GB2292944A - Low colour processing heat and light stabilizer system for polypropylene fiber - Google Patents

Low colour processing heat and light stabilizer system for polypropylene fiber

Info

Publication number
GB2292944A
GB2292944A GB9520527A GB9520527A GB2292944A GB 2292944 A GB2292944 A GB 2292944A GB 9520527 A GB9520527 A GB 9520527A GB 9520527 A GB9520527 A GB 9520527A GB 2292944 A GB2292944 A GB 2292944A
Authority
GB
United Kingdom
Prior art keywords
light stabilizer
polypropylene fiber
stabilizer system
processing heat
low colour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB9520527A
Other versions
GB2292944B (en
GB9520527D0 (en
Inventor
Douglas W Horsey
Iii Roswell E King
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB9520527D0 publication Critical patent/GB9520527D0/en
Publication of GB2292944A publication Critical patent/GB2292944A/en
Application granted granted Critical
Publication of GB2292944B publication Critical patent/GB2292944B/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/32—Compounds containing nitrogen bound to oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/527—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/019—Specific properties of additives the composition being defined by the absence of a certain additive

Abstract

Blends of long chain N,N-dialkylhydroxylamines, selected phosphites and selected hindered amines are suprisingly effective in providing processing, long term heat aging and light stability performance and especially gas fade resistance to polypropylene fibers in the absence of a traditionally used phenolic antioxidant.
GB9520527A 1993-04-15 1994-04-06 Low color processing, heat and light stabilizer system for polypropylene fiber Expired - Lifetime GB2292944B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US4808693A 1993-04-15 1993-04-15
PCT/IB1994/000056 WO1994024344A1 (en) 1993-04-15 1994-04-06 Low color processing, heat and light stabilizer system for polypropylene fiber

Publications (3)

Publication Number Publication Date
GB9520527D0 GB9520527D0 (en) 1995-12-13
GB2292944A true GB2292944A (en) 1996-03-13
GB2292944B GB2292944B (en) 1997-12-10

Family

ID=21952660

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9520527A Expired - Lifetime GB2292944B (en) 1993-04-15 1994-04-06 Low color processing, heat and light stabilizer system for polypropylene fiber

Country Status (20)

Country Link
JP (1) JP3424080B2 (en)
KR (1) KR100282620B1 (en)
CN (1) CN1051340C (en)
AT (1) AT405412B (en)
AU (1) AU6263294A (en)
BE (1) BE1006850A3 (en)
BR (1) BR9406876A (en)
CA (1) CA2160574C (en)
DE (2) DE4492361T1 (en)
DK (1) DK175151B1 (en)
FR (1) FR2704009B1 (en)
GB (1) GB2292944B (en)
HK (1) HK1005489A1 (en)
IT (1) IT1269313B (en)
NL (1) NL9420023A (en)
NO (1) NO309683B1 (en)
RU (1) RU2126065C1 (en)
SK (1) SK284817B6 (en)
TW (1) TW268052B (en)
WO (1) WO1994024344A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2278362B (en) * 1993-05-24 1997-08-13 Sandoz Ltd Processing stabiliser composition for polymers
GB2347426A (en) * 1999-03-01 2000-09-06 Ciba Sc Holding Ag Stabilizer combination for use in rotomolding polyolefins

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0710677A3 (en) * 1994-11-03 1998-02-04 Ciba SC Holding AG Process for producing stabilized olefin polymers
TW401437B (en) 1995-02-10 2000-08-11 Ciba Sc Holding Ag Synergistic stabilizer mixture
BR9707421A (en) 1996-02-12 2000-01-04 Fibervisions As Fibers containing particles
CN1064416C (en) * 1996-05-02 2001-04-11 上海石油化工股份有限公司 Method for manufacturing dyeable fine denier polypropylene fibre
KR100227221B1 (en) * 1997-04-01 1999-11-01 이정국 A polypropylene resin fiber composition having improved water-resistance and the textile using their fibers
US5834541A (en) * 1997-05-02 1998-11-10 Montell North America Inc. Olefin polymer composition having low smoke generation and fiber and film prepared therefrom
US5994436A (en) * 1997-12-18 1999-11-30 Montell North America Inc. Ductile gamma radiation resistant polyolefin composition and articles produced therefrom
US6172153B1 (en) * 1998-06-12 2001-01-09 Montell North America Inc. Olefin polymer composition having low smoke generation and fiber, film and fabric prepared therefrom
AU5788399A (en) * 1998-08-26 2000-03-21 Union Carbide Chemicals & Plastics Technology Corporation Novel polypropylene compositions
US6214915B1 (en) * 1998-12-10 2001-04-10 General Electric Company Stabilized thermoplastic compositions
US6444733B1 (en) * 1999-03-01 2002-09-03 Ciba Specialty Chemicals Corporation Stabilizer combination for the rotomolding process
JP2002097322A (en) * 2000-09-25 2002-04-02 Grand Polymer Co Ltd Polypropylene-based resin composition and molded product therefrom
JP4785135B2 (en) * 2006-07-31 2011-10-05 三菱レイヨン株式会社 Polypropylene flame retardant fiber
CN101195944B (en) * 2007-12-11 2011-09-07 卢宗广 Non-zillerite environment protection energy-saving diaphragm cloth and weaving method thereof
KR101062997B1 (en) 2009-05-29 2011-09-07 코오롱글로텍주식회사 Polypropylene short fibers with high heat resistance and light resistance, manufacturing method thereof, nonwoven fabric made therefrom
DE102010006364B4 (en) * 2010-01-29 2015-07-23 Carl Freudenberg Kg Use of sterically hindered amines for oxidation-stabilized polyolefins
CN106319665A (en) * 2015-06-15 2017-01-11 东丽纤维研究所（中国）有限公司 Colored polypropylene fiber and preparation method thereof
MX2019003759A (en) 2016-11-09 2019-07-04 Borealis Ag Polypropylene composition.
GB2584305B (en) * 2019-05-30 2022-07-13 Si Group Switzerland Chaa Gmbh Antidegradant blend
CN110229421B (en) * 2019-07-02 2021-11-09 中广核俊尔(浙江)新材料有限公司 High-temperature-resistant injection molding polypropylene material and preparation method and application thereof
CN111057288A (en) * 2019-12-12 2020-04-24 宿迁联盛科技股份有限公司 Composition for preventing polyolefin copolymer from photo-aging and polyolefin red-change

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0138767A1 (en) * 1983-10-11 1985-04-24 Ciba-Geigy Ag Stabilized polyolefinic compounds containing hydroxylamine derivatives
EP0276923A2 (en) * 1987-01-23 1988-08-03 Tonen Chemical Corporation Polyolefin composition
EP0323409A2 (en) * 1987-12-30 1989-07-05 Ciba-Geigy Ag Polyolefin compositions stabilized with long chain N,N-dialkylhydroxylamines

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60190443A (en) * 1984-03-13 1985-09-27 Mitsui Toatsu Chem Inc Polypropylene resin composition stable to radiation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0138767A1 (en) * 1983-10-11 1985-04-24 Ciba-Geigy Ag Stabilized polyolefinic compounds containing hydroxylamine derivatives
EP0276923A2 (en) * 1987-01-23 1988-08-03 Tonen Chemical Corporation Polyolefin composition
EP0323409A2 (en) * 1987-12-30 1989-07-05 Ciba-Geigy Ag Polyolefin compositions stabilized with long chain N,N-dialkylhydroxylamines

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2278362B (en) * 1993-05-24 1997-08-13 Sandoz Ltd Processing stabiliser composition for polymers
GB2347426A (en) * 1999-03-01 2000-09-06 Ciba Sc Holding Ag Stabilizer combination for use in rotomolding polyolefins
GB2347426B (en) * 1999-03-01 2001-10-10 Ciba Sc Holding Ag Stabilizer combination for rotomolding polyolefins

Also Published As

Publication number Publication date
GB2292944B (en) 1997-12-10
FR2704009A1 (en) 1994-10-21
WO1994024344A1 (en) 1994-10-27
CA2160574C (en) 2004-02-03
IT1269313B (en) 1997-03-26
CN1051340C (en) 2000-04-12
KR960702018A (en) 1996-03-28
CN1121362A (en) 1996-04-24
AU6263294A (en) 1994-11-08
HK1005489A1 (en) 1999-01-08
NO953932L (en) 1995-10-03
BE1006850A3 (en) 1995-01-03
DK175151B1 (en) 2004-06-21
FR2704009B1 (en) 1995-06-30
NO953932D0 (en) 1995-10-03
RU2126065C1 (en) 1999-02-10
BR9406876A (en) 1996-04-02
DE4492361C2 (en) 2003-10-16
NL9420023A (en) 1996-01-02
GB9520527D0 (en) 1995-12-13
KR100282620B1 (en) 2001-02-15
DE4492361T1 (en) 1997-08-21
ATA903394A (en) 1998-12-15
SK127295A3 (en) 1996-11-06
TW268052B (en) 1996-01-11
CA2160574A1 (en) 1994-10-27
NO309683B1 (en) 2001-03-12
ITMI940706A1 (en) 1995-10-14
JP3424080B2 (en) 2003-07-07
DK110995A (en) 1995-10-04
ITMI940706A0 (en) 1994-04-14
JPH08509031A (en) 1996-09-24
AT405412B (en) 1999-08-25
SK284817B6 (en) 2005-12-01

Similar Documents

Publication Publication Date Title
GB2292944A (en) Low colour processing heat and light stabilizer system for polypropylene fiber
NO171821C (en) CULTURE BLOCKS, LIKE A CULTURAL Plug, A CULTURAL Plug System,
IL106697A0 (en) Cutting insert with integral clamping means
EP0608074A3 (en) Bleed alleviation using PH-sensitive dyes.
FR2726755B1 (en)
AU4222497A (en) Compound having alkadienyl group as side chain, and liquid crystal composition using same
ATA35789A (en) CLAMPING BUSH, IN PARTICULAR SPRING CLAMP SLEEVE
ES2160706T3 (en) RUBBER ITEMS WITH A PERMEABILITY TO GASES.
ES2106920T3 (en) COMPOSITION THAT ALLOWS THERMAL STABILIZATION OF PROTEINS AND PRODUCT OBTAINED IN THIS WAY.
AU7742594A (en) Novel compositions
ES2153032T3 (en) METHOD AND APPLIANCE TO INSERT DIVISION ELEMENTS BETWEEN ARTICLES.
ES2175059T3 (en) COLOR MIXTURES, PROCEDURE FOR OBTAINING AND USING THEMSELVES.
HU9301030D0 (en) An acetylene derivative hqving retinoide-like effect being substituted with phenyl group and chromanyl, thio-chromanyl or tetra-hydro-quinoline one
DE69005429D1 (en) Phenolic antioxidant composition.
BR9607313A (en) Tube coupling to fix a tube to a coupling piece and process to fix a tube
DE59002689D1 (en) Wrap-around frame.
DE69716020D1 (en) Luminaire, in particular safety lighting block
ES2163121T3 (en) SOFTENING COMPOSITION FOR FABRICS.
DE9417339U1 (en) Arrangement for holding an optical fiber arc detector in switchgear, in particular low-voltage switchgear
FR2751510B1 (en) PRESERVED CUT VEGETAL
DE59005604D1 (en) Burner insert, in particular for candle-shaped illuminants.
ES1029098U (en) Improved socket. (Machine-translation by Google Translate, not legally binding)
SE9300458D0 (en) FIBER LIGHTING FOR CANDLE, CHRISTMAS OR EQUIVALENT
KR950005364U (en) Cigarettes with blue and red lines
DE9400476U1 (en) Shock cooling system, especially for asparagus

Legal Events

Date Code Title Description
732E Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977)
PE20 Patent expired after termination of 20 years

Expiry date: 20140405