BR112015021872A2 - processo para a carbonilação de éter dimetílico - Google Patents

processo para a carbonilação de éter dimetílico

Info

Publication number
BR112015021872A2
BR112015021872A2 BR112015021872A BR112015021872A BR112015021872A2 BR 112015021872 A2 BR112015021872 A2 BR 112015021872A2 BR 112015021872 A BR112015021872 A BR 112015021872A BR 112015021872 A BR112015021872 A BR 112015021872A BR 112015021872 A2 BR112015021872 A2 BR 112015021872A2
Authority
BR
Brazil
Prior art keywords
carbonylation
dimethyl ether
hydrogen
carbon monoxide
conducted
Prior art date
Application number
BR112015021872A
Other languages
English (en)
Inventor
Costin Gagea Bogdan
Jan Ditzel Evert
Glenn Sunley John
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of BR112015021872A2 publication Critical patent/BR112015021872A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo processo para a carbonilação de éter dimetílico um processo para a preparação de acetato de metila pela carbonilação de éter dimetílico com monóxido de carbono na presença de hidrogénio e um catalisador de zeólito em que, num primeiro passo, a carbonilação é conduzida com um monóxido de carbono a razão molar de hidrogénio de pelo menos 1 e, numa segunda e o passo subsequente, a carbonilação é conduzida com uma proporção molar de hidrogénio para monóxido de carbono maior do que 1.
BR112015021872A 2013-03-08 2014-03-06 processo para a carbonilação de éter dimetílico BR112015021872A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13158471 2013-03-08
PCT/EP2014/054397 WO2014135663A1 (en) 2013-03-08 2014-03-06 Process for the carbonylation of dimethyl ether

Publications (1)

Publication Number Publication Date
BR112015021872A2 true BR112015021872A2 (pt) 2017-07-18

Family

ID=47827089

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015021872A BR112015021872A2 (pt) 2013-03-08 2014-03-06 processo para a carbonilação de éter dimetílico

Country Status (12)

Country Link
US (1) US9499470B2 (pt)
EP (1) EP2964605A1 (pt)
JP (1) JP2016510057A (pt)
KR (1) KR20150128887A (pt)
CN (1) CN105339342B (pt)
BR (1) BR112015021872A2 (pt)
CA (1) CA2903670A1 (pt)
RU (1) RU2656599C2 (pt)
SG (1) SG11201507102VA (pt)
TW (1) TW201441189A (pt)
UA (1) UA115353C2 (pt)
WO (1) WO2014135663A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2903938A1 (en) * 2013-03-08 2014-09-12 Bp Chemicals Limited Carbonylation catalyst and process
US10695756B2 (en) 2015-06-12 2020-06-30 Enerkem, Inc. Metal-loaded zeolite catalysts for the halogen-free conversion of dimethyl ether to methyl acetate
CN106890665B (zh) * 2015-12-18 2020-06-09 中国科学院大连化学物理研究所 一种二甲醚羰基化生产乙酸甲酯的催化剂及其应用
CN106890671B (zh) * 2015-12-18 2019-03-08 中国科学院大连化学物理研究所 一种生产乙酸甲酯的催化剂、其制备方法及应用
RU2739320C2 (ru) 2016-04-19 2020-12-22 Бп Кемикэлз Лимитед Способ карбонилирования для получения метилацетата
CN107376987B (zh) * 2016-05-16 2020-06-26 天津大学 双模板剂法合成丝光沸石分子筛催化剂及其在甲醇/二甲醚羰基化反应中的应用
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission
WO2018004992A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Conversion of methane to dimethyl ether
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
CN113751072B (zh) * 2021-08-31 2022-11-08 厦门大学 一种二甲醚羰基化制备乙酸甲酯的催化剂及其制备方法和应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060252959A1 (en) * 2005-05-05 2006-11-09 The Regents Of The University Of California Process for carbonylation of alkyl ethers
EP1985608A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP1985362A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP1985606A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP2072123A1 (en) * 2007-12-19 2009-06-24 BP Chemicals Limited Regeneration of zeolite carbonylation catalysts
EP2189215A1 (en) * 2008-11-19 2010-05-26 BP Chemicals Limited Carbonylation process catalysed by mordenite supported on inorganic oxides

Also Published As

Publication number Publication date
RU2015142611A (ru) 2017-04-13
US20160016881A1 (en) 2016-01-21
CN105339342B (zh) 2018-06-15
RU2656599C2 (ru) 2018-06-06
EP2964605A1 (en) 2016-01-13
SG11201507102VA (en) 2015-10-29
UA115353C2 (uk) 2017-10-25
KR20150128887A (ko) 2015-11-18
US9499470B2 (en) 2016-11-22
WO2014135663A1 (en) 2014-09-12
CA2903670A1 (en) 2014-09-12
JP2016510057A (ja) 2016-04-04
TW201441189A (zh) 2014-11-01
CN105339342A (zh) 2016-02-17

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]