KR850004571A - 불포화 알데히드를 산화시키는 방법 - Google Patents
불포화 알데히드를 산화시키는 방법 Download PDFInfo
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- KR850004571A KR850004571A KR1019840007831A KR840007831A KR850004571A KR 850004571 A KR850004571 A KR 850004571A KR 1019840007831 A KR1019840007831 A KR 1019840007831A KR 840007831 A KR840007831 A KR 840007831A KR 850004571 A KR850004571 A KR 850004571A
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- KR
- South Korea
- Prior art keywords
- catalyst
- elements
- catalyst contains
- mainly composed
- composite oxide
- Prior art date
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- 150000001299 aldehydes Chemical class 0.000 title claims 2
- 239000003054 catalyst Substances 0.000 claims 12
- 238000000034 method Methods 0.000 claims 11
- 229910052802 copper Inorganic materials 0.000 claims 6
- 229910052749 magnesium Inorganic materials 0.000 claims 6
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims 4
- 229910052782 aluminium Inorganic materials 0.000 claims 4
- 229910052787 antimony Inorganic materials 0.000 claims 4
- 229910052785 arsenic Inorganic materials 0.000 claims 4
- 229910052793 cadmium Inorganic materials 0.000 claims 4
- 229910052792 caesium Inorganic materials 0.000 claims 4
- 229910052804 chromium Inorganic materials 0.000 claims 4
- 239000002131 composite material Substances 0.000 claims 4
- 229910052746 lanthanum Inorganic materials 0.000 claims 4
- 229910052748 manganese Inorganic materials 0.000 claims 4
- 229910052759 nickel Inorganic materials 0.000 claims 4
- 229910052698 phosphorus Inorganic materials 0.000 claims 4
- 229910052700 potassium Inorganic materials 0.000 claims 4
- 229910052702 rhenium Inorganic materials 0.000 claims 4
- 229910052701 rubidium Inorganic materials 0.000 claims 4
- 229910052709 silver Inorganic materials 0.000 claims 4
- 229910052718 tin Inorganic materials 0.000 claims 4
- 229910052719 titanium Inorganic materials 0.000 claims 4
- 229910052727 yttrium Inorganic materials 0.000 claims 4
- 229910052725 zinc Inorganic materials 0.000 claims 4
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052797 bismuth Inorganic materials 0.000 claims 2
- 229910052796 boron Inorganic materials 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000012808 vapor phase Substances 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 불포화된 알데히드를 주로하기 실험식의 원소 및 비율로 구성된 복합산화물 촉매(이는 P,Ce,Fe,Al 및 Ni를 거의 함유하지 않는다)의 존재하 및 임의로 스티임의 존재하에, 산소분자로 산화시켜서 아크롤레인으로부터 아크릴산을 제조하는 증기상 공정, MoaVbZreXdYeOf상기식에서, X는 Cu 및 Mg 중 1종이상이며 Y는 K,Rb,Cs,Sn,Ti,Cr,Re,Sb,Mn,Ge,Ba,Zn,Ag,Cd,La,As,Bi,B 및 W 중 1종 이상이고 a는 6 내지 18이며, b는 0.1 내지 10이고, c는 0.05내지 5이고, d는 0내지 3이고, e는 0내지 2이고, f는 존재하는 다른 원소의 원가가 요구치를 만족시키기에 충분한 수이다.
- 제1항에 있어서, a가 9내지 15이고, b가 0.5내지 5이며, c가 0.1내지 3이고, d가 0.01내지 2이며, e가 0내지 1인 방법.
- 아크롤레인을 주로 다음 실험식의 원소 및 비율로 구성된 복합산화물 촉매(이는 P,W1,Ce,Fe,Al 및 Ni를 거의 함유하지 않는다)의 존재하 및 임의로 스티임의 존재하에, 산소 분자에 산화시켜서 아크릴산을 제조하는 증기상공정 MoaVbZreXdYeOf상기식에서, X는 Cu 및 Mg 중 1종이상이며 Y는 K,Rb,Cs,Sn,Ti,Cr,Re,Sb,Mn,Ge,Ba,Zn,Ag,Cd,La,As,Bi 및 B중 1종 이상이며, a는 6내지 18이며, b는 0.1 내지 10이고, c는 0.05내지 5이고, d는 0내지 3이고, e는 0 내지 2이며, f는 존재하는 다른 원소의 원자가 요구치를 만족시키기에 충분한 수이다.
- 제3항에 있어서, a가 9내지 15, b가 0.5내지 5, c가 0.1 내지 3, d가 0.01내지 2, e가 0내지 1인 방법.
- 주로 다음 실험식의 원소 및 비율로 구성된 복합산화물 촉매 조성물. MoaVbZreXdYeOf상기식에서, X는 Cu 및 Mg 중 1종이상이며 Y는 K,Rb,Cs,Sn,Ti,Cr,Re,Sb,Mn,Ge,Ba,Zn,Ag,Cd,La,As,BiB및 W중 1종 이상이며, a는 6내지 18이며, b는 0.1 내지 10이고, c는 0.05내지 5이고, d는 0내지 3이고, e는 0 내지 2이며, f는 존재하는 다른 원소의 원자가 요구치를 만족시키기에 충분한 수이며, 상기촉매는 P,Ce,Al,Fe 및 Ni를 거의 함유하지 않는다.
- 제5항에 있어서, a가 9내지 15, b가 0.5 내지 5, c가 0.1 내지 3, d가 0.01내지 2, e가 0내지 1인 방법.
- 주로 다음 실험식의 원소 및 비율로 구성된 복합산화물 촉매산화물.MoaVbZreXdYeOf상기식에서, X는 Cu 및 Mg 중 1종이상이며 Y는 K,Rb,Cs,Sn,Ti,Cr,Re,Sb,Mn,Ge,Ba,Zn,Ag,Cd,La,As,Bi 및 B중 1종 이상이며, a는 6내지 18이며, b는 0.1 내지 10이고, c는 0.05내지 5이고, d는 0내지 3이고, e는 0 내지 2이며, f는 존재하는 다른 원소의 원자가 요구치를 만족시키기에 충분한 수이며, 상기촉매는 P,Ce,Al,Fe 및 Ni를 거의 함유하지 않는다.
- 제7항에 있어서, a가 9내지 15, b가 0.5 내지 5, c가 0.1 내지 3, d가 0.01내지 2, e가 0내지 1인 방법.
- 제1항에 있어서, 촉매가 Cu 및 Mg중 1종 이상을 함유하는 방법.
- 제3항에 있어서, 촉매가 Cu을 함유하는 방법.
- 제3항에 있어서, 촉매가 Mg을 함유하는 방법.
- 제5항에 있어서, 촉매가 Cu 및 Mg중 1종 이상을 함유하는 방법.
- 제7항에 있어서, 촉매가 Cu을 함유하는 방법.
- 제7항에 있어서, 촉매가 Mg을 함유하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US560289 | 1983-12-12 | ||
| US06/560,289 US4552978A (en) | 1983-12-12 | 1983-12-12 | Oxidation of unsaturated aldehydes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR850004571A true KR850004571A (ko) | 1985-07-25 |
| KR900006438B1 KR900006438B1 (ko) | 1990-08-31 |
Family
ID=24237148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019840007831A KR900006438B1 (ko) | 1983-12-12 | 1984-12-11 | 불포화 알데히드를 산화시키는 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4552978A (ko) |
| EP (1) | EP0146099B1 (ko) |
| JP (1) | JPS60149543A (ko) |
| KR (1) | KR900006438B1 (ko) |
| CN (1) | CN1024344C (ko) |
| DD (1) | DD237833A5 (ko) |
| DE (1) | DE3481705D1 (ko) |
| HU (1) | HUT38091A (ko) |
| RO (1) | RO90764B (ko) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3938937A1 (de) * | 1989-11-24 | 1991-05-29 | Wacker Chemitronic | Verfahren und vorrichtung zur herstellung von siliciumstaeben mit hohem sauerstoffgehalt durch tiegelfreies zonenziehen, dadurch erhaeltliche siliciumstaebe und daraus hergestellte siliciumscheiben |
| JP3537253B2 (ja) * | 1996-03-06 | 2004-06-14 | 株式会社日本触媒 | アクリル酸の製造方法 |
| CN100490973C (zh) * | 2004-11-26 | 2009-05-27 | 上海华谊丙烯酸有限公司 | 甲基丙烯醛选择氧化合成甲基丙烯酸的催化剂及其应用 |
| CN102247862B (zh) * | 2010-05-18 | 2013-12-04 | 中国石油天然气股份有限公司 | 一种多层复合金属氧化物催化剂及其制备方法 |
| CN104646018B (zh) * | 2013-11-19 | 2016-11-23 | 中国石油天然气股份有限公司 | 一种不饱和醛选择性氧化催化剂及其制备方法 |
| CN110586076A (zh) * | 2018-06-12 | 2019-12-20 | 中国石油化工股份有限公司 | 合成丙烯酸的催化剂 |
| CN110586071A (zh) * | 2018-06-12 | 2019-12-20 | 中国石油化工股份有限公司 | 用于生产丙烯酸的负载型催化剂 |
| CN110586070A (zh) * | 2018-06-12 | 2019-12-20 | 中国石油化工股份有限公司 | 负载型催化剂生产丙烯酸的方法 |
| CN110586122A (zh) * | 2018-06-12 | 2019-12-20 | 中国石油化工股份有限公司 | 丙烯酸催化剂 |
| CN110586123A (zh) * | 2018-06-12 | 2019-12-20 | 中国石油化工股份有限公司 | 负载型催化剂制备丙烯酸的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA988071A (en) * | 1970-09-24 | 1976-04-27 | Arthur W. Sleight | Catalyst compositions of scheelite crystal structure containing bismuth ions and cation vacancies |
| JPS5529062B2 (ko) * | 1973-10-31 | 1980-07-31 | ||
| JPS5195014A (en) * | 1975-02-14 | 1976-08-20 | arufua beeta fuhowakarubonsanno seizoho | |
| JPS5246016A (en) * | 1975-10-08 | 1977-04-12 | Japan Synthetic Rubber Co Ltd | Process for preparation of methacrylic acid |
| US4184981A (en) * | 1977-09-12 | 1980-01-22 | Celanese Corporation | Selective oxidation catalyst |
| EP0032012B1 (en) * | 1979-12-17 | 1984-02-15 | Monsanto Company | Oxidation and ammoxidation catalysts and their use |
-
1983
- 1983-12-12 US US06/560,289 patent/US4552978A/en not_active Expired - Fee Related
-
1984
- 1984-12-10 EP EP84115028A patent/EP0146099B1/en not_active Expired - Lifetime
- 1984-12-10 DE DE8484115028T patent/DE3481705D1/de not_active Expired - Fee Related
- 1984-12-11 RO RO116627A patent/RO90764B/ro unknown
- 1984-12-11 KR KR1019840007831A patent/KR900006438B1/ko not_active IP Right Cessation
- 1984-12-11 DD DD84270603A patent/DD237833A5/de not_active IP Right Cessation
- 1984-12-11 JP JP59261672A patent/JPS60149543A/ja active Pending
- 1984-12-12 HU HU844627A patent/HUT38091A/hu unknown
-
1985
- 1985-06-19 CN CN85104792A patent/CN1024344C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4552978A (en) | 1985-11-12 |
| CN85104792A (zh) | 1986-12-17 |
| DD237833A5 (de) | 1986-07-30 |
| DE3481705D1 (de) | 1990-04-26 |
| EP0146099B1 (en) | 1990-03-21 |
| EP0146099A3 (en) | 1986-04-09 |
| RO90764B (ro) | 1987-01-31 |
| HUT38091A (en) | 1986-04-28 |
| CN1024344C (zh) | 1994-04-27 |
| KR900006438B1 (ko) | 1990-08-31 |
| RO90764A (ro) | 1987-01-30 |
| JPS60149543A (ja) | 1985-08-07 |
| EP0146099A2 (en) | 1985-06-26 |
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| FPAY | Annual fee payment |
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