RU2527036C2 - Полимер на пропиленовой основе, изделия и способ их получения - Google Patents

Полимер на пропиленовой основе, изделия и способ их получения Download PDF

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RU2527036C2
RU2527036C2 RU2011132149/04A RU2011132149A RU2527036C2 RU 2527036 C2 RU2527036 C2 RU 2527036C2 RU 2011132149/04 A RU2011132149/04 A RU 2011132149/04A RU 2011132149 A RU2011132149 A RU 2011132149A RU 2527036 C2 RU2527036 C2 RU 2527036C2
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Prior art keywords
propylene
composition
substituted
phenylenedibenzoate
polymer
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RU2011132149/04A
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English (en)
Russian (ru)
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RU2011132149A (ru
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Уилльям Дж. ШЭРД
Линьфэн ЧЭНЬ
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У.Р.Грейс Энд Ко.-Конн.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/01—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis
    • C07C37/02—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis by substitution of halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by condensation involving hydroxy groups of phenols or alcohols or the ether or mineral ester group derived therefrom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
    • C07C37/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms by replacing a carboxyl or aldehyde group by a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/653—Pretreating with metals or metal-containing compounds with metals of C08F4/64 or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Catalysts (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Emergency Medicine (AREA)
RU2011132149/04A 2008-12-31 2009-12-31 Полимер на пропиленовой основе, изделия и способ их получения RU2527036C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US14195908P 2008-12-31 2008-12-31
US14190208P 2008-12-31 2008-12-31
US61/141,902 2008-12-31
US61/141,959 2008-12-31
PCT/US2009/069901 WO2010078485A1 (en) 2008-12-31 2009-12-31 Propylene-based polymer, articles, and process for producing same

Publications (2)

Publication Number Publication Date
RU2011132149A RU2011132149A (ru) 2013-02-10
RU2527036C2 true RU2527036C2 (ru) 2014-08-27

Family

ID=44952766

Family Applications (5)

Application Number Title Priority Date Filing Date
RU2011132149/04A RU2527036C2 (ru) 2008-12-31 2009-12-31 Полимер на пропиленовой основе, изделия и способ их получения
RU2011132064/04A RU2518065C2 (ru) 2008-12-31 2009-12-31 Композиции и изделия из статистического сополимера пропилена и способ их получения
RU2011132141/04A RU2553475C2 (ru) 2008-12-31 2009-12-31 Получение замещенных фенилен ароматических сложных диэфиров
RU2011132063/04A RU2518067C2 (ru) 2008-12-31 2009-12-31 Ударопрочный пропиленовый сополимер и способ его получения
RU2011132147/04A RU2522435C2 (ru) 2008-12-31 2009-12-31 Усовершенствованная прокаталитическая композиция и способ ее получения

Family Applications After (4)

Application Number Title Priority Date Filing Date
RU2011132064/04A RU2518065C2 (ru) 2008-12-31 2009-12-31 Композиции и изделия из статистического сополимера пропилена и способ их получения
RU2011132141/04A RU2553475C2 (ru) 2008-12-31 2009-12-31 Получение замещенных фенилен ароматических сложных диэфиров
RU2011132063/04A RU2518067C2 (ru) 2008-12-31 2009-12-31 Ударопрочный пропиленовый сополимер и способ его получения
RU2011132147/04A RU2522435C2 (ru) 2008-12-31 2009-12-31 Усовершенствованная прокаталитическая композиция и способ ее получения

Country Status (11)

Country Link
US (7) US8106138B2 (enExample)
EP (5) EP2373701B1 (enExample)
JP (7) JP5461583B2 (enExample)
KR (5) KR20110100311A (enExample)
CN (6) CN102325809B (enExample)
BR (5) BRPI0918348A8 (enExample)
MX (6) MX2011007155A (enExample)
MY (5) MY155383A (enExample)
RU (5) RU2527036C2 (enExample)
SG (5) SG172446A1 (enExample)
WO (5) WO2010078480A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
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US11421056B2 (en) 2017-11-13 2022-08-23 W.R. Grace & Co.-Conn. Polyolefin polymer composition
RU2781427C2 (ru) * 2017-04-12 2022-10-11 У. Р. Грейс Энд Ко.- Конн. Способ получения сополимеров пропилена с низким содержанием лос

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MX347799B (es) * 2007-08-24 2017-05-15 W R Grace & Co -Conn Sistema de catalizador auto-limitante con proporcion de aluminio a sca controlada y metodo.
EP2315789B1 (en) * 2008-08-21 2015-09-02 W.R. Grace & CO. - CONN. Catalyst composition with mixed selectivity control agent and polymerisation method using it
KR101686253B1 (ko) * 2008-08-21 2016-12-13 더블유.알. 그레이스 앤드 캄파니-콘. 고 용융 유동 내충격성 프로필렌 공중합체 및 방법
US8378045B2 (en) * 2008-12-31 2013-02-19 Dow Global Technologies Llc Thermoformed article with high stiffness and good optics
US8288585B2 (en) * 2008-12-31 2012-10-16 Dow Global Technologies Llc Procatalyst composition with substitute 1,2-phenylene aromatic diester internal donor and method
MX2011007147A (es) * 2008-12-31 2011-09-26 Dow Global Technologies Llc Produccion de diesteres aromaticos de fenileno substituidos.
CN102325809B (zh) * 2008-12-31 2014-04-09 陶氏环球技术有限责任公司 提高的前催化剂组合物和方法
MY183040A (en) * 2009-12-02 2021-02-08 Grace W R & Co Two atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture
JP5845195B2 (ja) * 2010-02-26 2016-01-20 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット ハロゲン化アミドエステルおよびそれによる内部電子供与体
US8604144B2 (en) * 2010-02-26 2013-12-10 Dow Global Technologies Llc Procatalyst composition with substituted amide ester internal electron donor
CN101845171A (zh) * 2010-04-20 2010-09-29 广州呈和科技有限公司 聚丙烯增刚成核剂组合物
US20140107274A1 (en) * 2010-12-20 2014-04-17 Braskem America, Inc. Propylene-based compositions of enhanced appearance and excellent mold flowability
WO2012088028A1 (en) 2010-12-21 2012-06-28 Dow Global Technologies Llc Process for production of high melt flow propylene-based polymer and product from same
US20120157645A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same
US9382343B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same
US8604146B2 (en) * 2010-12-21 2013-12-10 Dow Global Technologies Llc Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same
US9434796B2 (en) 2010-12-21 2016-09-06 W. R. Grace & Co.-Conn. Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same
US9382342B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same
US20120157295A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product
SG192716A1 (en) * 2011-03-01 2013-09-30 Dow Global Technologies Llc Process for improving bulk density with multi-contact procatalyst and product
EP2683771B1 (en) 2011-03-10 2015-04-15 Basell Poliolefine Italia S.r.l. Polyolefin-based containers
JP2014519477A (ja) * 2011-03-29 2014-08-14 ダウ グローバル テクノロジーズ エルエルシー 置換フェニレン芳香族ジエステルの製造
CA2742454C (en) 2011-06-09 2018-06-12 Nova Chemicals Corporation Methods for controlling ethylene copolymer properties
RU2014106216A (ru) * 2011-07-28 2015-09-10 У.Р.Грейс Энд Ко.-Конн. Полимер на основе пропилена с низким содержанием золы и способ
CN103703031B (zh) * 2011-07-28 2017-10-24 格雷斯公司 用于热封的丙烯/乙烯共聚物膜
US9133286B2 (en) 2011-08-30 2015-09-15 W. R. Grace & Co.-Conn Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same
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