AR087459A1 - Procedimiento para producir un catalizador que comprende una zeolita modificada con fosforo y el uso de dicha zeolita - Google Patents

Procedimiento para producir un catalizador que comprende una zeolita modificada con fosforo y el uso de dicha zeolita

Info

Publication number
AR087459A1
AR087459A1 ARP120102854A ARP120102854A AR087459A1 AR 087459 A1 AR087459 A1 AR 087459A1 AR P120102854 A ARP120102854 A AR P120102854A AR P120102854 A ARP120102854 A AR P120102854A AR 087459 A1 AR087459 A1 AR 087459A1
Authority
AR
Argentina
Prior art keywords
catalyst
zeolite
optionally
phosphorus
vaporization
Prior art date
Application number
ARP120102854A
Other languages
English (en)
Inventor
Nikolai Nesterenko
Delphine Minoux
Cindy Adam
Jean-Pierre Dath
Original Assignee
Total Res & Technology Feluy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Res & Technology Feluy filed Critical Total Res & Technology Feluy
Publication of AR087459A1 publication Critical patent/AR087459A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/655—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7088—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7096—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7026—MFS-type, e.g. ZSM-57
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente se refiere, en una primera realización, a un procedimiento para producir una zeolita modificada con fósforo que comprende los siguientes pasos en este orden, a) proveer una zeolita que comprende al menos un anillo de diez miembros en la estructura, realizando opcionalmente una vaporización de dicha zeolita, b) mezclar dicha zeolita del paso a) con al menos un componente seleccionado entre uno o más ligantes y aditivos de conformación, después conformar dicha mezcla, c) opcionalmente realizar un intercambio iónico, d) opcionalmente vaporizar el catalizar conformado, opcionalmente antes del paso c), siendo obligatoria al menos una entre dicha vaporización del paso d) y la vaporización del paso a), e) introducir fósforo en el catalizador para introducir al menos el 0,1% en peso de fósforo, realizándose dicha introducción mediante impregnación seca o deposición de vapor químico, f) introducir un metal, opcionalmente en forma simultánea con el paso e), g) opcionalmente lavar el catalizador, h) opcionalmente calcinar el catalizador, i) vaporizar el catalizador, lo que también se denomina el paso de equilibrado. En una segunda realización puede introducirse el fósforo por medios cualesquiera y en el paso i) la intensidad de vaporización (X) es al menos aproximadamente 2. En dicha segunda realización el catalizador ventajosamente es vaporizado a una temperatura superior a 625ºC, preferentemente en el intervalo de 700 a 800ºC. El metal del paso f) ventajosamente es calcio. La presente también se refiere al uso de dicho catalizador en la deshidratación de alcohol, el craqueo de olefina para producir olefinas más livianas, el MTO y la alquilación de compuestos aromáticos mediante alcoholes con olefinas y/o alcoholes.
ARP120102854A 2011-08-03 2012-08-03 Procedimiento para producir un catalizador que comprende una zeolita modificada con fosforo y el uso de dicha zeolita AR087459A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP11176391 2011-08-03

Publications (1)

Publication Number Publication Date
AR087459A1 true AR087459A1 (es) 2014-03-26

Family

ID=44648331

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP120102854A AR087459A1 (es) 2011-08-03 2012-08-03 Procedimiento para producir un catalizador que comprende una zeolita modificada con fosforo y el uso de dicha zeolita
ARP120102855A AR087460A1 (es) 2011-08-03 2012-08-03 Procedimiento para producir un catalizador que comprende una zeolita modificada con fosforo y el uso de dicha zeolita

Family Applications After (1)

Application Number Title Priority Date Filing Date
ARP120102855A AR087460A1 (es) 2011-08-03 2012-08-03 Procedimiento para producir un catalizador que comprende una zeolita modificada con fosforo y el uso de dicha zeolita

Country Status (13)

Country Link
US (2) US10300467B2 (es)
EP (2) EP2739393B1 (es)
KR (2) KR101980512B1 (es)
CN (2) CN103842078B (es)
AR (2) AR087459A1 (es)
BR (2) BR112014002327B1 (es)
CA (2) CA2842388C (es)
CO (3) CO7020925A2 (es)
EA (2) EA026722B1 (es)
ES (2) ES2865106T3 (es)
TW (2) TWI561300B (es)
UA (2) UA113632C2 (es)
WO (2) WO2013017499A1 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UA113632C2 (xx) * 2011-08-03 2017-02-27 Спосіб приготування каталізатора на основі модифікованого фосфором цеоліту і застосування такого каталізатора
WO2013017496A1 (en) * 2011-08-03 2013-02-07 Total Research & Technology Feluy Use of a catalyst comprising a phosphorus modified zeolite in an alcohol dehydration process
BR112014002583B1 (pt) * 2011-08-03 2020-11-10 Total Research & Technology Feluy catalisador compreendendo uma zeólita modificada por fósforo, com uma estrutura parcialmente alpo
CA2877560C (en) * 2012-06-29 2020-07-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
US20140005455A1 (en) 2012-06-29 2014-01-02 Basf Se Process for the conversion of oxygenates to olefins
US10005702B2 (en) 2012-06-29 2018-06-26 Basf Se Catalyst coating and process for the conversion of oxygenates to olefins
US9597669B2 (en) 2012-06-29 2017-03-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
US9796932B2 (en) 2013-12-19 2017-10-24 Basf Corporation FCC catalyst compositions containing boron oxide and phosphorus
US9895680B2 (en) 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
US20150174559A1 (en) * 2013-12-19 2015-06-25 Basf Corporation Phosphorus-Modified FCC Catalysts
WO2015094697A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Conversion of methanol to olefins and para-xylene
JP6545172B2 (ja) * 2013-12-20 2019-07-17 クラリアント・プロドゥクテ・（ドイチュラント）・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 含酸素化合物をオレフィンに転換するためのリン含有触媒
CA2925992C (en) 2013-12-20 2020-08-11 Exxonmobil Research And Engineering Company Catalyst for selective conversion of oxygenates to aromatics
WO2016107759A1 (en) 2014-12-31 2016-07-07 Total Research & Technology Feluy Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of sulfur containing compounds
BR112017014221A2 (pt) 2014-12-31 2018-03-06 Ifp Energies Now processo para a preparação olefinas pela desidratação de álcoois com menores efeitos colaterais compreendendo a adição de ácidos orgânicos
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
CN108187736B (zh) * 2018-01-20 2020-03-24 辽宁金易化工有限公司 具有核壳结构的三水铝石@sapo分子筛复合物及制备方法和在催化甲醇制烯烃中的应用
CN109364935B (zh) * 2018-12-10 2021-10-15 江苏奥利思特环保科技有限公司 一种低温脱硝催化剂及制备方法
CN114364652A (zh) * 2019-09-30 2022-04-15 陶氏环球技术有限责任公司 醚化方法
WO2021130686A1 (en) * 2019-12-27 2021-07-01 Ptt Global Chemical Public Company Limited A catalyst for producing light olefins from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms
CN111841619B (zh) * 2020-08-07 2023-05-19 山东京博石油化工有限公司 一种改性zsm-5分子筛催化剂、其制备方法及应用
CN114073978B (zh) * 2020-08-10 2023-06-30 中国科学院大连化学物理研究所 一种金属改性zsm-5分子筛及其制备方法和应用
CN114073976B (zh) * 2020-08-10 2023-04-07 中国科学院大连化学物理研究所 一种改性zsm-5分子筛及其制备方法和应用
US20240059630A1 (en) * 2021-01-11 2024-02-22 China Petroleum & Chemical Corporation Catalytic cracking agent containing phosphorus-modified molecular sieve, preparation process thereof, preparation system and use thereof
CN115340105B (zh) * 2021-05-14 2024-02-02 沈阳师范大学 具有硅磷骨架的分子筛材料及其制备方法
US11840505B1 (en) * 2022-09-07 2023-12-12 Saudi Arabian Oil Company Process and cracking catalyst for cracking butenes to produce light olefins

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3274124A (en) 1964-01-02 1966-09-20 Universal Oil Prod Co Process of preparing a silica-alumina supported group viii metal hydrocracking catalyst
US3909450A (en) 1973-12-26 1975-09-30 Universal Oil Prod Co Method of catalyst manufacture
US3972832A (en) 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4356338A (en) 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4318801A (en) * 1979-09-04 1982-03-09 Gulf Research & Development Company Supported nickel-molybdenum catalyst, preparation thereof, and hydrodesulfurization of hydrocarbon fractions using same
US4988659A (en) 1988-11-23 1991-01-29 Chevron Research Company Silica/alumina cogel catalysts
US5231064A (en) 1991-03-12 1993-07-27 Mobil Oil Corp. Cracking catalysts comprising phosphorus and method of preparing and using the same
US5171921A (en) * 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
EP0568913A3 (en) 1992-05-03 1995-03-22 Dalian Chemical Physics Inst Process for the conversion of methanol into light olefins and catalyst used therefor.
EP0921177A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921175A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921176A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921178A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of crystalline silicate catalyst having monoclinic structure
EP0920911A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of catalysts for olefin conversion
EP0921179A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP0921181A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of propylene
EP0921180A1 (en) 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
EP1061117A1 (en) 1999-06-16 2000-12-20 Fina Research S.A. Production of olefins
EP1061116A1 (en) 1999-06-16 2000-12-20 Fina Research S.A. Production of olefins
EP1061118A1 (en) 1999-06-17 2000-12-20 Fina Research S.A. Production of olefins
EP1195424A1 (en) 2000-10-05 2002-04-10 ATOFINA Research A process for cracking an olefin-rich hydrocarbon feedstock
US6797851B2 (en) * 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US7408092B2 (en) 2004-11-12 2008-08-05 Uop Llc Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst
RU2461537C2 (ru) * 2007-07-24 2012-09-20 Эксонмобил Кемикэл Пейтентс Инк. Получение ароматических соединений из алифатических
WO2009022990A1 (en) 2007-08-13 2009-02-19 Agency For Science, Technology And Research Modified catalyst composition for conversion of alcohol to alkene
EP2075303A1 (en) * 2007-12-18 2009-07-01 PRAD Research and Development N.V. Spacer fluid additive
EP2082802A1 (en) * 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining a catalyst composite
CN104761427A (zh) 2008-02-07 2015-07-08 道达尔研究技术弗吕公司 醇在结晶硅酸盐上的脱水
EP2238096A1 (en) 2008-02-07 2010-10-13 Total Petrochemicals Research Feluy Process to make olefins from ethanol
EA019181B1 (ru) 2008-02-07 2014-01-30 Тотал Петрокемикалс Рисерч Фелюй Дегидратация спиртов в присутствии инертного компонента
CN103274884A (zh) 2008-02-07 2013-09-04 道达尔石油化学产品研究弗吕公司 由乙醇制造烯烃的方法
CN102076637B (zh) * 2008-06-25 2014-04-09 道达尔石油化学产品研究弗吕公司 由有机物制造烯烃的方法
EP2151423A1 (en) * 2008-07-29 2010-02-10 Total Petrochemicals Research Feluy Process to make olefins from organics with reduced side reactions.
EP2348004A1 (en) * 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process
BR112014002583B1 (pt) * 2011-08-03 2020-11-10 Total Research & Technology Feluy catalisador compreendendo uma zeólita modificada por fósforo, com uma estrutura parcialmente alpo
WO2013017496A1 (en) * 2011-08-03 2013-02-07 Total Research & Technology Feluy Use of a catalyst comprising a phosphorus modified zeolite in an alcohol dehydration process
UA113632C2 (xx) * 2011-08-03 2017-02-27 Спосіб приготування каталізатора на основі модифікованого фосфором цеоліту і застосування такого каталізатора

Also Published As

Publication number Publication date
UA113632C2 (xx) 2017-02-27
KR20140050023A (ko) 2014-04-28
TWI561300B (en) 2016-12-11
US20140243568A1 (en) 2014-08-28
CN103842078A (zh) 2014-06-04
TW201313315A (zh) 2013-04-01
ES2865105T3 (es) 2021-10-15
EP2739392A1 (en) 2014-06-11
BR112014002530B1 (pt) 2024-01-09
EP2739392B1 (en) 2021-02-17
CN103874544B (zh) 2017-02-15
CO7020925A2 (es) 2014-08-11
CA2842388C (en) 2020-10-06
KR101948357B1 (ko) 2019-02-14
KR101980512B1 (ko) 2019-05-21
US20140194662A1 (en) 2014-07-10
CN103874544A (zh) 2014-06-18
CO6960530A2 (es) 2014-05-30
EA201490358A1 (ru) 2014-06-30
TWI565521B (zh) 2017-01-11
AR087460A1 (es) 2014-03-26
WO2013017499A1 (en) 2013-02-07
EA028645B1 (ru) 2017-12-29
KR20140050024A (ko) 2014-04-28
EP2739393B1 (en) 2021-02-17
WO2013017497A1 (en) 2013-02-07
CN103842078B (zh) 2017-09-26
UA113633C2 (xx) 2017-02-27
BR112014002327B1 (pt) 2020-12-08
US10464053B2 (en) 2019-11-05
EP2739393A1 (en) 2014-06-11
US10300467B2 (en) 2019-05-28
CO6890114A2 (es) 2014-03-10
CA2842388A1 (en) 2013-02-07
CA2843793A1 (en) 2013-02-07
BR112014002327A2 (pt) 2017-10-17
TW201318703A (zh) 2013-05-16
ES2865106T3 (es) 2021-10-15
BR112014002530A2 (pt) 2017-03-14
EA026722B1 (ru) 2017-05-31
EA201490386A1 (ru) 2014-08-29

Similar Documents

Publication Publication Date Title
AR087459A1 (es) Procedimiento para producir un catalizador que comprende una zeolita modificada con fosforo y el uso de dicha zeolita
AR087461A1 (es) Uso de un catalizador que comprende una zeolita modificada con fosforo en un proceso de deshidratacion de alcohol
Ibarra et al. Dual coke deactivation pathways during the catalytic cracking of raw bio-oil and vacuum gasoil in FCC conditions
BR112019003287A2 (pt) processo para sintetizar uma cetona interna k1, uso da cetona interna k1, e, método para preparar um composto a partir de uma cetona interna k1
Asadieraghi et al. In-situ catalytic upgrading of biomass pyrolysis vapor: Using a cascade system of various catalysts in a multi-zone fixed bed reactor
Wei et al. Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanol
AR087947A1 (es) Catalizador que comprende una zeolita modificada con fosforo que en parte tiene una estructura alpo
Olsbye et al. Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity
BR112012018501A8 (pt) Método para fazer um catalisador compreendendo uma zeólica modificada por fósforo para ser usada em um processo de desidratação de álcoois
Asadieraghi et al. In-situ catalytic upgrading of biomass pyrolysis vapor: Co-feeding with methanol in a multi-zone fixed bed reactor
AR092565A1 (es) Metodos para producir para-xileno y acido tereftalico
Keller et al. Design of base zeolite catalysts by alkali-metal grafting in alcoholic media
ES2559188T3 (es) Procedimiento para la obtención de a-olefinas lineales
BR112015031174A2 (pt) processo para a preparação de butadieno
BR112018000702A2 (pt) ?processo para preparação de um composto e, uso de um material zeolítico contendo boro?
AR095886A1 (es) Método para la preparación de un silicato de metal del grupo 4 y su uso
Zhu et al. Probing the Influence of SSZ‐13 Zeolite Pore Hierarchy in Methanol‐to‐Olefins Catalysis by Using Nanometer Accuracy by Stochastic Chemical Reactions Fluorescence Microscopy and Positron Emission Profiling
EA201590636A1 (ru) Способ получения каталитической композиции для гидрирования и каталитическая композиция для гидрирования
ES2557178R1 (es) Componente de catalizador para la polimerización de olefinas, catalizador y uso del mismo
Zhang et al. Development of magnesium oxide–zeolite catalysts for isomerization of fatty acids
AR102017A1 (es) Método para purificar una mezcla que comprende hidrocarburos líquidos, en especial btx y agua
AR073807A1 (es) Proceso para preparar el malato de sunitinib, sal de un acido mas debil que el malato como compuesto intermediario, y proceso para preparar dicha sal intermediaria.
Tian et al. Ionic liquid assisted synthesis of zeolite‐TON
BR112013002549A2 (pt) processo de produção de oleofinas a partir do isobutanol
He et al. Adsorption of benzene and propene in zeolite MCM-22: a grand canonical Monte Carlo study

Legal Events

Date Code Title Description
FG Grant, registration