ATE175590T1 - Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen - Google Patents

Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen

Info

Publication number
ATE175590T1
ATE175590T1 AT93917640T AT93917640T ATE175590T1 AT E175590 T1 ATE175590 T1 AT E175590T1 AT 93917640 T AT93917640 T AT 93917640T AT 93917640 T AT93917640 T AT 93917640T AT E175590 T1 ATE175590 T1 AT E175590T1
Authority
AT
Austria
Prior art keywords
catalysts
oxidation
pct
saturated hydrocarbons
sec
Prior art date
Application number
AT93917640T
Other languages
English (en)
Inventor
Diane Renata Cornel Huybrechts
Philip Luc Buskens
Georges Marie Karel Mathys
Luc Roger Marc Martens
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB929215822A external-priority patent/GB9215822D0/en
Priority claimed from GB939307910A external-priority patent/GB9307910D0/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ATE175590T1 publication Critical patent/ATE175590T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Secondary Cells (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Primary Cells (AREA)
AT93917640T 1992-07-24 1993-07-23 Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen ATE175590T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB929215822A GB9215822D0 (en) 1992-07-24 1992-07-24 Catalysts and their use in oxidation of saturated hydrocarbons
GB939307910A GB9307910D0 (en) 1993-04-16 1993-04-16 Catalysts and their use in oxidation of saturated hydrocarbons

Publications (1)

Publication Number Publication Date
ATE175590T1 true ATE175590T1 (de) 1999-01-15

Family

ID=26301322

Family Applications (1)

Application Number Title Priority Date Filing Date
AT93917640T ATE175590T1 (de) 1992-07-24 1993-07-23 Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen

Country Status (13)

Country Link
US (1) US5739076A (de)
EP (1) EP0651674B1 (de)
JP (1) JPH07509650A (de)
KR (2) KR100291875B1 (de)
AT (1) ATE175590T1 (de)
AU (1) AU678983B2 (de)
BR (1) BR9306794A (de)
CA (1) CA2140863C (de)
CZ (1) CZ16095A3 (de)
DE (1) DE69323083T2 (de)
PL (1) PL307245A1 (de)
TW (1) TW327165B (de)
WO (1) WO1994002245A1 (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5453511A (en) * 1993-12-23 1995-09-26 Arco Chemical Technology, L.P. Bis-piperidinium compounds
US5412122A (en) * 1993-12-23 1995-05-02 Arco Chemical Technology, L.P. Epoxidation process
US5374747A (en) * 1993-12-23 1994-12-20 Arco Chemical Technology, L.P. Epoxidation process and catalyst therefore
US5474754A (en) * 1994-08-15 1995-12-12 Arco Chemical Technology, L.P. Preparation of an aluminosilicotitanate isomorphous with zeolite beta
ATE179396T1 (de) 1994-09-28 1999-05-15 Arco Chem Tech Verfahren zur herstellung von wasserstoffperoxyd, integrierter prozess zur epoxydierung und alkylammoniumsalze von sulfonsäuresubstituiertem anthrahydrochinon und anthrachinon
FR2730722B1 (fr) * 1995-02-17 1997-04-30 Rhone Poulenc Chimie Zeolithe ti-beta a haute teneur en silice, son procede de preparation et son utilisation comme catalyseur d'oxydation
WO1997029991A1 (es) * 1996-02-16 1997-08-21 Consejo Superior Investigaciones Cientificas PROCEDIMIENTO DE PREPARACION DE ZEOLITA BETA CONTENIENDO Ti, Y SIN Al
US5663384A (en) * 1996-03-06 1997-09-02 Arco Chemical Technology, L.P. Asymetric epoxidation using a titanium-containing zeolite and a chiral hydroperoxide
ES2133042B1 (es) * 1996-03-14 2000-05-16 Univ Valencia Politecnica Sintesis de zeolita y zeotipos isomorfos a la zeolita beta.
US6191308B1 (en) 1996-04-26 2001-02-20 Exxon Chemical Patents Inc. Process for the manufacture of oxygenates
US6074447A (en) * 1997-02-21 2000-06-13 University Of Hawaii Hydrogen storage
ES2179753B1 (es) 2000-10-11 2005-02-16 Universidad Politecnica De Valencia Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion gasolina.
ES2183710B1 (es) 2001-04-12 2004-01-16 Univ Valencia Politecnica Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.
DE10146590A1 (de) * 2001-09-21 2003-04-10 Bayer Cropscience Ag Selektive Herbizide auf Basis von substituierten Thien-3-yl-sulfonylamino(thio)carbonyl-triazolin(thi)onen und Safenern
US20040054199A1 (en) * 2002-09-17 2004-03-18 Basf Aktiengesellschaft Process for epoxidation and catalyst to be used therein
DE10320634A1 (de) * 2003-05-08 2004-11-18 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
FR2869894B1 (fr) * 2004-05-10 2007-02-23 Inst Francais Du Petrole Methode de synthese de metalloaluminosilicate cristallise par synthese directe
EP1841535B1 (de) 2005-01-14 2017-11-08 Dow Global Technologies LLC Rekonstitution eines aktiven oxidationskatalysators
DE102009008144A1 (de) * 2009-02-09 2010-08-19 Nano-X Gmbh Verfahren zur Herstellung von Alkali- und Erdalkalilegierungen und Verwendung der Alkali- und Erdalkalilegierungen
CN102452922B (zh) * 2010-10-27 2014-08-20 中国石油化工股份有限公司 一种二元羧酸的生产方法
CN102452917B (zh) * 2010-10-27 2014-08-20 中国石油化工股份有限公司 一种催化氧化羟基酸的方法
CN105622386A (zh) * 2014-10-27 2016-06-01 湖南师范大学 一种环己酮合成己二酸的绿色工艺
CN105622385A (zh) * 2014-10-27 2016-06-01 湖南师范大学 清洁催化氧化环己酮制己二酸工艺及催化剂和催化剂制备方法
JP6621281B2 (ja) * 2015-09-18 2019-12-18 国立大学法人横浜国立大学 チタノシリケートの製造方法
CN111484031B (zh) * 2019-01-28 2023-03-10 中国石油化工股份有限公司 改性钛硅分子筛及其制备方法和应用以及硫醚氧化方法
CN116120157A (zh) * 2023-02-24 2023-05-16 山东京博石油化工有限公司 一种由环戊烷选择性氧化制备环戊酮的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4490565A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
US4590322A (en) * 1985-06-12 1986-05-20 Mobil Oil Corporation Use of hydrogen sulfide to improve benzene production over zeolites
US4798816A (en) * 1986-12-19 1989-01-17 Union Oil Company Of California Process for increasing the selectivity of an alkylation catalyst for monoalkylation
US4927525A (en) * 1988-08-30 1990-05-22 Mobil Oil Corporation Catalytic reforming with improved zeolite catalysts
US5412122A (en) * 1993-12-23 1995-05-02 Arco Chemical Technology, L.P. Epoxidation process

Also Published As

Publication number Publication date
DE69323083T2 (de) 1999-07-15
WO1994002245A1 (en) 1994-02-03
DE69323083D1 (de) 1999-02-25
EP0651674A1 (de) 1995-05-10
CZ16095A3 (en) 1995-10-18
TW327165B (en) 1998-02-21
AU678983B2 (en) 1997-06-19
KR960703803A (ko) 1996-08-31
KR950702451A (ko) 1995-07-29
EP0651674B1 (de) 1999-01-13
CA2140863A1 (en) 1994-02-03
JPH07509650A (ja) 1995-10-26
CA2140863C (en) 2004-04-20
KR100291875B1 (ko) 2001-11-05
US5739076A (en) 1998-04-14
BR9306794A (pt) 1998-12-08
AU4702393A (en) 1994-02-14
PL307245A1 (en) 1995-05-15

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