KR970028873A - 내식막용 박리액 조성물 및 이를 사용한 내식막 박리 방법 - Google Patents

내식막용 박리액 조성물 및 이를 사용한 내식막 박리 방법 Download PDF

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KR970028873A
KR970028873A KR1019960053572A KR19960053572A KR970028873A KR 970028873 A KR970028873 A KR 970028873A KR 1019960053572 A KR1019960053572 A KR 1019960053572A KR 19960053572 A KR19960053572 A KR 19960053572A KR 970028873 A KR970028873 A KR 970028873A
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마사히토 다나베
가즈마사 와키야
마사카즈 고바야시
도시마사 나카야마
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나카네 히사시
도쿄 오카 고교 가부시키가이샤
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/30Imagewise removal using liquid means
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/42Stripping or agents therefor
    • G03F7/422Stripping or agents therefor using liquids only
    • G03F7/423Stripping or agents therefor using liquids only containing mineral acids or salts thereof, containing mineral oxidizing substances, e.g. peroxy compounds
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/42Stripping or agents therefor
    • G03F7/422Stripping or agents therefor using liquids only
    • G03F7/425Stripping or agents therefor using liquids only containing mineral alkaline compounds; containing organic basic compounds, e.g. quaternary ammonium compounds; containing heterocyclic basic compounds containing nitrogen

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 (a) 불화수소산과 금속 비함유 염기와의 염, (b) 수용성 유기용매, (c) 물 및 임의의 (d) 내부식제를 포함하는 pH 5 내지 8의 내식막용 박리액 조성물에 관한 것이다. 내식막을 박리시키는 방법은 (1) 금속 필름을 갖는 기판상에 내식막층을 형성하는 단계, (2) 마스크 패턴을 통해 내식막층을 노광시키고, 내식막층을 현상하여 내식막 패턴을 형성하는 단계 및 (3) 마스크로서 내식막 패턴을 사용하여 기판을 건식-에칭시키고, 불필요한 내식막 및 변형된 내식막 필름을 박리액 조성물로 박리시키는 단계를 포함한다.

Description

내식막용 박리액 조성물 및 이를 사용한 내식막 박리 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. (a) 불화수소산과 금속 비함유 염기와의 염, (b) 수용성 유기 용매 및 (c) 물을 포함하는, pH 5 내지 8의 내식막용 박리액 조성물.
  2. 제1항에 있어서, 성분 (a)의 함량이 0.2 내지 8중량%이고 성분 (b)의 함량이 30 내지 90중량%이며 그 나머지가 성분(c)인 내식막용 박리액 조성물.
  3. 제1항에 있어서, 성분 (d)로서 내부식제를 추가로 포함하는 내식막용 박리액 조성물.
  4. 제3항에 있어서, 성분 (a)의 함량이 0.2 내지 8중량%이고 성분 (b)의 함량이 40 내지 80중량%이며 성분 (d)의 함량이 0.5 내지 15중량%이고 그 나머지가 성분 (c)인 내식막용 박리액 조성물.
  5. 제1항에 있어서, 성분 (a)가 하이드로실아민, 1급, 2급 또는 3급 지방족, 지환족, 방향족 및 헤테로사이클릭 아민, 암모니아수 및 탄소수 1 내지 4의 저급 알킬 4급 암모늄염 그룹중에서 선택된 하나 이상의 금속 비함유 염기와 불화수소산과의 염인 내식막용 박리액 조성물.
  6. 제5항에 있어서, 성분 (a)가 불화암모늄인 내식막용 박리액 조성물.
  7. 제1항에 있어서, 성분 (b)가 디에틸 설폭사이드, N,N-디메틸포름아미드, N,N-디메틸아세트아미드, N-메틸-2-피롤리돈, 1,3-디메딜-2-이미다졸리디논, 에틸렌 글리콜 및 디에틸렌 글리콜 모노부틸 에테르중에서 선택된 하나 이상의 성분인 내식막용 박리액 조성물.
  8. 제7항에 있어서, 성분 (b)가 에틸렌 글리콜 10중량% 이상을 포함하는 수용성 유기 용액인 내식막용 박리액 조성물.
  9. 제3항에 있어서, 성분 (d)가 방향족 하이드록실 화합물, 아세틸렌 알콜, 카복실 그룹-함유 유기 화합물 및 이의 무수물, 트리아졸 화합물 및 당류중에서 선택된 하나 이상의 성분인 내식막용 박리액 조성물.
  10. (1) 금속 필름을 갖는 기판상에 내식막 층을 형성시키는 단계, (2) 마스크 패턴을 통해 내식막 층을 노광시킨 후, 내식막층을 현상하여 내식막 패턴을 형성하는 단계 및 (3) 마스크로서 내식막 패턴을 사용하여 기판을 건식-에칭시킨 후, 불필요한 내식막 및 변형된 내식막 필름을, (a) 금속 비함유 염기와 불화수소산과의 염, (b) 수용성 유기 용매 및 (c) 물을 포함하는 pH 5 내지 8의 내식막용 박리액 조성물로 박리시키는 단계를 포함하는, 내식막 박리방법.
  11. 제10항에 있어서, 성분 (a)의 함량이 0.2 내지 8중량%이고 성분 (b)의 함량이 30 내지 90중량%이며 그 나머지가 성분 (c)인 방법.
  12. 제10항에 있어서, 내식막용 박리액 조성물이 성분 (d)로서 내부식제를 추가로 포함하는 방법.
  13. 제12항에 있어서, 성분 (a)의 함량이 0.2 내지 8중량%이고 성분 (b)의 함량이 40 내지 80중량%이며 성분 (d)의 함량이 0.5 내지 15중량%이고 그 나머지가 성분 (c)인 방법.
  14. 제10항에 있어서, 성분 (a)가 하이드록실아민, 1급, 2급 또는 3급 지방족, 지환족, 방향족 및 헤테로사이클릭 아민, 암모니아수 및 탄소수 1 내지 4의 저급 알킬 4급 암모늄염 그룹중에서 선택된 하나 이상의 금속 비함유 염기와 불화수소산과의 염인 방법.
  15. 제10항에 있어서, 성분 (a)가 불화암모늄인 방법.
  16. 제10항에 있어서, 성분 (b)가 디에틸 설폭사이드, N,N-디메틸포름아미드, N,N-디메틸아세트아미드, N-메틸-2-피롤리돈, 1,3-디에틸-2-이미다졸리디논, 에틸렌 글리콜 및 디에틸렌 글리콜 모노부틸 에테르중에서 선택된 하나 이상의 성분인 방법.
  17. 제16항에 있어서, 성분 (b)가 에틸렌 글리콜 10중량% 이상을 포함하는 수용성 유기 용매인 방법.
  18. 제12항에 있어서, 성분 (d)가 방향족 하이드록실 화합물, 아세틸렌 알콜, 카복실 그룹-함유 유기 화합물 및 이의 무수물, 트리아졸 화합물 및 당류중에서 선택된 하나 이상의 성분인 방법.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019960053572A 1995-11-13 1996-11-13 내식막용 박리액 조성물 및 이를 사용한 내식막 박리 방법 KR100222513B1 (ko)

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Application Number Priority Date Filing Date Title
JP95-317035 1995-11-13
JP31703595 1995-11-13
JP17987296A JP3236220B2 (ja) 1995-11-13 1996-06-21 レジスト用剥離液組成物
JP96-179872 1996-06-21

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KR970028873A true KR970028873A (ko) 1997-06-24
KR100222513B1 KR100222513B1 (ko) 1999-10-01

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US (2) US5792274A (ko)
EP (1) EP0773480B1 (ko)
JP (1) JP3236220B2 (ko)
KR (1) KR100222513B1 (ko)
DE (1) DE69620848T2 (ko)
TW (1) TW439018B (ko)

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