RU2004109136A - Способ и катализатор высокоактивной изомеризации - Google Patents
Способ и катализатор высокоактивной изомеризации Download PDFInfo
- Publication number
- RU2004109136A RU2004109136A RU2004109136/04A RU2004109136A RU2004109136A RU 2004109136 A RU2004109136 A RU 2004109136A RU 2004109136/04 A RU2004109136/04 A RU 2004109136/04A RU 2004109136 A RU2004109136 A RU 2004109136A RU 2004109136 A RU2004109136 A RU 2004109136A
- Authority
- RU
- Russia
- Prior art keywords
- component
- catalyst
- group
- mixtures
- thulium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 16
- 238000000034 method Methods 0.000 title claims 7
- 238000006317 isomerization reaction Methods 0.000 title claims 5
- 239000000203 mixture Substances 0.000 claims 9
- 229910052765 Lutetium Inorganic materials 0.000 claims 5
- 229910052775 Thulium Inorganic materials 0.000 claims 5
- 229910052769 Ytterbium Inorganic materials 0.000 claims 5
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims 5
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims 5
- 229910052691 Erbium Inorganic materials 0.000 claims 4
- 229910052689 Holmium Inorganic materials 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- 229910052771 Terbium Inorganic materials 0.000 claims 4
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims 4
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims 4
- 230000000737 periodic effect Effects 0.000 claims 4
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims 4
- 229910052727 yttrium Inorganic materials 0.000 claims 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 3
- -1 platinum group metals Chemical class 0.000 claims 3
- 239000000047 product Substances 0.000 claims 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims 2
- 150000002602 lanthanoids Chemical class 0.000 claims 2
- 239000012188 paraffin wax Substances 0.000 claims 2
- 239000011973 solid acid Substances 0.000 claims 2
- 101100208976 Schistosoma mansoni UPPA gene Proteins 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 239000012084 conversion product Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000001180 sulfating effect Effects 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Claims (13)
1. Катализатор, содержащий носитель, включающий нанесенный на него сульфатированный оксид или гидроксид по меньшей мере одного элемента IVB группы (IUPAC 4) периодической таблицы; первый компонент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, тербия, их смесей и иттрия, и второй компонент, содержащий по меньшей мере один металл группы платины.
2. Катализатор по п.1, в котором, первый компонент составляет 0,01-10 мас.% от количества катализатора, а второй компонент составляет 0,01-2 мас.% от количества катализатора в расчете на его элементный состав.
3. Катализатор по п.1, в котором элемент IVB группы (IUPAC 4) представляет собой цирконий.
4. Катализатор по п.1, 2 или 3, отличающийся тем, что он содержит 0,5-5% масс серы в расчете на элементный состав.
5. Катализатор по п.1, 2 или 3, в котором первый компонент представляет собой иттрий или один лантанидный элемент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, и тербия, а второй компонент представляет собой один металл, выбранный из металлов группы платины.
6. Катализатор по п.1, 2 или 3 дополнительно включающий третий компонент, выбранный из группы, состоящей из железа, кобальта, никеля, рения и их смесей.
7. Катализатор по пункту 6, в котором третий компонент представляет собой железо в количестве 0,1-5 мас.%, а второй компонент представляет собой платину.
8. Катализатор по п.2 или 3, в котором лантанидный компонент представляет собой иттербий, лютеций, тулий и их смеси.
9. Способ получения катализатора, предназначенного для конверсии углеводородов, содержащего сульфатированный носитель, включающий по меньшей мере одно вещество, выбранное из оксидов и гидроксидов элементов IVB группы (IUPAC 4) периодической таблицы, первый компонент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, тербия, их смесей и иттрия, и второй компонент, выбранный из металлов группы платины и их смесей, причем такой способ заключается в сульфатировании оксида или гидроксида по меньшей мере одного элемента IVB группы (IUPAC 4) периодической таблицы с образованием сульфатированного носителя; нанесении на сульфатированный носитель первого компонента; и последующего нанесения второго компонента с образованием указанного катализатора.
10. Способ конверсии углеводородов путем контактирования сырья с твердым кислотным катализатором, включающим носитель, содержащий сульфатированный оксид или гидроксид по меньшей мере одного элемента IVB группы (IUPAC 4) периодической таблицы, первый компонент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, тербия, их смесей и иттрия, и второй компонент, выбранный из металлов группы платины и их смесей, с образованием продуктов конверсии.
11. Способ по п.10, в котором парафиновое сырье подвергают изомеризации с целью получения продукта с повышенным содержанием изопарафинов, в результате контакта парафинового сырья с твердым кислотным катализатором в зоне изомеризации, в которой поддерживаются изомеризационные условия, включающие температуру в интервале 40-250°С, давление в интервале от 100 кПа до 10 МПа и среднечасовую скорость подачи жидкости 0,2-25 ч-1, с последующей регенерацией продукта обогащенного изопарафинами.
12. Способ по п.10 или 11, в котором катализатор изомеризации дополнительно включает тугоплавкий неорганический оксидный связующий компонент.
13. Способ по п.12, в котором дополнительно используют по меньшей мере часть обогащенного изопарафинами продукта для смешивания с бензином.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/942,237 US6706659B2 (en) | 2001-08-29 | 2001-08-29 | High-activity isomerization catalyst and process |
| US09/942,237 | 2001-08-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2004109136A true RU2004109136A (ru) | 2005-10-10 |
| RU2294797C2 RU2294797C2 (ru) | 2007-03-10 |
Family
ID=25477776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004109136/04A RU2294797C2 (ru) | 2001-08-29 | 2002-08-28 | Катализатор для конверсии углеводородов и способ получения катализатора, способ конверсии углеводородов |
Country Status (15)
| Country | Link |
|---|---|
| US (4) | US6706659B2 (ru) |
| EP (1) | EP1425095B1 (ru) |
| JP (1) | JP4217617B2 (ru) |
| KR (1) | KR100786600B1 (ru) |
| CN (1) | CN1254308C (ru) |
| AT (1) | ATE311249T1 (ru) |
| AU (1) | AU2002326792B2 (ru) |
| BR (1) | BR0212264B1 (ru) |
| CA (1) | CA2458885C (ru) |
| DE (1) | DE60207738T2 (ru) |
| ES (1) | ES2254718T3 (ru) |
| HU (1) | HU226762B1 (ru) |
| MX (1) | MXPA04001915A (ru) |
| RU (1) | RU2294797C2 (ru) |
| WO (1) | WO2003020420A1 (ru) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6979396B2 (en) * | 2001-08-29 | 2005-12-27 | Uop Llc | Combination reforming and isomerization process |
| US7015175B2 (en) * | 2001-08-29 | 2006-03-21 | Uop Llc | High-activity isomerization catalyst and process |
| US7022889B2 (en) * | 2001-08-29 | 2006-04-04 | Uop Llc | Isomerization process using novel catalyst |
| US6706659B2 (en) * | 2001-08-29 | 2004-03-16 | Uop Llc | High-activity isomerization catalyst and process |
| US7435329B1 (en) * | 2001-08-29 | 2008-10-14 | Uop Llc | Combination reforming and isomerization process |
| US7589041B2 (en) | 2004-04-23 | 2009-09-15 | Massachusetts Institute Of Technology | Mesostructured zeolitic materials, and methods of making and using the same |
| JP4790288B2 (ja) * | 2005-03-09 | 2011-10-12 | 石油コンビナート高度統合運営技術研究組合 | 石化ラフィネートの高オクタン価化法 |
| US7514590B1 (en) * | 2005-03-11 | 2009-04-07 | Uop Llc | Isomerization process with adsorptive separation |
| US7223898B2 (en) * | 2005-03-11 | 2007-05-29 | Uop Llc | Isomerization process |
| US20060270885A1 (en) * | 2005-05-31 | 2006-11-30 | Boyer Christopher C | Normal heptane isomerization |
| US8126938B2 (en) * | 2005-07-01 | 2012-02-28 | The Invention Science Fund I, Llc | Group content substitution in media works |
| US9426387B2 (en) | 2005-07-01 | 2016-08-23 | Invention Science Fund I, Llc | Image anonymization |
| US9583141B2 (en) | 2005-07-01 | 2017-02-28 | Invention Science Fund I, Llc | Implementing audio substitution options in media works |
| US20070005651A1 (en) * | 2005-07-01 | 2007-01-04 | Searete Llc, A Limited Liability Corporation Of The State Of Delaware | Restoring modified assets |
| US8203609B2 (en) * | 2007-01-31 | 2012-06-19 | The Invention Science Fund I, Llc | Anonymization pursuant to a broadcasted policy |
| US8732087B2 (en) | 2005-07-01 | 2014-05-20 | The Invention Science Fund I, Llc | Authorization for media content alteration |
| US9230601B2 (en) | 2005-07-01 | 2016-01-05 | Invention Science Fund I, Llc | Media markup system for content alteration in derivative works |
| US9065979B2 (en) | 2005-07-01 | 2015-06-23 | The Invention Science Fund I, Llc | Promotional placement in media works |
| US20070167663A1 (en) * | 2006-01-13 | 2007-07-19 | Catalytic Distillation Technologies | Isomerization of N-heptane in naphtha cuts |
| JP4812436B2 (ja) * | 2006-01-19 | 2011-11-09 | 石油コンビナート高度統合運営技術研究組合 | 石化ラフィネートからのベンゼン及びガソリン基材の製造方法 |
| JP4812439B2 (ja) * | 2006-01-19 | 2011-11-09 | 石油コンビナート高度統合運営技術研究組合 | 石化ラフィネートからのベンゼン及びガソリン基材の製造方法 |
| JP4812438B2 (ja) * | 2006-01-19 | 2011-11-09 | 石油コンビナート高度統合運営技術研究組合 | 石化ラフィネートからのベンゼン及びガソリン基材の製造方法 |
| JP4812437B2 (ja) * | 2006-01-19 | 2011-11-09 | 石油コンビナート高度統合運営技術研究組合 | 石化ラフィネートからのベンゼン及びガソリン基材の製造方法 |
| US8067332B2 (en) * | 2006-05-03 | 2011-11-29 | Samsung Sdi Co., Ltd. | Methanation catalyst, and carbon monoxide removing system, fuel processor, and fuel cell including the same |
| ES2319007B1 (es) * | 2006-12-07 | 2010-02-16 | Rive Technology, Inc. | Metodos para fabricar materiales zeoliticos mesoestructurados. |
| US9215512B2 (en) | 2007-04-27 | 2015-12-15 | Invention Science Fund I, Llc | Implementation of media content alteration |
| CA2625905C (en) | 2007-05-18 | 2012-06-12 | Uop Llc | Isomerization of benzene-containing feedstocks |
| CA2628361C (en) | 2007-05-18 | 2012-08-07 | Uop Llc | Isomerization of benzene-containing feedstocks |
| AU2008259834B2 (en) | 2007-06-01 | 2013-08-01 | Corbion Biotech, Inc. | Production of oil in microorganisms |
| WO2009022544A1 (ja) * | 2007-08-13 | 2009-02-19 | Asahi Kasei Chemicals Corporation | カルボン酸エステル製造用触媒、その製造方法、並びにカルボン酸エステルの製造方法 |
| US8206498B2 (en) * | 2007-10-25 | 2012-06-26 | Rive Technology, Inc. | Methods of recovery of pore-forming agents for mesostructured materials |
| AR078212A1 (es) | 2008-09-04 | 2011-10-26 | Basf Catalysts Llc | Catalizador para isomerizacion y metatesis de olefinas |
| ES2583639T3 (es) | 2008-11-28 | 2016-09-21 | Terravia Holdings, Inc. | Producción de aceites específicos en microorganismos heterótrofos |
| US8524625B2 (en) | 2009-01-19 | 2013-09-03 | Rive Technology, Inc. | Compositions and methods for improving the hydrothermal stability of mesostructured zeolites by rare earth ion exchange |
| EP2379449B1 (en) | 2009-01-19 | 2021-04-21 | W.R. Grace & CO. - CONN. | INTRODUCTION OF MESOPOROSITY IN LOW Si/Al ZEOLITES |
| JP5290912B2 (ja) | 2009-08-18 | 2013-09-18 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油基油の製造方法 |
| US8685875B2 (en) | 2009-10-20 | 2014-04-01 | Rive Technology, Inc. | Methods for enhancing the mesoporosity of zeolite-containing materials |
| JP5868962B2 (ja) | 2010-05-28 | 2016-02-24 | ソラザイム, インコーポレイテッドSolazyme Inc | 組み換え従属栄養性微生物から産生された用途に応じた油 |
| US8716544B2 (en) * | 2011-01-13 | 2014-05-06 | Uop Llc | Process for isomerizing a feed stream including one or more C4-C6 hydrocarbons |
| US8692046B2 (en) * | 2011-01-13 | 2014-04-08 | Uop Llc | Process for isomerizing a feed stream including one or more C4-C6 hydrocarbons |
| KR101964965B1 (ko) | 2011-02-02 | 2019-04-03 | 테라비아 홀딩스 인코포레이티드 | 재조합 유지성 미생물로부터 생산된 맞춤 오일 |
| CN103732537A (zh) | 2011-04-08 | 2014-04-16 | 瑞弗科技有限公司 | 中孔骨架结构改性的沸石 |
| CN103930369A (zh) | 2012-01-13 | 2014-07-16 | 瑞弗科技有限公司 | 低硅沸石的中孔隙率的引入 |
| US9376324B2 (en) | 2012-01-13 | 2016-06-28 | Rive Technology, Inc. | Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment |
| BR112014025719A8 (pt) | 2012-04-18 | 2017-10-03 | Solazyme Inc | Óleos customizados |
| US9567615B2 (en) | 2013-01-29 | 2017-02-14 | Terravia Holdings, Inc. | Variant thioesterases and methods of use |
| US9816079B2 (en) | 2013-01-29 | 2017-11-14 | Terravia Holdings, Inc. | Variant thioesterases and methods of use |
| US8765660B1 (en) | 2013-03-08 | 2014-07-01 | Rive Technology, Inc. | Separation of surfactants from polar solids |
| US9783836B2 (en) | 2013-03-15 | 2017-10-10 | Terravia Holdings, Inc. | Thioesterases and cells for production of tailored oils |
| US9290749B2 (en) | 2013-03-15 | 2016-03-22 | Solazyme, Inc. | Thioesterases and cells for production of tailored oils |
| EP2993993A2 (en) | 2013-04-26 | 2016-03-16 | Solazyme, Inc. | Low polyunsaturated fatty acid oils and uses thereof |
| MX369685B (es) | 2013-10-04 | 2019-11-19 | Terravia Holdings Inc | Aceites adaptables. |
| US9662640B2 (en) | 2013-12-27 | 2017-05-30 | Rive Technology, Inc. | Introducing mesoporosity into zeolite materials with a modified acid pre-treatment step |
| CN107087416A (zh) | 2014-07-24 | 2017-08-22 | 泰拉瑞亚控股公司 | 变体硫酯酶及使用方法 |
| BR112017005370A2 (pt) | 2014-09-18 | 2017-12-12 | Terravia Holdings Inc | acil-acp tioesterases e mutantes das mesmas |
| US9963349B2 (en) | 2014-12-11 | 2018-05-08 | Rive Technology, Inc. | Preparation of mesoporous zeolites with reduced processing |
| US10626019B2 (en) | 2014-12-30 | 2020-04-21 | W. R. Grace & Co.-Conn. | Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content |
| JP2018512851A (ja) | 2015-04-06 | 2018-05-24 | テラヴィア ホールディングス， インコーポレイテッド | Ｌｐａａｔアブレーションを有する油産生微細藻類 |
| US20180133695A1 (en) | 2015-05-08 | 2018-05-17 | Viridis Chemicals Private Limited | Additive composition for mixed metal oxide catalysts and its use in hydrocarbon conversion processes |
| RU2595341C1 (ru) * | 2015-06-29 | 2016-08-27 | Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" | Катализатор изомеризации парафиновых углеводородов и способ его приготовления |
| CN109772287A (zh) * | 2017-11-15 | 2019-05-21 | 中国石油天然气股份有限公司 | 一种烷烃异构化催化剂载体及其制备方法、该催化剂及其制备方法 |
| RU2693464C1 (ru) * | 2018-11-12 | 2019-07-03 | Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН, Институт катализа СО РАН) | Катализатор изомеризации н-бутана в изобутан, способ его приготовления и процесс получения изобутана с использованием данного катализатора |
| RU2717775C1 (ru) * | 2019-11-08 | 2020-03-25 | Общество С Ограниченной Ответственностью "Ррт" | Способ алкилирования ароматических углеводородов олефинами и реакционно-ректификационная система для его осуществления |
| CN111454130A (zh) * | 2020-04-20 | 2020-07-28 | 中国日用化学研究院有限公司 | 一种固体酸催化烯烃与二苯醚反应制备烷基二苯醚的工艺 |
| CN113289673B (zh) * | 2021-06-02 | 2022-10-04 | 润和科华催化剂(上海)有限公司 | 一种异构化催化剂及其制备方法和应用 |
| FR3128132A1 (fr) | 2021-10-19 | 2023-04-21 | IFP Energies Nouvelles | Catalyseur comprenant un oxyde de zirconium sulfaté dopé |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2939896A (en) | 1957-12-09 | 1960-06-07 | Phillips Petroleum Co | Isomerization process and catalyst |
| US3915845A (en) | 1973-12-06 | 1975-10-28 | Universal Oil Prod Co | Hydrocarbon conversion with a multimetallic catalytic composite |
| US4003826A (en) | 1973-12-06 | 1977-01-18 | Uop Inc. | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| FR2281342A1 (fr) | 1974-08-07 | 1976-03-05 | Raffinage Cie Francaise | Catalyseurs d'isomerisation d'hydrocarbures, procede de preparation desdits catalyseurs et applications de ceux-ci |
| US4024052A (en) | 1975-11-20 | 1977-05-17 | Uop Inc. | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| JPS55129232A (en) * | 1979-03-29 | 1980-10-06 | Teijin Yuka Kk | Isomerization of xylenes |
| JPS6168137A (ja) * | 1984-09-10 | 1986-04-08 | Res Assoc Util Of Light Oil | 固体酸触媒の製造方法 |
| DE3586228D1 (de) | 1984-09-10 | 1992-07-23 | Light Oil Utilization Res Ass | Fester starksauerer katalysator. |
| JPS61242641A (ja) | 1985-04-22 | 1986-10-28 | Res Assoc Util Of Light Oil | アルキル化反応用固体酸触媒 |
| JPS62285986A (ja) * | 1986-06-03 | 1987-12-11 | Res Assoc Util Of Light Oil | イソパラフインとオレフインから中間留分を製造する方法 |
| US4918041A (en) | 1988-09-21 | 1990-04-17 | Sun Refining And Marketing Company | Catalyst for hydrocarbon conversion and conversion process utilizing the same |
| US4956519A (en) | 1988-09-21 | 1990-09-11 | Sun Refining And Marketing Company | Catalyst for hydrocarbon conversion and conversion process utilizing the same |
| US4899012A (en) * | 1988-10-17 | 1990-02-06 | Uop | Catalyst for the isomerization of aromatics |
| US5019671A (en) | 1989-07-10 | 1991-05-28 | Sun Refining And Marketing Company | Liquid phase isomerization of alkanes |
| US5780383A (en) * | 1990-08-09 | 1998-07-14 | Sun Company, Inc. (R&M) | Solid superacid catalyst comprising group VII metal and having Ho less than -18 |
| US5182247A (en) | 1991-02-11 | 1993-01-26 | Texaco Inc. | Sulfated catalyst for skeletal isomerization of olefins |
| US5157199A (en) | 1991-04-01 | 1992-10-20 | Exxon Research And Engineering Co. | Isomerization of paraffins with strong solid acid catalyst and adamantane |
| US5212136A (en) * | 1991-11-27 | 1993-05-18 | Sun Company, Inc (R&M) | Solid-acid alkylation catalyst compositions for alkylation processes |
| US5214017A (en) | 1991-11-27 | 1993-05-25 | Sun Company, Inc. (R&M) | Solid-acid alkylation catalyst compositions for alkylation processes |
| US5340465A (en) * | 1993-10-14 | 1994-08-23 | Uop | Use of a metal oxide solid solution for sweetening a sour hydrocarbon fraction |
| US5491278A (en) | 1993-11-12 | 1996-02-13 | Sun Company, Inc. (R&M) | Alkylation process using solid superacid catalyst liquid phase |
| US5493067A (en) | 1993-11-12 | 1996-02-20 | Sun Company, Inc. (R&M) | Solid superacid alkylation catalyst compositions and alkylation method using the same |
| US5629257A (en) | 1994-01-21 | 1997-05-13 | Sun Company, Inc. (R&M) | Solid superacid catalysts comprising platinum metal |
| CA2140700C (en) | 1994-01-21 | 2005-09-27 | Benjamin S. Umansky | Solid superacid catalysts comprising platinum metal and hydrocarbon conversion processes using same |
| IT1271312B (it) * | 1994-12-21 | 1997-05-27 | Enirisorse Spa | Procedimento sol-gel per ottenere sfere,microsfere o rivestimenti di monoliti a forma cellulare,costituiti da ossido di zirconio puro o misto ad altri ossidi,utili come catalizzatori o supporti per catalizzatori |
| US5831139A (en) * | 1995-06-07 | 1998-11-03 | Uop Llc | Production of aliphatic gasoline |
| JPH0938494A (ja) * | 1995-07-28 | 1997-02-10 | Sekiyu Sangyo Kasseika Center | アルミナを結合材とする触媒成型方法 |
| US5837641A (en) * | 1996-01-16 | 1998-11-17 | Uop Llc | Method of promoting the activity of solid strong acid catalysts |
| US5786294A (en) | 1996-05-10 | 1998-07-28 | Northwestern University | Crystalline mesoporous zirconia catalysts having stable tetragonal pore wall structure |
| US6184430B1 (en) * | 1996-12-05 | 2001-02-06 | The United States Of America As Represented By The United States Department Of Energy | Hydrocracking and hydroisomerization of long-chain alkanes and polyolefins over metal-promoted anion-modified transition metal oxides |
| US6448198B1 (en) * | 1997-10-13 | 2002-09-10 | Total Raffinage Distribution S.A. | Acid catalyst with a sulfated zirconia base and its uses |
| FR2769519B1 (fr) * | 1997-10-13 | 1999-12-31 | Total Raffinage Distribution | Catalyseur acide a base de zircone sulfatee et ses utilisations |
| JP3989078B2 (ja) * | 1998-03-04 | 2007-10-10 | 株式会社ジャパンエナジー | 固体酸触媒の製造方法 |
| ITMI981630A1 (it) * | 1998-07-16 | 2000-01-16 | Agip Petroli | Catalizzatore superacido per la idroisomerizzazione di n-paraffine |
| IT1302034B1 (it) | 1998-08-31 | 2000-07-20 | Enirisorse Spa | Catalizzatori superacidi solidi per l'isomerizzazione di idrocarburi eprocedimento sol-gel per il loro ottenimento |
| US6593504B1 (en) * | 1998-10-19 | 2003-07-15 | Uop Llc | Selective aromatics transalkylation |
| CA2254129A1 (en) | 1998-11-13 | 2000-05-13 | Uop | Selective, rugged layered isomerization catalyst for use in a paraffin isomerization process |
| US6214764B1 (en) * | 1999-06-01 | 2001-04-10 | Uop Llc | Paraffin-isomerization catalyst and process |
| US6320089B1 (en) * | 1999-06-01 | 2001-11-20 | Uop Llc | Paraffin-isomerization catalyst and process |
| US6359179B1 (en) * | 1999-12-22 | 2002-03-19 | Uop Llc | Direct carbonylation of paraffins using solid strong acid catalyst |
| US7026268B2 (en) * | 2001-03-02 | 2006-04-11 | Japan Energy Corporation | Solid acid catalyst containing platinum group metal component and method for preparation thereof |
| US6979396B2 (en) * | 2001-08-29 | 2005-12-27 | Uop Llc | Combination reforming and isomerization process |
| US6706659B2 (en) * | 2001-08-29 | 2004-03-16 | Uop Llc | High-activity isomerization catalyst and process |
| US7022889B2 (en) * | 2001-08-29 | 2006-04-04 | Uop Llc | Isomerization process using novel catalyst |
| US7015175B2 (en) * | 2001-08-29 | 2006-03-21 | Uop Llc | High-activity isomerization catalyst and process |
| US7223898B2 (en) * | 2005-03-11 | 2007-05-29 | Uop Llc | Isomerization process |
-
2001
- 2001-08-29 US US09/942,237 patent/US6706659B2/en not_active Expired - Lifetime
-
2002
- 2002-08-28 HU HU0401513A patent/HU226762B1/hu not_active IP Right Cessation
- 2002-08-28 AT AT02761534T patent/ATE311249T1/de active
- 2002-08-28 CN CNB028181794A patent/CN1254308C/zh not_active Expired - Fee Related
- 2002-08-28 AU AU2002326792A patent/AU2002326792B2/en not_active Ceased
- 2002-08-28 RU RU2004109136/04A patent/RU2294797C2/ru not_active IP Right Cessation
- 2002-08-28 BR BRPI0212264-2A patent/BR0212264B1/pt not_active IP Right Cessation
- 2002-08-28 JP JP2003524722A patent/JP4217617B2/ja not_active Expired - Lifetime
- 2002-08-28 ES ES02761534T patent/ES2254718T3/es not_active Expired - Lifetime
- 2002-08-28 CA CA002458885A patent/CA2458885C/en not_active Expired - Fee Related
- 2002-08-28 MX MXPA04001915A patent/MXPA04001915A/es active IP Right Grant
- 2002-08-28 DE DE60207738T patent/DE60207738T2/de not_active Expired - Lifetime
- 2002-08-28 WO PCT/US2002/027577 patent/WO2003020420A1/en active IP Right Grant
- 2002-08-28 KR KR1020047002893A patent/KR100786600B1/ko active IP Right Grant
- 2002-08-28 EP EP02761534A patent/EP1425095B1/en not_active Expired - Lifetime
-
2003
- 2003-11-20 US US10/718,050 patent/US6927188B2/en not_active Expired - Lifetime
- 2003-11-20 US US10/717,812 patent/US6881873B2/en not_active Expired - Lifetime
-
2005
- 2005-01-21 US US11/040,979 patent/US7326819B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20040077915A1 (en) | 2004-04-22 |
| US6881873B2 (en) | 2005-04-19 |
| US20050161368A1 (en) | 2005-07-28 |
| CA2458885C (en) | 2007-12-04 |
| RU2294797C2 (ru) | 2007-03-10 |
| BR0212264B1 (pt) | 2013-02-19 |
| US7326819B2 (en) | 2008-02-05 |
| HUP0401513A2 (hu) | 2004-10-28 |
| ES2254718T3 (es) | 2006-06-16 |
| DE60207738T2 (de) | 2006-08-10 |
| JP2005501697A (ja) | 2005-01-20 |
| MXPA04001915A (es) | 2004-06-15 |
| US6927188B2 (en) | 2005-08-09 |
| CN1254308C (zh) | 2006-05-03 |
| US20030050523A1 (en) | 2003-03-13 |
| ATE311249T1 (de) | 2005-12-15 |
| HU226762B1 (en) | 2009-09-28 |
| CN1555291A (zh) | 2004-12-15 |
| HUP0401513A3 (en) | 2008-05-28 |
| BR0212264A (pt) | 2004-10-19 |
| EP1425095A1 (en) | 2004-06-09 |
| DE60207738D1 (de) | 2006-01-05 |
| KR20040029074A (ko) | 2004-04-03 |
| EP1425095B1 (en) | 2005-11-30 |
| JP4217617B2 (ja) | 2009-02-04 |
| CA2458885A1 (en) | 2003-03-13 |
| WO2003020420A1 (en) | 2003-03-13 |
| US6706659B2 (en) | 2004-03-16 |
| KR100786600B1 (ko) | 2007-12-21 |
| US20040259726A1 (en) | 2004-12-23 |
| AU2002326792B2 (en) | 2007-06-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2004109136A (ru) | Способ и катализатор высокоактивной изомеризации | |
| WO2005123250B1 (en) | High-activity isomerization catalyst and process | |
| DK2161076T3 (en) | Process for selective hydrogenation using a sulfide catalyst of a specific composition | |
| US4268488A (en) | Process for the catalytic reduction of nitrogen oxides in gaseous mixtures | |
| NO301068B1 (no) | Fremgangsmåte for fremstilling av en formbar deig av titandioksyd samt ekstrudater derav og deres anvendelse | |
| CN101722031B (zh) | 长链正构烷烃择形异构化催化剂及其制备方法和应用 | |
| KR930021262A (ko) | 지지체상에 ⅷ족 금속 및 ⅲa족 금속이 침착된 촉매 | |
| BR112017009820B1 (pt) | Método para formar um zeólito aluminossilicato | |
| CA2468152A1 (en) | Nox reduction composition for use in fcc processes | |
| EA010025B1 (ru) | Способ удаления cos из потока синтез-газа, включающего hs и cos | |
| KR940019838A (ko) | 예비가황된 촉매에 통과시키므로써 탄화수소로부터 수은을 제거하는 방법 | |
| JP2007177245A (ja) | 硫化触媒を利用する選択的水素化法 | |
| EP3900828A1 (en) | Catalyst having monolithic structure for reducing emission of nox in flue gas, preparation method therefor, and use method therefor | |
| WO2001049808A1 (en) | Activation of hydrocarbon synthesis catalysts with hydrogen and ammonia | |
| JP2009279584A (ja) | 接触的還元及び酸化方法 | |
| JP2002508701A (ja) | 天然マンガン鉱石を用いる窒素酸化物の除去方法 | |
| NO20023229L (no) | Hydrokarbonsyntesekatalysatorforbedring med hydrogen og ammoniakk | |
| Becerra et al. | Stable Ni/Al 2 O 3 catalysts for methane dry reforming: Effects of pretreatment | |
| JP2594463B2 (ja) | 脱水素反応用触媒及びその製法 | |
| JP2000061307A (ja) | 高分散型水蒸気改質触媒及び水素製造方法 | |
| KR850003427A (ko) | 탄화수소 전환법 | |
| PT1187669E (pt) | Metodo para a oxidacao catalitica de compostos organicos volateis | |
| JPH07171390A (ja) | 特にジルコニアを含む、高度に分散した金属酸化物に基づく触媒 | |
| JP2010194420A (ja) | 銅系触媒およびその前処理方法 | |
| Burmistrov et al. | Thiophene hydrogenolysis on NiS/SiO 2 catalysts |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200829 |