A (en) * | 1997-02-11 | 1997-11-04 | The Goodyear Tire & Rubber Company | Process for the preparation of organosilicon polysulfide compounds |
| US6013715A (en) * | 1997-04-22 | 2000-01-11 | Dow Corning Corporation | Thermoplastic silicone elastomers |
| DE19724312C1 (de) * | 1997-06-10 | 1998-12-10 | Danubia Petrochem Polymere | Feinzellige Polyolefinschaumstoffe, deren Herstellverfahren und Verwendung |
| KR100825539B1 (ko) * | 1997-08-21 | 2008-04-25 | 제너럴 일렉트릭 캄파니 | 차단된 메르캅토실란의 제조 방법 |
| US6153691A (en) * | 1998-10-07 | 2000-11-28 | Dow Corning Corporation | Thermoplastic silicone vulcanizates prepared by condensation cure |
| US6380316B1 (en) * | 1999-03-02 | 2002-04-30 | Dow Corning Corporation | Polyisobutylene copolymers having reactive silyl grafts |
| WO2000052071A1 (en) * | 1999-03-02 | 2000-09-08 | Exxon Chemical Patents Inc. | Silane grafted copolymers of an alpha-olefin and a vinyl aromatic monomer |
| US6177519B1 (en) * | 1999-03-02 | 2001-01-23 | Exxon Chemical Patents, Inc. | Silane grafted copolymers of an isomonoolefin and a vinyl aromatic monomer |
| DE19961972A1 (de) * | 1999-12-22 | 2001-06-28 | Degussa | Organosilan- und/oder Organosiloxan-haltige Mittel für gefülltes Polyamid |
| ATE252614T1 (de) * | 1999-12-30 | 2003-11-15 | Michelin Soc Tech | Kautschukzusammensetzung für reifen mit einem kupplungsmittel (wesiser füllstoff/dienelastomer),das durch einen thermisch initierbaren radikalstarter aktiviert wird |
| FR2803306B1 (fr) * | 1999-12-30 | 2006-09-22 | Rhodia Chimie Sa | Utilisation d'une association d'un compose a base d'organosilane fonctionnalise avec un activateur de couplage , comme systeme de couplage dans les compositions d4elastomeres dieniques comprenant une charge blanche |
| JP4861588B2 (ja) * | 1999-12-30 | 2012-01-25 | ソシエテ ド テクノロジー ミシュラン | エステル官能を有する（白色フィラー／エラストマー）カップリング剤を含むタイヤ用ゴム組成物 |
| BE1013243A3 (fr) * | 2000-01-21 | 2001-11-06 | Solvay | Composition a base de polyethylene reticulable. |
| JP4454784B2 (ja) * | 2000-04-25 | 2010-04-21 | 東レ・ダウコーニング株式会社 | 熱可塑性樹脂組成物および成形品 |
| JP4061824B2 (ja) * | 2000-07-25 | 2008-03-19 | 三井化学株式会社 | ゴム組成物 |
| DE10038488A1 (de) * | 2000-08-08 | 2002-02-21 | Bayer Ag | Isocyanatosilan- und mikrogelhaltige Kautschukmischungen |
| BR0113914A (pt) * | 2000-09-15 | 2003-07-01 | Michelin Soc Tech | Composição de borracha, processo para preparar uma composição elastomérica e para copular uma carga inorgânica e um elastÈmero isoprênico em uma composição elastomérica, utilização de uma composição de borracha e de citraconimido-alcoxissilano, pneumático e produto semi-acabado para pneumático |
| JP4252304B2 (ja) * | 2000-10-13 | 2009-04-08 | ソシエテ ド テクノロジー ミシュラン | カップリング剤として使用できる多官能性オルガノシラン及びその製造方法 |
| US6479580B1 (en) * | 2001-04-30 | 2002-11-12 | Dow Corning Corporation | Polyolefin thermoplastic silicone elastomers employing radical cure |
| EP1256593B1 (en) * | 2001-05-11 | 2010-07-28 | Borealis Technology Oy | Method for cross-linking a polymer article |
| DE50205120D1 (de) * | 2001-08-06 | 2006-01-05 | Degussa | Organosiliciumverbindungen |
| DE10142555A1 (de) * | 2001-08-30 | 2003-03-20 | Degussa | Mittel für die Verbesserung der Scorch-Bedingungen bei der Herstellung gepfropfter und/oder vernetzter Polymere sowie gefüllter Kunststoffe |
| DE10159859C1 (de) * | 2001-12-06 | 2003-01-16 | Fraunhofer Ges Forschung | Verfahren zur Herstellung von Styryl-funktionalisierten Silanen |
| EP1483303B1 (de) * | 2002-03-04 | 2006-05-31 | Basf Aktiengesellschaft | Verfahren zur herstellung von isobutenpolymeren |
| JP4125060B2 (ja) * | 2002-07-16 | 2008-07-23 | 日本特殊陶業株式会社 | スパークプラグ |
| ATE346103T1 (de) * | 2003-02-05 | 2006-12-15 | Dow Global Technologies Inc | Silan-feuchtigkeitsgehärtete wärmebeständige fasern aus polyolefin-elastomeren |
| AU2003207285A1 (en) * | 2003-02-06 | 2004-08-30 | Cellseed Inc. | High-density cell array board, process for producing the same and method of using the same |
| DE10308579B3 (de) * | 2003-02-27 | 2004-06-24 | Wacker-Chemie Gmbh | Verfahren zur Stabilisierung ungesättigter Organosiliziumverbindungen |
| US8008520B2 (en) * | 2003-07-03 | 2011-08-30 | Momentive Performance Materials Inc. | Process for the preparation of thiocarboxylate silane |
| JP4427291B2 (ja) * | 2003-09-03 | 2010-03-03 | 東亞合成株式会社 | 機能性膜の連続製造方法 |
| DE10351804A1 (de) * | 2003-11-06 | 2005-06-09 | Wacker-Chemie Gmbh | Verfahren zur Erhöhung der Elastizität von feuchtigkeitsgehärteten Elastomeren |
| DE10355318A1 (de) * | 2003-11-27 | 2005-06-23 | Wacker-Chemie Gmbh | Verfahren zur Herstellung von organyloxysilylterminierten Polymeren |
| US7291677B2 (en) * | 2003-12-15 | 2007-11-06 | Solvay Engineered Polymers, Inc. | Adherent, modified thermoplastic elastomeric blends, articles, and methods |
| US20090264584A1 (en) * | 2004-02-04 | 2009-10-22 | Dow Global Technologies Inc. | Silane moisture cured heat resistant fibers made from polyolefin elastomers |
| JP4500090B2 (ja) * | 2004-04-22 | 2010-07-14 | 株式会社日立製作所 | 情報管理システムと情報管理方法 |
| DE102004024009A1 (de) * | 2004-05-14 | 2005-12-01 | Goldschmidt Gmbh | Verwendung von neuen Polysiloxanen mit über SiOC-Gruppen gebundenen (Meth)acrylsäureestergruppen als Additive für strahlenhärtende Beschichtungen |
| US8883057B2 (en) * | 2004-06-07 | 2014-11-11 | Acushnet Company | Non-ionomeric silane crosslinked polyolefin golf ball layers |
| US7279529B2 (en) * | 2004-06-07 | 2007-10-09 | Acushnet Company | Non-ionomeric silane crosslinked polyolefin golf ball layers |
| US20060025506A1 (en) * | 2004-07-30 | 2006-02-02 | Weller Keith J | Silane compositions, processes for their preparation and rubber compositions containing same |
| DE102005057801A1 (de) * | 2005-01-20 | 2006-08-03 | Degussa Ag | Mercaptosilane |
| FR2886305B1 (fr) * | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique |
| FR2886304B1 (fr) * | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique |
| FR2886306B1 (fr) * | 2005-05-26 | 2007-07-06 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosiloxane |
| EP2039705A4 (en) * | 2006-07-07 | 2009-11-11 | Yokohama Rubber Co Ltd | MODIFIED RUBBER AND RUBBER COMPOSITION COMPRISING THEREOF |
| JP2008024091A (ja) * | 2006-07-19 | 2008-02-07 | Mitsuba Corp | 表面改質されたブレードラバー、ワイパ装置およびブレードラバーの表面改質方法 |
| JP5137174B2 (ja) * | 2006-10-06 | 2013-02-06 | 独立行政法人日本原子力研究開発機構 | シラン架橋構造を付与した燃料電池用高分子電解質膜の製造方法 |
| JP5745733B2 (ja) * | 2006-10-25 | 2015-07-08 | Jsr株式会社 | 変性重合体の製造方法、その方法により得られた変性重合体とそのゴム組成物 |
| ES2506096T3 (es) * | 2007-07-16 | 2014-10-13 | Dow Global Technologies Llc | Polímeros funcionalizados y artículos preparados a partir de los mismos |
| US8785553B2 (en) * | 2007-12-04 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Moisture curable propylene-α-olefin copolymers |
| GB0812186D0 (en) * | 2008-07-03 | 2008-08-13 | Dow Corning | Modified polyolefins |
| GB0812185D0 (en) * | 2008-07-03 | 2008-08-13 | Dow Corning | Polymers modified by silanes |
| JP2012525460A (ja) * | 2009-04-30 | 2012-10-22 | ダウ コーニング コーポレーション | シランにより変性したエラストマー組成物 |
| KR20120100704A (ko) * | 2009-04-30 | 2012-09-12 | 다우 코닝 코포레이션 | 실란에 의해 개질된 엘라스토머 조성물 |
| GB201000120D0 (en) * | 2010-01-06 | 2010-02-17 | Dow Corning | Process for forming crosslinked and branched polymers |
| GB201000116D0 (en) * | 2010-01-06 | 2010-02-17 | Dow Corning | Polyolefins modified by silicones |
| GB201000121D0 (en) * | 2010-01-06 | 2010-02-17 | Dow Corning | Modified polyolefins |
| GB201000117D0 (en) * | 2010-01-06 | 2010-02-17 | Dow Corning | Organopolysiloxanes containing an unsaturated group |
-
2008
- 2008-07-03 GB GBGB0812187.3A patent/GB0812187D0/en not_active Ceased
-
2009
- 2009-07-02 CA CA2729885A patent/CA2729885A1/en not_active Abandoned
- 2009-07-02 KR KR1020107029849A patent/KR20110052546A/ko not_active Ceased
- 2009-07-02 RU RU2011103769/04A patent/RU2489449C2/ru not_active IP Right Cessation
- 2009-07-02 MX MX2010013751A patent/MX2010013751A/es unknown
- 2009-07-02 BR BRPI0913927A patent/BRPI0913927A2/pt not_active IP Right Cessation
- 2009-07-02 EP EP09772177A patent/EP2318447A1/en not_active Withdrawn
- 2009-07-02 US US13/001,660 patent/US20110172367A1/en not_active Abandoned
- 2009-07-02 WO PCT/EP2009/004797 patent/WO2010000477A1/en not_active Ceased
- 2009-07-02 UA UAA201101187A patent/UA105637C2/uk unknown
- 2009-07-02 CN CN200980126042.7A patent/CN102083875B/zh not_active Expired - Fee Related
- 2009-07-02 JP JP2011515240A patent/JP5552484B2/ja not_active Expired - Fee Related
- 2009-07-03 TW TW098122707A patent/TW201016730A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011526311A (ja) | 2011-10-06 |
| JP5552484B2 (ja) | 2014-07-16 |
| UA105637C2 (uk) | 2014-06-10 |
| RU2011103769A (ru) | 2012-08-10 |
| RU2489449C2 (ru) | 2013-08-10 |
| CA2729885A1 (en) | 2010-01-07 |
| WO2010000477A1 (en) | 2010-01-07 |
| GB0812187D0 (en) | 2008-08-13 |
| CN102083875B (zh) | 2014-01-22 |
| BRPI0913927A2 (pt) | 2015-10-20 |
| EP2318447A1 (en) | 2011-05-11 |
| US20110172367A1 (en) | 2011-07-14 |
| KR20110052546A (ko) | 2011-05-18 |
| MX2010013751A (es) | 2011-03-29 |
| CN102083875A (zh) | 2011-06-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW201016730A (en) | Grafted polyethylene | |
| TWI439476B (zh) | 以矽烷改質之聚合物 | |
| TW201008963A (en) | Modified polyolefins | |
| CN102695726B (zh) | 改性的聚烯烃 | |
| JP2011503257A (ja) | シラン官能性樹脂の架橋のための現場での水分発生及び多官能性アルコールの使用 | |
| JP5845595B2 (ja) | エチレン系重合体ペレットおよび該ペレットを用いる押出成形方法 | |
| WO2011083047A1 (en) | Modified polyolefins | |
| JP2023147511A (ja) | 重合体、組成物、成形体及びリチウムイオン二次電池 | |
| JP3352631B2 (ja) | シラン架橋ポリオレフィン樹脂組成物及び絶縁ケーブル | |
| WO2010074925A1 (en) | In-situ catalyst and moisture generation for crosslinking of silane-functionalized polyolefins |