CO5930068A1 - Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso - Google Patents

Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso

Info

Publication number
CO5930068A1
CO5930068A1 CO06123231A CO06123231A CO5930068A1 CO 5930068 A1 CO5930068 A1 CO 5930068A1 CO 06123231 A CO06123231 A CO 06123231A CO 06123231 A CO06123231 A CO 06123231A CO 5930068 A1 CO5930068 A1 CO 5930068A1
Authority
CO
Colombia
Prior art keywords
microspheres
support
aluminum hydroxide
suspension
vanadium
Prior art date
Application number
CO06123231A
Other languages
English (en)
Inventor
Rubiano Luis Oswaldo Almanza
Hernandez Cesar Augusto Vergel
Marin Luis Javier Hoyos
Original Assignee
Ecopetrol Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecopetrol Sa filed Critical Ecopetrol Sa
Priority to CO06123231A priority Critical patent/CO5930068A1/es
Priority to JP2009539829A priority patent/JP5547490B2/ja
Priority to KR1020097013907A priority patent/KR20090092311A/ko
Priority to EP07859339.9A priority patent/EP2103670A4/en
Priority to CN2007800494476A priority patent/CN101573430B/zh
Priority to BRPI0720141-9A2A priority patent/BRPI0720141A2/pt
Priority to US12/518,043 priority patent/US8633129B2/en
Priority to PCT/IB2007/004311 priority patent/WO2008068627A2/es
Publication of CO5930068A1 publication Critical patent/CO5930068A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

? Procedimiento para preparar composiciones químicas útiles en el proceso de craqueo catalítico de hidrocarburos que se caracteriza porque comprende los siguientes pasos: a. Producción del soporte de hidróxido de aluminio tipo bohemita, gibsita, hidrargilita y/o mezclas de ellas. b. Impregnación de sales de bario tipo Ba(NO3)2 o BaCI2, sales de magnesio tipo Mg(NO3)2 y ácido fosfórico en solución sobre las micro-esferas de alúmina calcinadas. c. Secar y calcinar las micro-esferas impregnadas. d. Mezclar las micro-esferas del paso anterior con el catalizador. Procedimiento según la reivindicación 1 caracterizado porque el soporte se produce a partir de una suspensión de hidróxido de aluminio previamente peptizada, la cual es secada por aspersión para formar las micro-esferas del soporte y calcinada en presencia de vapor de agua. Procedimiento según la reivindicación 2 caracterizado porque la suspensión para producir el soporte tiene una concentración del 30% de hidróxido de aluminio. Procedimiento según la reivindicación 2 caracterizado porque la suspensión de hidróxido de aluminio es peptizada con una solución de ácido fórmico al 45%. Procedimiento según una cualquiera de las reivindicaciones anteriores caracterizado porque se adiciona como dispersante (NaPO4)6 al agua antes de adicionar el hidróxido de aluminio. Procedimiento para preparar composiciones químicas según una cualquiera de las reivindicaciones anteriores caracterizado porque las micro-esferas de soporte se producen a partir de una suspensión hidróxido de aluminio que es tratada con una solución de ácido fórmico al 45%, luego es secada por aspersión para formar las micro-esferas del soporte, seguido son sometidas a una corriente de aire/vapor de agua a una temperatura entre 500 y 800°C durante un periodo de tiempo que oscila entre 1 a 4 h y finalmente son tratadas en aire seco a la misma temperatura por 1 hora.
CO06123231A 2006-12-06 2006-12-06 Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso CO5930068A1 (es)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CO06123231A CO5930068A1 (es) 2006-12-06 2006-12-06 Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso
JP2009539829A JP5547490B2 (ja) 2006-12-06 2007-11-30 含浸を用いてバナジウムトラップを製造する方法および同方法により得られるバナジウムトラップ
KR1020097013907A KR20090092311A (ko) 2006-12-06 2007-11-30 함침에 의한 바나듐 트랩의 제조방법 및 결과의 바나듐 트랩
EP07859339.9A EP2103670A4 (en) 2006-12-06 2007-11-30 PROCESS FOR PRODUCING VANADIUM TRAPS BY IMPREGNATING AND VANADIUM TRAP THUS OBTAINED
CN2007800494476A CN101573430B (zh) 2006-12-06 2007-11-30 通过浸渍生产捕钒剂的方法和所得到的捕钒剂
BRPI0720141-9A2A BRPI0720141A2 (pt) 2006-12-06 2007-11-30 Processo de produção de filtros de vanádio por impregnação e filtro de vanádio produzido por tal processo
US12/518,043 US8633129B2 (en) 2006-12-06 2007-11-30 Method for producing vanadium traps by means of impregnation and resulting vanadium trap
PCT/IB2007/004311 WO2008068627A2 (es) 2006-12-06 2007-11-30 Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CO06123231A CO5930068A1 (es) 2006-12-06 2006-12-06 Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso

Publications (1)

Publication Number Publication Date
CO5930068A1 true CO5930068A1 (es) 2008-06-27

Family

ID=39492690

Family Applications (1)

Application Number Title Priority Date Filing Date
CO06123231A CO5930068A1 (es) 2006-12-06 2006-12-06 Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso

Country Status (8)

Country Link
US (1) US8633129B2 (es)
EP (1) EP2103670A4 (es)
JP (1) JP5547490B2 (es)
KR (1) KR20090092311A (es)
CN (1) CN101573430B (es)
BR (1) BRPI0720141A2 (es)
CO (1) CO5930068A1 (es)
WO (1) WO2008068627A2 (es)

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US9623377B2 (en) 2012-07-18 2017-04-18 Cummins Inc. Systems and methods for reducing secondary emissions from catalyst components
US9441167B2 (en) * 2013-12-19 2016-09-13 Basf Corporation Boron oxide in FCC processes
CN107583672B (zh) * 2016-07-08 2019-12-17 中国石化扬子石油化工有限公司 一种钒污染催化裂化催化剂活性提高方法
SG11202003751WA (en) 2017-11-10 2020-05-28 Basf Corp A metal trap for use in fluid catalytic cracking (fcc)
WO2019118815A1 (en) 2017-12-15 2019-06-20 Basf Corporation Vanadium traps for catalytic cracking processes

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Also Published As

Publication number Publication date
KR20090092311A (ko) 2009-08-31
US8633129B2 (en) 2014-01-21
EP2103670A2 (en) 2009-09-23
WO2008068627A2 (es) 2008-06-12
CN101573430A (zh) 2009-11-04
EP2103670A4 (en) 2015-05-27
JP2010511509A (ja) 2010-04-15
WO2008068627A3 (es) 2008-08-14
JP5547490B2 (ja) 2014-07-16
US20110143932A1 (en) 2011-06-16
BRPI0720141A2 (pt) 2014-12-02
CN101573430B (zh) 2013-09-25

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