GB1161974A - Synthetic Crystalline Aluminosilicate and method of preparing the same - Google Patents

Synthetic Crystalline Aluminosilicate and method of preparing the same

Info

Publication number
GB1161974A
GB1161974A GB17330/68A GB1733068A GB1161974A GB 1161974 A GB1161974 A GB 1161974A GB 17330/68 A GB17330/68 A GB 17330/68A GB 1733068 A GB1733068 A GB 1733068A GB 1161974 A GB1161974 A GB 1161974A
Authority
GB
United Kingdom
Prior art keywords
april
aluminosilicate
product
sio
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17330/68A
Inventor
Robert John Argauer
David Harold Olson
George Robert Landolt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1161974A publication Critical patent/GB1161974A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1,161,974. Crystalline alumino-silicate. MOBIL OIL CORPORATION. 10 April, 1968 [14 April, 1967], No. 17330/68. Heading C1A. [Also in Division C5] A solid crystalline sodium aluminosilicate has the composition (in mole ratios):- 0À8-1 Na 2 O : Al 2 O 3 : 20-60 SiO 2 in its dehydrated form, the crystals being tetragonal, with a = 23.2 Š, and c = 19.9 Š. This is prepared by heating a reaction mixture of mole ratio composition SiO 2 /Al 2 O 3 = 20 to 60; Na 2 O/Al 2 O 3 = at least one; [(CH 3 CH 2 CH 2 ) 4 N] 2 O/Al 2 O 3 = at least one; and H 2 O/(Na 2 O + [(CH 3 CH 2 CH 2 ) 4 - N] 2 O) = 5 to 50, at from 100‹ to 175‹ C. for from 5 to 60 days. The product is washed, dried and calcined at a temperature of from 100‹ to 600‹ C. for from 8 to 24 hours. The product may be ion exchanged with a solution containing mono-, di- or trivalent cations. The hydrogen, sodium, calcium, rare earth and silver forms of the aluminosilicate are described and claimed. These products may be used as catalysts in the cracking of liquid hydrocarbons. ([(CH 3 CH 2 CH 2 ) 4 N] 2 O represents the oxide derived from the quarternary propyl ammonium hydroxide.)
GB17330/68A 1967-04-14 1968-04-10 Synthetic Crystalline Aluminosilicate and method of preparing the same Expired GB1161974A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US63099367A 1967-04-14 1967-04-14

Publications (1)

Publication Number Publication Date
GB1161974A true GB1161974A (en) 1969-08-20

Family

ID=24529375

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17330/68A Expired GB1161974A (en) 1967-04-14 1968-04-10 Synthetic Crystalline Aluminosilicate and method of preparing the same

Country Status (6)

Country Link
BE (1) BE713576A (en)
DE (2) DE1767235C3 (en)
FR (1) FR1587860A (en)
GB (1) GB1161974A (en)
NL (1) NL160787C (en)
PH (1) PH12140A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2074006A5 (en) * 1969-12-18 1971-10-01 Mobil Oil Corp
DE2119723A1 (en) * 1970-04-23 1971-12-02 Mobil Oil Corp Crystalline zeolites and processes for their production
DE2213109A1 (en) * 1971-03-18 1972-09-21 Mobil Oil Corp Crystalline zeolites and processes for their preparation
EP0002900A1 (en) * 1977-12-23 1979-07-11 The British Petroleum Company p.l.c. Method for producing aluminosilicates and their use as catalysts and supports
EP0013630A1 (en) * 1979-01-15 1980-07-23 Mobil Oil Corporation ZSM-12 zeolite composition, method of preparing same and catalytic conversion therewith
EP0014059A1 (en) * 1979-01-15 1980-08-06 Mobil Oil Corporation New form of zeolite ZSM-11, preparation thereof and catalytic conversion therewith
US4242233A (en) 1977-12-23 1980-12-30 The British Petroleum Company Limited Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom
EP0036683A1 (en) * 1980-03-18 1981-09-30 Shell Internationale Researchmaatschappij B.V. Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture
EP0054386A1 (en) * 1980-12-17 1982-06-23 Imperial Chemical Industries Plc Zeolites
EP0183376A2 (en) * 1984-10-18 1986-06-04 Nippon Oil Co. Ltd. Method for dewaxing hydrocarbon oil
EP0258870A1 (en) * 1986-09-01 1988-03-09 Yeda Research And Development Company Limited Novel crystalline aluminosilicate zeolite catalysts and their use in the vapor phase isomerization of xylenes

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3758403A (en) * 1970-10-06 1973-09-11 Mobil Oil Olites catalytic cracking of hydrocarbons with mixture of zsm-5 and other ze
GB1403329A (en) * 1972-04-28 1975-08-28 Mobil Oil Corp Vapour-phase alkylation in presence of crystalline alumino silicate catalyst
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
NL177015C (en) * 1976-12-16 1985-07-16 Shell Int Research IMPROVED METHOD FOR PREPARING AN AROMATIC HYDROCARBON MIX.
GB1561590A (en) * 1976-12-20 1980-02-27 British Petroleum Co Zeolites containing gallium
US4139600A (en) * 1977-04-22 1979-02-13 Mobil Oil Corporation Synthesis of zeolite ZSM-5
GB1601915A (en) * 1977-05-25 1981-11-04 Mobil Oil Corp Method of preparation of large crystal alumino-silicate zeolite catalyst
DE3131648C2 (en) * 1981-08-11 1983-09-29 Chemische Werke Hüls AG, 4370 Marl Process for the production of crystalline metal silicates and their use
JPS60248629A (en) * 1984-05-23 1985-12-09 Agency Of Ind Science & Technol Preparation of lower olefin

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3308069A (en) * 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2074006A5 (en) * 1969-12-18 1971-10-01 Mobil Oil Corp
DE2119723A1 (en) * 1970-04-23 1971-12-02 Mobil Oil Corp Crystalline zeolites and processes for their production
DE2213109A1 (en) * 1971-03-18 1972-09-21 Mobil Oil Corp Crystalline zeolites and processes for their preparation
US4242233A (en) 1977-12-23 1980-12-30 The British Petroleum Company Limited Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom
EP0002900A1 (en) * 1977-12-23 1979-07-11 The British Petroleum Company p.l.c. Method for producing aluminosilicates and their use as catalysts and supports
US4346021A (en) 1977-12-23 1982-08-24 The British Petroleum Company Limited Method for producing aluminosilicates, their use as catalysts and supports and method for producing catalysts therefrom
EP0013630A1 (en) * 1979-01-15 1980-07-23 Mobil Oil Corporation ZSM-12 zeolite composition, method of preparing same and catalytic conversion therewith
EP0014059A1 (en) * 1979-01-15 1980-08-06 Mobil Oil Corporation New form of zeolite ZSM-11, preparation thereof and catalytic conversion therewith
EP0036683A1 (en) * 1980-03-18 1981-09-30 Shell Internationale Researchmaatschappij B.V. Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture
EP0054386A1 (en) * 1980-12-17 1982-06-23 Imperial Chemical Industries Plc Zeolites
EP0183376A2 (en) * 1984-10-18 1986-06-04 Nippon Oil Co. Ltd. Method for dewaxing hydrocarbon oil
EP0183376A3 (en) * 1984-10-18 1986-10-29 Nippon Oil Co. Ltd. Method for dewaxing hydrocarbon oil
EP0258870A1 (en) * 1986-09-01 1988-03-09 Yeda Research And Development Company Limited Novel crystalline aluminosilicate zeolite catalysts and their use in the vapor phase isomerization of xylenes

Also Published As

Publication number Publication date
DE1767235B2 (en) 1979-10-04
NL160787C (en) 1979-12-17
DE1767235A1 (en) 1971-09-09
DE1792783B1 (en) 1979-11-08
DE1767235C3 (en) 1980-07-17
FR1587860A (en) 1970-04-03
NL160787B (en) 1979-07-16
NL6805355A (en) 1968-10-15
DE1792783C2 (en) 1980-10-23
PH12140A (en) 1978-11-07
BE713576A (en) 1968-10-11

Similar Documents

Publication Publication Date Title
GB1161974A (en) Synthetic Crystalline Aluminosilicate and method of preparing the same
US3791964A (en) Hydrocarbon conversion process employing a crystalline aluminosilicate and method of preparing the same
US3355246A (en) Crystalline zeolite zk-21
GB1323710A (en) Shape selective conversion process for dewaxing hydrocarbon mixtures
GB1318157A (en) Process for preparation of high-silica zeolites
GB1186934A (en) High Silica Crystalline Zeolites and process for their preparation
GB1525782A (en) Process for the production of a crystalline zeolitic molecular sieve of type a
GB1117568A (en) Synthetic crystalline aluminosilicate
GB1279485A (en) Process for preparing high silica faujasite
JPS57123815A (en) Production of crystalline aluminosilicate zeolite
GB1333051A (en) Aluminosilicate zeolites and their use as shape selective catalysts
GB1061474A (en) Synthetic zeolites
GB1334243A (en) Crystalline zeolite and method of preparing the same
US4623526A (en) Process for the preparation of a crystalline titanoborosilicate
GB1514417A (en) Method of preparing zeolite of high silica to alumina ratio
ES489504A1 (en) Process for producing a boron containing zeolite with the structure of ZSM-5 and its use as a catalyst.
GB1334928A (en) Mordenite catalyst and use thereof
GB1188584A (en) Process for the preparation of Synthetic Zeolite Molecular Sieves
ES8601799A1 (en) Process for preparing type L zeolites by nucleating technique.
GB1528532A (en) Preparation of a zeolite catalyst
GB1270964A (en) Synthetic zeolite and method of preparation thereof
FR1264290A (en) Process for the catalytic preparation of ethylene glycol
GB870440A (en) Process for producing sodium zeolite a
GB1506429A (en) Catalyst for hydrocarbon processes and process for preparing same
GB1223698A (en) Zeolites

Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years