KR880009695A - 안티몬 및 텔루륨-함유 금속 산화물 촉매의 제조방법 - Google Patents
안티몬 및 텔루륨-함유 금속 산화물 촉매의 제조방법 Download PDFInfo
- Publication number
- KR880009695A KR880009695A KR1019880001852A KR880001852A KR880009695A KR 880009695 A KR880009695 A KR 880009695A KR 1019880001852 A KR1019880001852 A KR 1019880001852A KR 880001852 A KR880001852 A KR 880001852A KR 880009695 A KR880009695 A KR 880009695A
- Authority
- KR
- South Korea
- Prior art keywords
- silica
- tellurium
- antimony
- compound
- element selected
- Prior art date
Links
- 229910052714 tellurium Inorganic materials 0.000 title claims 5
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 title claims 5
- 229910052787 antimony Inorganic materials 0.000 title claims 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title claims 4
- 239000003054 catalyst Substances 0.000 title claims 4
- 229910044991 metal oxide Inorganic materials 0.000 title claims 4
- 150000004706 metal oxides Chemical class 0.000 title claims 4
- 238000004519 manufacturing process Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 21
- 239000000377 silicon dioxide Substances 0.000 claims 9
- 238000000034 method Methods 0.000 claims 6
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 3
- 150000002736 metal compounds Chemical class 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 239000007858 starting material Substances 0.000 claims 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 229910052770 Uranium Inorganic materials 0.000 claims 2
- 150000001463 antimony compounds Chemical class 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 239000000017 hydrogel Substances 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 239000002002 slurry Substances 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 239000011135 tin Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- 229910052790 beryllium Inorganic materials 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000011363 dried mixture Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229910021485 fumed silica Inorganic materials 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 229910052762 osmium Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 229910052701 rubidium Inorganic materials 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- 150000003498 tellurium compounds Chemical class 0.000 claims 1
- 229910052716 thallium Inorganic materials 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- (i) 안티몬 화합물, 하나 이상의 다가 금속 화합물, 및 실리카졸 및 실리카졸과 화이트카본, 훈증 실리카 또는 실리카 하이드로겔과의 혼합물중에서 선택된 실리카 지지 출불물질을 함유하는 슬러리를 pH 7이하에서 40℃이상의 온도로 가열하여 열처리된 슬러리를 제조하고, 별도로 (ii) 텔루륨-함유 용액으로서, 바나듐, 몰리브덴 및 텅스텐중에서 선택된 금속 하나 이상의 산화물, 옥시산 또는 옥시산염의 존재하에서 과산화 수소로 산화시킨 금속성 텔루륨-함유 용액을 제조한 다음, 상기 성분(i) 및 (ii) 를 혼합하고, 혼합물을 건조시킨후, 건조된 혼합물을 하소시킴을 특징으로 하여, 필수성분으로서 안티몬 화합물, 텔루륨 화합물, 다가 금속 화합물 및 실리카 지지 출발물질을 함유하는 수성 슬러리를 건조시키고, 형성된 고체를 하소시킴으로써 안티몬 및 텔루륨-함유 금속 산화물 촉매를 제조하는 방법.
- 제1항에 있어서, 다가 금속 화합물이 철, 코발트, 니켈, 주석, 우라늄, 크롬, 구리, 망간, 티탄 및 세륨 중에서 선택된 원소 하나 이상의 화합물인 방법.
- 제1항에 있어서, 안티몬 및 텔루륨-함유 금속 산화물 촉매가 하기 실험식으로 표현되는 방법.MeaSbbTecXdQeRfOg (SoO2)h상기식에서, Me는 Fe,Co,Ni,Sn,U,Cr,Cu,Mn,Ti 및 Ce 중에서 선택된 하나 이상의 원소이고, X는 V, Mo 및 W중에서 선택된 하나 이상의 원소이며, Q는 Li,Na,K,Rb,Cs,Be,Mg,Ca,Sr,Ba,Y,La,Zr,Th,Hf,Nb,Ta,Re,Ru,Os,Rh,Ir,Pd,Pt,Ag,Zn,Cd,Al,Ga,In,Tl,Ge,pb,As 및 Se 중에서 선택된 하나 이상의 원소이고, R은 B,P 및 Bi 중에서 선택된 하나 이상의 원소이며, a,b,c,d,e,f 및 g는 각각 하기와 같은 범위의 원자(atomic ratio) 를 나타낸다.a=5 내지 15, b=5 내지 100, c=0.1 내지 10, d=0 내지 15, e=0 내지 50, f=0 내지 10. g=상기 성분들에 의해 형성된 산화물에 상응하는 수, h=10 내지 200.
- 제1항에 있어서, 실리카 지지 출발물질이 실리카졸로 이루어진 방법.
- 제1항에 있어서, 실리카 지지 출발물질이 실리카 성분 총중량을 기준하여 70중량% 이하의 화이트 카본, 훈증실리카 또는 실리카 하이드로겔과 30중량% 이상의 실리카졸의 혼합물인 방법.
- 제1항에 있어서, 상기 안티몬 및 텔루륨-함유 금속 산화물 촉매가 유동베드(fluidized bed)반응에 사용되는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62039068A JPH0763628B2 (ja) | 1987-02-24 | 1987-02-24 | アンチモン・テルル含有金属酸化物触媒の製法 |
| JP62-39068 | 1987-02-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR880009695A true KR880009695A (ko) | 1988-09-15 |
Family
ID=12542809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880001852A KR880009695A (ko) | 1987-02-24 | 1988-02-23 | 안티몬 및 텔루륨-함유 금속 산화물 촉매의 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4826802A (ko) |
| EP (1) | EP0281280B1 (ko) |
| JP (1) | JPH0763628B2 (ko) |
| KR (1) | KR880009695A (ko) |
| DE (1) | DE3860956D1 (ko) |
| ES (1) | ES2018607B3 (ko) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2226375T3 (es) * | 1998-04-23 | 2005-03-16 | Mitsubishi Rayon Co., Ltd. | Catalizador para producir nitrilo insaturado. |
| CN1166452C (zh) * | 1998-08-28 | 2004-09-15 | 旭化成株式会社 | 从丙烷或异丁烷生产丙烯腈或甲基丙烯腈中所使用的氧化催化剂的制备方法 |
| JP2001029788A (ja) * | 1999-07-21 | 2001-02-06 | Mitsubishi Rayon Co Ltd | モリブデン−ビスマス−鉄含有金属酸化物流動層触媒の製法 |
| TWI268806B (en) * | 1999-09-15 | 2006-12-21 | Rohm & Haas | A catalyst useful for oxidation of alkanes |
| TW583023B (en) * | 2000-12-22 | 2004-04-11 | Nippon Kayaku Kk | Alkane oxidizing catalyst, method for producing the same and method for producing unsaturated oxygen-containing compound |
| US6943135B2 (en) | 2001-04-12 | 2005-09-13 | Rohm And Haas Company | NOx treated mixed metal oxide catalyst |
| TW548133B (en) * | 2001-04-12 | 2003-08-21 | Rohm & Haas | NOx treated mixed metal oxide catalyst |
| JP4159759B2 (ja) * | 2001-04-13 | 2008-10-01 | ダイヤニトリックス株式会社 | モリブデン−ビスマス−鉄含有複合酸化物流動層触媒の製法 |
| JP4030740B2 (ja) * | 2001-10-11 | 2008-01-09 | ダイヤニトリックス株式会社 | アンモ酸化用触媒の製造方法 |
| US7642214B2 (en) | 2003-06-10 | 2010-01-05 | Nippon Kayaku Kabushiki Kaisha | Catalyst for oxidation of alkane, process for preparing thereof and process for producing unsaturated oxygen-containing compound |
| CN102458654B (zh) | 2009-06-11 | 2014-12-31 | 三菱瓦斯化学株式会社 | 氨氧化催化剂及使用该催化剂的腈化合物的制造方法 |
| WO2012094121A1 (en) * | 2011-01-05 | 2012-07-12 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
| WO2012094118A1 (en) * | 2011-01-05 | 2012-07-12 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
| WO2012094119A1 (en) * | 2011-01-05 | 2012-07-12 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
| WO2012094120A1 (en) * | 2011-01-05 | 2012-07-12 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5318014B2 (ko) * | 1974-02-09 | 1978-06-13 | ||
| JPS56126448A (en) * | 1980-03-12 | 1981-10-03 | Nitto Chem Ind Co Ltd | Production of antimony-containing oxide catalyst |
| US4377500A (en) * | 1981-07-08 | 1983-03-22 | The Standard Oil Co. | Catalysts |
| JPS5811041A (ja) * | 1981-07-13 | 1983-01-21 | Nitto Chem Ind Co Ltd | アンチモン含有金属酸化物触媒の製法 |
| JPS60137438A (ja) * | 1983-09-28 | 1985-07-22 | Nitto Chem Ind Co Ltd | アンチモン含有金属酸化物触媒の製法 |
| JPS60166039A (ja) * | 1984-02-07 | 1985-08-29 | Nitto Chem Ind Co Ltd | アンチモン含有酸化物触媒の製法 |
| JPS60166037A (ja) * | 1984-02-07 | 1985-08-29 | Nitto Chem Ind Co Ltd | シリカ担持アンチモン含有酸化物触媒の製法 |
-
1987
- 1987-02-24 JP JP62039068A patent/JPH0763628B2/ja not_active Expired - Lifetime
-
1988
- 1988-02-18 DE DE8888301385T patent/DE3860956D1/de not_active Expired - Fee Related
- 1988-02-18 EP EP88301385A patent/EP0281280B1/en not_active Expired - Lifetime
- 1988-02-18 ES ES88301385T patent/ES2018607B3/es not_active Expired - Lifetime
- 1988-02-23 KR KR1019880001852A patent/KR880009695A/ko not_active Application Discontinuation
- 1988-02-24 US US07/159,997 patent/US4826802A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0763628B2 (ja) | 1995-07-12 |
| DE3860956D1 (de) | 1990-12-13 |
| EP0281280B1 (en) | 1990-11-07 |
| JPS63209755A (ja) | 1988-08-31 |
| EP0281280A1 (en) | 1988-09-07 |
| ES2018607B3 (es) | 1991-04-16 |
| US4826802A (en) | 1989-05-02 |
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