ES2191813T3 - Procedimiento para preparar catalizadores de oxidacion y amoxidacion mejorados a base de oxido de vanadio-antimonio. - Google Patents
Procedimiento para preparar catalizadores de oxidacion y amoxidacion mejorados a base de oxido de vanadio-antimonio.Info
- Publication number
- ES2191813T3 ES2191813T3 ES97305415T ES97305415T ES2191813T3 ES 2191813 T3 ES2191813 T3 ES 2191813T3 ES 97305415 T ES97305415 T ES 97305415T ES 97305415 T ES97305415 T ES 97305415T ES 2191813 T3 ES2191813 T3 ES 2191813T3
- Authority
- ES
- Spain
- Prior art keywords
- valencia
- vanadio
- amoxidation
- procedure
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
LA INVENCION SE REFIERE A UN METODO DE OBTENCION DE UN CATALIZADOR QUE PRESENTA LA SIGUIENTE FORMULA EMPIRICA DONDE A = SN, TI, O MEZCLAS DE LOS MISMOS D = AL MENOS UN ELEMENTO SELECCIONADO A PARTIR DE LI, MG, NA, CA, SR, BA, CO, FE, CR, GA, NI, ZN, GE, NB, MO, W, CU, TI, TA, SE, BI, CE, IN, AS, B, AL Y MN, Y DONDE M = 0,5 A 10 A = 0 A 10 D = 0 A 10 X = NUMERO DE ATOMOS DE OXIGENO NECESARIOS PARA SATISFACER LOS REQUERIMIENTOS DE VALENCIA DE LOS OTROS ELEMENTOS. DICHO METODO CONSISTE EN HACER REACCIONAR UN ION DE MONOPEROXIDOVANADIO, VO(O 2 + , EN SOLUCION ACUOSA, CON UNA PRIMERA PORCION DE UN COMPUESTO DE SB QUE CONTIENE SB CON UNA VALENCIA 3 + , REDUCIENDO ASI LA VALENCIA MEDIA DEL V A MENOS DE 5 + , Y OXIDANDO EL SB HASTA UNA VALENCIA DE 5 + ; ELIMINAR EL AGUA DE LA SOLUCION PARA FORMAR UN PRECURSOR DEL SECO DEL CATALIZADOR; Y CALCINAR DICHO PRECURSOR A UNA TEMPERATURA ENTRE 650 Y 950ºC PARA FORMAR EL CATALIZADOR. LA MEJORA CONSISTE EN AÑADIR AL MENOS UNA SEGUNDA PORCION DE UN COMPUESTODE SB, TRAS LA ADICION DE LA PRIMERA PORCION DE COMPUESTO DE SB QUE HA REACCIONADO PARCIALMENTE CON EL ION DE MONOPEROXIDOVANADIO.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/469,980 US5693587A (en) | 1995-06-06 | 1995-06-06 | Method for preparing vanadium antimony oxide based oxidation and ammoxidation catalysts |
SG1997002351A SG66375A1 (en) | 1995-06-06 | 1997-07-02 | Method for preparing improved vanadium antimony oxide based oxidation and ammoxidation catalysts |
EP97305415A EP0891810B1 (en) | 1995-06-06 | 1997-07-18 | Method for preparing improved vanadium antimony oxide based oxidation and ammoxidation catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2191813T3 true ES2191813T3 (es) | 2003-09-16 |
Family
ID=40749861
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97305415T Expired - Lifetime ES2191813T3 (es) | 1995-06-06 | 1997-07-18 | Procedimiento para preparar catalizadores de oxidacion y amoxidacion mejorados a base de oxido de vanadio-antimonio. |
Country Status (5)
Country | Link |
---|---|
US (1) | US5693587A (es) |
EP (1) | EP0891810B1 (es) |
DE (1) | DE69718777T2 (es) |
ES (1) | ES2191813T3 (es) |
SG (1) | SG66375A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5854172A (en) * | 1997-01-17 | 1998-12-29 | The Standard Oil Company | Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O |
DE19815279A1 (de) * | 1998-04-06 | 1999-10-07 | Basf Ag | Multimetalloxidmassen |
US6162760A (en) * | 1999-02-08 | 2000-12-19 | The Standard Oil Company | Arsenic promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation |
US6284196B1 (en) | 1999-04-01 | 2001-09-04 | Bp Corporation North America Inc. | Apparatus for monitor and control of an ammoxidation reactor with a fourier transform infrared spectrometer |
US6710011B2 (en) | 2001-12-21 | 2004-03-23 | Saudi Basic Industries Corporatioin | Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same |
DE10335454A1 (de) * | 2003-08-02 | 2005-02-24 | Reilly Industries, Inc., Indianapolis | Verfahren zur Herstellung von Cyanopyridinen und dafür geeignete Katalysatoren |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US31364A (en) * | 1861-02-12 | Butter-worker | ||
US4746641A (en) * | 1984-08-22 | 1988-05-24 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
US5094989A (en) * | 1990-12-21 | 1992-03-10 | The Standard Oil Company | Process for activation of catalysts |
US5214016A (en) * | 1992-04-02 | 1993-05-25 | The Standard Oil Company | Method of making catalysts containing vanadium, antimony and tin |
US5498588A (en) * | 1994-09-09 | 1996-03-12 | The Standard Oil Company | Surface modification and promotion of vanadium antimony oxide catalysts |
-
1995
- 1995-06-06 US US08/469,980 patent/US5693587A/en not_active Expired - Fee Related
-
1997
- 1997-07-02 SG SG1997002351A patent/SG66375A1/en unknown
- 1997-07-18 ES ES97305415T patent/ES2191813T3/es not_active Expired - Lifetime
- 1997-07-18 DE DE69718777T patent/DE69718777T2/de not_active Expired - Fee Related
- 1997-07-18 EP EP97305415A patent/EP0891810B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69718777T2 (de) | 2003-06-26 |
EP0891810A1 (en) | 1999-01-20 |
EP0891810B1 (en) | 2003-01-29 |
SG66375A1 (en) | 1999-07-20 |
DE69718777D1 (de) | 2003-03-06 |
US5693587A (en) | 1997-12-02 |
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