EA201490358A1 - Способ приготовления катализатора на основе модифицированного фосфором цеолита и применение такого цеолита - Google Patents

Способ приготовления катализатора на основе модифицированного фосфором цеолита и применение такого цеолита

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Publication number
EA201490358A1
EA201490358A1 EA201490358A EA201490358A EA201490358A1 EA 201490358 A1 EA201490358 A1 EA 201490358A1 EA 201490358 A EA201490358 A EA 201490358A EA 201490358 A EA201490358 A EA 201490358A EA 201490358 A1 EA201490358 A1 EA 201490358A1
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EA
Eurasian Patent Office
Prior art keywords
catalyst
zeolite
discretion
phosphorus
alcohols
Prior art date
Application number
EA201490358A
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English (en)
Other versions
EA026722B1 (ru
Inventor
Николай Нестеренко
Дельфине Миноукс
Синди Адам
Жан-Пьер Дат
Original Assignee
Тотал Ресерч & Технолоджи Фелай
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Application filed by Тотал Ресерч & Технолоджи Фелай filed Critical Тотал Ресерч & Технолоджи Фелай
Publication of EA201490358A1 publication Critical patent/EA201490358A1/ru
Publication of EA026722B1 publication Critical patent/EA026722B1/ru

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    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
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    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/655—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Заявляемое изобретение в первом варианте реализации относится к способу приготовления модифицированного фосфором цеолита, включающему следующие шаги в указанной последовательности: а) взять цеолит, в структуру которого входит хотя бы одно десятичленное кольцо, по усмотрению выполнить ионообмен; b) обработать указанный цеолит паром, с) ввести в катализатор по меньшей мере 0,1 мас.% фосфора, применяя сухую импрегнацию или парофазное химическое осаждение, d) смешать цеолит, указанный на шаге с), как минимум, с одним из связующих компонентов и структуронаправляющих агентов; е) сформовать полученную смесь; f) ввести металл, по усмотрению, одновременно с шагом d), g) по усмотрению промыть катализатор; h) по усмотрению кальцинировать (прокалить)катализатор; i) обработать катализатор паром - шаг, называемый также приведением в равновесное состояние. Во втором варианте реализации фосфор может быть введён любым способом, и на шаге i) интенсивность парообработки (X) по меньшей мере около 2. Во втором варианте реализации катализатор предпочтительно подвергают обработке паром при температуре выше 625°С, преимущественно в диапазоне от 700 до 800°С. Металл на шаге f) предпочтительно кальций. Настоящее изобретение также относится к применению указанного катализатора для дегидратации спиртов, крекинга олефинов с выделением более лёгких олефинов, в конверсии МТО и алкилировании ароматических углеводородов спиртами с олефинами и/или спиртами.
EA201490358A 2011-08-03 2012-07-25 Способ получения катализатора на основе модифицированного фосфором цеолита и применение такого катализатора EA026722B1 (ru)

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EA201490358A EA026722B1 (ru) 2011-08-03 2012-07-25 Способ получения катализатора на основе модифицированного фосфором цеолита и применение такого катализатора

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Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112014002583B1 (pt) * 2011-08-03 2020-11-10 Total Research & Technology Feluy catalisador compreendendo uma zeólita modificada por fósforo, com uma estrutura parcialmente alpo
EP2739390B1 (en) * 2011-08-03 2021-03-10 Total Research & Technology Feluy Method of converting at least an alcohol into light olefins
ES2865105T3 (es) * 2011-08-03 2021-10-15 Total Res & Technology Feluy Procedimiento de preparación de un catalizador que comprende una zeolita modificada con fósforo y uso de dicha zeolita
US10005702B2 (en) 2012-06-29 2018-06-26 Basf Se Catalyst coating and process for the conversion of oxygenates to olefins
JP6433892B2 (ja) * 2012-06-29 2018-12-05 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 酸素含有物質をオレフィンに転化するための触媒及び方法
US9597669B2 (en) 2012-06-29 2017-03-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
US20140005455A1 (en) 2012-06-29 2014-01-02 Basf Se Process for the conversion of oxygenates to olefins
US20150174559A1 (en) * 2013-12-19 2015-06-25 Basf Corporation Phosphorus-Modified FCC Catalysts
US9796932B2 (en) 2013-12-19 2017-10-24 Basf Corporation FCC catalyst compositions containing boron oxide and phosphorus
US9895680B2 (en) 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
CN105814010B (zh) * 2013-12-20 2020-04-03 埃克森美孚研究工程公司 用于将含氧化合物转化成芳香族化合物的催化剂
US9790139B2 (en) 2013-12-20 2017-10-17 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
CN105828943B (zh) * 2013-12-20 2019-03-08 科莱恩产品（德国）有限公司 用于使含氧化合物转化成烯烃的含磷催化剂
WO2016107759A1 (en) 2014-12-31 2016-07-07 Total Research & Technology Feluy Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of sulfur containing compounds
WO2016107758A1 (en) 2014-12-31 2016-07-07 Total Research & Technology Feluy Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of organic acids
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
CN108187736B (zh) * 2018-01-20 2020-03-24 辽宁金易化工有限公司 具有核壳结构的三水铝石@sapo分子筛复合物及制备方法和在催化甲醇制烯烃中的应用
CN109364935B (zh) * 2018-12-10 2021-10-15 江苏奥利思特环保科技有限公司 一种低温脱硝催化剂及制备方法
EP4037829A1 (en) * 2019-09-30 2022-08-10 Dow Global Technologies LLC Methods of etherification
US20230038518A1 (en) * 2019-12-27 2023-02-09 Ptt Global Chemical Public Company Limited A catalyst for producing light olefins from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms and a process for producing light olefins by using a catalyst thereof
CN111841619B (zh) * 2020-08-07 2023-05-19 山东京博石油化工有限公司 一种改性zsm-5分子筛催化剂、其制备方法及应用
CN114073978B (zh) * 2020-08-10 2023-06-30 中国科学院大连化学物理研究所 一种金属改性zsm-5分子筛及其制备方法和应用
CN114073976B (zh) * 2020-08-10 2023-04-07 中国科学院大连化学物理研究所 一种改性zsm-5分子筛及其制备方法和应用
EP4275789A1 (en) * 2021-01-11 2023-11-15 China Petroleum & Chemical Corporation Catalytic cracking agent containing phosphorus modified molecular sieve, and preparation method therefor, preparation system thereof and use thereof
CN115340105B (zh) * 2021-05-14 2024-02-02 沈阳师范大学 具有硅磷骨架的分子筛材料及其制备方法
US11840505B1 (en) * 2022-09-07 2023-12-12 Saudi Arabian Oil Company Process and cracking catalyst for cracking butenes to produce light olefins

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3274124A (en) 1964-01-02 1966-09-20 Universal Oil Prod Co Process of preparing a silica-alumina supported group viii metal hydrocracking catalyst
US3909450A (en) 1973-12-26 1975-09-30 Universal Oil Prod Co Method of catalyst manufacture
US3972832A (en) 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4356338A (en) * 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4318801A (en) * 1979-09-04 1982-03-09 Gulf Research & Development Company Supported nickel-molybdenum catalyst, preparation thereof, and hydrodesulfurization of hydrocarbon fractions using same
US4988659A (en) 1988-11-23 1991-01-29 Chevron Research Company Silica/alumina cogel catalysts
US5231064A (en) 1991-03-12 1993-07-27 Mobil Oil Corp. Cracking catalysts comprising phosphorus and method of preparing and using the same
US5171921A (en) 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
EP0568913A3 (en) 1992-05-03 1995-03-22 Dalian Chemical Physics Inst Process for the conversion of methanol into light olefins and catalyst used therefor.
EP0921180A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921178A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of crystalline silicate catalyst having monoclinic structure
EP0921177A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921179A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921175A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921181A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of propylene
EP0921176A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0920911A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of catalysts for olefin conversion
EP1061117A1 (en) 1999-06-16 2000-12-20 Fina Research S.A. Production of olefins
EP1061116A1 (en) 1999-06-16 2000-12-20 Fina Research S.A. Production of olefins
EP1061118A1 (en) 1999-06-17 2000-12-20 Fina Research S.A. Production of olefins
EP1195424A1 (en) 2000-10-05 2002-04-10 ATOFINA Research A process for cracking an olefin-rich hydrocarbon feedstock
US6797851B2 (en) * 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US7408092B2 (en) 2004-11-12 2008-08-05 Uop Llc Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst
US7982080B2 (en) * 2007-07-24 2011-07-19 Teng Xu Production of aromatics from aliphatics
BRPI0815417A8 (pt) 2007-08-13 2018-10-30 Agency Science Tech & Res composição de catalisador modificada para conversão de álcool em alceno
EP2075303A1 (en) * 2007-12-18 2009-07-01 PRAD Research and Development N.V. Spacer fluid additive
EP2082802A1 (en) * 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining a catalyst composite
CN101939275A (zh) 2008-02-07 2011-01-05 道达尔石油化学产品研究弗吕公司 醇在惰性组分存在下的脱水
EP2238092A1 (en) 2008-02-07 2010-10-13 Total Petrochemicals Research Feluy Process to make olefins from ethanol
EP2238096A1 (en) 2008-02-07 2010-10-13 Total Petrochemicals Research Feluy Process to make olefins from ethanol
MX2010008723A (es) * 2008-02-07 2010-11-30 Total Petrochemicals Res Feluy Deshidratacion de alcoholes en silicatos cristalinos.
EP2303807B1 (en) * 2008-06-25 2019-08-07 Total Research & Technology Feluy Process to make olefins from oxygenates
EP2151423A1 (en) * 2008-07-29 2010-02-10 Total Petrochemicals Research Feluy Process to make olefins from organics with reduced side reactions.
EP2348004A1 (en) * 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process
EP2739390B1 (en) * 2011-08-03 2021-03-10 Total Research & Technology Feluy Method of converting at least an alcohol into light olefins
BR112014002583B1 (pt) * 2011-08-03 2020-11-10 Total Research & Technology Feluy catalisador compreendendo uma zeólita modificada por fósforo, com uma estrutura parcialmente alpo
ES2865105T3 (es) * 2011-08-03 2021-10-15 Total Res & Technology Feluy Procedimiento de preparación de un catalizador que comprende una zeolita modificada con fósforo y uso de dicha zeolita

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