KR970027154A - 예비-성형된 규소 개질된 유기 중합체의 가교결합된 에멀젼 - Google Patents

예비-성형된 규소 개질된 유기 중합체의 가교결합된 에멀젼 Download PDF

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KR970027154A
KR970027154A KR1019960051646A KR19960051646A KR970027154A KR 970027154 A KR970027154 A KR 970027154A KR 1019960051646 A KR1019960051646 A KR 1019960051646A KR 19960051646 A KR19960051646 A KR 19960051646A KR 970027154 A KR970027154 A KR 970027154A
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organic polymer
modified organic
polymer
silicon
group
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KR1019960051646A
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KR100304995B1 (ko
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에릭 쥬드 조프레
아서 제임스 첼레피스
안드레아스 토마스 프란츠 볼프
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루이스 노만 에드워드
다우 코닝 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08L101/10—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08J2300/108—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

본 발명은 규소 개질된 유기 중합체, 규소 개질된 유기 중합체의 혼합물, 규소 개질된 유기 중합체(들)와 통상의 유기 중합체와의 혼합물, 규소 개질된 유기 중합체(들)와 실록산 중합체와의 혼합물, 알케닐 그룹을 함유하는 유기 중합체와 실록산 중합체와의 혼합물, 알케닐 그룹을 함유하는 유기 중합체와 규소 개질된 유기 중합체와의 혼합물, 상기 중합체의 혼합물 및 상기 중합체(들)와 유기 가소제 또는 용매와의 혼합물로 이루어진 그룹으로부터 선택된 예비성형된 중합체를 포함하는 가교결합된 중합체 분산액에 관한 것이다.

Description

예비-성형된 규소 개질된 유기 중합체의 가교결합된 에멀젼
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (1)

  1. 규소 개질된 유기 중합체(a)[여기서, 규소 개질된 유기 중합체는 점도가 5 내지 500Paㆍs이고, 유리전이온도가 20℃ 이하이며 화학식(1)의 치환체를 1 내지 5개를 갖는 유기 중합체이다] 100중량부, 계면활성제(b) 0.5 내지 10중량부 및 물(c) 0.5 내지 1000중량부로 이루어진 예비혼합물을 형성하는 단계, 예비혼합물을 교반하여 에멀젼을 형성하는 단계 및 에멀젼 중에서 규소 개질된 유기 중합체의 가교결합을 촉진하는 단계를 포함하여, 가교결합된 규소 개질된 유기 중합체의 수성 분산액을 형성하는 방법.
    -Y-(XbR1 2-bSiO)mSiXaR1 3-a(I)
    상기 화학식 (1)에서, R1은 동일하거나 상이하고 탄소수 1 내지 20의 알킬, 알케닐, 아릴 또는 아르알킬 그룹 또는 화학식R2 3SiO-의 트리오가노실록시 그룹(여기서, R2는 독립적으로 탄소수 1 내지 20의 1가 탄화수소 그룹이다)이고, X는 동일하거나 상이하며 하이드록실 그룹, 축합성 또는 가수분해성 그룹이며, Y는 유기 중합체 및 치환체의 규소 원자에 가수분해적으로 안정한 결합을 형성하는 2가 그룹이고, a는 0 내지 3의 정수이며, b는 0 내지 2의 정수인데, 단, a가 0인 경우, 치환제의 하나 이상의 실록산 단위에서 b는 1 또는 2이며, m은 0 내지 19의 정수인데, 단, m이 0인 경우, a는 1,2 또는 3이다.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960051646A 1995-11-02 1996-11-02 가교결합되고 규소 개질된 유기중합체의 수성분산액을 형성하는 방법 KR100304995B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/552,162 1995-11-02
US08/552,162 US5840800A (en) 1995-11-02 1995-11-02 Crosslinked emulsions of pre-formed silicon modified organic polymers

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KR970027154A true KR970027154A (ko) 1997-06-24
KR100304995B1 KR100304995B1 (ko) 2001-11-22

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US (1) US5840800A (ko)
EP (1) EP0771855B1 (ko)
JP (1) JPH09165454A (ko)
KR (1) KR100304995B1 (ko)
CN (1) CN1071349C (ko)
AU (1) AU703181B2 (ko)
CA (1) CA2189195A1 (ko)
DE (1) DE69628714T2 (ko)
TW (1) TW322499B (ko)

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CA2189195A1 (en) 1997-05-03
EP0771855A3 (en) 1997-11-12
EP0771855A2 (en) 1997-05-07
DE69628714T2 (de) 2004-04-22
US5840800A (en) 1998-11-24
TW322499B (ko) 1997-12-11
EP0771855B1 (en) 2003-06-18
AU7055196A (en) 1997-05-08
KR100304995B1 (ko) 2001-11-22
JPH09165454A (ja) 1997-06-24
DE69628714D1 (de) 2003-07-24
CN1151998A (zh) 1997-06-18
AU703181B2 (en) 1999-03-18
CN1071349C (zh) 2001-09-19

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