KR840000273A - 안티모네이트 촉매의 제조방법 - Google Patents

안티모네이트 촉매의 제조방법 Download PDF

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KR840000273A
KR840000273A KR1019820003028A KR820003028A KR840000273A KR 840000273 A KR840000273 A KR 840000273A KR 1019820003028 A KR1019820003028 A KR 1019820003028A KR 820003028 A KR820003028 A KR 820003028A KR 840000273 A KR840000273 A KR 840000273A
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catalyst
support material
slurry
mixed
compound
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KR1019820003028A
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KR880001496B1 (ko
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칼 그라셀리 로버트
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라리 윌리엄 에반스
더 스탠다드 오일 캄파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8435—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

안티모네이트 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기 (1)단계에서의 공급원 화합물과 혼합하는 지지물질이 훈연 촉매 지지물질 및 촉매 지지물 졸(sol)로 이루어짐을 특징으로 하여, (1) 안티모. 이트-기준 산화 작화합물의 모든성분을 함유한 공급원화합물 및 상기 지지물질을 혼합하여 전-촉매 슬러리를 형성시키고, (2) 상기 전-촉매 슬러리에서 액체를 제거하여 전-촉매를 형성시킨 다음, (3) 상기 전-촉매를 고온에서 가열하여 촉매를 형성시키는, 촉매지체상에 지지된 상기 산화착화합물을 함유하는 유동상촉매를 제조하는 단일슬러리 방법.
  2. 제1항에 있어서, 실리카 졸 및 훈연 실리카를 상기 공급원 화합물과 혼합시키는 방법.
  3. 제2항에 있어서, 상기 훈연 실리카 및 상기 실리카졸을 상기 공급원 화합물과 혼합하기 전에 함께 혼합하는 방법.
  4. 제1항에 있어서, 상기 안티모네이트-기준 촉매가 다음 일반식을 갖는 방법.
    AaBbSbcOx
    상기식에서 : A는 Fe, U, Sn, Th, Cr, Ti, Ce, Mg 및/또는 Mn이고, B는 Zr, V, W, Mo, As, B, Cu, Pr, Al, Te, 희토류금속, 알카리금속, Mg 및/또는 Bi 이외의 알카리 토금속이고, a는 0내지 10이고 b는 0내지 10이고 c는 0.1내지 40이고, A가 Sn 및/또는 Ti가 아닐경우 a+b<c이고 x는 존재하는 다른 원소에서 요구되는 원자가로써 결정된 수이다.
  5. 제4항에 있어서, a는 0.1 내지 10이고, b는 0.01 내지 10이고, c는 0.1 내지 20인 방법.
  6. 제5항에 있어서, 4b=a+c인 방법.
  7. 제6항에 있어서, A가 Fe 및/또는 Sn인 방법.
  8. 제7항에 있어서, b/c는 1/10내지 5/10인 방법.
  9. 제8항에 있어서, b/c는 2/10내지 4/10인 방법.
  10. 청구범위(1)의 방법에 의해 제조된 촉매.
  11. 청구범위(4)의 방법에 의해 제조된 촉매.
  12. 하기(1)단계에서의 공급된 화합물과 혼합하는 지지물이 훈연 촉매 지지물질 및 촉매 지지물질 졸로 이루어지고 하기 전-촉매 슬러리가 훈연 촉매 지지물질 및 하나이상의 공급원 화합물을 함유한 슬러리-유도 고체생성물질을 첨가함이 없이 형성시킴을 특징으로 하여, (1) 안티모네이트-기준 산화착화합물의 모든 성분을 함유한 공급원 화합물 및 상기 지지물질을 혼합하여 전-촉매 슬러리를 형성시키고, (2) 상기 전-촉매 슬러리에서 액체를 제거하여 전-촉매를 형성시킨다음(3) 상기 전-촉매를 고온에서 가열하여 촉매를 형성시키는, 촉매지지체상에 지지된 상기 산화착화합물을 함유하는 유동상촉매를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR8203028A 1981-07-08 1982-07-07 안티모네이트-기본 촉매의 제조방법 KR880001496B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US281160 1981-07-08
US281,160 1981-07-08
US06/281,160 US4377500A (en) 1981-07-08 1981-07-08 Catalysts

Publications (2)

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KR840000273A true KR840000273A (ko) 1984-02-18
KR880001496B1 KR880001496B1 (ko) 1988-08-16

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Country Status (12)

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US (1) US4377500A (ko)
EP (1) EP0069439B1 (ko)
JP (1) JPS5811045A (ko)
KR (1) KR880001496B1 (ko)
BR (1) BR8203314A (ko)
CA (1) CA1177468A (ko)
DE (1) DE3267980D1 (ko)
ES (1) ES8303115A1 (ko)
IN (1) IN158093B (ko)
MX (1) MX159067A (ko)
PT (1) PT75207B (ko)
TR (1) TR21656A (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0115646A1 (en) * 1983-02-08 1984-08-15 Stamicarbon B.V. Oxidation catalysts and their preparation procedure
JPS60166037A (ja) * 1984-02-07 1985-08-29 Nitto Chem Ind Co Ltd シリカ担持アンチモン含有酸化物触媒の製法
JPS61231291A (ja) * 1985-04-01 1986-10-15 日本鋼管株式会社 スパイラル状リブ付被覆ケ−ブル
JPH022734Y2 (ko) * 1985-05-08 1990-01-23
JPH0763628B2 (ja) * 1987-02-24 1995-07-12 日東化学工業株式会社 アンチモン・テルル含有金属酸化物触媒の製法
US6395676B2 (en) 1994-02-22 2002-05-28 The Standard Oil Company Process for the preparation of fluid bed vinyl acetate catalyst
ES2321162T3 (es) 1997-04-15 2009-06-03 Csir Compuestos y composiciones farmaceuticas que tienen actividad supresora del apetito.
GB2396815B (en) 1999-10-27 2004-09-08 Phytopharm Plc A composition comprising a pregnenone derivative and an NSAID
GB2363985B (en) 2000-06-30 2004-09-29 Phytopharm Plc Extracts,compounds & pharmaceutical compositions having anti-diabetic activity and their use
US6916763B2 (en) * 2002-11-27 2005-07-12 Solutia Inc. Process for preparing a catalyst for the oxidation and ammoxidation of olefins
EP1691921A1 (en) * 2003-12-18 2006-08-23 Avantium International B.V. Catalysts for alkane or alkene oxidation and ammoxidation

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3524823A (en) * 1965-08-30 1970-08-18 Goodrich Co B F Catalyst and method of preparing unsaturated acids and aldehydes
US3338952A (en) * 1965-11-15 1967-08-29 Standard Oil Co Process for the catalytic ammoxidation of olefins to nitriles
US3431292A (en) * 1966-12-23 1969-03-04 Standard Oil Co Olefinic nitriles by ammoxidation of olefins with promoted antimony oxideuranium oxide catalyst
DE2050155C3 (de) * 1970-10-13 1978-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Verfahren zur Herstellung eines Antimon, Molybdän, Vanadin und Wolfram enthaltenden Oxydationskatalysators
US4083804A (en) * 1974-02-09 1978-04-11 Nitto Chemical Industry Co., Ltd. Catalyst for use in and process for preparing acrylonitrile
GB1553801A (en) * 1977-05-13 1979-10-10 Nitto Chemical Industry Co Ltd Process for production of attrition resistant antimony oxide containing fluidized bed catalyst having controlled particle size distribution
US4242236A (en) * 1979-03-29 1980-12-30 Chevron Research Company 65-130 Angstrom mean radius silica-alumina catalyst support
US4280929A (en) * 1979-09-17 1981-07-28 Standard Oil Company Attrition resistant-higher active component fluid bed catalysts

Also Published As

Publication number Publication date
KR880001496B1 (ko) 1988-08-16
MX159067A (es) 1989-04-14
IN158093B (ko) 1986-08-30
TR21656A (tr) 1985-01-18
PT75207B (en) 1984-06-27
EP0069439A3 (en) 1984-03-28
US4377500A (en) 1983-03-22
EP0069439A2 (en) 1983-01-12
CA1177468A (en) 1984-11-06
ES510138A0 (es) 1983-02-01
DE3267980D1 (en) 1986-01-30
EP0069439B1 (en) 1985-12-18
PT75207A (en) 1982-08-01
JPS5811045A (ja) 1983-01-21
JPH0316177B2 (ko) 1991-03-04
BR8203314A (pt) 1983-05-24
ES8303115A1 (es) 1983-02-01

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