GB1473035A - Catalyst and process for producing unsaturated carboxylic acid - Google Patents

Catalyst and process for producing unsaturated carboxylic acid

Info

Publication number
GB1473035A
GB1473035A GB2344875A GB2344875A GB1473035A GB 1473035 A GB1473035 A GB 1473035A GB 2344875 A GB2344875 A GB 2344875A GB 2344875 A GB2344875 A GB 2344875A GB 1473035 A GB1473035 A GB 1473035A
Authority
GB
United Kingdom
Prior art keywords
catalyst
composition
carboxylic acid
unsaturated carboxylic
producing unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2344875A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Publication of GB1473035A publication Critical patent/GB1473035A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

1473035 Oxidation catalyst MITSUBISHI RAYON CO Ltd 29 May 1975 [31 May 1974] 23448/75 Heading B1E [Also in Division Cl] An oxidic catalyst composition for the oxidative formation of acrylic or methacrylic acid from the corresponding unsaturated aldehyde has the general formula wherein: X is at least one of Sb, V, W, Fe, Mn and Sn; Y is at least one of Li, Na, K, Rb and Cs; a = 0.025-1; b = 1; c = 0.0025- 0.5; O#d<0.015; e = 0.0025-1.0; f = 0.003-0.417 and g is a value to satisfy valency requirements. The composition may be formed by evaporating solvent from a solution of compounds of -the elements followed by calcination. The composition may be supported e.g. on silica, alumina or silicon carbide.
GB2344875A 1974-05-31 1975-05-29 Catalyst and process for producing unsaturated carboxylic acid Expired GB1473035A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP49062067A JPS5827255B2 (en) 1974-05-31 1974-05-31 Method for producing unsaturated fatty acids

Publications (1)

Publication Number Publication Date
GB1473035A true GB1473035A (en) 1977-05-11

Family

ID=13189375

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2344875A Expired GB1473035A (en) 1974-05-31 1975-05-29 Catalyst and process for producing unsaturated carboxylic acid

Country Status (5)

Country Link
JP (1) JPS5827255B2 (en)
DE (1) DE2523757C3 (en)
FR (1) FR2275436A1 (en)
GB (1) GB1473035A (en)
NL (1) NL7506423A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005769A1 (en) * 1978-05-31 1979-12-12 Nippon Kayaku Kabushiki Kaisha A process for producing methacrolein and methacrylic acid
EP0088328A2 (en) * 1982-03-10 1983-09-14 BASF Aktiengesellschaft Oxidation catalyst, in particular for the preparation of methyacrylic acid by the vapour phase oxidation of methacrolein
US4409128A (en) 1980-08-09 1983-10-11 Basf Aktiengesellschaft Oxidation catalyst, especially for the preparation of methacrylic acid by gas phase oxidation of methacrolein
EP0100057A1 (en) * 1982-07-20 1984-02-08 Mitsubishi Kasei Corporation Process for producing methacrylic acid and/or methacrylic acid ester
US4467113A (en) * 1978-12-13 1984-08-21 Nippon Kayaku Kabushiki Kaisha Process for producing methacrylic acid
US4595778A (en) * 1983-03-11 1986-06-17 Basf Aktiengesellschaft Preparation of methacrylic acid and catalyst therefor
US4925823A (en) * 1982-03-10 1990-05-15 Basf Aktiengesellschaft Process and catalyst for the preparation of methacrylic acid
US6930201B2 (en) * 2000-12-25 2005-08-16 Mitsubishi Rayon Co., Ltd. Process for producing methacrylic acid
EP2261196A1 (en) * 2008-04-09 2010-12-15 Nippon Shokubai Co., Ltd. Process for the production of acrolein and/or acrylic acid

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51115414A (en) * 1975-04-03 1976-10-12 Mitsubishi Rayon Co Ltd Process for preparation of unsaturated fatty acids
JPS5946934B2 (en) * 1976-02-09 1984-11-15 東ソー株式会社 Method for manufacturing methacrylic acid
US4085065A (en) 1976-10-19 1978-04-18 The Standard Oil Company (Ohio) Process for the preparation of unsaturated acids from unsaturated aldehydes
JPS5924140B2 (en) * 1977-10-31 1984-06-07 日本化薬株式会社 Method for producing methacrylic acid and catalyst
US4252682A (en) * 1978-12-26 1981-02-24 Halcon Research And Development Corp. Catalyst for producing methacrylic acid
NL7909142A (en) * 1978-12-26 1980-06-30 Halcon Res & Dev CATALYST AND METHOD FOR PREPARING METHACRYLIC ACID.
JPS55124734A (en) * 1979-03-22 1980-09-26 Nippon Kayaku Co Ltd Preparation of methacrylic acid
CA1199905A (en) * 1982-06-07 1986-01-28 William J. Kennelly Catalyst compositions and their use for the preparation of unsaturated carboxylic acids

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57297B2 (en) * 1974-01-19 1982-01-06

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005769A1 (en) * 1978-05-31 1979-12-12 Nippon Kayaku Kabushiki Kaisha A process for producing methacrolein and methacrylic acid
US4467113A (en) * 1978-12-13 1984-08-21 Nippon Kayaku Kabushiki Kaisha Process for producing methacrylic acid
US4530916A (en) * 1978-12-13 1985-07-23 Nippon Kayaku Kabushiki Kaisha Catalyst for use in a methacrylic acid process
US4409128A (en) 1980-08-09 1983-10-11 Basf Aktiengesellschaft Oxidation catalyst, especially for the preparation of methacrylic acid by gas phase oxidation of methacrolein
US4925823A (en) * 1982-03-10 1990-05-15 Basf Aktiengesellschaft Process and catalyst for the preparation of methacrylic acid
EP0088328A3 (en) * 1982-03-10 1984-05-30 Basf Aktiengesellschaft Oxidation catalyst, in particular for the preparation of methyacrylic acid by the vapour phase oxidation of methacrolein
US4489170A (en) * 1982-03-10 1984-12-18 Basf Aktiengesellschaft Oxidation catalyst, especially for the preparation of methacrylic acid by gas phase oxidation of methacrolein
EP0088328A2 (en) * 1982-03-10 1983-09-14 BASF Aktiengesellschaft Oxidation catalyst, in particular for the preparation of methyacrylic acid by the vapour phase oxidation of methacrolein
EP0100057A1 (en) * 1982-07-20 1984-02-08 Mitsubishi Kasei Corporation Process for producing methacrylic acid and/or methacrylic acid ester
US4595778A (en) * 1983-03-11 1986-06-17 Basf Aktiengesellschaft Preparation of methacrylic acid and catalyst therefor
US6930201B2 (en) * 2000-12-25 2005-08-16 Mitsubishi Rayon Co., Ltd. Process for producing methacrylic acid
EP2261196A1 (en) * 2008-04-09 2010-12-15 Nippon Shokubai Co., Ltd. Process for the production of acrolein and/or acrylic acid
EP2261196A4 (en) * 2008-04-09 2012-05-30 Nippon Catalytic Chem Ind Process for the production of acrolein and/or acrylic acid
US8415498B2 (en) 2008-04-09 2013-04-09 Nippon Shokubai Co., Ltd. Process for producing acrolein and/or acrylic acid

Also Published As

Publication number Publication date
NL7506423A (en) 1975-12-02
JPS5827255B2 (en) 1983-06-08
DE2523757B2 (en) 1978-05-03
DE2523757A1 (en) 1976-01-15
JPS50151816A (en) 1975-12-06
DE2523757C3 (en) 1979-01-04
FR2275436A1 (en) 1976-01-16

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19950528