AR092565A1 - Metodos para producir para-xileno y acido tereftalico - Google Patents
Metodos para producir para-xileno y acido tereftalicoInfo
- Publication number
- AR092565A1 AR092565A1 ARP130103291A ARP130103291A AR092565A1 AR 092565 A1 AR092565 A1 AR 092565A1 AR P130103291 A ARP130103291 A AR P130103291A AR P130103291 A ARP130103291 A AR P130103291A AR 092565 A1 AR092565 A1 AR 092565A1
- Authority
- AR
- Argentina
- Prior art keywords
- xylene
- para
- ethylene
- catalyst
- hexanedione
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
- C07C15/08—Xylenes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/42—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion
- C07C2/44—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion of conjugated dienes only
- C07C2/46—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/867—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
- C07C49/12—Ketones containing more than one keto group
- C07C49/14—Acetylacetone, i.e. 2,4-pentanedione
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/14—Monocyclic dicarboxylic acids
- C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
- C07C63/26—1,4 - Benzenedicarboxylic acid
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
- C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/10—Chlorides
- C07C2527/11—Hydrogen chloride
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/122—Compounds comprising a halogen and copper
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
- C07C2527/126—Aluminium chloride
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/16—Phosphorus; Compounds thereof containing oxygen
- C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
- C07C2527/173—Phosphoric acid or other acids with the formula Hn+2PnO3n+1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2527/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- C07C2527/19—Molybdenum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/025—Sulfonic acids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente descripción proporciona métodos para producir para-xileno, tolueno y otros compuestos a partir de fuentes renovables (por ejemplo, celulosa, hemicelulosa, almidón, azúcar) y de etileno en presencia de un catalizador. Por ejemplo, la celulosa y/o la hemicelulosa se pueden convertir en 2,5-dimetilfurano (DMF), lo que puede ser convertido en para-xileno por cicloadición de etileno a DMF. A continuación, el para-xileno puede oxidarse para formar ácido tereftálico. Reivindicación 1: Un método para producir para-xileno, que comprende: a) proporcionar 2,5-hexanodiona; b) proporcionar etileno; c) proporcionar un catalizador; d) combinar la 2,5-hexanodiona, el etileno y el catalizador para formar una mezcla de reacción; y e) producir para-xileno a partir de -al menos- una parte de la 2,5-hexanodiona en la mezcla de reacción. Reivindicación 4: El método de la reivindicación 3, donde el sistema de disolvente comprende un disolvente alifático C₁₋₂₀, un disolvente aromático C₆₋₂₀, un disolvente alquil fenilo, un éter C₂₋₂₀, un éster C₂₋₂₀, un alcohol C₁₋₂₀, una cetona C₂₋₂₀ o cualesquiera combinaciones o mezclas de éstos. Reivindicación 7: El método de la reivindicación 1, donde el catalizador comprende un catión metálico que se selecciona del grupo que consiste de Zn²⁺, Cu²⁺, Ni²⁺, Co²⁺, Al³⁺, In³⁺, Fe³⁺, La³⁺, Gd³⁺ e Y³⁺.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261701276P | 2012-09-14 | 2012-09-14 | |
US13/838,761 US8889938B2 (en) | 2012-03-15 | 2013-03-15 | Methods of producing para-xylene |
Publications (1)
Publication Number | Publication Date |
---|---|
AR092565A1 true AR092565A1 (es) | 2015-04-22 |
Family
ID=50278710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP130103291A AR092565A1 (es) | 2012-09-14 | 2013-09-13 | Metodos para producir para-xileno y acido tereftalico |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP2895446A1 (es) |
JP (1) | JP6503294B2 (es) |
KR (1) | KR20150055014A (es) |
CN (1) | CN104918901A (es) |
AR (1) | AR092565A1 (es) |
BR (1) | BR112015005701A2 (es) |
HK (1) | HK1212674A1 (es) |
IN (1) | IN2015DN02933A (es) |
MX (1) | MX2015003313A (es) |
TW (1) | TW201425272A (es) |
WO (1) | WO2014043468A1 (es) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6047162B2 (ja) | 2011-09-16 | 2016-12-21 | マイクロマイダス,インコーポレイテッド | パラ−キシレンおよびテレフタル酸の生産方法 |
US8889938B2 (en) | 2012-03-15 | 2014-11-18 | Micromidas, Inc. | Methods of producing para-xylene |
US10392317B2 (en) | 2012-09-14 | 2019-08-27 | Micromidas, Inc. | Methods of producing para-xylene and terephthalic acid |
MY196287A (en) | 2013-03-14 | 2023-03-24 | Micromidas Inc | Methods For Purifying 5-(Halomethyl)Furfural |
US20140296600A1 (en) * | 2013-04-01 | 2014-10-02 | University Of Delaware | Production of para-xylene by catalytically reacting 2,5-dimethylfuran and ethylene in a solvent |
CN111662254A (zh) | 2013-09-20 | 2020-09-15 | 微麦德斯公司 | 生产5-(卤甲基)糠醛的方法 |
WO2015175528A1 (en) * | 2014-05-12 | 2015-11-19 | Micromidas, Inc. | Methods of producing compounds from 5-(halomethyl)furfural |
CN106565396B (zh) * | 2015-10-12 | 2019-04-12 | 中国石油化工股份有限公司 | 环加成生产芳烃的方法 |
KR102394356B1 (ko) * | 2015-10-23 | 2022-05-04 | 에스케이케미칼 주식회사 | 디메틸테레프탈레이트의 제조 방법 |
EP3387038A1 (en) | 2015-12-11 | 2018-10-17 | Societe Anonyme des Eaux Minerales d'Evian Et en Abrege "S.A.E.M.E" | Pet polymer with an anti-crystallization comonomer that can be bio-sourced |
WO2017146581A1 (en) | 2016-02-26 | 2017-08-31 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | Aromatic compounds from furanics |
EP3210979A1 (en) | 2016-02-26 | 2017-08-30 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Aromatic compounds from furanics |
KR101949431B1 (ko) * | 2016-11-04 | 2019-02-19 | 한국과학기술연구원 | 실리카에 담지된 헤테로폴리산 촉매 및 이를 이용한 파라자일렌의 제조방법 |
CN108117489B (zh) * | 2016-11-29 | 2020-10-16 | 中国科学院大连化学物理研究所 | 一种由巴豆醛和甲醛制备酯的方法 |
CN108117478B (zh) * | 2016-11-29 | 2021-02-05 | 中国科学院大连化学物理研究所 | 1,4-环己烷二甲醇或1,4-环己烷二甲酸的制备方法 |
TWI630192B (zh) * | 2017-07-28 | 2018-07-21 | 遠東新世紀股份有限公司 | Method for preparing alkylbenzene |
KR102394369B1 (ko) * | 2017-11-27 | 2022-05-04 | 에스케이케미칼 주식회사 | 디메틸테레프탈레이트의 제조방법 |
KR102024755B1 (ko) * | 2018-01-22 | 2019-11-04 | 한국과학기술연구원 | 실리카에 담지된 헤테로폴리산 촉매 및 이를 이용한 디알킬 테레프탈레이트의 제조방법 |
CN111217659B (zh) * | 2018-11-27 | 2021-04-16 | 中国科学院大连化学物理研究所 | 一种由异戊二烯和甲基对苯醌制备2,6-二甲基萘的方法 |
CN111004078B (zh) * | 2019-12-24 | 2021-03-26 | 北京化工大学 | 一种生物基对二甲苯的制备方法 |
CN115385771B (zh) * | 2021-05-21 | 2024-05-28 | 中国石油化工股份有限公司 | 一种对二甲苯的制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003055280A (ja) * | 2001-08-17 | 2003-02-26 | Nippon Petrochemicals Co Ltd | 縮合環含有化合物の製法 |
JPWO2009110402A1 (ja) * | 2008-03-03 | 2011-07-14 | 東レ株式会社 | パラキシレンの製造方法 |
US8314267B2 (en) * | 2009-06-26 | 2012-11-20 | Uop Llc | Carbohydrate route to para-xylene and terephthalic acid |
JP5299972B2 (ja) * | 2009-12-04 | 2013-09-25 | 独立行政法人産業技術総合研究所 | フラン類の製造方法 |
JP6047162B2 (ja) * | 2011-09-16 | 2016-12-21 | マイクロマイダス,インコーポレイテッド | パラ−キシレンおよびテレフタル酸の生産方法 |
-
2013
- 2013-09-13 IN IN2933DEN2015 patent/IN2015DN02933A/en unknown
- 2013-09-13 MX MX2015003313A patent/MX2015003313A/es unknown
- 2013-09-13 JP JP2015532075A patent/JP6503294B2/ja active Active
- 2013-09-13 KR KR1020157009382A patent/KR20150055014A/ko not_active Application Discontinuation
- 2013-09-13 CN CN201380059080.1A patent/CN104918901A/zh active Pending
- 2013-09-13 TW TW102133178A patent/TW201425272A/zh unknown
- 2013-09-13 EP EP13766444.7A patent/EP2895446A1/en not_active Withdrawn
- 2013-09-13 WO PCT/US2013/059660 patent/WO2014043468A1/en active Application Filing
- 2013-09-13 BR BR112015005701A patent/BR112015005701A2/pt not_active IP Right Cessation
- 2013-09-13 AR ARP130103291A patent/AR092565A1/es unknown
-
2016
- 2016-01-21 HK HK16100689.8A patent/HK1212674A1/zh unknown
Also Published As
Publication number | Publication date |
---|---|
IN2015DN02933A (es) | 2015-09-18 |
HK1212674A1 (zh) | 2016-06-17 |
TW201425272A (zh) | 2014-07-01 |
BR112015005701A2 (pt) | 2017-07-04 |
MX2015003313A (es) | 2015-07-14 |
EP2895446A1 (en) | 2015-07-22 |
KR20150055014A (ko) | 2015-05-20 |
CN104918901A (zh) | 2015-09-16 |
JP2015531786A (ja) | 2015-11-05 |
WO2014043468A1 (en) | 2014-03-20 |
JP6503294B2 (ja) | 2019-04-17 |
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