KR950702451A - 촉매 및 포화 탄화수소의 산화시 이들의 용도(catalysts and their use in oxidation of saturated hydrocarbons) - Google Patents

촉매 및 포화 탄화수소의 산화시 이들의 용도(catalysts and their use in oxidation of saturated hydrocarbons) Download PDF

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KR950702451A
KR950702451A KR1019950700268A KR19950700268A KR950702451A KR 950702451 A KR950702451 A KR 950702451A KR 1019950700268 A KR1019950700268 A KR 1019950700268A KR 19950700268 A KR19950700268 A KR 19950700268A KR 950702451 A KR950702451 A KR 950702451A
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use according
catalyst
oxidation
catalysts
zeolite beta
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KR100291875B1 (ko
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다이안 리나타 코넬리아 하이브레슈츠
필립 루크 부스켄즈
죠지 마리아 카렐 마씨즈
루크 로저 마르크 마르텡즈
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피터 찰스 보우덴
엑손 케미칼 패턴츠 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
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    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Secondary Cells (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Primary Cells (AREA)

Abstract

산화 촉매로서 유기 하이드로페록사이드를 사용하는 유기 화합물의 산화 반응을 위한 촉매로서 유용한 것으로 밝혀진 신규한 티탄제올라이트 베타 촉매, 이들은 개환 산화 촉매로서 특히 유용하며 사이클로섹산으로부터 아디프산을 제조하는데 사용할 수 있다.

Description

촉매 및 포화 탄화수소의 산화시 이들의 용도(CATALYSTS AND THEIR USE IN OXIDATION OF SATURATED HYDROCARBONS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 티탄 베타(a) 및 문헌[Journal of the Chemical Society]에 따라 합성한 생성물(b)에 대한 확산 반사 분광법(Diffuse Reflectance Spectroscopy)결과이다.
제2도는 본 발명의 티탄 베타(a)및 문헌[Journal of the Chemical Society]에 따라 합성한 생성물(b)에 대한 적외선 스펙트럼이다.

Claims (11)

  1. 산화 촉매로서 유기 하이드로페록사이드 및/또는 N2O를 사용하는 유기 화합물의 산화 반응을 위한 촉매로서 티탄 함유 제올라이트 베타의 용도.
  2. 제1항에 있어서, 사기 촉매를, 열수 처리한후 하기 몰 조성을 가진 티탄 함유 제올라이트 베타를 수득하는 합성 혼합물로부터 과산화수소의 존재하에 제조하는 용도 : SiO2(0.0001-0.2)TiO2(0.005-0.100)Al2O2(10-100)H2O (0.1-1)TEAOH
  3. 제2항에 있어서, 상기 합성 혼합물중 티탄 및 실리콘과 알루미늄의 몰비가 10내지 200범위인 용도.
  4. 제2또는 제3항에 있어서, TEOT를 산화 티탄의 공급원으로서 사용할 때, TEOT 몰당 10 내지 200몰을 제공하는 양으로 과산환 수소를 사용하는 용도.
  5. 제1내지 제4항중 어느 한 항에 있어서, 상기 촉매를 후처리하는 용도.
  6. 제5항에 있어서, 무기산을 사용하여 후처리하는 용도.
  7. 제5항에 있어서, 무기 염기를 사용하여 후처리하는 용도.
  8. 제5항에 있어서, 증기를 사용하여 후처리하는 용도.
  9. 제5내지 제8항중 어느 한항에 있어서, 후처리한 후 소성시키는 용도.
  10. 확산 반사 분광법(Diffuse Reflectance Spectroscopy)에서, 47500㎝-1의 파수에서 흡수띠를 갖는 티탄 함유 제올라이트 베타.
  11. 제10항에 따른 촉매의 존재하에 하이드로페록사이드를 사용하여 사이클로헥산을 산화시킴을 포함하는 아디프산의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950700268A 1992-07-24 1993-07-23 촉매및포화탄화수소의산화시이들의용도 KR100291875B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB929215822A GB9215822D0 (en) 1992-07-24 1992-07-24 Catalysts and their use in oxidation of saturated hydrocarbons
GB9215822.9 1992-07-24
GB9307910.1 1993-04-16
GB939307910A GB9307910D0 (en) 1993-04-16 1993-04-16 Catalysts and their use in oxidation of saturated hydrocarbons
PCT/EP1993/001972 WO1994002245A1 (en) 1992-07-24 1993-07-23 Catalysts and their use in oxidation of satured hydrocarbons

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KR950702451A true KR950702451A (ko) 1995-07-29
KR100291875B1 KR100291875B1 (ko) 2001-11-05

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KR1019950700268A KR100291875B1 (ko) 1992-07-24 1993-07-23 촉매및포화탄화수소의산화시이들의용도
KR1019960700313A KR960703803A (ko) 1992-07-24 1994-07-23 제올라이트의 제조 방법(process for the manufacture of a zeolite)

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KR1019960700313A KR960703803A (ko) 1992-07-24 1994-07-23 제올라이트의 제조 방법(process for the manufacture of a zeolite)

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US (1) US5739076A (ko)
EP (1) EP0651674B1 (ko)
JP (1) JPH07509650A (ko)
KR (2) KR100291875B1 (ko)
AT (1) ATE175590T1 (ko)
AU (1) AU678983B2 (ko)
BR (1) BR9306794A (ko)
CA (1) CA2140863C (ko)
CZ (1) CZ16095A3 (ko)
DE (1) DE69323083T2 (ko)
PL (1) PL307245A1 (ko)
TW (1) TW327165B (ko)
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CN102452922B (zh) * 2010-10-27 2014-08-20 中国石油化工股份有限公司 一种二元羧酸的生产方法
CN105622385A (zh) * 2014-10-27 2016-06-01 湖南师范大学 清洁催化氧化环己酮制己二酸工艺及催化剂和催化剂制备方法
CN105622386A (zh) * 2014-10-27 2016-06-01 湖南师范大学 一种环己酮合成己二酸的绿色工艺
JP6621281B2 (ja) * 2015-09-18 2019-12-18 国立大学法人横浜国立大学 チタノシリケートの製造方法
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CN116120157A (zh) * 2023-02-24 2023-05-16 山东京博石油化工有限公司 一种由环戊烷选择性氧化制备环戊酮的方法

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AU678983B2 (en) 1997-06-19
CA2140863A1 (en) 1994-02-03
TW327165B (en) 1998-02-21
CA2140863C (en) 2004-04-20
JPH07509650A (ja) 1995-10-26
BR9306794A (pt) 1998-12-08
AU4702393A (en) 1994-02-14
CZ16095A3 (en) 1995-10-18
KR960703803A (ko) 1996-08-31
PL307245A1 (en) 1995-05-15
US5739076A (en) 1998-04-14
EP0651674A1 (en) 1995-05-10
ATE175590T1 (de) 1999-01-15
DE69323083T2 (de) 1999-07-15
WO1994002245A1 (en) 1994-02-03
KR100291875B1 (ko) 2001-11-05
EP0651674B1 (en) 1999-01-13

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