ES2181600B1 - Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos. - Google Patents

Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos.

Info

Publication number
ES2181600B1
ES2181600B1 ES200101756A ES200101756A ES2181600B1 ES 2181600 B1 ES2181600 B1 ES 2181600B1 ES 200101756 A ES200101756 A ES 200101756A ES 200101756 A ES200101756 A ES 200101756A ES 2181600 B1 ES2181600 B1 ES 2181600B1
Authority
ES
Spain
Prior art keywords
catalyst
amoxidation
acrylonitrile
derivatives
processes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES200101756A
Other languages
English (en)
Other versions
ES2181600A1 (es
Inventor
Nieto Jose Manuel Lopez
Asuncion Pablo Botella
Espriu Benjamin Solsona
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES200101756A priority Critical patent/ES2181600B1/es
Priority to PCT/ES2002/000357 priority patent/WO2003008096A1/es
Priority to JP2003513694A priority patent/JP2004534650A/ja
Priority to EP02748887A priority patent/EP1473081A1/en
Publication of ES2181600A1 publication Critical patent/ES2181600A1/es
Application granted granted Critical
Priority to US10/759,384 priority patent/US7355062B2/en
Publication of ES2181600B1 publication Critical patent/ES2181600B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8894—Technetium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un catalizador para la oxidación selectiva y la amoxidación de alcanos y/o alquenos, particularmente en procesos de obtención de ácido acrílico, acrilonitrilo y derivados de los mismos, que comprende al menos un óxido, preferentemente un óxido mixto calcinado, de Mo, Te, V, Cu y al menos otro componente A seleccionado entre Nb, Ta, Sn, Se, W, Ti, Fe, Co, Ni, Cr, Ga, Sb, Bi, una tierra rara, alcalino o alcalinotérreo, presentando el catalizador, en forma calcinada, un difractograma de rayos X con cinco líneas de difracción intensas, típicamente las más intensas, correspondientes a ángulos 2q de difracción de 22,1+0,4; 27,1+0,4; 28,1+0,4; 36,0+0,4 y 45,1+0,4. En una realización preferida, el catalizador tiene la fórmula empírica: MoTehViCujAkOx en la que h, i, j, k son valores comprendidos entre 0,001 y 4,0 y x depende del estado de oxidación o valencia de los elementos Mo, Te, V, Cu y A.
ES200101756A 2001-07-17 2001-07-17 Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos. Expired - Fee Related ES2181600B1 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES200101756A ES2181600B1 (es) 2001-07-17 2001-07-17 Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos.
PCT/ES2002/000357 WO2003008096A1 (es) 2001-07-17 2002-07-16 Un catalizador para la oxidación selectiva y la amoxidación de alcanos y/o alquenos, particularmente en procesos de obtención de ácido acrílico, acrilonitrilo y derivados de los mismos
JP2003513694A JP2004534650A (ja) 2001-07-17 2002-07-16 特にアクリル酸、アクリロニトリルおよびこれらの誘導体の入手法におけるアルカンおよび／またはアルケンの選択的酸化とアンモ酸化用触媒
EP02748887A EP1473081A1 (en) 2001-07-17 2002-07-16 Catalyst for the selective oxidation and ammoxidation of alkanes and/or alkenes, particularly in processes for obtaining acrylic acid, acrylonitrile and the derivatives thereof
US10/759,384 US7355062B2 (en) 2001-07-17 2004-01-16 Catalyst for selective oxidation and amoxidation of alkanes and/or alkenes, particularly in processes for obtaining acrylic acid, acrylonitrile and the derivatives thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200101756A ES2181600B1 (es) 2001-07-17 2001-07-17 Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos.

Publications (2)

Publication Number Publication Date
ES2181600A1 ES2181600A1 (es) 2003-02-16
ES2181600B1 true ES2181600B1 (es) 2004-01-16

Family

ID=8498525

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200101756A Expired - Fee Related ES2181600B1 (es) 2001-07-17 2001-07-17 Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos.

Country Status (5)

Country Link
US (1) US7355062B2 (es)
EP (1) EP1473081A1 (es)
JP (1) JP2004534650A (es)
ES (1) ES2181600B1 (es)
WO (1) WO2003008096A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2192983B1 (es) 2002-01-31 2004-09-16 Universidad Politecnica De Valencia. Un catalizador para la deshidrogenacion oxidativa de etano a eteno.
US7524792B2 (en) * 2003-06-04 2009-04-28 Basf Aktiengesellschaft Preparation of catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu
CN103073415B (zh) * 2013-01-29 2015-12-23 沈阳化工大学 一种丙烯一步氧化制备丙烯酸的工艺方法
CN103073416A (zh) * 2013-01-29 2013-05-01 新兴能源科技有限公司 一种丙烯酸的制备方法
CN103626676B (zh) * 2013-12-14 2015-08-26 济南开发区星火科学技术研究院 以丙烷为原料制备丙烯腈的方法
CA2993683A1 (en) * 2018-02-02 2019-08-02 Nova Chemicals Corporation Method for in situ high activity odh catalyst
JP7186295B2 (ja) * 2019-06-05 2022-12-08 株式会社日本触媒 アクリル酸製造用触媒とその製造方法およびアクリル酸の製造方法
JP7360557B2 (ja) * 2020-09-03 2023-10-12 株式会社日本触媒 アクリル酸製造用触媒とその製造方法およびアクリル酸の製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4316855A (en) * 1979-12-28 1982-02-23 The Standard Oil Co. Multiply promoted Sn-Sb oxide catalysts
DE3726328A1 (de) * 1987-08-07 1989-02-16 Basf Chemicals Ltd Verfahren zur herstellung von acrylnitril
US5079207A (en) * 1990-12-03 1992-01-07 The Standard Oil Company Catalyst for ammoxidation of paraffins
KR930004254A (ko) 1991-08-08 1993-03-22 에또 다께또시 니트릴의 제조방법
US5198580A (en) 1991-11-18 1993-03-30 The Standard Oil Company Process for oxidation of propane
DE69402567T2 (de) 1993-01-28 1997-11-27 Mitsubishi Chem Corp Methode zur Herstellung einer ungesättigten Carbonsäure
FR2754817B1 (fr) 1996-10-21 2000-03-17 Toagosei Co Ltd Procede de production d'acide acrylique a partir de propane et d'oxygene gazeux
US6166241A (en) 1996-11-15 2000-12-26 Mitsubishi Chemical Corporation Process for the simultaneous preparation of acrylonitrile and arcylic acid
ID24821A (id) 1997-07-14 2000-08-24 Mitsubishi Chem Corp Metode untuk reaksi oksidasi katalitik fasa gas dari suatu senyawa hidrokarbon
EP0895809B1 (en) 1997-08-05 2014-03-19 Asahi Kasei Kabushiki Kaisha Process Using Niobium-containing Aqueous Solution in Producing Niobium-containing Oxide Catalyst
CA2271397A1 (en) * 1998-05-21 1999-11-21 Rohm And Haas Company A process for preparing a catalyst

Also Published As

Publication number Publication date
EP1473081A1 (en) 2004-11-03
US7355062B2 (en) 2008-04-08
WO2003008096A1 (es) 2003-01-30
JP2004534650A (ja) 2004-11-18
ES2181600A1 (es) 2003-02-16
US20040230070A1 (en) 2004-11-18

Similar Documents

Publication Publication Date Title
ES2192983B1 (es) Un catalizador para la deshidrogenacion oxidativa de etano a eteno.
ES2181600B1 (es) Un catalizador para la oxidacion selectiva y la amoxidacion de alcanosy/o alquenos, particularmente en procesos de obtencion de acido acrilico, acrilonitrilo y derivadosn de los mismos.
AR045953A2 (es) Catalizador para la oxidacion selectiva de etano o mezclas de etano y etileno mas oxigeno
ES2200702B1 (es) Catalizador conteniendo un material solido cristalino microporoso y proceso para mejorar la calidad de fracciones diesel utilizando dicho catalizador.
DK1871522T3 (da) Fremgangsmåde til fremstilling af forbedrede katalysatorer til selektiv oxidation af propan til acrylsyre
ES2055501T3 (es) Composicion catalitica a base de hierro, de antimonio y de molibdeno y procedimiento para su preparacion.
BR9909164A (pt) Catalisador e processo para a oxidação de etano e/ou etileno
WO2004071653A8 (en) Composition comprising a metal hydroxy salt, its preparation and use as catalyst or sorbent
BR0001460B1 (pt) composição catalisadora e processo para a oxidação de etano em etileno e/ou ácido acético.
WO2007025241A3 (en) Absorbable surgical materials
DE60011939D1 (de) Spule mit fadenzuführmittel für grasschneidevorrichtung und schneidkopf für grasschneidevorrichtung mit solcher spule
TW200702305A (en) Thermoelectrical conversion material, manufacturing method thereof and thermoelectrical conversion element
MX2020004442A (es) Tapon perforador y metodo para producir el mismo.
BR9909847A (pt) Material para armazenamento de hidrogênio ligado mecanicamente
MY133735A (en) Selective electrocatalytic oxidation of hydrocarbons
NO20052174L (no) Blandet metalloksidkatalysator og fremgangsmate for fremstilling av eddiksyre
DK0901454T3 (da) Fremgangsmåde til fremstilling af eddikesyre
ES2200701B1 (es) Catalizador de hidrocraqueo conteniendo un material solido cristalino microporoso y uso de dicho catalizador para el hidrocraqueo de alimentacion de hidrocarburos.
MD2003C2 (ro) Complecşi interni de cupru (II) cu acţiune antimicrobiană şi antimicotică
ZA200602579B (en) Pentafluorosulfanyl, benzoylguanidines, method for their production, their use as medicaments or diagnostic agents and medicament containing the same
JP2004065797A5 (es)
ES2191813T3 (es) Procedimiento para preparar catalizadores de oxidacion y amoxidacion mejorados a base de oxido de vanadio-antimonio.
WO2004010829A3 (en) Strip merchandisers
CL2004001110A1 (es) Composicion herbicida que comprende una mezcla de un herbicida de benzonitrilo y uno o mas agentes bioactivos, metodo de preparacion de la composicion, util para reprimir el crecimiento de malezas.
EP1020432A3 (en) Highly active and selective catalysts for the production of unsaturated nitriles, methods of and using the same

Legal Events

Date Code Title Description
EC2A Search report published

Date of ref document: 20030216

Kind code of ref document: A1

FG2A Definitive protection

Ref document number: 2181600B1

Country of ref document: ES

FD2A Announcement of lapse in spain

Effective date: 20180807