KR920006032A - 철-안티몬-몰리브덴-함유 산화물 촉매 조성물 및 이의 제조 방법 - Google Patents
철-안티몬-몰리브덴-함유 산화물 촉매 조성물 및 이의 제조 방법 Download PDFInfo
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- KR920006032A KR920006032A KR1019910015664A KR910015664A KR920006032A KR 920006032 A KR920006032 A KR 920006032A KR 1019910015664 A KR1019910015664 A KR 1019910015664A KR 910015664 A KR910015664 A KR 910015664A KR 920006032 A KR920006032 A KR 920006032A
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- element selected
- aqueous slurry
- catalyst composition
- iron
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- 239000003054 catalyst Substances 0.000 title claims 10
- OBGNYJVWHXNTAB-UHFFFAOYSA-N [Fe].[Mo].[Sb] Chemical compound [Fe].[Mo].[Sb] OBGNYJVWHXNTAB-UHFFFAOYSA-N 0.000 title claims 3
- 238000002360 preparation method Methods 0.000 title 1
- 239000002002 slurry Substances 0.000 claims 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 9
- 238000000034 method Methods 0.000 claims 7
- 229910052763 palladium Inorganic materials 0.000 claims 5
- 229910052782 aluminium Inorganic materials 0.000 claims 4
- 229910052719 titanium Inorganic materials 0.000 claims 4
- 229910052797 bismuth Inorganic materials 0.000 claims 3
- 229910052792 caesium Inorganic materials 0.000 claims 3
- 229910052742 iron Inorganic materials 0.000 claims 3
- 229910052744 lithium Inorganic materials 0.000 claims 3
- 229910052748 manganese Inorganic materials 0.000 claims 3
- 229910052759 nickel Inorganic materials 0.000 claims 3
- 229910052758 niobium Inorganic materials 0.000 claims 3
- 229910052708 sodium Inorganic materials 0.000 claims 3
- 229910052714 tellurium Inorganic materials 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- 229910052726 zirconium Inorganic materials 0.000 claims 3
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- 229910052779 Neodymium Inorganic materials 0.000 claims 2
- 229910052777 Praseodymium Inorganic materials 0.000 claims 2
- 229910052776 Thorium Inorganic materials 0.000 claims 2
- 229910052770 Uranium Inorganic materials 0.000 claims 2
- 229910052785 arsenic Inorganic materials 0.000 claims 2
- 229910052788 barium Inorganic materials 0.000 claims 2
- 229910052790 beryllium Inorganic materials 0.000 claims 2
- 229910052796 boron Inorganic materials 0.000 claims 2
- 229910052793 cadmium Inorganic materials 0.000 claims 2
- 229910052791 calcium Inorganic materials 0.000 claims 2
- 239000002738 chelating agent Substances 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 229910052732 germanium Inorganic materials 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- 229910052735 hafnium Inorganic materials 0.000 claims 2
- 229910052738 indium Inorganic materials 0.000 claims 2
- 229910052741 iridium Inorganic materials 0.000 claims 2
- 229910052746 lanthanum Inorganic materials 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 229910052762 osmium Inorganic materials 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- 229910052702 rhenium Inorganic materials 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 claims 2
- 229910052701 rubidium Inorganic materials 0.000 claims 2
- 229910052707 ruthenium Inorganic materials 0.000 claims 2
- 229910052711 selenium Inorganic materials 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 229910052712 strontium Inorganic materials 0.000 claims 2
- 229910052715 tantalum Inorganic materials 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- 229910052727 yttrium Inorganic materials 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 239000013522 chelant Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 229910052745 lead Inorganic materials 0.000 claims 1
- 239000013081 microcrystal Substances 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
- B01J38/30—Treating with free oxygen-containing gas in gaseous suspension, e.g. fluidised bed
- B01J38/32—Indirectly heating or cooling material within regeneration zone or prior to entry into regeneration zone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/881—Molybdenum and iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
- C01C3/0216—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0241—Preparation in gaseous phase from alcohols or aldehydes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 미소결정 크기가 100Å 이상인 결정성 안티몬산 철을 포함하는, 하기 실험식으로 표시되는 산화 반응용 철-안티몬-몰리브덴-함유 산화물 촉매 조성물.FeaSbbMocLdKeMmNnQgRrTtOx상기식에서, L은 Bi 및 Te로 이루어진 그룹중에서 선택된 원소 하나이상을 나타내고, M은 Cu,Mg,Zn,La,Ce,Al,Cr,Mn,Co,Ni 및 Sn으로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내며, Be, Ca, Sr, Ba, Y, Pr, Nd, Th, U, Ti, Zr, Hf, Nb, Ta, Re, Ru, Os, Rh, Ir, Pd, Pt, Ag, Au, Cd, Al, Ga, In, Ge 및 Pd로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내고, Q는 V 및 W로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내며; R은 Li,Na,Se로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내며, T는 B,P,As 및 Rb,Cs 및 Ti로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내며, a,b,c,d,e,n,q,r,t 및 X는 각각, 원자비를 나타내며 a는 10이고 b는 5 내지 30이고, d는 0.01 내지 10이며, e는 0.01 내지 5이고, m은 0 내지 300이며, n은 0 내지 10이고, q는 0 내지 5이며, r은 0 내지 3이고, t는 0 내지 5이며, x는 상기에 언급한 성분들을 합하여 제조한 산화물에 상응하는 측정된 산소 원자의 수를 나타낸다.
- 제1항에 있어서, 촉매중의 안티몬산철의 미소결정 크기가 200Å 미만인 촉매 조성물.
- 제1항에 있어서, M이 Zn, Ce, Cr, Mn, Co 및 Ni로 이루어진 그룹중에서 선택된 하나 이상의 원소이고, N이 Ti, Zr, Nb, Pd, Ag, Ge 및 Pb로 이루어진 그룹중에서 선택된 하나 이상의 원소이며, R이 Li, Na 및 Cs로 이루어진 그룹중에서 선택된 하나 이상의 원소이고, T가 B 및/또는 P인 촉매 조성물.
- 제1항에 있어서, 촉매 조성물중의 성분들의 비를 나타내는 a가 10이고, b가 6 내지 30이며, c가 6 내지 20이고, d가 0.1 내지 8이며, e가 0.02 내지 2이고, m은 0 내지 20이며, n은 0 내지 5이고, q는 0 내지 4이며, r은 0 내지 2.5이고 t가 0 내지 4인 촉매 조성물.
- 제1항에 있어서, T성분으로서 P를 사용하고, P/Fe의 원자비가 0.3이하인 촉매 조성물.
- 제1항에 있어서, 산화물 촉매를 담체상에 지지시킨 촉매 조성물.
- 주성분으로 (ⅰ) 안티몬산철, (ⅱ) 몰리브덴, (ⅲ) 비스무트 및 텔루륨으로 이루어진 그룹중에서 선택된 원소 하나 이상, 및 (ⅳ) 칼륨을 함유하는 수성 슬러리, 또는 상기한 주성분[(ⅰ),(ⅱ),(ⅲ) 및 (ⅳ)] 및 (ⅴ) 실험식에서 M,N,Q,R 및 T로서 표시된 촉매 성분으로 이루어진 그룹중에서 선택된 원소 하나 이상을 함유하는 수성 슬러리를 제조하고; 수성 슬러리를 건조시킨 다음; 건조된 생성물을 하소시키는 단계들을 포함하여, 미소 결정 크기가 100Å이상인 결정성 안티몬산철을 포함하는, 하기 실험식으로 표시되는 산화 반응용 철-안티몬-몰리브덴-함유 산화물 촉매 조성물을 제조하는 방법.FeaSbbMocLdKeMmNnQgRrTtOx상기식에서, L은 Bi 및 Te로 이루어진 그룹중에서 선택된 원소 하나이상을 나타내고, M은 Cu,Mg,Zn,La,Ce,Al,Cr,Mn,Co,Ni 및 Sn으로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내며, N은 Be, Ca, Sr, Ba, Y, Pr, Nd, Th, U, Ti, Zr, Hf, Nb, Ta, Re, Ru, Os, Rh, Ir, Pd, Pt, Ag, Au, Cd, Al, ga, In, Ge 및 Pd로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내고, Q는 V 및 W로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내며; R은 Li, Na, Rb, Cs및 TI로 이루어진 그룹중에서 선택된원소 하나이상을 나타내고, T는 B,P,As 및 Se로 이루어진 그룹중에서 선택된 원소 하나 이상을 나타내고, a,b,c,d,e,m,n,q,r,t 및 X는 각각, 원자비를 나타내며 a는 10이고 b는 5 내지 60이며, c는 5 내지 30이고, d는 0.01 내지 10이며, e는 0.01 내지 5이고, m은 0 내지 30이며, n은 0 내지 10이고, q는 0 내지 5이며, r은 0 내지 3이고, t는 0 내지 5이면, x는 상기에 언급한 성분들을 합하여 제조한 산화물에 상응하는 측정된 산소 원자의 수를 나타낸다.
- 제7항에 있어서, 수성 슬러리가 담체 성분용 원료 물질을 함유하는 방법.
- 제7항에 있어서, 수성 슬러리의 pH를 5이하로 조절하는 방법.
- 제7항에 있어서, 수성 슬러리의 pH를 7이상으로 조절하는 방법.
- 제7항에 있어서, 수성 슬러리의 pH를 6이상으로 조절하고 수성 슬러리가 킬레이트제를 함유하는 방법.
- 제7항에 있어서, 수성 슬러리의 pH를 6이상으로 조절하고 수성 슬러리가 킬레이트제 및 철 킬레이트 화합물을 함유하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP90-237002 | 1990-09-10 | ||
| JP02237002A JP3142549B2 (ja) | 1990-09-10 | 1990-09-10 | 鉄・アンチモン・モリブデン含有酸化物触媒組成物およびその製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR920006032A true KR920006032A (ko) | 1992-04-27 |
| KR100191368B1 KR100191368B1 (ko) | 1999-06-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019910015664A KR100191368B1 (ko) | 1990-09-10 | 1991-09-09 | 철-안티몬-몰리브덴함유 산화물 촉매 조성물 및 이의 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5132269A (ko) |
| EP (1) | EP0475351B1 (ko) |
| JP (1) | JP3142549B2 (ko) |
| KR (1) | KR100191368B1 (ko) |
| DE (1) | DE69101685T2 (ko) |
| ES (1) | ES2055501T3 (ko) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19519004A1 (de) * | 1995-05-24 | 1996-11-28 | Hoechst Ag | Neue selen- und rutheniumhaltige Metalloxidkatalysatoren sowie ein Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19519008A1 (de) * | 1995-05-24 | 1996-11-28 | Hoechst Ag | Neue ruthenium- und selen- oder schwefelhaltige Metalloxidkatalysatoren sowie ein Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP3982852B2 (ja) * | 1995-06-30 | 2007-09-26 | 三菱レイヨン株式会社 | 流動層プロセス |
| KR100204729B1 (ko) * | 1997-03-17 | 1999-06-15 | 성재갑 | 아크롤레인 부분산화용 촉매의 제조 방법 |
| US5840648A (en) * | 1997-09-02 | 1998-11-24 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile and hydrogen cyanide |
| JP3875023B2 (ja) * | 1998-02-13 | 2007-01-31 | コリア リサーチ インスティチュート オブ ケミカル テクノロジイ | コアー殻触媒相の固形触媒とその製造方法 |
| DE69920437T2 (de) | 1998-04-23 | 2005-10-06 | Mitsubishi Rayon Co., Ltd. | Katalysator zur herstellung von ungesättigten nitrilen |
| WO1999054037A1 (fr) * | 1998-04-23 | 1999-10-28 | Mitsubishi Rayon Co., Ltd. | Catalyseur de production de nitrile insature |
| JP3573959B2 (ja) | 1998-05-12 | 2004-10-06 | ダイヤニトリックス株式会社 | モリブデン含有酸化物流動層触媒の再生法 |
| US6384275B2 (en) | 1998-09-23 | 2002-05-07 | Lg Chem, Ltd. | Method of producing acrylic acid using a catalyst for acrolein oxidation |
| US6060421A (en) * | 1998-12-23 | 2000-05-09 | Saudi Basic Industries Corporation | Catalysts for the oxidation of ethane to acetic acid, methods of making and using the same |
| US6037304A (en) | 1999-01-11 | 2000-03-14 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
| US6017846A (en) * | 1999-01-11 | 2000-01-25 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
| WO2000048971A1 (en) * | 1999-02-22 | 2000-08-24 | Symyx Technologies, Inc. | Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes |
| US6436871B1 (en) * | 1999-02-22 | 2002-08-20 | Symyx Technologies, Inc. | Catalysts for oxidative dehydrogenation |
| US6355854B1 (en) | 1999-02-22 | 2002-03-12 | Symyx Technologies, Inc. | Processes for oxidative dehydrogenation |
| AU5165600A (en) * | 1999-05-27 | 2000-12-18 | Solutia Inc. | Process for improving activity and selectivity of ammoxidation catalyst |
| JP2001029788A (ja) * | 1999-07-21 | 2001-02-06 | Mitsubishi Rayon Co Ltd | モリブデン−ビスマス−鉄含有金属酸化物流動層触媒の製法 |
| JP3819192B2 (ja) | 1999-10-18 | 2006-09-06 | ダイヤニトリックス株式会社 | アクリロニトリルの製造法 |
| US6723869B1 (en) | 1999-10-18 | 2004-04-20 | Mitsubishi Rayon Co., Ltd. | Method for producing acrylonitrile, catalyst for use therein and method for preparing the same |
| US6486091B1 (en) | 2000-03-14 | 2002-11-26 | Saudi Basic Industries Corporation | Process for making highly active and selective catalysts for the production of unsaturated nitriles |
| US6337424B1 (en) * | 2000-04-28 | 2002-01-08 | Saudi Basic Industries Corporation | Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same |
| US6588966B2 (en) * | 2000-09-15 | 2003-07-08 | Quantum Engineering, Inc. | End of train coupler mounting device |
| JP4666334B2 (ja) * | 2000-09-18 | 2011-04-06 | 旭化成ケミカルズ株式会社 | 酸化又はアンモ酸化用酸化物触媒の製造方法 |
| US6734136B2 (en) | 2000-09-28 | 2004-05-11 | Rohm And Haas Company | IR and/or SM promoted multi-metal oxide catalyst |
| US6677497B2 (en) | 2001-03-22 | 2004-01-13 | Symyx Technologies, Inc. | Ni catalysts and methods for alkane dehydrogenation |
| JP4159759B2 (ja) * | 2001-04-13 | 2008-10-01 | ダイヤニトリックス株式会社 | モリブデン−ビスマス−鉄含有複合酸化物流動層触媒の製法 |
| JP4030740B2 (ja) * | 2001-10-11 | 2008-01-09 | ダイヤニトリックス株式会社 | アンモ酸化用触媒の製造方法 |
| WO2003039744A1 (fr) * | 2001-11-08 | 2003-05-15 | Mitsubishi Chemical Corporation | Catalyseur a base d'oxyde composite et son procede de preparation |
| JP4242197B2 (ja) * | 2003-04-18 | 2009-03-18 | ダイヤニトリックス株式会社 | アクリロニトリル合成用触媒 |
| JP4503315B2 (ja) * | 2004-03-09 | 2010-07-14 | ダイヤニトリックス株式会社 | 鉄・アンチモン・テルル含有金属酸化物触媒の製造方法 |
| US20090023952A1 (en) | 2005-02-18 | 2009-01-22 | Mitsubishi Rayon Co., Ltd. | Palladium-containing catalyst, method for producing same, and method for producing alpha, beta-unsaturated carboxylic acid |
| US7732367B2 (en) | 2005-07-25 | 2010-06-08 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
| US7851397B2 (en) | 2005-07-25 | 2010-12-14 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
| US7649111B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
| US7649112B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon |
| KR100807972B1 (ko) | 2005-08-10 | 2008-02-28 | 주식회사 엘지화학 | 아크릴산 선택성이 높은 복합 금속 산화물 촉매 |
| PL1937617T3 (pl) * | 2005-09-20 | 2010-10-29 | Arkema France | Sposób wytwarzania produktów częściowego utleniania niższych alkoholi przez bezpośrednie utlenianie niższego alkoholu oraz katalizatory stosowane w tym sposobie |
| JP4902991B2 (ja) * | 2005-12-27 | 2012-03-21 | 三菱レイヨン株式会社 | 酸化物触媒の製造方法 |
| FR2912742B1 (fr) * | 2007-02-16 | 2010-03-05 | Arkema France | Procede de synthese d'acrylonitrile a partir de glycerol |
| EP2152412A2 (en) * | 2007-05-03 | 2010-02-17 | Shell Internationale Research Maatschappij B.V. | A catalyst, its preparation and use |
| CN101422735B (zh) * | 2007-11-01 | 2010-12-15 | 中国石油天然气股份有限公司 | 一种乙苯脱氢制苯乙烯的催化剂及其制备方法 |
| JP5011176B2 (ja) | 2008-03-14 | 2012-08-29 | ダイヤニトリックス株式会社 | アクリロニトリル合成用触媒およびアクリロニトリルの製造方法 |
| CN101579631A (zh) * | 2009-06-22 | 2009-11-18 | 上海华谊丙烯酸有限公司 | 一种用于低碳烯烃选择氧化制备不饱和醛反应的催化剂的制备方法 |
| JP5560642B2 (ja) | 2009-10-09 | 2014-07-30 | 三菱レイヨン株式会社 | 複合酸化物触媒の製造方法 |
| JP5663902B2 (ja) * | 2010-03-05 | 2015-02-04 | 三菱レイヨン株式会社 | メタクリル酸製造用触媒の製造方法 |
| JP5609254B2 (ja) * | 2010-05-14 | 2014-10-22 | 三菱レイヨン株式会社 | 複合酸化物触媒の製造方法 |
| US9199921B2 (en) | 2011-04-21 | 2015-12-01 | Asahi Kasei Chemicals Corporation | Silica-supported catalyst |
| US8921257B2 (en) | 2011-12-02 | 2014-12-30 | Saudi Basic Industries Corporation | Dual function partial oxidation catalyst for propane to acrylic acid conversion |
| US9328063B2 (en) | 2012-02-29 | 2016-05-03 | Mitsubishi Rayon Co., Ltd. | Method for producing acrylonitrile |
| EP2821392B1 (en) | 2012-02-29 | 2019-06-19 | Mitsubishi Chemical Corporation | Method for producing acrylonitrile |
| US9181178B2 (en) | 2012-02-29 | 2015-11-10 | Mitsubishi Rayon Co., Ltd. | Method for producing acrylonitrile |
| US8722940B2 (en) | 2012-03-01 | 2014-05-13 | Saudi Basic Industries Corporation | High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
| US20160008794A1 (en) * | 2013-02-21 | 2016-01-14 | Mitsubishi Rayon Co., Ltd. | Catalyst for acrylonitrile production and method for producing acrylonitrile |
| JPWO2014129566A1 (ja) * | 2013-02-25 | 2017-02-02 | 三菱レイヨン株式会社 | アクリロニトリル製造用触媒の製造方法およびアクリロニトリルの製造方法 |
| US9492814B2 (en) | 2013-04-08 | 2016-11-15 | Saudi Basic Industries Corporation | Catalyst for conversion of propylene to product comprising a carboxylic acid moiety |
| KR101507686B1 (ko) * | 2013-05-06 | 2015-03-31 | 주식회사 엘지화학 | 메조포러스 복합 산화물 촉매, 그 제조방법 및 이를 이용한 1,3부타디엔 합성방법 |
| WO2014182026A1 (ko) * | 2013-05-06 | 2014-11-13 | (주) 엘지화학 | 부타디엔 제조를 위한 산화촉매 및 그 제조방법 |
| KR101495478B1 (ko) | 2013-05-06 | 2015-02-23 | 주식회사 엘지화학 | 부타디엔 제조를 위한 산화촉매 및 그 제조방법 |
| KR20180100178A (ko) * | 2016-01-09 | 2018-09-07 | 어센드 퍼포먼스 머티리얼즈 오퍼레이션즈 엘엘씨 | 아크릴로나이트릴 반응기 공급 스트림에서 사이안화 수소의 직접 제조를 위한 촉매 조성물 및 공정 |
| CN107684927B (zh) * | 2016-08-03 | 2020-07-28 | 万华化学集团股份有限公司 | 一种用于氯化氢氧化制备氯气的催化剂及其制备方法和用途 |
| JP6467115B2 (ja) * | 2016-08-31 | 2019-02-06 | 旭化成株式会社 | 触媒の製造方法、及びアクリロニトリルの製造方法 |
| JP6914114B2 (ja) * | 2017-06-23 | 2021-08-04 | 旭化成株式会社 | 金属酸化物触媒及びその製造方法ならびにそれを用いたアクリロニトリルの製造方法 |
| WO2018043007A1 (ja) * | 2016-08-31 | 2018-03-08 | 旭化成株式会社 | 触媒の製造方法、及びアクリロニトリルの製造方法 |
| CN114100652B (zh) * | 2021-12-10 | 2023-10-13 | 北京道思克矿山装备技术有限公司 | 一种甲醇气相催化氨氧化生产氰化氢的催化剂及其制备方法和应用 |
| CN115555025B (zh) * | 2022-10-31 | 2024-01-26 | 河北建材职业技术学院 | 一种高分散钴钼双金属催化剂的制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4111984A (en) * | 1973-06-11 | 1978-09-05 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, and unsaturated fatty acids |
| US4018712A (en) * | 1973-12-27 | 1977-04-19 | Monsanto Company | Oxidation/ammoxidation catalyst |
| JPS5318014B2 (ko) * | 1974-02-09 | 1978-06-13 | ||
| US4306090A (en) * | 1979-10-12 | 1981-12-15 | Rohm And Haas Company | Catalyst compositions and their use for the preparation of methacrolein |
| US4290920A (en) * | 1979-12-28 | 1981-09-22 | The Standard Oil Co. | Sb-containing catalysts by Sb-oxide impregnation |
| JPS63122642A (ja) * | 1986-11-11 | 1988-05-26 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
| JPH0763629B2 (ja) * | 1987-12-25 | 1995-07-12 | 日東化学工業株式会社 | 流動層反応に適する鉄・アンチモン・リン含有触媒の製法 |
| JPH0764555B2 (ja) * | 1988-04-05 | 1995-07-12 | 日東化学工業株式会社 | 青酸製法 |
| JP2747920B2 (ja) * | 1989-02-16 | 1998-05-06 | 日東化学工業株式会社 | 酸化反応に適するモリブデン含有金属酸化物流動層触媒の製法 |
-
1990
- 1990-09-10 JP JP02237002A patent/JP3142549B2/ja not_active Expired - Lifetime
-
1991
- 1991-09-09 US US07/756,708 patent/US5132269A/en not_active Expired - Lifetime
- 1991-09-09 KR KR1019910015664A patent/KR100191368B1/ko not_active IP Right Cessation
- 1991-09-10 DE DE69101685T patent/DE69101685T2/de not_active Expired - Fee Related
- 1991-09-10 EP EP91115276A patent/EP0475351B1/en not_active Expired - Lifetime
- 1991-09-10 ES ES91115276T patent/ES2055501T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2055501T3 (es) | 1994-08-16 |
| DE69101685T2 (de) | 1994-08-25 |
| DE69101685D1 (de) | 1994-05-19 |
| KR100191368B1 (ko) | 1999-06-15 |
| JP3142549B2 (ja) | 2001-03-07 |
| EP0475351B1 (en) | 1994-04-13 |
| JPH04118051A (ja) | 1992-04-20 |
| US5132269A (en) | 1992-07-21 |
| EP0475351A1 (en) | 1992-03-18 |
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