KR960011047B1 - 에틸렌 옥사이드의 촉매적 제조를 위한 촉매 및 그 제조방법 - Google Patents
에틸렌 옥사이드의 촉매적 제조를 위한 촉매 및 그 제조방법 Download PDFInfo
- Publication number
- KR960011047B1 KR960011047B1 KR1019870012263A KR870012263A KR960011047B1 KR 960011047 B1 KR960011047 B1 KR 960011047B1 KR 1019870012263 A KR1019870012263 A KR 1019870012263A KR 870012263 A KR870012263 A KR 870012263A KR 960011047 B1 KR960011047 B1 KR 960011047B1
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- silver
- rhenium
- metal
- cesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Television Signal Processing For Recording (AREA)
- Analogue/Digital Conversion (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/926,025 US4766105A (en) | 1986-10-31 | 1986-10-31 | Ethylene oxide catalyst and process for preparing the catalyst |
| US926025 | 1986-10-31 | ||
| US06/926,026 US4761394A (en) | 1986-10-31 | 1986-10-31 | Ethylene oxide catalyst and process for preparing the catalyst |
| US926,025 | 1986-10-31 | ||
| US926026 | 1992-08-07 | ||
| US926,026 | 1992-08-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR880004850A KR880004850A (ko) | 1988-06-27 |
| KR960011047B1 true KR960011047B1 (ko) | 1996-08-16 |
Family
ID=27129915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019870012263A Expired - Lifetime KR960011047B1 (ko) | 1986-10-31 | 1987-10-30 | 에틸렌 옥사이드의 촉매적 제조를 위한 촉매 및 그 제조방법 |
Country Status (33)
| Country | Link |
|---|---|
| EP (1) | EP0266015B1 (enExample) |
| JP (1) | JP2619660B2 (enExample) |
| KR (1) | KR960011047B1 (enExample) |
| CN (1) | CN1013481B (enExample) |
| AT (1) | ATE69977T1 (enExample) |
| AU (1) | AU592478B2 (enExample) |
| BG (1) | BG60854B1 (enExample) |
| BR (1) | BR8705810A (enExample) |
| CA (1) | CA1304346C (enExample) |
| CS (2) | CS272779B2 (enExample) |
| DE (1) | DE3774999D1 (enExample) |
| DK (1) | DK170916B1 (enExample) |
| DZ (1) | DZ1139A1 (enExample) |
| EG (1) | EG18719A (enExample) |
| ES (1) | ES2028860T3 (enExample) |
| FI (1) | FI89681C (enExample) |
| GR (1) | GR3003662T3 (enExample) |
| HU (1) | HU202132B (enExample) |
| IE (1) | IE60557B1 (enExample) |
| IL (1) | IL84232A (enExample) |
| IN (1) | IN169589B (enExample) |
| MA (1) | MA21096A1 (enExample) |
| MX (1) | MX170627B (enExample) |
| MY (1) | MY102984A (enExample) |
| NO (1) | NO173219C (enExample) |
| NZ (1) | NZ222342A (enExample) |
| PH (1) | PH25304A (enExample) |
| PL (1) | PL157773B1 (enExample) |
| PT (1) | PT86038B (enExample) |
| RU (1) | RU1831369C (enExample) |
| SG (1) | SG126392G (enExample) |
| TR (1) | TR26675A (enExample) |
| YU (2) | YU46082B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120046706A (ko) * | 2010-11-02 | 2012-05-10 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 알루미나 지지체, 그 제조 방법, 및 그로부터 제조된 은 촉매, 그리고 그 용도 |
Families Citing this family (146)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8626687D0 (en) * | 1986-11-07 | 1986-12-10 | Shell Int Research | Preparing silver catalyst |
| US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5057481A (en) * | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| GB8810006D0 (en) * | 1988-04-27 | 1988-06-02 | Shell Int Research | Process for preparation of ethylene oxide |
| US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| CA1339317C (en) * | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
| DE68925767T2 (de) * | 1988-08-30 | 1996-08-14 | Union Carbide Corp | Katalysatoren für die Herstellung von Ethylenoxid und Verfahren zur deren Herstellung |
| US5187140A (en) * | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
| US5145824A (en) * | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
| US5100859A (en) * | 1991-01-22 | 1992-03-31 | Norton Company | Catalyst carrier |
| US5407888A (en) * | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
| KR100296941B1 (ko) * | 1993-07-28 | 2001-10-22 | 유현식 | 산화에틸렌제조용은담지촉매 |
| US5447897A (en) * | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
| PL176216B1 (pl) * | 1993-07-07 | 1999-05-31 | Shell Int Research | Katalizator epoksydowania oraz sposób wytwarzania katalizatora epoksydowania |
| US5364826A (en) * | 1993-09-13 | 1994-11-15 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| US5418202A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5545603A (en) * | 1994-11-01 | 1996-08-13 | Shell Oil Company | Ethylene oxide catalyst and process |
| EP0789693B1 (en) * | 1994-11-01 | 1999-01-07 | Shell Internationale Researchmaatschappij B.V. | Process for preparing ethylene oxide catalysts |
| JP4172827B2 (ja) † | 1994-12-15 | 2008-10-29 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 酸化エチレン触媒の製造方法 |
| EA000106B1 (ru) * | 1995-04-18 | 1998-08-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ каталитического газофазного окисления этилена |
| US5705661A (en) * | 1995-09-25 | 1998-01-06 | Mitsubishi Chemical Corporation | Catalyst for production of ethylene oxide |
| US5703001A (en) * | 1996-10-25 | 1997-12-30 | Scientific Design Company, Inc. | Promoted silver catalyst |
| US5736483A (en) * | 1996-10-25 | 1998-04-07 | Scientific Design Co., Inc. | Niobium or tantalum promoted silver catalyst |
| US5864047A (en) * | 1997-04-10 | 1999-01-26 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing rhenium and potassium promoters |
| US5780656A (en) * | 1997-04-14 | 1998-07-14 | Scientific Design Company, Inc. | Ethylene oxide catalyst and process |
| US5905053A (en) * | 1997-09-02 | 1999-05-18 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
| US5854167A (en) * | 1997-09-02 | 1998-12-29 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
| US5958824A (en) * | 1997-09-02 | 1999-09-28 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
| EP1125632A1 (en) | 2000-02-07 | 2001-08-22 | Bayer Aktiengesellschaft | Process for the epoxidation of olefins using gold-containing catalysts |
| US6372925B1 (en) | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
| JP5089008B2 (ja) | 2000-09-26 | 2012-12-05 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 反応管におけるロッド状インサート |
| US6509485B2 (en) * | 2001-02-22 | 2003-01-21 | Sri International | Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts |
| US7193094B2 (en) | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| US20030162984A1 (en) * | 2002-02-25 | 2003-08-28 | Lockemeyer John Robert | Catalyst and a process using the catalyst |
| US6831037B2 (en) | 2002-02-25 | 2004-12-14 | Saint-Gobain Norpro Corporation | Catalyst carriers |
| US6750173B2 (en) | 2002-04-08 | 2004-06-15 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
| AU2003243757A1 (en) * | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| MX245604B (es) | 2002-06-28 | 2007-05-04 | Shell Int Research | Metodo para iniciar un proceso de epoxidacion y proceso de epoxidacion de una olefina. |
| MX257124B (es) * | 2002-06-28 | 2008-05-14 | Shell Int Research | Metodo para iniciar un proceso de epoxidacion, catalizador y proceso de epoxidacion de una olefina. |
| MY136774A (en) | 2003-02-28 | 2008-11-28 | Shell Int Research | Method of improving the operation of a manufacturing process |
| MY146505A (en) * | 2003-02-28 | 2012-08-15 | Shell Int Research | A method of manufacturing ethylene oxide |
| TWI346574B (en) * | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
| MXPA05010375A (es) * | 2003-04-01 | 2005-11-17 | Shell Int Research | Proceso de epoxidacion de olefina y catalizador para utilizar en el proceso. |
| US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US6846774B2 (en) * | 2003-04-23 | 2005-01-25 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
| US6858560B2 (en) | 2003-04-23 | 2005-02-22 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
| US20040225138A1 (en) | 2003-05-07 | 2004-11-11 | Mcallister Paul Michael | Reactor system and process for the manufacture of ethylene oxide |
| CA2524890C (en) * | 2003-05-07 | 2012-09-11 | Shell Internationale Research Maatschappij B.V. | Silver-containing catalysts, the manufacture of such silvercontaining catalysts, and the use thereof |
| US20040224841A1 (en) | 2003-05-07 | 2004-11-11 | Marek Matusz | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| CN101757914A (zh) | 2003-10-16 | 2010-06-30 | 陶氏技术投资有限责任公司 | 用于烯化氧制备的具有提高稳定性、效率和/或活性的催化剂 |
| TW200600190A (en) | 2004-04-01 | 2006-01-01 | Shell Int Research | Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation |
| MY140566A (en) * | 2004-06-18 | 2009-12-31 | Shell Int Research | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
| WO2006028544A2 (en) | 2004-06-18 | 2006-03-16 | Shell International Research Maatschappij B.V. | A process for the production of an olefin oxide, a 1,2-diol, a 1.2-diol ether, or an alkanolamine |
| EP1786797B1 (en) | 2004-08-12 | 2014-11-26 | Velocys, Inc. | Process for converting ethylene to ethylene oxide using microchannel process technology |
| MX2007002386A (es) | 2004-09-01 | 2007-04-23 | Shell Int Research | Proceso para epoxidacion de olefinas, catalizador para uso en el proceso, soporte para uso en la preparacion del catalizador, y proceso para preparar el soporte. |
| US8536083B2 (en) | 2004-09-01 | 2013-09-17 | Shell Oil Company | Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
| JP5421587B2 (ja) * | 2005-03-22 | 2014-02-19 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | エチレンオキシドの製造のための反応器システムおよびプロセス |
| JP5101498B2 (ja) | 2005-06-07 | 2012-12-19 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒、触媒の製造方法、およびオレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、またはアルカノールアミンの製造方法 |
| TWI334363B (en) | 2005-06-07 | 2010-12-11 | Saint Gobain Ceramics | A catalyst carrier |
| US8318627B2 (en) * | 2005-08-10 | 2012-11-27 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for preparation of a catalyst carrier |
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| US7459589B2 (en) | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| US7750170B2 (en) | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
| US7704908B2 (en) | 2005-12-22 | 2010-04-27 | Shell Oil Company | Method for reusing rhenium from a donor spent epoxidation catalyst |
| TW200738332A (en) * | 2006-02-03 | 2007-10-16 | Shell Int Research | A process for treating a catalyst, the catalyst, and use of the catalyst |
| CN101360562B (zh) * | 2006-04-10 | 2013-02-06 | 三菱化学株式会社 | 环氧乙烷制造用催化剂及其制造方法、以及环氧乙烷的制造方法 |
| EP1955766A4 (en) * | 2006-04-10 | 2013-02-13 | Mitsubishi Chem Corp | CATALYST FOR ETHYLENE OXIDE GENERATION, PRODUCTION METHOD AND METHOD FOR PRODUCING ETHYLENE OXIDE |
| US20090270640A1 (en) * | 2006-04-21 | 2009-10-29 | Basf Aktiengesellschaft | Method for production of ethylene oxide in a microchannel reactor |
| JP4267015B2 (ja) | 2006-09-29 | 2009-05-27 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| US8501664B2 (en) | 2006-11-20 | 2013-08-06 | Shell Oil Company | Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst |
| EP2152681B1 (en) * | 2007-05-09 | 2017-03-29 | Shell Internationale Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| TWI446964B (zh) * | 2007-05-09 | 2014-08-01 | Shell Int Research | 環氧化催化劑,製備該催化劑之方法及製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法 |
| TWI464154B (zh) * | 2007-05-09 | 2014-12-11 | Shell Int Research | 製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法 |
| US7696368B2 (en) * | 2007-05-11 | 2010-04-13 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Start-up of high selectivity catalysts in olefin oxide plants |
| US9144765B2 (en) | 2007-05-18 | 2015-09-29 | Shell Oil Company | Reactor system, an absorbent and a process for reacting a feed |
| CN101678267A (zh) | 2007-05-18 | 2010-03-24 | 国际壳牌研究有限公司 | 反应器系统和用于制备1,2-二醇、1,2-二醇醚、1,2-碳酸酯和烷醇胺的方法 |
| CA2686852A1 (en) | 2007-05-18 | 2008-11-27 | Shell Internationale Research Maatschappij B.V. | A reactor system, an absorbent and a process for reacting a feed |
| US7713903B2 (en) | 2007-08-27 | 2010-05-11 | Shell Oil Company | Carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, A 1,2-diol, A 1,2-diol ether, or an alkanolamine |
| US7507845B1 (en) * | 2007-08-27 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co Kg | Process for production of an olefin oxide |
| WO2009088040A1 (ja) * | 2008-01-11 | 2009-07-16 | Nippon Shokubai Co., Ltd. | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| DE102008011767B4 (de) | 2008-02-28 | 2012-07-26 | Basf Se | Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen |
| US7910518B2 (en) * | 2008-03-10 | 2011-03-22 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Geometrically sized solid shaped carrier for olefin epoxidation catalyst |
| DE102008014910A1 (de) | 2008-03-19 | 2009-09-24 | Basf Se | Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung |
| CN102056909B (zh) * | 2008-05-07 | 2014-03-05 | 国际壳牌研究有限公司 | 环氧化工艺的开车方法及环氧乙烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法 |
| JP5868703B2 (ja) * | 2008-05-07 | 2016-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法 |
| CN102066351B (zh) | 2008-05-15 | 2014-03-12 | 国际壳牌研究有限公司 | 制备亚烷基碳酸酯和/或亚烷基二醇的方法 |
| US8273912B2 (en) | 2008-05-15 | 2012-09-25 | Shell Oil Company | Process for the preparation of an alkylene carbonate and an alkylene glycol |
| CN102099345A (zh) * | 2008-07-14 | 2011-06-15 | 万罗赛斯公司 | 使用微通道工艺技术制造环氧乙烷的方法 |
| CN102099346A (zh) | 2008-07-14 | 2011-06-15 | 巴斯夫欧洲公司 | 制备环氧乙烷的方法 |
| WO2010040688A1 (de) | 2008-10-08 | 2010-04-15 | Basf Se | Verfahren zur herstellung eines alkylenoxids |
| JP2010234264A (ja) * | 2009-03-31 | 2010-10-21 | Nippon Shokubai Co Ltd | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| US9090577B2 (en) | 2009-03-31 | 2015-07-28 | Nippon Shokubai Co., Ltd. | Catalyst for producing ethylene oxide and method for producing ethylene oxide |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120046706A (ko) * | 2010-11-02 | 2012-05-10 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 알루미나 지지체, 그 제조 방법, 및 그로부터 제조된 은 촉매, 그리고 그 용도 |
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