KR920012014A - 파라핀의 암모산화법 - Google Patents

파라핀의 암모산화법 Download PDF

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Publication number
KR920012014A
KR920012014A KR1019910021636A KR910021636A KR920012014A KR 920012014 A KR920012014 A KR 920012014A KR 1019910021636 A KR1019910021636 A KR 1019910021636A KR 910021636 A KR910021636 A KR 910021636A KR 920012014 A KR920012014 A KR 920012014A
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KR
South Korea
Prior art keywords
paraffin
paraffins
equation
balance
general formula
Prior art date
Application number
KR1019910021636A
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English (en)
Inventor
프랭크 브래즈딜 제임스
클레어 글래서 린다
안토니 토프트 마크
Original Assignee
라리 윌리암 에반스
더 스탠다드 오일 컴패니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 라리 윌리암 에반스, 더 스탠다드 오일 컴패니 filed Critical 라리 윌리암 에반스
Publication of KR920012014A publication Critical patent/KR920012014A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
    • C07C255/07—Mononitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

파라핀의 암모산화법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 반응지대중에서 하기 일반식(1)에 의해 나타낸 원소들을 하기의 상대 원자비로 포함하는 산화 금속 촉매와 3-5개의 탄소원자를 갖는 파라핀, 및 산소 및 암모니아를 촉매식 접속시켜 전술한 반응물을 촉매식 반응시킴으로써 α, β-불포화된 모노니트릴을 제조하는 방법으로서, 반응지대에 공급된 반응물이 2내지 16의 파라핀 : NH3의 몰비 및 1내지 10의 파라핀 : O2의 몰비를 가짐을 특징으로 하는 α, β-불포화된 모노니트릴의 제조방법 :
    VvAaDdSnmSbnCucOx(식 1)
    상기식에서, A는 Te 및 Bi로부터 선택되고, D는 Mo, W, Ti, Ge, Ce, La, Cr, Mn, Mg, Ca, Co, Ni, Fe, Nb, Ta, Ag, Zn, Cd, B, P, Na, K 및 Cs로부터 선택된 하나이상의 임의의 원소이고, a는 0.001 내지 30이고, d는 0 내지 30이고, c는 0.01 내지 30이고, m는 0.1 내지 60이고, n은 0.1 내지 60이고, n/v는 12보다 크며 100보다 작고, m+n은 v+a+c+d 이상이며, x는 존재하는 원소들의 균형량에 의해 결정된다.
  2. 제1항에 있어서, 파라핀이 프레판임을 특징으로 하는 방법.
  3. 하기 일반식(1)에 의해 나타낸 원소들을 하기의 상대 원자비로 포함하는 산화 금속 촉매 :
    VvAaDdSnmSbnCucOx(식 1)
    상기식에서, A는 Te 및 Bi로부터 선택되고, D는 Mo, W, Ti, Ge, Ce, La, Cr, Mn, Mg, Ca, Co, Ni, Fe, Nb, Ta, Ag, Zn, Cd, B, P, Na, K 및 Cs로부터 선택된 하나이상의 임의의 원소이고, a는 0.001 내지 30이고, d는 0 내지 30이고, c는 0.001 내지 30이고, m는 0.1 내지 60이고, n은 0.1 내지 60이고, n/v는 12보다 크며 100보다 작고, m+n은 v+a+c+d이상이며, x는 존재하는 원소들의 균형량에 의해 결정된다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910021636A 1990-12-03 1991-11-29 파라핀의 암모산화법 KR920012014A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/620,814 US5079207A (en) 1990-12-03 1990-12-03 Catalyst for ammoxidation of paraffins
US07/620,814 1990-12-03

Publications (1)

Publication Number Publication Date
KR920012014A true KR920012014A (ko) 1992-07-25

Family

ID=24487507

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910021636A KR920012014A (ko) 1990-12-03 1991-11-29 파라핀의 암모산화법

Country Status (8)

Country Link
US (1) US5079207A (ko)
EP (1) EP0489506A1 (ko)
JP (1) JPH04275266A (ko)
KR (1) KR920012014A (ko)
CN (1) CN1062137A (ko)
BR (1) BR9105234A (ko)
CA (1) CA2055739A1 (ko)
MX (1) MX9102342A (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5214016A (en) * 1992-04-02 1993-05-25 The Standard Oil Company Method of making catalysts containing vanadium, antimony and tin
KR100247524B1 (ko) * 1994-05-31 2000-03-15 겐지 아이다 아크릴산 제조용 촉매 및 이 촉매를 이용한 아크릴산의 제조방법
US5498588A (en) * 1994-09-09 1996-03-12 The Standard Oil Company Surface modification and promotion of vanadium antimony oxide catalysts
US5688739A (en) * 1995-05-01 1997-11-18 The Standard Oil Company Ammoxidation catalysts containing germanium to produce high yields of acrylonitrile
US5770757A (en) * 1995-06-05 1998-06-23 The Standard Oil Company Ammoxidation catalysts containing germanium to produce high yields of acrylonitrile
US5750760A (en) * 1995-10-05 1998-05-12 Mitsubishi Chemical Corporation Method for producing a nitrile
US5854172A (en) * 1997-01-17 1998-12-29 The Standard Oil Company Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O
UA57721C2 (uk) * 1997-08-11 2003-07-15 Асахі Касеі Кабусікі Кайся Спосіб виготовлення акрилонітрилу або метакрилонітрилу із пропану або ізобутану
US6235678B1 (en) 1999-06-11 2001-05-22 Saudi Basic Industries Corporation Catalyst system for oxidative dehydrogenation of paraffins
JP3548466B2 (ja) 1999-09-09 2004-07-28 独立行政法人 科学技術振興機構 アンモ酸化反応用Ｓｂ−Ｒｅ複合酸化物触媒
ES2181600B1 (es) 2001-07-17 2004-01-16 Univ Valencia Politecnica Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos.
US6710011B2 (en) 2001-12-21 2004-03-23 Saudi Basic Industries Corporatioin Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same
US7449426B2 (en) * 2005-11-29 2008-11-11 Saudi Basic Industries Corporation Catalyst composition without antimony or molybdenum for ammoxidation of alkanes, a process of making and a process of using thereof
CN106833801B (zh) * 2017-02-23 2020-07-28 广州市芬芳环保科技有限公司 Fe-Ti-Tb三元复合型节煤固硫除焦添加剂及其制备方法和应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4316855A (en) * 1979-12-28 1982-02-23 The Standard Oil Co. Multiply promoted Sn-Sb oxide catalysts
US4339394A (en) * 1980-10-01 1982-07-13 The Standard Oil Co. Process of ammoxidation of olefins in the presence of multiply promoted Sn-Sb oxide catalysts
US4532083A (en) * 1982-10-29 1985-07-30 The Standard Oil Company Multiply promoted Sn/Sb oxide catalysts
ATE93841T1 (de) * 1988-04-14 1993-09-15 Standard Oil Co Ohio Ammonoxidation von paraffinen und dafuer geeigneter katalysator.

Also Published As

Publication number Publication date
CN1062137A (zh) 1992-06-24
US5079207A (en) 1992-01-07
JPH04275266A (ja) 1992-09-30
CA2055739A1 (en) 1992-06-04
BR9105234A (pt) 1992-08-18
EP0489506A1 (en) 1992-06-10
MX9102342A (es) 1992-06-01

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