ES2183710B1 - Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel. - Google Patents

Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.

Info

Publication number
ES2183710B1
ES2183710B1 ES200100960A ES200100960A ES2183710B1 ES 2183710 B1 ES2183710 B1 ES 2183710B1 ES 200100960 A ES200100960 A ES 200100960A ES 200100960 A ES200100960 A ES 200100960A ES 2183710 B1 ES2183710 B1 ES 2183710B1
Authority
ES
Spain
Prior art keywords
sulfur compounds
catalysts
elimination
fraction diesel
removal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES200100960A
Other languages
English (en)
Other versions
ES2183710A1 (es
Inventor
Canos Avelino Corma
Marcelo E Domine
Martinez Cristina Martinez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES200100960A priority Critical patent/ES2183710B1/es
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to CA002443891A priority patent/CA2443891A1/en
Priority to EP02722297A priority patent/EP1391497A1/en
Priority to RU2003132876/04A priority patent/RU2003132876A/ru
Priority to CZ20033070A priority patent/CZ20033070A3/cs
Priority to PCT/ES2002/000179 priority patent/WO2002083819A1/es
Priority to PL373895A priority patent/PL199085B1/pl
Priority to MXPA03009251A priority patent/MXPA03009251A/es
Priority to JP2002582158A priority patent/JP2004531605A/ja
Publication of ES2183710A1 publication Critical patent/ES2183710A1/es
Priority to US10/683,557 priority patent/US7371318B2/en
Priority to MA27352A priority patent/MA26313A1/fr
Priority to HR20030909A priority patent/HRP20030909A2/hr
Application granted granted Critical
Publication of ES2183710B1 publication Critical patent/ES2183710B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Abstract

Proceso y catalizadores para la eliminación de compuestos de azufre de la fracción diesel. En la presente invención se describe un proceso para la eliminación de compuestos de azufre presentes en la fracción diesel, mediante su oxidación utilizando hidroperóxidos y un catalizador o mezclas de catalizadores, los cuales están basados en tamices moleculares conteniendo poros con anillos de 12 o más miembros, como por ejemplo zeolitas Beta, ITQ-7, UTD-1, Mordenita, y materiales mesoporosos como por ejemplo MCM-41 y otros amorfos, todos ellos conteniendo Ti en su composición.
ES200100960A 2001-04-12 2001-04-12 Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel. Expired - Fee Related ES2183710B1 (es)

Priority Applications (12)

Application Number Priority Date Filing Date Title
ES200100960A ES2183710B1 (es) 2001-04-12 2001-04-12 Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.
JP2002582158A JP2004531605A (ja) 2001-04-12 2002-04-11 ディーゼル留分から硫黄化合物を除去するための方法と触媒
RU2003132876/04A RU2003132876A (ru) 2001-04-12 2002-04-11 Способ и катализаторы для удаления соединений серы из дизельной фракции
CZ20033070A CZ20033070A3 (en) 2001-04-12 2002-04-11 Method and catalysts for the elimination of sulfur compounds from the diesel fraction
PCT/ES2002/000179 WO2002083819A1 (es) 2001-04-12 2002-04-11 Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel
PL373895A PL199085B1 (pl) 2001-04-12 2002-04-11 Sposób usuwania związków siarki z frakcji oleju napędowego i służące do tego katalizatory
CA002443891A CA2443891A1 (en) 2001-04-12 2002-04-11 Method and catalysts for the elimination of sulfur compounds from the diesel fraction
EP02722297A EP1391497A1 (en) 2001-04-12 2002-04-11 Method and catalysts for the elimination of sulfur compounds from the diesel fraction
MXPA03009251A MXPA03009251A (es) 2001-04-12 2002-04-11 Un procedimiento para eliminar azufre de la fraccion diesel.
US10/683,557 US7371318B2 (en) 2001-04-12 2003-10-10 Method and catalysts for the elimination of sulphur compounds from the diesel fraction
MA27352A MA26313A1 (fr) 2001-04-12 2003-10-10 Procede et catalyseurs pour l'elimination des composants de souffre de la fraction diesel.
HR20030909A HRP20030909A2 (en) 2001-04-12 2003-11-10 Method and catalysts for the elimination of sulphur compounds from the diesel fraction

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200100960A ES2183710B1 (es) 2001-04-12 2001-04-12 Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.

Publications (2)

Publication Number Publication Date
ES2183710A1 ES2183710A1 (es) 2003-03-16
ES2183710B1 true ES2183710B1 (es) 2004-01-16

Family

ID=8497542

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200100960A Expired - Fee Related ES2183710B1 (es) 2001-04-12 2001-04-12 Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.

Country Status (12)

Country Link
US (1) US7371318B2 (es)
EP (1) EP1391497A1 (es)
JP (1) JP2004531605A (es)
CA (1) CA2443891A1 (es)
CZ (1) CZ20033070A3 (es)
ES (1) ES2183710B1 (es)
HR (1) HRP20030909A2 (es)
MA (1) MA26313A1 (es)
MX (1) MXPA03009251A (es)
PL (1) PL199085B1 (es)
RU (1) RU2003132876A (es)
WO (1) WO2002083819A1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
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ES2192969B1 (es) * 2001-11-30 2004-12-16 Universidad Poletecnica De Valencia. Proceso y catalizadores para la oxidacion selectiva de compuestos de azufre presentes en gasolina, queroseno y diesel.
ES2192967B1 (es) * 2001-11-20 2004-09-16 Universidad Politecnica De Valencia. Proceso y catalizadores para la oxidacion de compuestos de azufre de las fracciones gasolina, queroseno y diesel.
EP1462504A1 (en) * 2001-11-20 2004-09-29 Consejo Superior De Investigaciones Cientificas Method of oxidising sulphur compounds present in gasoline, kerosene and diesel fractions
ES2200707B1 (es) * 2002-08-07 2005-05-01 Universidad Politecnica De Valencia Proceso para la oxidacion de mercaptanos, compuestos tiofenicos y sus derivados, en las fracciones gasolina, queroseno y diesel.
WO2005012458A1 (en) * 2003-08-01 2005-02-10 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
BRPI0519500A2 (pt) * 2004-12-29 2009-02-03 Bp Corp North America Inc processo para a dessulfurizaÇço de uma carga de alimentaÇço de destilado para produzir combustÍvel de transporte de refinaria ou componentes de mistura para combustÍvel de transporte de refinaria
CA2619318C (en) * 2005-08-15 2011-11-01 Arizona Chemical Company Low sulfur tall oil fatty acid
US8715489B2 (en) * 2005-09-08 2014-05-06 Saudi Arabian Oil Company Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures
US7744749B2 (en) 2005-09-08 2010-06-29 Saudi Arabian Oil Company Diesel oil desulfurization by oxidation and extraction
CA2685850C (en) 2007-05-03 2016-06-28 Auterra, Inc. Product containing monomer and polymers of titanyls and methods for making same
ES2311408B1 (es) * 2007-07-10 2010-01-13 Consejo Superior De Investigaciones Cientificas Procedimiento de eliminacion de azufre en combustibles liquidos.
US8298404B2 (en) 2010-09-22 2012-10-30 Auterra, Inc. Reaction system and products therefrom
BRPI0821570A2 (pt) * 2008-03-26 2015-09-08 Auterra Inc catalisadores de sulfoxidação e métodos e sistemas para utilizar os mesmos
US9206359B2 (en) 2008-03-26 2015-12-08 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US9061273B2 (en) 2008-03-26 2015-06-23 Auterra, Inc. Sulfoxidation catalysts and methods and systems of using same
US8894843B2 (en) 2008-03-26 2014-11-25 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8197671B2 (en) * 2008-03-26 2012-06-12 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8241490B2 (en) * 2008-03-26 2012-08-14 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8764973B2 (en) 2008-03-26 2014-07-01 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8962774B2 (en) 2010-07-12 2015-02-24 Reliance Industries Limited Attrition resistant catalyst system for manufacture of polyolefins
US9828557B2 (en) 2010-09-22 2017-11-28 Auterra, Inc. Reaction system, methods and products therefrom
CN102826566A (zh) * 2012-09-25 2012-12-19 宁夏兴平精细化工股份有限公司 一种用于硫醚氧化的介孔分子筛的合成方法
US10246647B2 (en) 2015-03-26 2019-04-02 Auterra, Inc. Adsorbents and methods of use
US10450516B2 (en) 2016-03-08 2019-10-22 Auterra, Inc. Catalytic caustic desulfonylation

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US3642833A (en) * 1969-04-02 1972-02-15 Shell Oil Co Olefin epoxidation
US3923843A (en) * 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
US3816301A (en) * 1972-06-30 1974-06-11 Atlantic Richfield Co Process for the desulfurization of hydrocarbons
US3919402A (en) * 1973-08-06 1975-11-11 Kvb Inc Petroleum oil desulfurization process
IT1127311B (it) * 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
US4830733A (en) * 1987-10-05 1989-05-16 Uop Integrated process for the removal of sulfur compounds from fluid streams
ATE175590T1 (de) 1992-07-24 1999-01-15 Exxon Chemical Patents Inc Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen
ES2092428B1 (es) * 1993-06-15 1997-08-01 Univ Valencia Politecnica Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.
FR2730722B1 (fr) * 1995-02-17 1997-04-30 Rhone Poulenc Chimie Zeolithe ti-beta a haute teneur en silice, son procede de preparation et son utilisation comme catalyseur d'oxydation
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Also Published As

Publication number Publication date
MA26313A1 (fr) 2004-10-01
HRP20030909A2 (en) 2004-08-31
MXPA03009251A (es) 2004-01-29
CA2443891A1 (en) 2002-10-24
RU2003132876A (ru) 2005-05-10
CZ20033070A3 (en) 2004-03-17
US20040140247A1 (en) 2004-07-22
JP2004531605A (ja) 2004-10-14
WO2002083819A1 (es) 2002-10-24
US7371318B2 (en) 2008-05-13
ES2183710A1 (es) 2003-03-16
EP1391497A1 (en) 2004-02-25
PL373895A1 (en) 2005-09-19
PL199085B1 (pl) 2008-08-29

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