KR830003931A - 개량된 Sb-함유 촉매의 제조방법 - Google Patents

개량된 Sb-함유 촉매의 제조방법 Download PDF

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KR830003931A
KR830003931A KR1019800004982A KR800004982A KR830003931A KR 830003931 A KR830003931 A KR 830003931A KR 1019800004982 A KR1019800004982 A KR 1019800004982A KR 800004982 A KR800004982 A KR 800004982A KR 830003931 A KR830003931 A KR 830003931A
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catalyst
mixtures
antimony
tin
iron
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KR1019800004982A
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KR840000412B1 (ko
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다나라이 수레쉬 데브
프랭크 브레즈딜 제임스
칼 그라셀리 로버트
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래리 윌리암 에반스
더 스탠다드 오일 캄파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

개량된 Sb-함유 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 안티모니 함유 산화물 착염 촉매에, 이 촉매내의 안티모니를 기준으로 0.1내지 25%의 안티모니를 함유한 안티모니 화합물을 첨가하여 촉매 성능이 개량된 촉매를 제조하는 방법.
  2. 다음 구조식의 촉매를 사용한 상기 특허청구 범위 1의 방법.
    AaBbCcMdSbeOx
    여기서 M은 우라늄, 철, 망간, 세륨, 토륨, 주석, 티타늄 또는 이들의 혼합물이며 바람직하기로는 우라늄, 철, 주석 또는 이들의 혼합물이며,
    A는 몰리브덴, 텅스텐 또는 이들의 혼합물;
    B는 바나듐, 텔루륨, 크롬, 구리, 비스무트 또는 이들의 혼합물이고
    C는 니켈, 코발트, 알칼리금속, 알칼리토금속 또는 이들의 혼합물이며
    0 ≤a ≤10 0 ≤b ≤10
    0 ≤c ≤10 0.1 ≤d ≤10
    5 ≤e ≤100이며
    x는 산소가 촉매내의 다른 원소들과 원자가의 균형을 이루기 위해 필요한 수치이고
  3. 생성된 촉매가 다음 구조식의 촉매인 상기 특허청구 범위 1의 방법.
    AaBbCcMdSbeOx
    여기서 M은 우라늄, 철, 망간, 세륨, 토륨, 주석, 티타늄 또는 이들의 혼합물이며 바람직하기로는, 우라늄, 철, 주석 또는 이들의 혼합물이며,
    A는 몰리브덴, 텅스텐 또는 이들의 혼합물;
    B는 바나듐, 텔루륨, 크롬, 구리, 비스무트 또는 이들의 혼합물이고
    C는 니켈, 코발트, 알칼리금속, 알칼리 토금속 또는 이들의 혼합물이며
    0 ≤a ≤10 0 ≤b ≤10
    0 ≤c ≤10 0.1 ≤d ≤10
    5 ≤e ≤100이며
    x는 산소가 촉매내의 다른 원소들과 원자가의 균형을 이루기 위해 필요한 수치이고
  4. 안티모니 함유 산화물 착염 촉매에 이 촉매내의 안티모니를 기준으로 0.1 내지 25%의 안티모니를 함유한 안티모니 화합물을 첨가하여 촉매적 성능을 개량시킨 다음 구조식의 촉매.
    AaBbCcMdSbeOx
    여기서
    M은 우라늄, 철, 망간, 세륨, 토륨, 주석, 티타늄 또는 이들의 혼합물이며 바람직하기로는 우라늄, 철, 주석 또는 이들의 혼합물이며,
    A는 몰리브덴, 텅스텐 또는 이들의 혼합물;
    B는 바나듐, 텔루륨, 크롬, 구리, 비스무트 또는 이들의 혼합물이고
    C는 니켈, 코발트, 알칼리금속, 알칼리 토금속 또는 이들의 혼합물이며
    0 ≤a ≤10 0 ≤b ≤10
    0 ≤c ≤10 0.1 ≤d ≤10
    5 ≤e ≤100이며
    x는 산소가 촉매내의 다른 원소들과 원자가의 균형을 이루기 위해 필요한 수치이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019800004982A 1979-12-28 1980-12-27 개량된 안티몬-기본 산화 촉매 조성물 KR840000412B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US107942 1979-12-28
US06/107,942 US4290920A (en) 1979-12-28 1979-12-28 Sb-containing catalysts by Sb-oxide impregnation

Publications (2)

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KR830003931A true KR830003931A (ko) 1983-06-30
KR840000412B1 KR840000412B1 (ko) 1984-04-02

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KR1019800004982A KR840000412B1 (ko) 1979-12-28 1980-12-27 개량된 안티몬-기본 산화 촉매 조성물

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US (1) US4290920A (ko)
EP (1) EP0036464B1 (ko)
JP (1) JPS56102944A (ko)
KR (1) KR840000412B1 (ko)
AT (1) AT380806B (ko)
BR (1) BR8008484A (ko)
DE (1) DE3065848D1 (ko)
ES (1) ES8205575A1 (ko)
IN (1) IN155018B (ko)
TR (1) TR21685A (ko)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58140056A (ja) * 1982-02-16 1983-08-19 Nitto Chem Ind Co Ltd アンモ酸化方法
JPS5990633A (ja) * 1982-11-12 1984-05-25 Nitto Chem Ind Co Ltd アンチモン含有金属酸化物触媒の製造法または活性化法
US4863892A (en) * 1983-08-16 1989-09-05 Phillips Petroleum Company Antifoulants comprising tin, antimony and aluminum for thermal cracking processes
US4746641A (en) * 1984-08-22 1988-05-24 Standard Oil Company Ammoxidation of paraffins and catalysts therefor
US4783545A (en) * 1985-12-20 1988-11-08 The Standard Oil Company Method for ammoxidation of paraffins and catalyst system therefor
US4788173A (en) * 1985-12-20 1988-11-29 The Standard Oil Company Catalytic mixtures for ammoxidation of paraffins
US4769357A (en) * 1986-02-27 1988-09-06 Mitsubishi Petrochemical Company Limited Process for producing composite oxide catalyst
US4960921A (en) * 1986-09-08 1990-10-02 The Standard Oil Company Multiply promoted MN-SB oxide catalysts
US4767739A (en) * 1987-04-20 1988-08-30 The Standard Oil Company Catalyst system for ammoxidation of paraffins
US5134105A (en) * 1990-03-19 1992-07-28 The Standard Oil Company Catalyst for propylene ammoxidation to acrylonitrile
JP3142549B2 (ja) * 1990-09-10 2001-03-07 三菱レイヨン株式会社 鉄・アンチモン・モリブデン含有酸化物触媒組成物およびその製法
BE1005723A5 (fr) * 1992-03-25 1993-12-28 Univ Catholique Louvain Systeme catalytique pour l'oxydation selective de compose organique et procede de preparation d'un tel systeme.
TR27951A (tr) * 1992-06-23 1995-11-08 Standard Oil Co Ohio Akrilonitrile propilen amoksidasyonu icin gelistirilmis bir islem ve katalizör.
US5498588A (en) * 1994-09-09 1996-03-12 The Standard Oil Company Surface modification and promotion of vanadium antimony oxide catalysts
JP3786297B2 (ja) * 1995-03-03 2006-06-14 日本化薬株式会社 触媒の製造方法
GB2302291B (en) * 1995-06-15 1999-07-07 Basf Plc Ammoxidation of propane and preparation of catalyst therefor
WO2003101616A1 (fr) * 2002-05-31 2003-12-11 China Petroleum & Chemical Corporation Procede pour regenerer un catalyseur contenant du titane
TW200400851A (en) * 2002-06-25 2004-01-16 Rohm & Haas PVD supported mixed metal oxide catalyst
EP3897974A4 (en) * 2018-12-17 2022-11-02 California Institute of Technology ANTIMONIATE ELECTROCATALYST FOR ELECTROCHEMICAL REACTION
KR20210132111A (ko) 2019-02-21 2021-11-03 어센드 퍼포먼스 머티리얼즈 오퍼레이션즈 엘엘씨 안티몬 촉매를 안정화시키는 방법

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL135670C (ko) * 1963-05-09
US3325504A (en) * 1965-04-23 1967-06-13 Standard Oil Co Manufacture of aromatic nitriles and aldehydes
US3338952A (en) * 1965-11-15 1967-08-29 Standard Oil Co Process for the catalytic ammoxidation of olefins to nitriles
US3431292A (en) * 1966-12-23 1969-03-04 Standard Oil Co Olefinic nitriles by ammoxidation of olefins with promoted antimony oxideuranium oxide catalyst
GB1229283A (ko) * 1967-07-19 1971-04-21
JPS5242552B2 (ko) * 1974-08-01 1977-10-25
JPS5223589A (en) * 1975-08-18 1977-02-22 Mitsubishi Petrochem Co Ltd Catalyst for producing alpha,beta-unsaturaded carboxylic acid
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
CA1127137A (en) * 1977-12-20 1982-07-06 Dev D. Suresh Ammoxidation of olefins with novel antimonate catalysts

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Publication number Publication date
US4290920A (en) 1981-09-22
DE3065848D1 (en) 1984-01-12
ES498136A0 (es) 1982-06-16
JPS56102944A (en) 1981-08-17
EP0036464A2 (en) 1981-09-30
ES8205575A1 (es) 1982-06-16
TR21685A (tr) 1985-02-18
ATA615480A (de) 1985-12-15
EP0036464A3 (en) 1981-11-18
IN155018B (ko) 1984-12-22
BR8008484A (pt) 1981-07-14
EP0036464B1 (en) 1983-12-07
AT380806B (de) 1986-07-10
KR840000412B1 (ko) 1984-04-02

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