KR940021620A - 폴리에테르에스테르아미드 및 제전성 수지조성물 - Google Patents

폴리에테르에스테르아미드 및 제전성 수지조성물 Download PDF

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KR940021620A
KR940021620A KR1019940004146A KR19940004146A KR940021620A KR 940021620 A KR940021620 A KR 940021620A KR 1019940004146 A KR1019940004146 A KR 1019940004146A KR 19940004146 A KR19940004146 A KR 19940004146A KR 940021620 A KR940021620 A KR 940021620A
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resin
resin composition
weight
antistatic
polyolefin
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야수히로오 우에다
에이이치 센다
요시쭈구 타카이
토키코 코쿠부
토시아키 오카모토
에이지 이치하라
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후지모토 타케히코
산요오카세이코오교오 카부시키가이샤
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
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    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/20—Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
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    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
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    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
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    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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Abstract

내열성, 영구제전성 및 열가소성수지 간에 우수한 상용성을 보유하는 폴리에테르에스테르아미드와, 이 폴리에테르에스테르아미드를 함유하는 제전성 수지조성물에 관한 것이다. 폴리에테르에스테르아미드는, 말단에 카르복실기를 보유하는 수평균 분자량이 200~5,000의 폴리아미드올리고머와, 옥시알키렌단위를 함유하는 수평균 분자량이 300~3,000의 비스페놀화합물로 실질적으로 2성분으로 구성되어 있다.
폴리에테르에스테르아미드를 3~40중량%, 열가소성수지가 60~97중량%의 수지조성물로 하여, 제전성과 내열성에 우수한 제전성 수지조성물로 얻을 수 있다. 이 제전성 수지조성물에는, 상용화제로서 카르복실기, 에폭시기 등으로부터 선택되는 관능기를 보유하는 비닐중합체, 또는 폴리올레핀블럭과 방향족 비닐중합체블럭을 보유하는 블록폴리머를 가할 수 있다. 적어도 97중량%의 폴리에테르에스테르아미드와 적어도 0.01중량%의 알카리금속 또는 알카리토류금속의 할로겐화물로 구성된 수지조성물을 폴리에테르에스테르아미드와 마찬가지로 사용하면 더욱 열가소성수지의 제전성을 개량할 수 있다.

Description

폴리에테르에스테르아미드 및 제전성 수지조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (20)

  1. 실질적으로 말단에 카르복실기를 보유하는 수평균 분자량이 200~5,000의 폴리아미드올리고머(1)와, 옥시알키렌단위를 함유하는 수평균 분자량이 300~3,000의 비스페놀화합물(2)로부터 유도되는 잔기로 이루어지는 폴리에테르에스테르아미드.
  2. 제 1 항에 있어서, 비스페놀화합물의 수평균 분자량이 1,600~3,000인 폴리에테르에스테르아미드.
  3. 제 1 항 기재의 폴리에테르에스테르아미드가 3~40중량%, 열가소성수지가 60~97중량% 함유되어 있는 제전성 수지조성물.
  4. 제 3 항에 있어서, 열가소성수지가 폴리올레핀수지, 폴리아미드수지, 폴리에스테르수지, 폴리카아보네이트수지, 폴리아세탈수지, 및 스티렌류, 아크릴산에스테르, 메타크릴산에스테르, 아크릴로니트릴, 메타크릴로니트릴 및 부타디엔으로부터 선택되는 적어도 2종의 단량체의 공중합체로부터 선택되는 제전성 수지조성물.
  5. 제 4 항에 있어서, 폴리올레핀수지가 폴리프로필렌인 제전성 수지조성물.
  6. 제 3 항에 있어서, 열가소성수지가 폴리올레핀수지와 폴리아미드수지, 폴리에스테르수지 또는 폴리아세탈수지와의 조합인 제전성 수지조성물.
  7. 제 3 항에 있어서, 제전성 수지조성물의 총중량에 대하여, 열가소성수지가 55~95중량%의 폴리올레핀과, 1~20중량%의 폴리아미드수지, 폴리에스테르수지 또는 폴리아세탈수지로 구성된 제전성 수지조성물.
  8. 제 3 항에 있어서, 열가소성수지가 폴리카아보네이트수지와 스티렌류, 아크릴산에스테르, 메타크릴산에스테르, 아크릴로니트릴, 메타크릴로니트릴 및 부타디엔에서 선택되는 적어도 2종의 단량체의 공중합체와의 조합인 제전성 수지조성물.
  9. 적어도 60중량%인 제 3 항 기재의 제전성 수지조성물과 카르복실기, 에폭시기, 아미노기, 수산기, 폴리옥시알키렌기, 술폰산기 및 술폰산염의 기에서 선택되는 관능기를 보유하는 비닐중합체 및 폴리올레핀블럭과 방향족 비닐중합체블럭을 보유하는 블록폴리머로부터 선택되는 수지로 구성되고, 40중량%를 초과하지 않는 양의 상용화제를 함유하는 제전성 수지조성물.
  10. 제 9 항에 있어서, 관능기를 보유하는 비닐중합체가 (1) 수평균 분자량 800~25,000, 산가(價) 5~150의 카르복실기를 함유하는 폴리올레핀수지, (2) 수평균 분자량 800~25,000, 수산기가(價) 5~150의 수산기를 함유하는 폴리올레핀수지 및 (3) 수평균 분자량 800~25,000, 산가 5~150의 카르복실기를 함유하는 폴리올레핀수지가 폴리옥시알키렌 모노 또는 폴리올(polyol)로 에스테르화되어 제조된 수평균 분자량 1,000~28,000의 변성폴리올레핀수지로부터 선택되는 제전성 수지조성물.
  11. 적어도 97중량%의 제 1 항 기재의 폴리에테르에스테르아미드 및 적어도 0.01중량%의 알카리금속 또는 알카리토류금속의 할로겐화물로 구성되는 수지조성물.
  12. 제11항에 있어서, 알카리금속의 할로겐화물이 염화나트륨 또는 염화칼륨인 수지조성물.
  13. 제11항에 있어서, 60~97중량%의 열가소성수지와, 청구항 11기재의 3~40중량%의 수지조성물로 구성되는 재전성 수지조성물.
  14. 제13항에 있어서, 열가소성수지가 폴리올레핀수지, 폴리아미드수지, 폴리에스테르수지, 폴리카아보네이트수지, 폴리아세탈수지, 및 스티렌류, 아크릴산에스테르, 메타크릴산에스테르, 아크릴로니트릴, 메타크릴로니트릴 및 부타디엔에서 선택되는 적어도 2종의 단량체의 공중합체로부터 선택되는 제전성 수지조성물.
  15. 제14항에 있어서, 폴리올레핀수지가 폴리프로필렌인 제전성 수지조성물.
  16. 제13항에 있어서, 열가소성수지가 폴리올레핀수지와, 폴리아미드수지, 폴리에스테르수지 또는 폴리아세탈수지와의 조합인 제전성 수지조성물.
  17. 제13항에 있어서, 제전성 수지조성물의 총중량에 대하여, 열가소성수지가 55~95중량%의 폴리올레핀수지와 1~20중량%의 폴리아미드수지, 폴리에스테르수지 또는 폴리아세탈수지로 구성된 제전성 수지조성물.
  18. 제13항에 있어서, 열가소성수지가 폴리카아보네이트수지와 스티렌류, 아크릴산에스테르, 메타크릴산에스테르, 아크릴로니트릴, 메타크릴로니트릴 및 부타디엔에서 선택되는 적어도 2종의 단량체의 공중합체와의 조합인 제전성 수지조성물.
  19. 적어도 60중량%인 제13항 기재의 제전성 수지조성물과 카르복실기, 에폭시기, 아미노기, 수산기, 폴리옥시알키렌기, 술폰산기 및 술폰산염의 기에서 선택되는 관능기를 보유하는 비닐중합체 및 폴리올레핀블럭과 방향족 비닐중합체블럭을 보유하는 블록폴리머로부터 선택되는 수지로 구성된, 40중량%를 초과하지 않는 양의 상용화제를 함유하는 제전성 수지조성물.
  20. 제19항에 있어서, 관능기를 보유하는 비닐중합체가 (1) 수평균 분자량 800~25,000, 산가 5~150의 카르복실기를 함유하는 폴리올레핀수지, (2) 수평균 분자량 800~25,000, 수산기가 5~150의 수산기를 함유하는 폴리올레핀수지 및, (3) 수평균 분자량 800~25,000, 산가 5~150의 카르복실기를 함유하는 폴리올레핀수지가, 폴리옥시알키렌 모노 또는 폴리올로 에스테르화된 수평균 분자량 1,000~28,000의 변성폴리올레핀수지로부터 선택되는 제전성 수지조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940004146A 1993-03-03 1994-03-03 폴리에테르에스테르아미드및제전성수지조성물 KR100300273B1 (ko)

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JP93-67521 1993-03-03
JP6752193 1993-03-03
JP93-85616 1993-03-19
JP8561693 1993-03-19
JP11371593 1993-04-16
JP93-113715 1993-04-16
JP5276089A JP2538512B2 (ja) 1993-03-03 1993-10-06 樹脂組成物
JP93-276089 1993-10-06
JP5283984A JP2711988B2 (ja) 1993-03-03 1993-10-18 樹脂組成物
JP93-283984 1993-10-18
JP93-301031 1993-11-05
JP893-301031 1993-11-05
JP30103193 1993-11-05

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EP0613919A1 (en) 1994-09-07
US5652326A (en) 1997-07-29
EP0613919B1 (en) 1997-10-29
KR100300273B1 (ko) 2002-01-09
US5886098A (en) 1999-03-23
DE69406476T2 (de) 1998-03-19
US5604284A (en) 1997-02-18

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