CO4890864A1 - Trampas de vanadio para catalizadores de ruptura catalitica - Google Patents

Trampas de vanadio para catalizadores de ruptura catalitica

Info

Publication number
CO4890864A1
CO4890864A1 CO97057402A CO97057402A CO4890864A1 CO 4890864 A1 CO4890864 A1 CO 4890864A1 CO 97057402 A CO97057402 A CO 97057402A CO 97057402 A CO97057402 A CO 97057402A CO 4890864 A1 CO4890864 A1 CO 4890864A1
Authority
CO
Colombia
Prior art keywords
catalytic
agent
vanadium
composition
catalyst
Prior art date
Application number
CO97057402A
Other languages
English (en)
Inventor
Carlos Alexander Trujillo
Uribe Uriel Navarro
Aguilar Luis Alfredo Oviedo
Original Assignee
Colombiana De Petroleos Ecopet
Univ Nac De Colombia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colombiana De Petroleos Ecopet, Univ Nac De Colombia filed Critical Colombiana De Petroleos Ecopet
Priority to CO97057402A priority Critical patent/CO4890864A1/es
Priority to BR9710934-7A priority patent/BR9710934A/pt
Priority to US09/143,367 priority patent/US6159887A/en
Publication of CO4890864A1 publication Critical patent/CO4890864A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/521—Metal contaminant passivation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)

Abstract

Una composición catalítica aplicable al proceso de rupturacatalítica de hidrocarburos, compuesta por una zeolita como matriz y un agente que causa inactivación al vanadio, en donde dicho agente puede ser un compuesto de fórmula M(PO3 )2 , M2 P2 O7 , M3 (P4 O2 ), M10 (OH)2 (P4 O6 ), M(H2 PO2 ), MHPO4 , 3M3 (PO4 )2 .MCO3 , M(H2 PO2 )2 , MHPO3 , M(PO2 )2 , M2 P2 O6 y A(PO3 )3 , donde M representa un metal bivalente y A representa un metal trivalente, o mezclas de dos o más de estos compuestos.Una composición catalítica aplicable al proceso de ruptura catalítica de hidrocarburos, compuesta porun catalizador de ruptura catalítica y un segundo componente separado de composición distinta al catalizador, que actúa como agente que causa inactivación al vanadio o como trampa para la retención del mismo, en donde dicho segundo componente separado se encuentra dentro del grupo formado por M(PO3 )2 , M2 P2 O7 , M3 (P4 O2 ), M10 (OH)2 , (P4 O6 ); M(H2 PO4 )2 , MHPO4 , 3M3 (PO4 )2 .MCO3 , M(H2 PO2 )2 , MHPO3 , M(PO2 )2 , M2 P2 O6 y A(PO3 )3 , o es una mezcla o mezclas de dos o más de dicho grupo, en donde M representa un catión metálico bivalente y A representa un catión metálico trivalente.La composición catalítica de la reivindicación 2 en donde dicho segundo componente separado se encuentra soportado sobre un material inerte del grupo compuesto por alúmina, sílice, óxido de magnesio, óxido de titanio, óxido de zirconio, fosfato de aluminio, aluminosilicatos, zeolitas, caolín, sepiolita y arcillas.La composición catalítica de la reivindicación 1 en donde dicho agente que causa inactivación de vanadio constituye entre el 5 y el 10% en peso de la masa total de dicha composición catalítica aproximadamente.Una composición catalítica de cualquiera de las reivindicaciones anteriores en donde el agente que causa inactivación al vanadio es el pirofosfato de bario de fórmula Ba2 P2 O7 .
CO97057402A 1997-10-02 1997-10-02 Trampas de vanadio para catalizadores de ruptura catalitica CO4890864A1 (es)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CO97057402A CO4890864A1 (es) 1997-10-02 1997-10-02 Trampas de vanadio para catalizadores de ruptura catalitica
BR9710934-7A BR9710934A (pt) 1997-10-02 1997-12-04 Interceptador de vanádio para catalisadores de ruptura catalìtica
US09/143,367 US6159887A (en) 1997-10-02 1998-08-28 Vanadium traps for catalyst for catalytic cracking

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CO97057402A CO4890864A1 (es) 1997-10-02 1997-10-02 Trampas de vanadio para catalizadores de ruptura catalitica

Publications (1)

Publication Number Publication Date
CO4890864A1 true CO4890864A1 (es) 2000-02-28

Family

ID=40318004

Family Applications (1)

Application Number Title Priority Date Filing Date
CO97057402A CO4890864A1 (es) 1997-10-02 1997-10-02 Trampas de vanadio para catalizadores de ruptura catalitica

Country Status (3)

Country Link
US (1) US6159887A (es)
BR (1) BR9710934A (es)
CO (1) CO4890864A1 (es)

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US6281378B1 (en) * 1995-06-08 2001-08-28 Nippon Shokubai Co., Ltd. Vanadium-containing catalysts, process for manufacturing and use of the same
US20100010279A1 (en) * 2004-04-02 2010-01-14 Ranjit Kumar Catalyst Compositions Comprising Metal Phosphate Bound Zeolite and Methods of Using Same to Catalytically Crack Hydrocarbons
US20050227853A1 (en) * 2004-04-02 2005-10-13 Ranjit Kumar Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons
EP1907509B1 (en) * 2005-06-29 2019-05-08 W.R. Grace & Co.-Conn. Pentasil catalyst for light olefins in fluidized catalytic units
US7993623B2 (en) 2007-06-29 2011-08-09 Albemarle Netherlands B.V. Additives for removal of metals poisonous to catalysts during fluidized catalytic cracking of hydrocarbons
CO5930067A1 (es) 2006-12-06 2008-06-27 Ecopetrol Sa Trampa de vanadio para el proceso de ruptura catalitica y su preparacion
CO5930068A1 (es) * 2006-12-06 2008-06-27 Ecopetrol Sa Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso
US8137535B2 (en) * 2008-01-29 2012-03-20 Kellogg Brown & Root Llc Method for adjusting catalyst activity
US9029291B2 (en) * 2011-01-12 2015-05-12 Basf Corporation Rare earth-containing attrition resistant vanadium trap for catalytic cracking catalyst
US10005072B2 (en) 2012-07-23 2018-06-26 W. R. Grace & Co.-Conn High matrix surface area catalytic cracking catalyst stabilized with magnesium and silica
US9993810B2 (en) 2012-07-23 2018-06-12 W. R. Grace & Co.-Conn Silica sol bound catalytic cracking catalyst stabilized with magnesium
KR20180075687A (ko) * 2015-11-24 2018-07-04 바스프 코포레이션 부틸렌 수율을 증가시키기 위한 유동 접촉 분해 촉매
CN112121581A (zh) * 2020-09-23 2020-12-25 苏州云式环境科技有限公司 工业尾气处理系统

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Also Published As

Publication number Publication date
BR9710934A (pt) 2000-05-09
US6159887A (en) 2000-12-12

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