BR112015031174B8 - processo em fase gasosa para a preparação de butadieno - Google Patents
processo em fase gasosa para a preparação de butadienoInfo
- Publication number
- BR112015031174B8 BR112015031174B8 BR112015031174A BR112015031174A BR112015031174B8 BR 112015031174 B8 BR112015031174 B8 BR 112015031174B8 BR 112015031174 A BR112015031174 A BR 112015031174A BR 112015031174 A BR112015031174 A BR 112015031174A BR 112015031174 B8 BR112015031174 B8 BR 112015031174B8
- Authority
- BR
- Brazil
- Prior art keywords
- butadiene
- preparation
- elements
- phase process
- gas phase
- Prior art date
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000000634 powder X-ray diffraction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
- C01B39/085—Group IVB- metallosilicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
- C07C1/2076—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)- moiety is eliminated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/62—Synthesis on support in or on other molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/86—Borosilicates; Aluminoborosilicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
a presente invenção diz respeito a um processo de fase gasosa para a preparação de butadieno compreendendo (i) prover uma corrente de gás g-1 compreendendo etanol; (ii) colocar a corrente de gás g-1 compreendendo etanol em contato com um catalisador, obtendo, por meio disso, uma corrente de gás g-2 compreendendo butadieno, em que o catalisador compreende um material zeolítico com uma estrutura em treliça compreendendo yo2, y valendo para um ou mais elementos tetravalentes, em que pelo menos uma porção de y compreendida na estrutura em treliça é substituída de maneira isomorfa por um ou mais elementos x, assim como diz respeito a um material zeolítico com uma estrutura em treliça yo2, y estando para um ou mais elementos tetravalentes, em que pelo menos uma porção de y compreendida na estrutura em treliça é substituída de maneira isomorfa por um ou mais elementos x, em que o material zeolítico apresenta um padrão de difração de pó de raio x específico. diz respeito, ainda, ao uso desse material.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13171800.9 | 2013-06-13 | ||
EP13171800 | 2013-06-13 | ||
PCT/EP2014/062391 WO2014198901A1 (en) | 2013-06-13 | 2014-06-13 | Process for the preparation of butadiene |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112015031174A2 BR112015031174A2 (pt) | 2017-07-25 |
BR112015031174B1 BR112015031174B1 (pt) | 2020-12-01 |
BR112015031174B8 true BR112015031174B8 (pt) | 2020-12-22 |
Family
ID=48578939
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015031174A BR112015031174B8 (pt) | 2013-06-13 | 2014-06-13 | processo em fase gasosa para a preparação de butadieno |
Country Status (7)
Country | Link |
---|---|
US (1) | US9878965B2 (pt) |
EP (1) | EP3007823B1 (pt) |
JP (1) | JP6545157B2 (pt) |
CN (1) | CN105451881B (pt) |
BR (1) | BR112015031174B8 (pt) |
WO (1) | WO2014198901A1 (pt) |
ZA (1) | ZA201509117B (pt) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102558113B1 (ko) | 2015-02-12 | 2023-07-24 | 바스프 에스이 | Bea 골격 구조를 갖는 탈알루미늄화된 제올라이트 물질의 제조 방법 |
US10202324B2 (en) | 2015-05-04 | 2019-02-12 | Basf Se | Process for the preparation of melonal |
FR3038851B1 (fr) * | 2015-07-13 | 2019-11-08 | IFP Energies Nouvelles | Catalyseur a base de tantale depose sur silice pour la transformation de l'ethanol en butadiene |
JP6559039B2 (ja) * | 2015-10-19 | 2019-08-14 | 日本化薬株式会社 | 共役ジオレフィン製造用触媒と、その製造方法 |
EP3178788A1 (en) * | 2015-12-08 | 2017-06-14 | Basf Se | A tin-containing zeolitic material having a bea framework structure |
US10179323B2 (en) * | 2016-06-07 | 2019-01-15 | Fina Technology, Inc. | Metal oxide catalyst systems for conversion of ethanol to butadiene |
CN106824259B (zh) * | 2016-12-21 | 2019-07-12 | 南开大学 | 用于乙醇转化制备1,3-丁二烯的含锌钇分子筛催化剂、制备方法及使用方法 |
RU2656602C1 (ru) * | 2017-03-31 | 2018-06-06 | Общество с ограниченной ответственностью "ЭТБ каталитические технологии" (ООО "ЭТБ КаТ") | Одностадийный способ получения бутадиена |
CN109694084B (zh) * | 2017-10-20 | 2020-12-01 | 中国石油化工股份有限公司 | Doh沸石分子筛的制备方法 |
CN109746041B (zh) * | 2017-11-07 | 2022-07-12 | 万华化学集团股份有限公司 | 一种Ti-MWW分子筛的改性方法以及环十二酮肟的制备方法 |
CN109833904B (zh) * | 2017-11-29 | 2020-08-11 | 中国科学院大连化学物理研究所 | 一种酸碱双功能催化剂、其制备方法及在乙醇转化反应中的应用 |
CN109894144B (zh) * | 2017-12-07 | 2021-08-17 | 中国科学院大连化学物理研究所 | 一种1,3-丁二烯的合成方法及其催化剂的制备方法 |
JP7197507B2 (ja) * | 2017-12-27 | 2022-12-27 | 積水化学工業株式会社 | 触媒及びその製造方法並びに前記触媒を用いたジエン化合物の製造方法 |
FR3090631B1 (fr) * | 2018-12-21 | 2020-12-25 | Ifp Energies Now | Procédé de production de butadiène à partir d’éthanol avec régénération in situ du catalyseur de la deuxième étape réactionnelle |
DE102019106698A1 (de) * | 2019-03-15 | 2020-09-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Katalytische Herstellung von Butadien |
JPWO2023007676A1 (pt) * | 2021-07-29 | 2023-02-02 | ||
CN113663721B (zh) * | 2021-09-07 | 2023-10-17 | 陕西延长石油(集团)有限责任公司 | 一种乙醇制备1,3-丁二烯的催化剂的制备方法及其应用 |
CN113996330B (zh) * | 2021-11-12 | 2022-08-30 | 中国科学院大连化学物理研究所 | 一种球磨法制备的Zr基MFI分子筛催化剂及其应用 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB331482A (en) | 1929-01-30 | 1930-06-30 | Serge Vassiliewitsch Lebedev | Improvements in or relating to the preparation of diolefines directly from alcohols |
US2421361A (en) * | 1942-09-29 | 1947-05-27 | Carbide & Carbon Chem Corp | Process for making diolefins |
JPS60127217A (ja) * | 1983-12-09 | 1985-07-06 | Japan Synthetic Rubber Co Ltd | チタノシリケ−トゼオライトの製造方法 |
JPH0689340B2 (ja) * | 1986-08-08 | 1994-11-09 | 旭化成工業株式会社 | 炭化水素からオレフイン類および芳香族炭化水素を製造する方法 |
JPH04368339A (ja) * | 1991-06-12 | 1992-12-21 | Idemitsu Kosan Co Ltd | 有機化合物の接触転化方法 |
DE19939416A1 (de) * | 1999-08-20 | 2001-02-22 | Basf Ag | Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs |
KR101152768B1 (ko) * | 2010-04-22 | 2012-06-18 | 금호석유화학 주식회사 | 에탄올로부터 1,3-부타디엔 제조를 위한 나노 실리카계 촉매 및 이를 이용한 1,3-부타디엔의 제조방법 |
RU2440962C1 (ru) * | 2010-07-29 | 2012-01-27 | Общество с ограниченной ответственностью "УНИСИТ" (ООО "УНИСИТ") | Одностадийный способ получения бутадиена |
CN102918009B (zh) * | 2011-01-26 | 2015-10-21 | 住友橡胶工业株式会社 | 合成系统、轮胎用橡胶化学药品、轮胎用合成橡胶以及充气轮胎 |
CN102515198B (zh) * | 2011-11-21 | 2013-06-26 | 浙江大学 | 一种整体型杂原子取代多级孔道分子筛及其合成方法 |
US9371239B2 (en) * | 2012-11-05 | 2016-06-21 | Basf Se | Tin-containing zeolitic material having an MWW-type framework structure |
-
2014
- 2014-06-13 JP JP2016518511A patent/JP6545157B2/ja not_active Expired - Fee Related
- 2014-06-13 CN CN201480044612.9A patent/CN105451881B/zh not_active Expired - Fee Related
- 2014-06-13 WO PCT/EP2014/062391 patent/WO2014198901A1/en active Application Filing
- 2014-06-13 BR BR112015031174A patent/BR112015031174B8/pt not_active IP Right Cessation
- 2014-06-13 EP EP14729683.4A patent/EP3007823B1/en active Active
- 2014-06-13 US US14/897,379 patent/US9878965B2/en active Active
-
2015
- 2015-12-14 ZA ZA2015/09117A patent/ZA201509117B/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP6545157B2 (ja) | 2019-07-17 |
WO2014198901A1 (en) | 2014-12-18 |
CN105451881A (zh) | 2016-03-30 |
ZA201509117B (en) | 2020-05-27 |
US20160145171A1 (en) | 2016-05-26 |
BR112015031174A2 (pt) | 2017-07-25 |
US9878965B2 (en) | 2018-01-30 |
CN105451881B (zh) | 2019-08-16 |
BR112015031174B1 (pt) | 2020-12-01 |
EP3007823A1 (en) | 2016-04-20 |
EP3007823B1 (en) | 2022-12-28 |
JP2016521719A (ja) | 2016-07-25 |
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