NO321464B1 - Blanding inneholdende en molekylsil av pentasil-type, og fremstilling og anvendelse derav - Google Patents
Blanding inneholdende en molekylsil av pentasil-type, og fremstilling og anvendelse derav Download PDFInfo
- Publication number
- NO321464B1 NO321464B1 NO19984332A NO984332A NO321464B1 NO 321464 B1 NO321464 B1 NO 321464B1 NO 19984332 A NO19984332 A NO 19984332A NO 984332 A NO984332 A NO 984332A NO 321464 B1 NO321464 B1 NO 321464B1
- Authority
- NO
- Norway
- Prior art keywords
- weight
- molecular sieve
- mixture
- pentasil
- zsm
- Prior art date
Links
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims description 85
- 239000002808 molecular sieve Substances 0.000 title claims description 82
- 239000000203 mixture Substances 0.000 title claims description 41
- 238000000034 method Methods 0.000 claims description 40
- 229910052698 phosphorus Inorganic materials 0.000 claims description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 22
- 239000005977 Ethylene Substances 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 21
- 229910052749 magnesium Inorganic materials 0.000 claims description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 18
- 239000011574 phosphorus Substances 0.000 claims description 18
- 239000010457 zeolite Substances 0.000 claims description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 15
- 229910052725 zinc Inorganic materials 0.000 claims description 15
- 229910052791 calcium Inorganic materials 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000004523 catalytic cracking Methods 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 229910052593 corundum Inorganic materials 0.000 claims description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000011777 magnesium Substances 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 15
- 238000002441 X-ray diffraction Methods 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 13
- 239000008367 deionised water Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 239000011575 calcium Substances 0.000 description 9
- -1 carbonyl olefins Chemical class 0.000 description 9
- 238000005336 cracking Methods 0.000 description 9
- 238000004876 x-ray fluorescence Methods 0.000 description 9
- 238000001354 calcination Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000007233 catalytic pyrolysis Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 6
- 229910052723 transition metal Inorganic materials 0.000 description 6
- 150000003624 transition metals Chemical class 0.000 description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 5
- 150000001342 alkaline earth metals Chemical class 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 235000011007 phosphoric acid Nutrition 0.000 description 5
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000006317 isomerization reaction Methods 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- 238000007323 disproportionation reaction Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000004230 steam cracking Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000839426 Chlamydia virus Chp1 Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Inorganic materials [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN97116435A CN1072031C (zh) | 1997-09-17 | 1997-09-17 | 一种五元环分子筛组合物的制备方法 |
CN97116445A CN1072032C (zh) | 1997-09-17 | 1997-09-17 | 多产乙烯和丙烯的五元环分子筛组合物 |
Publications (3)
Publication Number | Publication Date |
---|---|
NO984332D0 NO984332D0 (no) | 1998-09-17 |
NO984332L NO984332L (no) | 1999-03-18 |
NO321464B1 true NO321464B1 (no) | 2006-05-15 |
Family
ID=25744360
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19984332A NO321464B1 (no) | 1997-09-17 | 1998-09-17 | Blanding inneholdende en molekylsil av pentasil-type, og fremstilling og anvendelse derav |
Country Status (5)
Country | Link |
---|---|
US (1) | US6080698A (fr) |
EP (1) | EP0903178B2 (fr) |
JP (1) | JP3741548B2 (fr) |
DE (1) | DE69819989T3 (fr) |
NO (1) | NO321464B1 (fr) |
Families Citing this family (56)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004167306A (ja) * | 2002-11-18 | 2004-06-17 | Ict:Kk | 排ガス浄化用触媒および排ガス浄化方法 |
ES2209656B2 (es) * | 2002-12-13 | 2005-06-16 | Celaya Emparanza Y Galdos, S.A. (Cegasa) | Un elemento electroquimico o pila y un catodo para el mismo. |
TWI259106B (en) * | 2003-06-30 | 2006-08-01 | China Petrochemical Technology | Catalyst conversion process for increasing yield of light olefins |
US7084318B2 (en) * | 2003-08-01 | 2006-08-01 | Saudi Basic Industries Corporation | Toluene methylation process |
US7060864B2 (en) * | 2003-09-30 | 2006-06-13 | Saudi Basic Industries Corporation | Toluene methylation process |
CN1257769C (zh) * | 2003-10-31 | 2006-05-31 | 中国石油化工股份有限公司 | 一种含磷和金属组分的mfi结构分子筛及其应用 |
US7060644B2 (en) * | 2004-01-08 | 2006-06-13 | Saudi Basic Industries Corporation | Aromatic alkylation catalyst and method |
US6943131B1 (en) * | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
BRPI0509507B1 (pt) * | 2004-03-31 | 2021-02-23 | Research Institute Of Petroleum Processing, Sinopec | catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador |
US20050227853A1 (en) * | 2004-04-02 | 2005-10-13 | Ranjit Kumar | Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons |
US7285511B2 (en) * | 2004-04-23 | 2007-10-23 | Saudi Basic Industries Corporation | Method of modifying zeolite catalyst |
US7399727B2 (en) * | 2004-04-23 | 2008-07-15 | Saudi Basic Industries Corporation | Zeolite catalyst and method |
WO2005123251A1 (fr) * | 2004-06-09 | 2005-12-29 | Saudi Basic Industries Corporation | Catalyseur en zeolithe modifie par fluorure et methode |
US7615143B2 (en) * | 2004-07-30 | 2009-11-10 | Exxonmobil Chemical Patents Inc. | Hydrothermally stable catalyst and its use in catalytic cracking |
CN100478420C (zh) * | 2004-09-15 | 2009-04-15 | 中国石油化工股份有限公司 | 一种催化裂化助剂及其制备方法 |
US7304194B2 (en) * | 2005-05-05 | 2007-12-04 | Saudi Basic Industries Corporation | Hydrothermal treatment of phosphorus-modified zeolite catalysts |
KR100598988B1 (ko) * | 2005-05-18 | 2006-07-12 | 주식회사 하이닉스반도체 | 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법 |
CN100425534C (zh) * | 2005-05-31 | 2008-10-15 | 中国石油化工股份有限公司 | 一种改性β沸石 |
JP5185816B2 (ja) * | 2005-06-29 | 2013-04-17 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 流動接触ユニットにおける軽質オレフィン用ペンタシル触媒 |
US7368410B2 (en) * | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
CN100400161C (zh) * | 2005-09-16 | 2008-07-09 | 中国石油化工股份有限公司 | 一种用于催化裂解制取低碳烯烃的改性分子筛 |
US8003258B2 (en) * | 2006-01-19 | 2011-08-23 | The Gillette Company | Alkaline cell with improved anode |
CN101134913B (zh) | 2006-08-31 | 2011-05-18 | 中国石油化工股份有限公司 | 一种烃类催化转化方法 |
CN101134172B (zh) * | 2006-08-31 | 2010-10-27 | 中国石油化工股份有限公司 | 一种烃类转化催化剂 |
CO5930068A1 (es) * | 2006-12-06 | 2008-06-27 | Ecopetrol Sa | Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso |
BRPI0815417A8 (pt) * | 2007-08-13 | 2018-10-30 | Agency Science Tech & Res | composição de catalisador modificada para conversão de álcool em alceno |
EP2082801A1 (fr) * | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Processus pour obtenir des tamis moléculaires modifiés |
KR100979580B1 (ko) | 2008-02-05 | 2010-09-01 | 에스케이에너지 주식회사 | 경질올레핀 생산용 탄화수소 접촉 분해 촉매 및 그제조방법 |
US8846559B2 (en) * | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
BRPI0805207B1 (pt) * | 2008-11-25 | 2019-11-12 | Petroleo Brasileiro Sa Petrobras | processo de craqueamento catalítico de uma corrente de hidrocarbonetos para maximização de olefinas leves |
US8062987B2 (en) | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
CN102050462B (zh) * | 2009-10-30 | 2012-10-17 | 中国石油天然气股份有限公司 | 一种提高水热稳定性的双组元改性分子筛及制备方法 |
CN101905118B (zh) * | 2010-06-29 | 2012-07-11 | 北京化工大学 | 一种高效催化裂化烟气硫转移剂活性组元的制备方法 |
RU2442650C1 (ru) * | 2010-08-11 | 2012-02-20 | Учреждение Российской Академии Наук Ордена Трудового Красного Знамени Институт Нефтехимического Синтеза Им. А.В. Топчиева Ран (Инхс Ран) | Катализатор, способ его приготовления и способ получения смеси углеводородов с низким содержанием ароматических соединений |
US9181146B2 (en) | 2010-12-10 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
CN103055919B (zh) * | 2011-10-18 | 2015-08-26 | 中国石油化工股份有限公司 | 一种蒸汽裂解制丙烯的规整结构催化剂 |
CN103055916B (zh) * | 2011-10-21 | 2015-06-17 | 中国石油化工股份有限公司 | 一种催化裂化催化剂的制备方法 |
US8921633B2 (en) | 2012-05-07 | 2014-12-30 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
US8937205B2 (en) | 2012-05-07 | 2015-01-20 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes |
US9181147B2 (en) | 2012-05-07 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
CN102989501A (zh) * | 2012-12-11 | 2013-03-27 | 神华集团有限责任公司 | H-zsm-5分子筛催化剂制备方法及制得的催化剂 |
EP2980050B1 (fr) * | 2013-03-29 | 2019-10-23 | NGK Insulators, Ltd. | Corps assemblé en oxyde de métal-aluminophosphate et son procédé de production |
CN103301875B (zh) * | 2013-06-14 | 2015-10-28 | 华东师范大学 | 一种mfi型硅铝分子筛/铝纤维复合材料及其制备方法和应用 |
CN104556120B (zh) * | 2013-10-22 | 2017-01-25 | 中国石油化工股份有限公司 | 一种金属改性y型分子筛的制备方法 |
CN104549442B (zh) * | 2013-10-28 | 2017-04-19 | 中国石油化工股份有限公司 | 醋酸乙烯催化剂和由醋酸亚乙酯合成醋酸乙烯的方法 |
CN105013525B (zh) * | 2014-04-24 | 2017-10-03 | 中国石油化工股份有限公司 | 一种提高低碳烯烃浓度的催化裂化助剂及其制备方法 |
US10815432B2 (en) * | 2015-09-22 | 2020-10-27 | Hindustan Petroleum Corporation Limited | Additive and a catalyst composition comprising the additive for FCC process |
CN105618127B (zh) * | 2016-02-02 | 2018-01-05 | 北京化工大学 | 一种钼纳米颗粒高分散于分子筛结晶内部的催化剂及其制备方法与应用 |
CN114073978B (zh) * | 2020-08-10 | 2023-06-30 | 中国科学院大连化学物理研究所 | 一种金属改性zsm-5分子筛及其制备方法和应用 |
CN114715911B (zh) * | 2021-01-05 | 2024-03-12 | 中国石油化工股份有限公司 | 含磷和金属的多级孔zsm-5分子筛及其制备方法 |
JP2024506852A (ja) * | 2021-02-01 | 2024-02-15 | ビーエーエスエフ コーポレーション | Ynu-5ゼオライト、それの調製方法、及び使用方法 |
JP2022134963A (ja) * | 2021-03-04 | 2022-09-15 | 千代田化工建設株式会社 | 複合体触媒、複合体触媒の製造方法および低級オレフィンの製造方法 |
CN115518678B (zh) * | 2021-06-24 | 2023-11-10 | 中国石油化工股份有限公司 | 一种轻烃催化裂解催化剂及其制备方法与应用 |
US11680210B2 (en) * | 2021-11-04 | 2023-06-20 | Chevron U.S.A. Inc. | Catalytic cracking of glyceride oils with deactivated phosphorus-containing ZSM-5 light olefins additives |
CN114192184B (zh) * | 2021-12-31 | 2023-08-11 | 新疆理工学院 | 一种裂解催化剂及其制备方法和应用 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1334243A (en) * | 1969-10-10 | 1973-10-17 | Mobil Oil Corp | Crystalline zeolite and method of preparing the same |
US3702886A (en) * | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
US4137195A (en) * | 1976-10-21 | 1979-01-30 | Mobil Oil Corporation | Catalyst for disproportionation of toluene |
DE3066649D1 (en) * | 1979-12-07 | 1984-03-22 | British Petroleum Co Plc | Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports |
EP0040463B1 (fr) * | 1980-05-19 | 1984-09-05 | Mobil Oil Corporation | Méthode donnant lieu à des réactions sélectives avec des catalyseurs de zéolithes modifiés par du fer et (ou) du cobalt |
US4581215A (en) * | 1981-06-26 | 1986-04-08 | Mobil Oil Corporation | Para-selective zeolite catalysts treated with halogen compounds |
US4365104A (en) * | 1981-06-26 | 1982-12-21 | Mobil Oil Corporation | Para-selective zeolite catalysts treated with sulfur compounds |
CA1182800A (fr) * | 1981-06-26 | 1985-02-19 | Warren W. Kaeding | Traitement des catalyseurs a zeolites pour ameliorer la selectivite en para |
DE3370469D1 (en) * | 1982-11-16 | 1987-04-30 | Hoechst Ag | Aluminium silicates with a zeolite structure and process for their preparation |
US4548914A (en) * | 1983-08-26 | 1985-10-22 | Mobil Oil Corporation | Zeolite catalysts of improved activity and para-selectivity |
CN85100463B (zh) * | 1985-04-03 | 1988-06-01 | 南开大学 | ″直接法″合成zsm-5分子筛 |
JPH0729943B2 (ja) * | 1988-03-09 | 1995-04-05 | 日本石油化学株式会社 | p−イソブチルエチルベンゼンを選択的に製造する方法 |
DE3913163A1 (de) * | 1989-04-21 | 1990-10-25 | Basf Ag | Verfahren zur herstellung von benzylmethylethern |
CN1027632C (zh) * | 1990-07-23 | 1995-02-15 | 中国石油化工总公司石油化工科学研究院 | 含稀土五元环结构高硅沸石的制备方法 |
JPH0622105A (ja) † | 1992-07-03 | 1994-01-28 | Konica Corp | 画像形成装置 |
CN1030326C (zh) * | 1992-08-27 | 1995-11-22 | 中国石油化工总公司石油化工科学研究院 | 石油烃的催化热裂解方法 |
JPH06157359A (ja) * | 1992-11-24 | 1994-06-03 | Cosmo Sogo Kenkyusho:Kk | 低級炭化水素の低重合方法 |
JP3278510B2 (ja) † | 1993-11-25 | 2002-04-30 | 出光興産株式会社 | 排ガス浄化用触媒およびその製造方法 |
-
1998
- 1998-09-17 JP JP26370398A patent/JP3741548B2/ja not_active Expired - Lifetime
- 1998-09-17 DE DE69819989T patent/DE69819989T3/de not_active Expired - Lifetime
- 1998-09-17 NO NO19984332A patent/NO321464B1/no not_active IP Right Cessation
- 1998-09-17 EP EP98307583A patent/EP0903178B2/fr not_active Expired - Lifetime
- 1998-09-17 US US09/154,581 patent/US6080698A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69819989D1 (de) | 2004-01-08 |
JPH11157831A (ja) | 1999-06-15 |
DE69819989T2 (de) | 2004-09-02 |
EP0903178B1 (fr) | 2003-11-26 |
NO984332D0 (no) | 1998-09-17 |
NO984332L (no) | 1999-03-18 |
DE69819989T3 (de) | 2012-10-04 |
JP3741548B2 (ja) | 2006-02-01 |
EP0903178A1 (fr) | 1999-03-24 |
US6080698A (en) | 2000-06-27 |
EP0903178B2 (fr) | 2012-05-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
NO321464B1 (no) | Blanding inneholdende en molekylsil av pentasil-type, og fremstilling og anvendelse derav | |
US5951963A (en) | Phosphorous containing zeolite having MFI type structure | |
JP5065257B2 (ja) | 改質ゼオライトβ | |
RU2409422C2 (ru) | Катализатор конверсии углеводородов | |
RU2494809C2 (ru) | Катализатор для каталитического крекинга углеводорода, который применяют при получении легкого олефина, и способ его получения | |
CA2562905C (fr) | Compositions zeolitiques d'aluminosilicates cristallins uzm-8 et uzm-8hs et processus utilisant ces compositions | |
CA2527071C (fr) | Synthese in-situ de zsm 5 | |
BRPI0621983B1 (pt) | processo para a conversão catalítica de hidrocarbonetos | |
NZ199431A (en) | Aluminosilicates and catalysts therefrom | |
BRPI0509507B1 (pt) | catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador | |
US20150165428A1 (en) | Catalytic cracking catalyst for high-efficiency conversion of heavy oil and preparation method thereof | |
JP2769044B2 (ja) | 接触分解方法 | |
WO2005042404A1 (fr) | Tamis moleculaire a structure mfi contenant des composants phosphores et metalliques, procede de preparation et d'utilisation de ce dernier | |
JP5588973B2 (ja) | 結晶質メタロシリケートの製造方法 | |
JP4996783B2 (ja) | 燐含有ゼオライトim−5、触媒組成物、その調製法および接触クラッキングにおけるその使用法 | |
US6007698A (en) | Process for cracking hydrocarbon feeds using a catalyst comprising an IM-5 zeolite which is optionally dealuminated | |
CA2067630A1 (fr) | Synthese de zeolite beta | |
US6969692B2 (en) | Process for the preparation of doped pentasil-type zeolites using a doped reactant | |
CA2496898C (fr) | Processus de preparation de zeolites de type pensatile dopes au moyen d'un reactif dope | |
AU650358B2 (en) | Zeolite-type material | |
US5238675A (en) | Gallium zeolites | |
WO2022155523A1 (fr) | Cristallisation à l'état pseudo-solide de zéolites et utilisations de celle-ci |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK1K | Patent expired |