GB1161974A - Synthetic Crystalline Aluminosilicate and method of preparing the same - Google Patents
Synthetic Crystalline Aluminosilicate and method of preparing the sameInfo
- Publication number
- GB1161974A GB1161974A GB17330/68A GB1733068A GB1161974A GB 1161974 A GB1161974 A GB 1161974A GB 17330/68 A GB17330/68 A GB 17330/68A GB 1733068 A GB1733068 A GB 1733068A GB 1161974 A GB1161974 A GB 1161974A
- Authority
- GB
- United Kingdom
- Prior art keywords
- april
- aluminosilicate
- product
- sio
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
- C01B39/40—Type ZSM-5 using at least one organic template directing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1,161,974. Crystalline alumino-silicate. MOBIL OIL CORPORATION. 10 April, 1968 [14 April, 1967], No. 17330/68. Heading C1A. [Also in Division C5] A solid crystalline sodium aluminosilicate has the composition (in mole ratios):- 0À8-1 Na 2 O : Al 2 O 3 : 20-60 SiO 2 in its dehydrated form, the crystals being tetragonal, with a = 23.2 Š, and c = 19.9 Š. This is prepared by heating a reaction mixture of mole ratio composition SiO 2 /Al 2 O 3 = 20 to 60; Na 2 O/Al 2 O 3 = at least one; [(CH 3 CH 2 CH 2 ) 4 N] 2 O/Al 2 O 3 = at least one; and H 2 O/(Na 2 O + [(CH 3 CH 2 CH 2 ) 4 - N] 2 O) = 5 to 50, at from 100‹ to 175‹ C. for from 5 to 60 days. The product is washed, dried and calcined at a temperature of from 100‹ to 600‹ C. for from 8 to 24 hours. The product may be ion exchanged with a solution containing mono-, di- or trivalent cations. The hydrogen, sodium, calcium, rare earth and silver forms of the aluminosilicate are described and claimed. These products may be used as catalysts in the cracking of liquid hydrocarbons. ([(CH 3 CH 2 CH 2 ) 4 N] 2 O represents the oxide derived from the quarternary propyl ammonium hydroxide.)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63099367A | 1967-04-14 | 1967-04-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1161974A true GB1161974A (en) | 1969-08-20 |
Family
ID=24529375
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB17330/68A Expired GB1161974A (en) | 1967-04-14 | 1968-04-10 | Synthetic Crystalline Aluminosilicate and method of preparing the same |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE713576A (en) |
DE (2) | DE1767235C3 (en) |
FR (1) | FR1587860A (en) |
GB (1) | GB1161974A (en) |
NL (1) | NL160787C (en) |
PH (1) | PH12140A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2074006A5 (en) * | 1969-12-18 | 1971-10-01 | Mobil Oil Corp | |
DE2119723A1 (en) * | 1970-04-23 | 1971-12-02 | Mobil Oil Corp | Crystalline zeolites and processes for their production |
DE2213109A1 (en) * | 1971-03-18 | 1972-09-21 | Mobil Oil Corp | Crystalline zeolites and processes for their preparation |
EP0002900A1 (en) * | 1977-12-23 | 1979-07-11 | The British Petroleum Company p.l.c. | Method for producing aluminosilicates and their use as catalysts and supports |
EP0013630A1 (en) * | 1979-01-15 | 1980-07-23 | Mobil Oil Corporation | ZSM-12 zeolite composition, method of preparing same and catalytic conversion therewith |
EP0014059A1 (en) * | 1979-01-15 | 1980-08-06 | Mobil Oil Corporation | New form of zeolite ZSM-11, preparation thereof and catalytic conversion therewith |
US4242233A (en) | 1977-12-23 | 1980-12-30 | The British Petroleum Company Limited | Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom |
EP0036683A1 (en) * | 1980-03-18 | 1981-09-30 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture |
EP0054386A1 (en) * | 1980-12-17 | 1982-06-23 | Imperial Chemical Industries Plc | Zeolites |
EP0183376A2 (en) * | 1984-10-18 | 1986-06-04 | Nippon Oil Co. Ltd. | Method for dewaxing hydrocarbon oil |
EP0258870A1 (en) * | 1986-09-01 | 1988-03-09 | Yeda Research And Development Company Limited | Novel crystalline aluminosilicate zeolite catalysts and their use in the vapor phase isomerization of xylenes |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3758403A (en) * | 1970-10-06 | 1973-09-11 | Mobil Oil | Olites catalytic cracking of hydrocarbons with mixture of zsm-5 and other ze |
GB1403329A (en) * | 1972-04-28 | 1975-08-28 | Mobil Oil Corp | Vapour-phase alkylation in presence of crystalline alumino silicate catalyst |
US3751504A (en) * | 1972-05-12 | 1973-08-07 | Mobil Oil Corp | Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation |
NL177015C (en) * | 1976-12-16 | 1985-07-16 | Shell Int Research | IMPROVED METHOD FOR PREPARING AN AROMATIC HYDROCARBON MIX. |
GB1561590A (en) * | 1976-12-20 | 1980-02-27 | British Petroleum Co | Zeolites containing gallium |
US4139600A (en) * | 1977-04-22 | 1979-02-13 | Mobil Oil Corporation | Synthesis of zeolite ZSM-5 |
GB1601915A (en) * | 1977-05-25 | 1981-11-04 | Mobil Oil Corp | Method of preparation of large crystal alumino-silicate zeolite catalyst |
DE3131648C2 (en) * | 1981-08-11 | 1983-09-29 | Chemische Werke Hüls AG, 4370 Marl | Process for the production of crystalline metal silicates and their use |
JPS60248629A (en) * | 1984-05-23 | 1985-12-09 | Agency Of Ind Science & Technol | Preparation of lower olefin |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3308069A (en) * | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
-
1968
- 1968-04-10 GB GB17330/68A patent/GB1161974A/en not_active Expired
- 1968-04-11 FR FR1587860D patent/FR1587860A/fr not_active Expired
- 1968-04-11 BE BE713576D patent/BE713576A/xx not_active IP Right Cessation
- 1968-04-13 DE DE1767235A patent/DE1767235C3/en not_active Expired
- 1968-04-13 DE DE1792783A patent/DE1792783C2/en not_active Expired
- 1968-04-16 NL NL6805355.A patent/NL160787C/en not_active IP Right Cessation
-
1973
- 1973-11-09 PH PH15210A patent/PH12140A/en unknown
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2074006A5 (en) * | 1969-12-18 | 1971-10-01 | Mobil Oil Corp | |
DE2119723A1 (en) * | 1970-04-23 | 1971-12-02 | Mobil Oil Corp | Crystalline zeolites and processes for their production |
DE2213109A1 (en) * | 1971-03-18 | 1972-09-21 | Mobil Oil Corp | Crystalline zeolites and processes for their preparation |
US4242233A (en) | 1977-12-23 | 1980-12-30 | The British Petroleum Company Limited | Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom |
EP0002900A1 (en) * | 1977-12-23 | 1979-07-11 | The British Petroleum Company p.l.c. | Method for producing aluminosilicates and their use as catalysts and supports |
US4346021A (en) | 1977-12-23 | 1982-08-24 | The British Petroleum Company Limited | Method for producing aluminosilicates, their use as catalysts and supports and method for producing catalysts therefrom |
EP0013630A1 (en) * | 1979-01-15 | 1980-07-23 | Mobil Oil Corporation | ZSM-12 zeolite composition, method of preparing same and catalytic conversion therewith |
EP0014059A1 (en) * | 1979-01-15 | 1980-08-06 | Mobil Oil Corporation | New form of zeolite ZSM-11, preparation thereof and catalytic conversion therewith |
EP0036683A1 (en) * | 1980-03-18 | 1981-09-30 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture |
EP0054386A1 (en) * | 1980-12-17 | 1982-06-23 | Imperial Chemical Industries Plc | Zeolites |
EP0183376A2 (en) * | 1984-10-18 | 1986-06-04 | Nippon Oil Co. Ltd. | Method for dewaxing hydrocarbon oil |
EP0183376A3 (en) * | 1984-10-18 | 1986-10-29 | Nippon Oil Co. Ltd. | Method for dewaxing hydrocarbon oil |
EP0258870A1 (en) * | 1986-09-01 | 1988-03-09 | Yeda Research And Development Company Limited | Novel crystalline aluminosilicate zeolite catalysts and their use in the vapor phase isomerization of xylenes |
Also Published As
Publication number | Publication date |
---|---|
DE1767235B2 (en) | 1979-10-04 |
NL160787C (en) | 1979-12-17 |
DE1767235A1 (en) | 1971-09-09 |
DE1792783B1 (en) | 1979-11-08 |
DE1767235C3 (en) | 1980-07-17 |
FR1587860A (en) | 1970-04-03 |
NL160787B (en) | 1979-07-16 |
NL6805355A (en) | 1968-10-15 |
DE1792783C2 (en) | 1980-10-23 |
PH12140A (en) | 1978-11-07 |
BE713576A (en) | 1968-10-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |