NL9420023A - Stabilisatiesysteem voor polypropeenvezels tegen verkleuring tijdens het verwerken en tegen verkleuring door warmte en licht. - Google Patents
Stabilisatiesysteem voor polypropeenvezels tegen verkleuring tijdens het verwerken en tegen verkleuring door warmte en licht. Download PDFInfo
- Publication number
- NL9420023A NL9420023A NL9420023A NL9420023A NL9420023A NL 9420023 A NL9420023 A NL 9420023A NL 9420023 A NL9420023 A NL 9420023A NL 9420023 A NL9420023 A NL 9420023A NL 9420023 A NL9420023 A NL 9420023A
- Authority
- NL
- Netherlands
- Prior art keywords
- amino
- bis
- triazine
- tert
- tetramethylpiperidin
- Prior art date
Links
- -1 polypropylene Polymers 0.000 title claims description 102
- 239000000835 fiber Substances 0.000 title claims description 78
- 239000004743 Polypropylene Substances 0.000 title claims description 67
- 229920001155 polypropylene Polymers 0.000 title claims description 67
- 230000006641 stabilisation Effects 0.000 title description 33
- 238000011105 stabilization Methods 0.000 title description 33
- 238000002845 discoloration Methods 0.000 title description 10
- 239000002530 phenolic antioxidant Substances 0.000 claims description 41
- 150000001412 amines Chemical class 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 35
- 238000006068 polycondensation reaction Methods 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 25
- 239000003381 stabilizer Substances 0.000 claims description 25
- 238000005562 fading Methods 0.000 claims description 23
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 16
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 14
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- YZXTWMQYSSMUFH-UHFFFAOYSA-N 4-[6-(1-amino-2,2,6,6-tetramethylpiperidin-4-yl)hexyl]-2,2,6,6-tetramethylpiperidin-1-amine Chemical compound C1C(C)(C)N(N)C(C)(C)CC1CCCCCCC1CC(C)(C)N(N)C(C)(C)C1 YZXTWMQYSSMUFH-UHFFFAOYSA-N 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000003760 tallow Substances 0.000 claims description 10
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 10
- 239000007983 Tris buffer Substances 0.000 claims description 8
- 230000007774 longterm Effects 0.000 claims description 8
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 claims description 7
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 7
- 230000000087 stabilizing effect Effects 0.000 claims description 7
- 239000001384 succinic acid Substances 0.000 claims description 7
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- UQAMDAUJTXFNAD-UHFFFAOYSA-N 4-(4,6-dichloro-1,3,5-triazin-2-yl)morpholine Chemical compound ClC1=NC(Cl)=NC(N2CCOCC2)=N1 UQAMDAUJTXFNAD-UHFFFAOYSA-N 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- WSLDIBCXIOECNX-UHFFFAOYSA-N octylhydrazine Chemical compound CCCCCCCCNN WSLDIBCXIOECNX-UHFFFAOYSA-N 0.000 claims description 5
- KTNPVRSKFWZJEZ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-1-amine Chemical compound CC1(C)CCCC(C)(C)N1N KTNPVRSKFWZJEZ-UHFFFAOYSA-N 0.000 claims description 4
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- ZEFSGHVBJCEKAZ-UHFFFAOYSA-N bis(2,4-ditert-butyl-6-methylphenyl) ethyl phosphite Chemical compound CC=1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1OP(OCC)OC1=C(C)C=C(C(C)(C)C)C=C1C(C)(C)C ZEFSGHVBJCEKAZ-UHFFFAOYSA-N 0.000 claims description 4
- ITUWQZXQRZLLCR-UHFFFAOYSA-N n,n-dioctadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCCCCCC ITUWQZXQRZLLCR-UHFFFAOYSA-N 0.000 claims description 4
- KCZIUKYAJJEIQG-UHFFFAOYSA-N 1,3,5-triazin-2-amine Chemical compound NC1=NC=NC=N1 KCZIUKYAJJEIQG-UHFFFAOYSA-N 0.000 claims description 3
- 230000015556 catabolic process Effects 0.000 claims description 3
- 238000006731 degradation reaction Methods 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- HMADMAFEFZHZLM-UHFFFAOYSA-N 2,4-dichloro-6-(2,4,4-trimethylpentan-2-yl)-2h-1,3,5-triazin-1-amine Chemical compound CC(C)(C)CC(C)(C)C1=NC(Cl)=NC(Cl)N1N HMADMAFEFZHZLM-UHFFFAOYSA-N 0.000 claims description 2
- NPYDPROENPLGBR-UHFFFAOYSA-N 4,6-dichloro-n-cyclohexyl-1,3,5-triazin-2-amine Chemical compound ClC1=NC(Cl)=NC(NC2CCCCC2)=N1 NPYDPROENPLGBR-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- IFVTZJHWGZSXFD-UHFFFAOYSA-N biphenylene Chemical group C1=CC=C2C3=CC=CC=C3C2=C1 IFVTZJHWGZSXFD-UHFFFAOYSA-N 0.000 claims description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 230000003247 decreasing effect Effects 0.000 claims 2
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000007789 gas Substances 0.000 description 27
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 18
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 10
- 238000009472 formulation Methods 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 239000000155 melt Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical group CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 150000002443 hydroxylamines Chemical class 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- IJSHDLMZAZXDIP-UHFFFAOYSA-N 1-[6-(3-amino-2,2,6,6-tetramethylpiperidin-1-yl)hexyl]-2,2,6,6-tetramethylpiperidin-3-amine Chemical compound NC1C(N(C(CC1)(C)C)CCCCCCN1C(C(CCC1(C)C)N)(C)C)(C)C IJSHDLMZAZXDIP-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ILPYHDWANUBJNJ-UHFFFAOYSA-N P(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C Chemical compound P(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C ILPYHDWANUBJNJ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000003878 thermal aging Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/019—Specific properties of additives the composition being defined by the absence of a certain additive
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4808693A | 1993-04-15 | 1993-04-15 | |
| US4808693 | 1993-04-15 | ||
| IB9400056 | 1994-04-06 | ||
| PCT/IB1994/000056 WO1994024344A1 (en) | 1993-04-15 | 1994-04-06 | Low color processing, heat and light stabilizer system for polypropylene fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL9420023A true NL9420023A (nl) | 1996-01-02 |
Family
ID=21952660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL9420023A NL9420023A (nl) | 1993-04-15 | 1994-04-06 | Stabilisatiesysteem voor polypropeenvezels tegen verkleuring tijdens het verwerken en tegen verkleuring door warmte en licht. |
Country Status (20)
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2705679B1 (fr) * | 1993-05-24 | 1998-07-10 | Sandoz Sa | Nouvelles compositions stabilisantes des matières polymères, à base de phosphonites ou phosphites et d'un stabilisant contre l'hydrolyse. |
| EP0710677A3 (de) * | 1994-11-03 | 1998-02-04 | Ciba SC Holding AG | Verfahren zur Herstellung von stabilisierten Olefinpolymeren |
| TW401437B (en) | 1995-02-10 | 2000-08-11 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
| DE69707838T2 (de) | 1996-02-12 | 2002-07-11 | Borealis A/S, Lyngby | Teilchen enthaltende fasern |
| CN1064416C (zh) * | 1996-05-02 | 2001-04-11 | 上海石油化工股份有限公司 | 可染细旦聚丙烯纤维的制造方法 |
| KR100227221B1 (ko) * | 1997-04-01 | 1999-11-01 | 이정국 | 발수성이 향상된 폴리프로필렌 섬유용 수지 조성물 및 이를 이용한 직물 |
| US5834541A (en) * | 1997-05-02 | 1998-11-10 | Montell North America Inc. | Olefin polymer composition having low smoke generation and fiber and film prepared therefrom |
| US5994436A (en) * | 1997-12-18 | 1999-11-30 | Montell North America Inc. | Ductile gamma radiation resistant polyolefin composition and articles produced therefrom |
| US6172153B1 (en) * | 1998-06-12 | 2001-01-09 | Montell North America Inc. | Olefin polymer composition having low smoke generation and fiber, film and fabric prepared therefrom |
| AU5788399A (en) * | 1998-08-26 | 2000-03-21 | Union Carbide Chemicals & Plastics Technology Corporation | Novel polypropylene compositions |
| US6214915B1 (en) * | 1998-12-10 | 2001-04-10 | General Electric Company | Stabilized thermoplastic compositions |
| NL1014465C2 (nl) * | 1999-03-01 | 2002-01-29 | Ciba Sc Holding Ag | Stabilisatorcombinatie voor het rotomoldingproces. |
| US6444733B1 (en) * | 1999-03-01 | 2002-09-03 | Ciba Specialty Chemicals Corporation | Stabilizer combination for the rotomolding process |
| JP2002097322A (ja) * | 2000-09-25 | 2002-04-02 | Grand Polymer Co Ltd | ポリプロピレン系樹脂組成物およびその成形品 |
| JP4785135B2 (ja) * | 2006-07-31 | 2011-10-05 | 三菱レイヨン株式会社 | ポリプロピレン系難燃繊維 |
| CN101195944B (zh) * | 2007-12-11 | 2011-09-07 | 卢宗广 | 无石棉环保节能型隔膜布及其织造方法 |
| KR101062997B1 (ko) | 2009-05-29 | 2011-09-07 | 코오롱글로텍주식회사 | 고내열성 및 내광성을 지닌 폴리프로필렌 단섬유 및 이의 제조방법, 이로 만들어진 부직포 |
| DE102010006364B4 (de) * | 2010-01-29 | 2015-07-23 | Carl Freudenberg Kg | Verwendung von sterisch gehinderten Aminen für oxidationsstabilisierte Polyolefine |
| CN106319665A (zh) * | 2015-06-15 | 2017-01-11 | 东丽纤维研究所（中国）有限公司 | 一种有色聚丙烯纤维及其制备方法 |
| MX2019003759A (es) * | 2016-11-09 | 2019-07-04 | Borealis Ag | Composicion de polipropileno. |
| JP7584228B2 (ja) * | 2019-04-26 | 2024-11-15 | 株式会社コーセー | マニュキュア容器 |
| GB2584305B (en) * | 2019-05-30 | 2022-07-13 | Si Group Switzerland Chaa Gmbh | Antidegradant blend |
| CN110229421B (zh) * | 2019-07-02 | 2021-11-09 | 中广核俊尔(浙江)新材料有限公司 | 一种耐高温注塑聚丙烯材料及其制备方法和应用 |
| CN111057288A (zh) * | 2019-12-12 | 2020-04-24 | 宿迁联盛科技股份有限公司 | 一种防聚烯烃共聚物光老化、防聚烯烃红变的组合物 |
| CN116355303A (zh) * | 2023-03-16 | 2023-06-30 | 天津利安隆新材料股份有限公司 | 一种高分子材料组合物及其在es纤维中的应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH626385A5 (enrdf_load_stackoverflow) * | 1976-02-05 | 1981-11-13 | Ciba Geigy Ag | |
| US4590231A (en) * | 1983-10-11 | 1986-05-20 | Ciba-Geigy Corporation | Polyolefin compositions stabilized against degradation using hydroxylamine derivatives |
| JPS60190443A (ja) * | 1984-03-13 | 1985-09-27 | Mitsui Toatsu Chem Inc | 放射線に安定なポリプロピレン樹脂組成物 |
| JP2553537B2 (ja) * | 1987-01-23 | 1996-11-13 | 東燃化学 株式会社 | ポレプロピレン繊維防糸用組成物 |
| US4876300A (en) * | 1987-12-30 | 1989-10-24 | Ciba-Geigy Corporation | Polyolefin compositions stabilized with long chain N,N-dialkylhydroxylamines |
-
1994
- 1994-03-26 TW TW083102663A patent/TW268052B/zh not_active IP Right Cessation
- 1994-04-06 WO PCT/IB1994/000056 patent/WO1994024344A1/en active Application Filing
- 1994-04-06 RU RU95120604A patent/RU2126065C1/ru active
- 1994-04-06 CN CN94191786A patent/CN1051340C/zh not_active Expired - Lifetime
- 1994-04-06 DE DE4492361T patent/DE4492361T1/de active Granted
- 1994-04-06 HK HK98104631A patent/HK1005489A1/xx not_active IP Right Cessation
- 1994-04-06 NL NL9420023A patent/NL9420023A/nl active Search and Examination
- 1994-04-06 AT AT0903394A patent/AT405412B/de not_active IP Right Cessation
- 1994-04-06 CA CA002160574A patent/CA2160574C/en not_active Expired - Lifetime
- 1994-04-06 SK SK1272-95A patent/SK284817B6/sk not_active IP Right Cessation
- 1994-04-06 AU AU62632/94A patent/AU6263294A/en not_active Abandoned
- 1994-04-06 GB GB9520527A patent/GB2292944B/en not_active Expired - Lifetime
- 1994-04-06 KR KR1019950704499A patent/KR100282620B1/ko not_active Expired - Lifetime
- 1994-04-06 JP JP52295194A patent/JP3424080B2/ja not_active Expired - Lifetime
- 1994-04-06 BR BR9406876A patent/BR9406876A/pt not_active IP Right Cessation
- 1994-04-06 DE DE4492361A patent/DE4492361C2/de not_active Expired - Lifetime
- 1994-04-14 IT ITMI940706A patent/IT1269313B/it active IP Right Grant
- 1994-04-14 FR FR9404431A patent/FR2704009B1/fr not_active Expired - Lifetime
- 1994-04-14 BE BE9400382A patent/BE1006850A3/fr not_active IP Right Cessation
-
1995
- 1995-10-03 NO NO953932A patent/NO309683B1/no not_active IP Right Cessation
- 1995-10-04 DK DK199501109A patent/DK175151B1/da not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR100282620B1 (ko) | 2001-02-15 |
| DK175151B1 (da) | 2004-06-21 |
| CN1121362A (zh) | 1996-04-24 |
| GB9520527D0 (en) | 1995-12-13 |
| RU2126065C1 (ru) | 1999-02-10 |
| HK1005489A1 (en) | 1999-01-08 |
| JPH08509031A (ja) | 1996-09-24 |
| AU6263294A (en) | 1994-11-08 |
| NO953932L (no) | 1995-10-03 |
| AT405412B (de) | 1999-08-25 |
| GB2292944A (en) | 1996-03-13 |
| CN1051340C (zh) | 2000-04-12 |
| SK127295A3 (en) | 1996-11-06 |
| CA2160574C (en) | 2004-02-03 |
| GB2292944B (en) | 1997-12-10 |
| KR960702018A (ko) | 1996-03-28 |
| SK284817B6 (sk) | 2005-12-01 |
| CA2160574A1 (en) | 1994-10-27 |
| FR2704009B1 (fr) | 1995-06-30 |
| BR9406876A (pt) | 1996-04-02 |
| TW268052B (enrdf_load_stackoverflow) | 1996-01-11 |
| NO953932D0 (no) | 1995-10-03 |
| WO1994024344A1 (en) | 1994-10-27 |
| DE4492361C2 (de) | 2003-10-16 |
| ITMI940706A0 (it) | 1994-04-14 |
| BE1006850A3 (fr) | 1995-01-03 |
| DE4492361T1 (de) | 1997-08-21 |
| IT1269313B (it) | 1997-03-26 |
| FR2704009A1 (fr) | 1994-10-21 |
| ITMI940706A1 (it) | 1995-10-14 |
| ATA903394A (de) | 1998-12-15 |
| NO309683B1 (no) | 2001-03-12 |
| DK110995A (da) | 1995-10-04 |
| JP3424080B2 (ja) | 2003-07-07 |
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