ES2156514A1 - Materiales microporosos de alta superficie activos en reacciones de oxidacion. - Google Patents

Materiales microporosos de alta superficie activos en reacciones de oxidacion.

Info

Publication number
ES2156514A1
ES2156514A1 ES009802567A ES9802567A ES2156514A1 ES 2156514 A1 ES2156514 A1 ES 2156514A1 ES 009802567 A ES009802567 A ES 009802567A ES 9802567 A ES9802567 A ES 9802567A ES 2156514 A1 ES2156514 A1 ES 2156514A1
Authority
ES
Spain
Prior art keywords
tiq
oxidation reactions
called
preparation
activity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009802567A
Other languages
English (en)
Other versions
ES2156514B1 (es
Inventor
Marcelo Eduardo Domine
Canos Avelino Corma
Segui Vicente Fornes
Morales Urbano Diaz
Moret Jose Luis Jorda
Garcia Fernando Rey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES9802567A priority Critical patent/ES2156514B1/es
Priority to PCT/ES1999/000393 priority patent/WO2000034181A1/es
Publication of ES2156514A1 publication Critical patent/ES2156514A1/es
Application granted granted Critical
Publication of ES2156514B1 publication Critical patent/ES2156514B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"Materiales microporosos de alta superficie activos en reacciones de oxidación". La presente invención se refiere a un material microporoso formado por oxígeno, silicio, germanio, aluminio, boro, galio, zirconio y/o titanio en su composición denominado TIQ-2, al procedimiento de su preparación y a sus aplicaciones catalíticas en reacciones de oxidación. El método de preparación del material TIQ-2 se basa en la incorporación de las especies de titanio y/o zirconio mediante un procedimiento postsíntesis a un sólido preparado por deslaminación del precursor zeolítico de estructura laminar. Asimismo, se reivindica un material con características similares al TIQ-2, pero que además posee grupos orgánicos anclados en su superficie denominado METIQ-2, al procedimiento de su preparación y a sus aplicaciones como catalizador en reacciones de oxidación.a incorporación de las especies orgánicas durante la síntesis del material denominado METIQ-2 se realiza mediante un proceso postsíntesis sobre el material TIQ-2.
ES9802567A 1998-12-04 1998-12-04 Materiales microporosos de alta superficie activos en reacciones de oxidacion. Expired - Fee Related ES2156514B1 (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES9802567A ES2156514B1 (es) 1998-12-04 1998-12-04 Materiales microporosos de alta superficie activos en reacciones de oxidacion.
PCT/ES1999/000393 WO2000034181A1 (es) 1998-12-04 1999-12-03 Materiales microporosos de alta superficie activos en reacciones de oxidacion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9802567A ES2156514B1 (es) 1998-12-04 1998-12-04 Materiales microporosos de alta superficie activos en reacciones de oxidacion.

Publications (2)

Publication Number Publication Date
ES2156514A1 true ES2156514A1 (es) 2001-06-16
ES2156514B1 ES2156514B1 (es) 2002-02-16

Family

ID=8306040

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9802567A Expired - Fee Related ES2156514B1 (es) 1998-12-04 1998-12-04 Materiales microporosos de alta superficie activos en reacciones de oxidacion.

Country Status (2)

Country Link
ES (1) ES2156514B1 (es)
WO (1) WO2000034181A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6114551A (en) * 1999-10-04 2000-09-05 Mobil Oil Corporation Olefin epoxidation catalysts
ES2178910B1 (es) * 1999-11-24 2003-12-16 Univ Valencia Politecnica Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6.
ES2179753B1 (es) 2000-10-11 2005-02-16 Universidad Politecnica De Valencia Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion gasolina.
ES2183710B1 (es) 2001-04-12 2004-01-16 Univ Valencia Politecnica Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.
US20090118372A1 (en) * 2004-11-23 2009-05-07 Adelaide Research & Innovation Pty Ltd. Inhibitors Of Biotin Protein Ligase

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5137861A (en) * 1991-01-22 1992-08-11 Mobil Oil Corp. Catalyst comprising a hydrogenation metal and a delaminated layered silicate
WO1997017290A1 (en) * 1995-11-08 1997-05-15 Shell Internationale Research Maatschappij B.V. Oxide materials and catalyst compositions containing them

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5137861A (en) * 1991-01-22 1992-08-11 Mobil Oil Corp. Catalyst comprising a hydrogenation metal and a delaminated layered silicate
WO1997017290A1 (en) * 1995-11-08 1997-05-15 Shell Internationale Research Maatschappij B.V. Oxide materials and catalyst compositions containing them

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CORMA, A. et al., Strategies to improve the epoxidation activity and selectivity of Ti-MCM-41, Chem. Commun. (Cambridge) 1998, (20), paginas 2211-2212, 21.10.1998. Todo el documento. *
MASCHMEYER, T., Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica, Nature, Vol. 378, paginas 159-162, 09.11.1995. Todo el documento. *

Also Published As

Publication number Publication date
WO2000034181A1 (es) 2000-06-15
ES2156514B1 (es) 2002-02-16

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