BR112015031174A2 - processo para a preparação de butadieno - Google Patents

processo para a preparação de butadieno

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Publication number
BR112015031174A2
BR112015031174A2 BR112015031174A BR112015031174A BR112015031174A2 BR 112015031174 A2 BR112015031174 A2 BR 112015031174A2 BR 112015031174 A BR112015031174 A BR 112015031174A BR 112015031174 A BR112015031174 A BR 112015031174A BR 112015031174 A2 BR112015031174 A2 BR 112015031174A2
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BR
Brazil
Prior art keywords
lattice structure
butadiene
elements
gas stream
zeolitic material
Prior art date
Application number
BR112015031174A
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English (en)
Other versions
BR112015031174B8 (pt
BR112015031174B1 (pt
Inventor
Parvulescu Andrei-Nicolae
Lange De Oliveira Armin
Schwab Ekkehard
Spanhoff Kirsten
Feyen Mathias
Marx Stefan
Müller Ulrich
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of BR112015031174A2 publication Critical patent/BR112015031174A2/pt
Publication of BR112015031174B1 publication Critical patent/BR112015031174B1/pt
Publication of BR112015031174B8 publication Critical patent/BR112015031174B8/pt

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/2076—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)- moiety is eliminated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/86—Borosilicates; Aluminoborosilicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

a presente invenção diz respeito a um processo de fase gasosa para a preparação de butadieno compreendendo (i) prover uma corrente de gás g-1 compreendendo etanol; (ii) colocar a corrente de gás g-1 compreendendo etanol em contato com um catalisador, obtendo, por meio disso, uma corrente de gás g-2 compreendendo butadieno, em que o catalisador compreende um material zeolítico com uma estrutura em treliça compreendendo yo2, y valendo para um ou mais elementos tetravalentes, em que pelo menos uma porção de y compreendida na estrutura em treliça é substituída de maneira isomorfa por um ou mais elementos x, assim como diz respeito a um material zeolítico com uma estrutura em treliça yo2, y estando para um ou mais elementos tetravalentes, em que pelo menos uma porção de y compreendida na estrutura em treliça é substituída de maneira isomorfa por um ou mais elementos x, em que o material zeolítico apresenta um padrão de difração de pó de raio x específico. diz respeito, ainda, ao uso desse material.
BR112015031174A 2013-06-13 2014-06-13 processo em fase gasosa para a preparação de butadieno BR112015031174B8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13171800 2013-06-13
EP13171800.9 2013-06-13
PCT/EP2014/062391 WO2014198901A1 (en) 2013-06-13 2014-06-13 Process for the preparation of butadiene

Publications (3)

Publication Number Publication Date
BR112015031174A2 true BR112015031174A2 (pt) 2017-07-25
BR112015031174B1 BR112015031174B1 (pt) 2020-12-01
BR112015031174B8 BR112015031174B8 (pt) 2020-12-22

Family

ID=48578939

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015031174A BR112015031174B8 (pt) 2013-06-13 2014-06-13 processo em fase gasosa para a preparação de butadieno

Country Status (7)

Country Link
US (1) US9878965B2 (pt)
EP (1) EP3007823B1 (pt)
JP (1) JP6545157B2 (pt)
CN (1) CN105451881B (pt)
BR (1) BR112015031174B8 (pt)
WO (1) WO2014198901A1 (pt)
ZA (1) ZA201509117B (pt)

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* Cited by examiner, † Cited by third party
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WO2016128917A1 (en) 2015-02-12 2016-08-18 Basf Se Process for the preparation of a dealuminated zeolitic material having the bea framework structure
EP3292099B1 (en) 2015-05-04 2020-07-22 Basf Se Process for the preparation of melonal
FR3038851B1 (fr) * 2015-07-13 2019-11-08 IFP Energies Nouvelles Catalyseur a base de tantale depose sur silice pour la transformation de l'ethanol en butadiene
JP6559039B2 (ja) * 2015-10-19 2019-08-14 日本化薬株式会社 共役ジオレフィン製造用触媒と、その製造方法
EP3178788A1 (en) * 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
US10179323B2 (en) * 2016-06-07 2019-01-15 Fina Technology, Inc. Metal oxide catalyst systems for conversion of ethanol to butadiene
CN106824259B (zh) * 2016-12-21 2019-07-12 南开大学 用于乙醇转化制备1,3-丁二烯的含锌钇分子筛催化剂、制备方法及使用方法
RU2656602C1 (ru) * 2017-03-31 2018-06-06 Общество с ограниченной ответственностью "ЭТБ каталитические технологии" (ООО "ЭТБ КаТ") Одностадийный способ получения бутадиена
CN109694084B (zh) * 2017-10-20 2020-12-01 中国石油化工股份有限公司 Doh沸石分子筛的制备方法
CN109746041B (zh) * 2017-11-07 2022-07-12 万华化学集团股份有限公司 一种Ti-MWW分子筛的改性方法以及环十二酮肟的制备方法
CN109833904B (zh) * 2017-11-29 2020-08-11 中国科学院大连化学物理研究所 一种酸碱双功能催化剂、其制备方法及在乙醇转化反应中的应用
CN109894144B (zh) * 2017-12-07 2021-08-17 中国科学院大连化学物理研究所 一种1,3-丁二烯的合成方法及其催化剂的制备方法
US11446635B2 (en) * 2017-12-27 2022-09-20 Sekisui Chemical Co., Ltd. Catalyst and method for producing same, and method for producing diene compound using said catalyst
FR3090631B1 (fr) * 2018-12-21 2020-12-25 Ifp Energies Now Procédé de production de butadiène à partir d’éthanol avec régénération in situ du catalyseur de la deuxième étape réactionnelle
DE102019106698A1 (de) * 2019-03-15 2020-09-17 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Katalytische Herstellung von Butadien
CN117500592A (zh) * 2021-07-29 2024-02-02 通伊欧轮胎株式会社 1,3-丁二烯用合成催化剂及其制备方法、以及1,3-丁二烯的制备方法
CN113663721B (zh) * 2021-09-07 2023-10-17 陕西延长石油（集团）有限责任公司 一种乙醇制备1,3-丁二烯的催化剂的制备方法及其应用
CN113996330B (zh) * 2021-11-12 2022-08-30 中国科学院大连化学物理研究所 一种球磨法制备的Zr基MFI分子筛催化剂及其应用

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Also Published As

Publication number Publication date
JP2016521719A (ja) 2016-07-25
WO2014198901A1 (en) 2014-12-18
JP6545157B2 (ja) 2019-07-17
CN105451881B (zh) 2019-08-16
US9878965B2 (en) 2018-01-30
BR112015031174B8 (pt) 2020-12-22
CN105451881A (zh) 2016-03-30
EP3007823B1 (en) 2022-12-28
US20160145171A1 (en) 2016-05-26
EP3007823A1 (en) 2016-04-20
BR112015031174B1 (pt) 2020-12-01
ZA201509117B (en) 2020-05-27

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