EA201490359A1 - Применение катализатора на основе модифицированного фосфором цеолита в процессе дегидратации спиртов - Google Patents
Применение катализатора на основе модифицированного фосфором цеолита в процессе дегидратации спиртовInfo
- Publication number
- EA201490359A1 EA201490359A1 EA201490359A EA201490359A EA201490359A1 EA 201490359 A1 EA201490359 A1 EA 201490359A1 EA 201490359 A EA201490359 A EA 201490359A EA 201490359 A EA201490359 A EA 201490359A EA 201490359 A1 EA201490359 A1 EA 201490359A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- optionally
- steam
- phosphorus
- zeolite
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 3
- 239000011574 phosphorus Substances 0.000 title abstract 3
- 208000005156 Dehydration Diseases 0.000 title 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 4
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- 238000011282 treatment Methods 0.000 abstract 3
- 239000010457 zeolite Substances 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000009388 chemical precipitation Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000011067 equilibration Methods 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/28—Phosphorising
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
В первом варианте реализации изобретение относится к применению катализатора для конвертации по меньшей мере одного спирта в лёгкие олефины в процессе дегидратации с получением олефина, имеющего одинаковое со спиртом число атомов углерода, при этом катализатор приготовлен на основе модифицированного фосфором цеолита способом, включающим следующие шаги в указанной последовательности: а) взять цеолит, в структуру которого входит хотя бы одно десятичленное кольцо, по усмотрению обработать цеолит паром; b) смешать цеолит, указанный в шаге а), как минимум с одним из связующих компонентов и структуронаправляющих агентов, после чего сформовать смесь; с) по усмотрению выполнить ионообмен; d) по усмотрению обработать паром сформованный катализатор, произвольно - перед шагом с), при этом по меньшей мере одна из указанных обработок паром на шаге d) и на шаге а) обязательна; е) ввести в катализатор по меньшей мере 0,1 мас.% фосфора, применяя сухую импрегнацию или парофазное химическое осаждение; f) по усмотрению ввести металл, произвольно - одновременно с шагом е); g) по усмотрению промыть катализатор; h) по усмотрению кальцинировать (прокалить) катализатор; i) обработать катализатор паром - шаг, называемый также приведением в равновесное состояние. Во втором варианте реализации фосфор может быть введён любым способом, и на шаге i) интенсивность парообработки (X) по меньшей мере около 2. Во втором варианте реализации катализатор предпочтительно подвергают обработке паром при температуре выше 625°С, преимущественно - в диапазоне от 700 до 800°С. Металл на шаге f) предпочтительно - кальций.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11290360 | 2011-08-03 | ||
| EP11290360.4 | 2011-08-03 | ||
| PCT/EP2012/064579 WO2013017496A1 (en) | 2011-08-03 | 2012-07-25 | Use of a catalyst comprising a phosphorus modified zeolite in an alcohol dehydration process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201490359A1 true EA201490359A1 (ru) | 2014-08-29 |
| EA028628B1 EA028628B1 (ru) | 2017-12-29 |
Family
ID=46579032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201490359A EA028628B1 (ru) | 2011-08-03 | 2012-07-25 | Применение катализатора на основе модифицированного фосфором цеолита в процессе дегидратации спиртов |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9862653B2 (ru) |
| EP (1) | EP2739390B1 (ru) |
| KR (1) | KR101948358B1 (ru) |
| CN (1) | CN103842079B (ru) |
| AR (1) | AR087461A1 (ru) |
| BR (1) | BR112014002420B1 (ru) |
| CA (1) | CA2842386A1 (ru) |
| DK (1) | DK2739390T3 (ru) |
| EA (1) | EA028628B1 (ru) |
| ES (1) | ES2868140T3 (ru) |
| PL (1) | PL2739390T3 (ru) |
| TW (1) | TW201318702A (ru) |
| UA (1) | UA112781C2 (ru) |
| WO (1) | WO2013017496A1 (ru) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2739391B1 (en) * | 2011-08-03 | 2021-02-17 | Total Research & Technology Feluy | Catalyst comprising a phosphorus modified zeolite and having partly an alpo structure |
| US10300467B2 (en) * | 2011-08-03 | 2019-05-28 | Total Research & Technology Feluy | Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite |
| JP6521979B2 (ja) * | 2013-12-20 | 2019-05-29 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 含酸素化合物をオレフィンに変換するための触媒および方法 |
| WO2016107759A1 (en) * | 2014-12-31 | 2016-07-07 | Total Research & Technology Feluy | Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of sulfur containing compounds |
| EP3126313B1 (en) | 2014-12-31 | 2017-10-18 | Total Research & Technology Feluy | Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of organic acids |
| CN107108398B (zh) | 2015-02-23 | 2023-10-10 | 维尔萨利斯股份公司 | 用于含氧化合物的脱水的方法 |
| CN106146235B (zh) * | 2015-05-15 | 2019-06-18 | 内蒙古丰汇化工有限公司 | 由甲醇一步法制备烃类产品的方法 |
| WO2018004993A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Reduction of greenhouse gas emission |
| WO2018004994A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Fluidized bed membrane reactor |
| WO2018004992A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Conversion of methane to dimethyl ether |
| EP3555033A1 (en) * | 2016-12-14 | 2019-10-23 | ExxonMobil Research and Engineering Company | Production of high octane hydrocarbon from isobutane via tert-butanol |
| IT201700074911A1 (it) | 2017-07-04 | 2019-01-04 | Versalis Spa | Procedimento per la produzione di olefine da alcoli |
| RU2020125400A (ru) * | 2018-01-12 | 2022-02-14 | Альбемарл Корпорейшн | Катализатор fcc с более чем одним диоксидом кремния |
| CN108636448A (zh) * | 2018-04-18 | 2018-10-12 | 佛山市飞程信息技术有限公司 | 一种用于乙醇脱水制乙烯的催化剂 |
| IT201900015069A1 (it) | 2019-08-27 | 2021-02-27 | Versalis Spa | Catalizzatore comprendente coke e procedimento per la produzione di dieni. |
| CN114405538B (zh) * | 2022-01-27 | 2023-03-21 | 吉林大学 | 一种多级孔Fe/ZSM-5分子筛及其制备方法和应用 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3274124A (en) | 1964-01-02 | 1966-09-20 | Universal Oil Prod Co | Process of preparing a silica-alumina supported group viii metal hydrocracking catalyst |
| US3909450A (en) | 1973-12-26 | 1975-09-30 | Universal Oil Prod Co | Method of catalyst manufacture |
| US3972832A (en) | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
| US4356338A (en) * | 1979-07-27 | 1982-10-26 | Mobil Oil Corporation | Extending catalyst life by treating with phosphorus and/or steam |
| US4318801A (en) * | 1979-09-04 | 1982-03-09 | Gulf Research & Development Company | Supported nickel-molybdenum catalyst, preparation thereof, and hydrodesulfurization of hydrocarbon fractions using same |
| US4988659A (en) | 1988-11-23 | 1991-01-29 | Chevron Research Company | Silica/alumina cogel catalysts |
| US5231064A (en) | 1991-03-12 | 1993-07-27 | Mobil Oil Corp. | Cracking catalysts comprising phosphorus and method of preparing and using the same |
| US5171921A (en) | 1991-04-26 | 1992-12-15 | Arco Chemical Technology, L.P. | Production of olefins |
| EP0568913A3 (en) | 1992-05-03 | 1995-03-22 | Dalian Chemical Physics Inst | Process for the conversion of methanol into light olefins and catalyst used therefor. |
| US6423879B1 (en) * | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
| ATE270318T1 (de) * | 1998-09-28 | 2004-07-15 | Bp Corp North America Inc | Verfahren zur herstellung von olefinen unter verwendung eines pentasil-zeolith enthaltenden katalysators |
| US6797851B2 (en) | 2001-08-30 | 2004-09-28 | Exxonmobil Chemical Patents Inc. | Two catalyst process for making olefin |
| US7408092B2 (en) | 2004-11-12 | 2008-08-05 | Uop Llc | Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst |
| EP2188051A4 (en) | 2007-08-13 | 2011-11-02 | Agency Science Tech & Res | MODIFIED CATALYST COMPOSITION FOR CONVERTING ALCOHOL TO ALKEN |
| EP2082802A1 (en) | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining a catalyst composite |
| CN101939276B (zh) | 2008-02-07 | 2013-05-08 | 道达尔石油化学产品研究弗吕公司 | 由乙醇制造烯烃的方法 |
| WO2009098262A1 (en) * | 2008-02-07 | 2009-08-13 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| JP2011511037A (ja) | 2008-02-07 | 2011-04-07 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | 不活性成分の存在下でのアルコールの脱水 |
| US20110105815A1 (en) | 2008-02-07 | 2011-05-05 | Total Petrochemicals Research Feluy | Process to Make Olefins from Ethanol |
| EP2348004A1 (en) * | 2010-01-25 | 2011-07-27 | Total Petrochemicals Research Feluy | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
| US10300467B2 (en) * | 2011-08-03 | 2019-05-28 | Total Research & Technology Feluy | Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite |
| EP2739391B1 (en) * | 2011-08-03 | 2021-02-17 | Total Research & Technology Feluy | Catalyst comprising a phosphorus modified zeolite and having partly an alpo structure |
-
2012
- 2012-07-25 EP EP12738463.4A patent/EP2739390B1/en active Active
- 2012-07-25 EA EA201490359A patent/EA028628B1/ru not_active IP Right Cessation
- 2012-07-25 US US14/236,726 patent/US9862653B2/en active Active
- 2012-07-25 KR KR1020147002726A patent/KR101948358B1/ko active IP Right Grant
- 2012-07-25 PL PL12738463T patent/PL2739390T3/pl unknown
- 2012-07-25 DK DK12738463.4T patent/DK2739390T3/da active
- 2012-07-25 ES ES12738463T patent/ES2868140T3/es active Active
- 2012-07-25 CN CN201280048602.3A patent/CN103842079B/zh active Active
- 2012-07-25 BR BR112014002420-0A patent/BR112014002420B1/pt active IP Right Grant
- 2012-07-25 UA UAA201402014A patent/UA112781C2/uk unknown
- 2012-07-25 CA CA2842386A patent/CA2842386A1/en not_active Abandoned
- 2012-07-25 WO PCT/EP2012/064579 patent/WO2013017496A1/en active Application Filing
- 2012-08-03 AR ARP120102856A patent/AR087461A1/es not_active Application Discontinuation
- 2012-08-03 TW TW101127921A patent/TW201318702A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2739390A1 (en) | 2014-06-11 |
| AR087461A1 (es) | 2014-03-26 |
| CA2842386A1 (en) | 2013-02-07 |
| KR101948358B1 (ko) | 2019-02-14 |
| TW201318702A (zh) | 2013-05-16 |
| US20140243570A1 (en) | 2014-08-28 |
| ES2868140T3 (es) | 2021-10-21 |
| PL2739390T3 (pl) | 2021-10-11 |
| EA028628B1 (ru) | 2017-12-29 |
| BR112014002420A2 (pt) | 2017-10-31 |
| WO2013017496A1 (en) | 2013-02-07 |
| CN103842079B (zh) | 2016-12-28 |
| CN103842079A (zh) | 2014-06-04 |
| DK2739390T3 (da) | 2021-03-29 |
| BR112014002420B1 (pt) | 2024-01-09 |
| US9862653B2 (en) | 2018-01-09 |
| UA112781C2 (uk) | 2016-10-25 |
| EP2739390B1 (en) | 2021-03-10 |
| KR20140046456A (ko) | 2014-04-18 |
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