GB1334243A - Crystalline zeolite and method of preparing the same - Google Patents

Crystalline zeolite and method of preparing the same

Info

Publication number
GB1334243A
GB1334243A GB4316470A GB4316470A GB1334243A GB 1334243 A GB1334243 A GB 1334243A GB 4316470 A GB4316470 A GB 4316470A GB 4316470 A GB4316470 A GB 4316470A GB 1334243 A GB1334243 A GB 1334243A
Authority
GB
United Kingdom
Prior art keywords
tea
zeolite
hours
sio
metal cations
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4316470A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1334243A publication Critical patent/GB1334243A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/365—Type ZSM-8; Type ZSM-11; ZSM 5/11 intermediate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming

Abstract

1334243 Zeolite ZSM-8 MOBIL OIL CORP 9 Sept 1970 [10 Oct 1969] 43164/70 Heading C1A [Also in Division C5] A crystalline zeolite having an X-ray diffraction pattern substantially as in Table 1 (not illustrated), the most intense bands of which are at 11À1. 10À0 and 3À85 Š, is prepared by forming a reaction solution having a molar constitution in terms of the following oxides and hydroxide SiO 2 /Al 2 O 3 = 10:200; Na 2 O/(TEA)OH = 0À05 : 0À20; (TEA)OH : SiO 2 = 0À08 : 1À0; H 2 O/(TEA)OH = 80 : 200 (TEA = tetraethylammonium group) and reacting until crystals of said zeolite are formed. The reaction may take from 6 hours to 60 days. The product zeolite may be treated by (a) calcinating, e.g. at 500- 1500‹ F. for 1-48 hours, (b) steam treatment at up to 1500‹ F., (c) ion exchange to replace cations therein by, e.g. H, NH 4 <SP>+</SP>, metal cations, e.g. rare earth metal cations, or mixtures thereof or by combinations of such treatments.
GB4316470A 1969-10-10 1970-09-09 Crystalline zeolite and method of preparing the same Expired GB1334243A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US86541869A 1969-10-10 1969-10-10

Publications (1)

Publication Number Publication Date
GB1334243A true GB1334243A (en) 1973-10-17

Family

ID=25345467

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4316470A Expired GB1334243A (en) 1969-10-10 1970-09-09 Crystalline zeolite and method of preparing the same

Country Status (3)

Country Link
DE (1) DE2049755A1 (en)
GB (1) GB1334243A (en)
NL (1) NL7014807A (en)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0036683A1 (en) * 1980-03-18 1981-09-30 Shell Internationale Researchmaatschappij B.V. Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture
EP0042225A1 (en) * 1980-06-12 1981-12-23 Imperial Chemical Industries Plc Zeolite synthesis
EP0057016A2 (en) * 1981-01-27 1982-08-04 Toray Industries, Inc. Process for preparing crystalline aluminosilicate zeolites
JPS5845111A (en) * 1981-09-11 1983-03-16 Toa Nenryo Kogyo Kk Crystalline aluminosilicate, its manufacture and converting method for organic starting material using it
US4507512A (en) * 1983-05-31 1985-03-26 Toa Nenryo Kogyo Kabushiki Kaisha Process for hydration of olefins
US4560542A (en) * 1984-12-06 1985-12-24 Exxon Research And Engineering Co. Method for the preparation of zeolites using a low water low alkali metal content gel
US4604470A (en) * 1984-05-25 1986-08-05 Hoechst Aktiengesellschaft Process for the isomerization of halogenated thiophenes
US4783541A (en) * 1984-09-13 1988-11-08 Hoechst Aktiengesellschaft Process for isomerizing alkylthiophenes
US4935561A (en) * 1984-06-02 1990-06-19 Hoechst Aktiengesellschaft Process for isomerizing monochlorotoluenes or dichlorotoluenes
US4944273A (en) * 1988-02-24 1990-07-31 Robert Bosch Gmbh Zeolites as specific adsorbents for NOX and CO
US4975258A (en) * 1988-08-03 1990-12-04 The British Petroleum Company, P.L.C. Novel crystalline (metallo) silicates and germanates
US5125231A (en) * 1990-06-08 1992-06-30 Corning Incorporated Dual converter engine exhaust system for reducing hydrocarbon emissions
EP0697505A1 (en) 1994-08-02 1996-02-21 Corning Incorporated In-line adsorber system
US5603216A (en) * 1994-08-02 1997-02-18 Corning Incorporated By-pass adsorber system
US6080698A (en) * 1997-09-17 2000-06-27 China Petrochemical Corporation Pentasil-type molecular sieve containing composition and its preparation method
US6089014A (en) * 1990-06-08 2000-07-18 Corning Incorporated Engine exhaust system with reduced hydrocarbon emissions
US7122496B2 (en) 2003-05-01 2006-10-17 Bp Corporation North America Inc. Para-xylene selective adsorbent compositions and methods
US10532962B2 (en) 2016-02-02 2020-01-14 Sabic Global Technologies B.V. Conversion of shale gas to aromatics
US11964262B2 (en) 2018-10-18 2024-04-23 China Petroleum & Chemical Corporation Phosphorus-containing rare-earth-containing MFI structure molecular sieve rich in mesopore, preparation method, and catalyst containing same and application thereof

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3756942A (en) * 1972-05-17 1973-09-04 Mobil Oil Corp Process for the production of aromatic compounds
DE2333068C3 (en) * 1973-06-29 1983-06-09 Degussa Ag, 6000 Frankfurt Process for the preparation of a powdery crystalline zeolitic molecular sieve of type A and its use
BR8200670A (en) * 1981-02-09 1982-12-14 Mobil Oil Corp PROCESS TO SYNTHESIZE A ZEOLITE
DE69223680T2 (en) * 1991-05-17 1998-07-30 Asahi Chemical Ind Process for producing a particulate zeolite

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0036683A1 (en) * 1980-03-18 1981-09-30 Shell Internationale Researchmaatschappij B.V. Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture
EP0042225A1 (en) * 1980-06-12 1981-12-23 Imperial Chemical Industries Plc Zeolite synthesis
EP0057016A2 (en) * 1981-01-27 1982-08-04 Toray Industries, Inc. Process for preparing crystalline aluminosilicate zeolites
EP0057016A3 (en) * 1981-01-27 1982-09-29 Toray Industries, Inc. Process for preparing crystalline aluminosilicate zeolites
JPS6144805B2 (en) * 1981-09-11 1986-10-04 Toa Nenryo Kogyo Kk
JPS5845111A (en) * 1981-09-11 1983-03-16 Toa Nenryo Kogyo Kk Crystalline aluminosilicate, its manufacture and converting method for organic starting material using it
US4507512A (en) * 1983-05-31 1985-03-26 Toa Nenryo Kogyo Kabushiki Kaisha Process for hydration of olefins
US4604470A (en) * 1984-05-25 1986-08-05 Hoechst Aktiengesellschaft Process for the isomerization of halogenated thiophenes
US4935561A (en) * 1984-06-02 1990-06-19 Hoechst Aktiengesellschaft Process for isomerizing monochlorotoluenes or dichlorotoluenes
US4783541A (en) * 1984-09-13 1988-11-08 Hoechst Aktiengesellschaft Process for isomerizing alkylthiophenes
US4560542A (en) * 1984-12-06 1985-12-24 Exxon Research And Engineering Co. Method for the preparation of zeolites using a low water low alkali metal content gel
US4944273A (en) * 1988-02-24 1990-07-31 Robert Bosch Gmbh Zeolites as specific adsorbents for NOX and CO
US4975258A (en) * 1988-08-03 1990-12-04 The British Petroleum Company, P.L.C. Novel crystalline (metallo) silicates and germanates
US5125231A (en) * 1990-06-08 1992-06-30 Corning Incorporated Dual converter engine exhaust system for reducing hydrocarbon emissions
US6089014A (en) * 1990-06-08 2000-07-18 Corning Incorporated Engine exhaust system with reduced hydrocarbon emissions
EP0697505A1 (en) 1994-08-02 1996-02-21 Corning Incorporated In-line adsorber system
US5603216A (en) * 1994-08-02 1997-02-18 Corning Incorporated By-pass adsorber system
US6080698A (en) * 1997-09-17 2000-06-27 China Petrochemical Corporation Pentasil-type molecular sieve containing composition and its preparation method
US7122496B2 (en) 2003-05-01 2006-10-17 Bp Corporation North America Inc. Para-xylene selective adsorbent compositions and methods
US10532962B2 (en) 2016-02-02 2020-01-14 Sabic Global Technologies B.V. Conversion of shale gas to aromatics
US11964262B2 (en) 2018-10-18 2024-04-23 China Petroleum & Chemical Corporation Phosphorus-containing rare-earth-containing MFI structure molecular sieve rich in mesopore, preparation method, and catalyst containing same and application thereof

Also Published As

Publication number Publication date
DE2049755A1 (en) 1971-04-22
NL7014807A (en) 1971-04-14

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees