TW200835737A - Polyurethane compositions and articles prepared therefrom, and methods for making the same - Google Patents
Polyurethane compositions and articles prepared therefrom, and methods for making the same Download PDFInfo
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- TW200835737A TW200835737A TW96140982A TW96140982A TW200835737A TW 200835737 A TW200835737 A TW 200835737A TW 96140982 A TW96140982 A TW 96140982A TW 96140982 A TW96140982 A TW 96140982A TW 200835737 A TW200835737 A TW 200835737A
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- ethylene
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- 239000000203 mixture Substances 0.000 title claims abstract description 398
- 239000004814 polyurethane Substances 0.000 title claims abstract description 156
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 149
- 238000000034 method Methods 0.000 title claims description 85
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 89
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 78
- 239000000463 material Substances 0.000 claims abstract description 52
- 150000001336 alkenes Chemical class 0.000 claims abstract description 51
- 239000006185 dispersion Substances 0.000 claims abstract description 47
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229920000728 polyester Polymers 0.000 claims abstract description 26
- 239000000853 adhesive Substances 0.000 claims abstract description 24
- 230000001070 adhesive effect Effects 0.000 claims abstract description 24
- 238000000576 coating method Methods 0.000 claims abstract description 24
- 239000004417 polycarbonate Substances 0.000 claims abstract description 20
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 19
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 239000006260 foam Substances 0.000 claims abstract description 17
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 8
- 239000004626 polylactic acid Substances 0.000 claims abstract description 8
- 230000001681 protective effect Effects 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims description 272
- 239000005977 Ethylene Substances 0.000 claims description 157
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 154
- 229920000140 heteropolymer Polymers 0.000 claims description 148
- 229920001577 copolymer Polymers 0.000 claims description 111
- 150000002009 diols Chemical class 0.000 claims description 109
- -1 polyetherimine Polymers 0.000 claims description 98
- 239000000178 monomer Substances 0.000 claims description 84
- 239000004711 α-olefin Substances 0.000 claims description 64
- 239000010695 polyglycol Substances 0.000 claims description 58
- 229920000151 polyglycol Polymers 0.000 claims description 58
- 238000002844 melting Methods 0.000 claims description 56
- 230000008018 melting Effects 0.000 claims description 56
- 239000004970 Chain extender Substances 0.000 claims description 53
- 230000000052 comparative effect Effects 0.000 claims description 53
- 239000000155 melt Substances 0.000 claims description 45
- 125000005442 diisocyanate group Chemical group 0.000 claims description 39
- 239000000758 substrate Substances 0.000 claims description 39
- 239000000126 substance Substances 0.000 claims description 37
- 229920001169 thermoplastic Polymers 0.000 claims description 37
- 239000004416 thermosoftening plastic Substances 0.000 claims description 37
- 239000002253 acid Substances 0.000 claims description 35
- 230000004927 fusion Effects 0.000 claims description 34
- 229920000098 polyolefin Polymers 0.000 claims description 32
- 239000000654 additive Substances 0.000 claims description 29
- 229920005989 resin Polymers 0.000 claims description 29
- 239000011347 resin Substances 0.000 claims description 29
- 238000009826 distribution Methods 0.000 claims description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 125000001931 aliphatic group Chemical group 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 27
- 238000003860 storage Methods 0.000 claims description 25
- 238000007906 compression Methods 0.000 claims description 24
- 230000006835 compression Effects 0.000 claims description 24
- 229930195733 hydrocarbon Natural products 0.000 claims description 24
- 238000006116 polymerization reaction Methods 0.000 claims description 24
- 239000003981 vehicle Substances 0.000 claims description 24
- 229920006112 polar polymer Polymers 0.000 claims description 23
- 238000010828 elution Methods 0.000 claims description 22
- 238000011084 recovery Methods 0.000 claims description 22
- 229920000768 polyamine Polymers 0.000 claims description 21
- 239000004215 Carbon black (E152) Substances 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 20
- 150000002148 esters Chemical class 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 229920005862 polyol Polymers 0.000 claims description 18
- 150000003077 polyols Chemical class 0.000 claims description 18
- 239000003973 paint Substances 0.000 claims description 17
- 229920001971 elastomer Polymers 0.000 claims description 16
- 239000004744 fabric Substances 0.000 claims description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 15
- 238000002347 injection Methods 0.000 claims description 15
- 239000007924 injection Substances 0.000 claims description 15
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- 229920000570 polyether Polymers 0.000 claims description 14
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 12
- 239000002649 leather substitute Substances 0.000 claims description 12
- 238000004132 cross linking Methods 0.000 claims description 11
- 230000001186 cumulative effect Effects 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 8
- 238000000465 moulding Methods 0.000 claims description 8
- 229910052707 ruthenium Inorganic materials 0.000 claims description 8
- XSCLFFBWRKTMTE-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCCC(CN=C=O)C1 XSCLFFBWRKTMTE-UHFFFAOYSA-N 0.000 claims description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 7
- 229920002678 cellulose Polymers 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 239000004922 lacquer Substances 0.000 claims description 7
- 239000000779 smoke Substances 0.000 claims description 7
- 229920000180 alkyd Polymers 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 239000010985 leather Substances 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- 238000003723 Smelting Methods 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 238000013329 compounding Methods 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 238000007670 refining Methods 0.000 claims description 5
- 239000005060 rubber Substances 0.000 claims description 5
- QXRRAZIZHCWBQY-UHFFFAOYSA-N 1,1-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1(CN=C=O)CCCCC1 QXRRAZIZHCWBQY-UHFFFAOYSA-N 0.000 claims description 4
- OQLZINXFSUDMHM-UHFFFAOYSA-N Acetamidine Chemical compound CC(N)=N OQLZINXFSUDMHM-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 4
- 239000004640 Melamine resin Substances 0.000 claims description 4
- 229920000954 Polyglycolide Polymers 0.000 claims description 4
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical group C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 4
- 238000000748 compression moulding Methods 0.000 claims description 4
- 239000004633 polyglycolic acid Substances 0.000 claims description 4
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 4
- 229920000271 Kevlar® Polymers 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000004761 kevlar Substances 0.000 claims description 3
- 229920001225 polyester resin Polymers 0.000 claims description 3
- 239000004645 polyester resin Substances 0.000 claims description 3
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 238000005266 casting Methods 0.000 claims description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 229920006132 styrene block copolymer Polymers 0.000 claims description 2
- 235000010980 cellulose Nutrition 0.000 claims 4
- ROHUXHMNZLHBSF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCC(CN=C=O)CC1 ROHUXHMNZLHBSF-UHFFFAOYSA-N 0.000 claims 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 2
- 229940068984 polyvinyl alcohol Drugs 0.000 claims 2
- UPGATMBHQQONPH-UHFFFAOYSA-N 2-aminooxycarbonylbenzoic acid Chemical compound NOC(=O)C1=CC=CC=C1C(O)=O UPGATMBHQQONPH-UHFFFAOYSA-N 0.000 claims 1
- RZTOWFMDBDPERY-UHFFFAOYSA-N Delta-Hexanolactone Chemical compound CC1CCCC(=O)O1 RZTOWFMDBDPERY-UHFFFAOYSA-N 0.000 claims 1
- 244000166124 Eucalyptus globulus Species 0.000 claims 1
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical group CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 claims 1
- 239000004697 Polyetherimide Substances 0.000 claims 1
- 150000002118 epoxides Chemical class 0.000 claims 1
- 235000003599 food sweetener Nutrition 0.000 claims 1
- 210000004072 lung Anatomy 0.000 claims 1
- 229920001601 polyetherimide Polymers 0.000 claims 1
- 229920005990 polystyrene resin Polymers 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 229910000679 solder Inorganic materials 0.000 claims 1
- 238000005476 soldering Methods 0.000 claims 1
- 239000003765 sweetening agent Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 59
- 239000000523 sample Substances 0.000 description 50
- 239000012948 isocyanate Substances 0.000 description 39
- 238000000113 differential scanning calorimetry Methods 0.000 description 38
- 150000002513 isocyanates Chemical class 0.000 description 33
- 238000012360 testing method Methods 0.000 description 33
- 238000006243 chemical reaction Methods 0.000 description 32
- 229920001400 block copolymer Polymers 0.000 description 30
- 150000001993 dienes Chemical class 0.000 description 29
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 29
- 125000000524 functional group Chemical group 0.000 description 28
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 28
- 239000000243 solution Substances 0.000 description 27
- KWKAKUADMBZCLK-UHFFFAOYSA-N methyl heptene Natural products CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 26
- 150000001875 compounds Chemical class 0.000 description 23
- 239000000047 product Substances 0.000 description 23
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 22
- 239000002904 solvent Substances 0.000 description 21
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 20
- 239000005062 Polybutadiene Substances 0.000 description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 150000002430 hydrocarbons Chemical class 0.000 description 18
- 229920002857 polybutadiene Polymers 0.000 description 18
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 16
- 229920000573 polyethylene Polymers 0.000 description 16
- 229920005604 random copolymer Polymers 0.000 description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 15
- 230000035882 stress Effects 0.000 description 15
- 239000000052 vinegar Substances 0.000 description 15
- 235000021419 vinegar Nutrition 0.000 description 15
- 150000001412 amines Chemical class 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 13
- 239000004606 Fillers/Extenders Substances 0.000 description 13
- 239000004698 Polyethylene Substances 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
- 238000004458 analytical method Methods 0.000 description 13
- 125000003118 aryl group Chemical group 0.000 description 13
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 13
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 12
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000007792 addition Methods 0.000 description 12
- 239000002585 base Substances 0.000 description 12
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical group OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 12
- 150000004985 diamines Chemical class 0.000 description 12
- 238000001125 extrusion Methods 0.000 description 12
- 239000000945 filler Substances 0.000 description 12
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 12
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- 239000012071 phase Substances 0.000 description 12
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 11
- 238000001816 cooling Methods 0.000 description 11
- 238000002425 crystallisation Methods 0.000 description 11
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- 125000004122 cyclic group Chemical group 0.000 description 11
- 239000000806 elastomer Substances 0.000 description 11
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- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 10
- 229920002397 thermoplastic olefin Polymers 0.000 description 10
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical group C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 9
- 238000005481 NMR spectroscopy Methods 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
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- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 8
- 238000011088 calibration curve Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 7
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- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
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- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 7
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
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- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
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- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000005755 formation reaction Methods 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
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- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 6
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
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- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 238000005194 fractionation Methods 0.000 description 5
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 5
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
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- 229910052703 rhodium Inorganic materials 0.000 description 1
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- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
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Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/69—Polymers of conjugated dienes
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- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Body Structure For Vehicles (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Sealing Material Composition (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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| TW96140976A TW200835736A (en) | 2006-11-01 | 2007-10-31 | Polyurethane compositions and articles prepared therefrom, and methods for making the same |
| TW97118096A TW200904889A (en) | 2006-11-01 | 2008-05-16 | Compositions of thermoplastic polyurethane (TPU), polybutadiene and polydiene-based TPU |
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| TW96140976A TW200835736A (en) | 2006-11-01 | 2007-10-31 | Polyurethane compositions and articles prepared therefrom, and methods for making the same |
| TW97118096A TW200904889A (en) | 2006-11-01 | 2008-05-16 | Compositions of thermoplastic polyurethane (TPU), polybutadiene and polydiene-based TPU |
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| CA (2) | CA2668142A1 (enExample) |
| DE (1) | DE602007005398D1 (enExample) |
| TW (4) | TW200835737A (enExample) |
| WO (3) | WO2008057878A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| TWI413586B (enExample) * | 2009-08-18 | 2013-11-01 |
Families Citing this family (161)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20080102239A1 (en) | 2005-07-28 | 2008-05-01 | High Voltage Graphics, Inc. | End of roll paper sensing and system management |
| JP5225845B2 (ja) * | 2005-09-12 | 2013-07-03 | ダウ グローバル テクノロジーズ エルエルシー | エチレン／α−オレフィン組成物から調製された自動車部品 |
| TW200835737A (en) * | 2006-11-01 | 2008-09-01 | Dow Global Technologies Inc | Polyurethane compositions and articles prepared therefrom, and methods for making the same |
| US8475905B2 (en) | 2007-02-14 | 2013-07-02 | High Voltage Graphics, Inc | Sublimation dye printed textile |
| US8653191B2 (en) * | 2007-07-27 | 2014-02-18 | Dow Global Technologies Llc | Polyolefin compositions and articles prepared therefrom, and methods for making the same |
| CN104305834B (zh) * | 2007-12-21 | 2017-06-09 | 陶氏环球技术有限责任公司 | 地毯，地毯衬垫和使用烯烃嵌段共聚物制备它们的方法 |
| WO2009148902A1 (en) * | 2008-06-03 | 2009-12-10 | Dow Global Technologies Inc. | A composite dispersion, method of producing the same, and articles made therefrom |
| KR100933465B1 (ko) | 2008-07-03 | 2009-12-23 | 주식회사 산청 | 열가소성 접착제 조성물 및 이에 의한 화학보호복 |
| US20100092720A1 (en) * | 2008-10-15 | 2010-04-15 | High Voltage Graphics, Inc. | Multi-Colored Two-Part Flocked Transfer and Method of Making and Process of Using the Same |
| US20110209897A1 (en) * | 2008-11-21 | 2011-09-01 | David Denton | Olefin-Based Polymers, a Process for Making the Same, and a Medium Voltage Cable Sheath Comprising the Same |
| CN101412798B (zh) * | 2008-11-21 | 2011-08-10 | 优洁（亚洲）有限公司 | 软质聚氨酯低回弹泡沫及其制备方法 |
| JP5671472B2 (ja) | 2008-12-09 | 2015-02-18 | ダイネーゼ ソシエタ ペル アチオーニ | 身体保護装置およびそのような装置を組み込んだ衣服 |
| EP2373188B1 (en) | 2008-12-09 | 2012-02-08 | Dainese S.p.A. | Garment adapted to be associated to a device for the personal protection of a user |
| WO2010075098A1 (en) | 2008-12-15 | 2010-07-01 | Textile Management Associates, Inc. | Method of recycling synthetic turf and infill product |
| EP3421552B1 (en) | 2008-12-16 | 2022-05-25 | Dow Global Technologies LLC | A coating composition comprising polymer encapsulated metal oxide opacifying pigments and a process of producing the same |
| KR101559999B1 (ko) * | 2008-12-29 | 2015-10-13 | 엘지전자 주식회사 | 디스플레이 장치 |
| EP2473541A1 (en) | 2009-03-30 | 2012-07-11 | Dow Global Technologies LLC | Hybrid dispersions and methods for producing the same |
| US8209885B2 (en) * | 2009-05-11 | 2012-07-03 | Brooks Sports, Inc. | Shoe assembly with non-linear viscous liquid |
| US8129015B2 (en) * | 2009-05-14 | 2012-03-06 | International Automotive Components North America, Inc. | Modified moldable urethane with tunable haptics |
| US20100294363A1 (en) * | 2009-05-22 | 2010-11-25 | Mitsubishi Polyester Film, Inc. | Coated Polyester Film For Lamination to Ethylene-Vinyl Acetate Layers |
| US9885149B2 (en) * | 2009-07-08 | 2018-02-06 | Dow Global Technologies Llc | Carpet and carpet backing |
| KR101716916B1 (ko) | 2009-07-24 | 2017-03-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 코팅된 용기 장치, 그의 제조 방법 |
| KR101824641B1 (ko) * | 2009-10-26 | 2018-02-01 | 인비스타 테크놀러지스 에스.에이 알.엘. | 폴리우레탄 탄성사 및 그의 제조 방법 |
| EP2493955A1 (en) | 2009-10-30 | 2012-09-05 | Dow Global Technologies LLC | Alkyd dispersion, and a process for producing the same |
| US8455576B2 (en) * | 2009-12-18 | 2013-06-04 | Dow Global Technologies Llc | Halogen free, flame retardant compositions for wire and cable applications |
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