KR830005900A - 메타크롤레인 산화촉매 - Google Patents
메타크롤레인 산화촉매 Download PDFInfo
- Publication number
- KR830005900A KR830005900A KR1019810002828A KR810002828A KR830005900A KR 830005900 A KR830005900 A KR 830005900A KR 1019810002828 A KR1019810002828 A KR 1019810002828A KR 810002828 A KR810002828 A KR 810002828A KR 830005900 A KR830005900 A KR 830005900A
- Authority
- KR
- South Korea
- Prior art keywords
- element selected
- oxidation catalyst
- methacrolein
- catalyst
- formula
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 4
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 title claims 3
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- 230000001590 oxidative effect Effects 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- 229910052790 beryllium Inorganic materials 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- 229910052745 lead Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052753 mercury Inorganic materials 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052701 rubidium Inorganic materials 0.000 claims 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (2)
- 다음 일반식(I)의 촉매 조성물Mo·12Po·1-3Mo·1-3Cao·1-2Vo·1-2Xo·01-2YaOb(I)상기 일반식에서M는 칼륨, 루비듐 및 세슘중에서 선정한 1개 이상의 원소이고,X는 Ba,La,Ga,Al,Ag,Cd,Ti,Tl,Hg,Pb 및 Zn중에서 선정한 1개 이상의 원소이며,Y는 a〉 0인 경우 Fe,Co,Ni,Sr,Mn,In,Ta,Ga,S 및 Be중에서 선정한 1개 이상의 원소이고a는 0내지 약 2의 수이며 또b는 존재하는 기타원소의 원자가를 만족시키는 수이이다.
- 상기 일반식(I)의촉매량만큼의 촉매존재하의 산화조건하에서 메타크롤레인을 산소분자와 접촉시키는 것을 특징으로 하여, 메타크롤레인을 산화시켜 메타클릴산을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US175,236 | 1980-08-05 | ||
US06/175,236 US4301031A (en) | 1980-08-05 | 1980-08-05 | Methacrolein oxidation catalysts |
US175236 | 1993-12-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830005900A true KR830005900A (ko) | 1983-09-14 |
KR840000986B1 KR840000986B1 (ko) | 1984-07-13 |
Family
ID=22639503
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019810002828A KR840000986B1 (ko) | 1980-08-05 | 1981-08-04 | 메타크롤레인 산화용 촉매 조성물 |
Country Status (7)
Country | Link |
---|---|
US (1) | US4301031A (ko) |
EP (1) | EP0051348B1 (ko) |
JP (1) | JPS5732734A (ko) |
KR (1) | KR840000986B1 (ko) |
CA (1) | CA1163618A (ko) |
DE (1) | DE3169806D1 (ko) |
MX (1) | MX159633A (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3030243A1 (de) * | 1980-08-09 | 1982-03-18 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
US4410448A (en) * | 1981-12-28 | 1983-10-18 | The Standard Oil Company | Method for controlling the change in the crush strength of a catalyst particle during finishing calcination |
US4710484A (en) * | 1982-06-25 | 1987-12-01 | The Standard Oil Company | Method for preparing a supported mixed-metal oxide oxidation catalyst |
US4558029A (en) * | 1982-09-13 | 1985-12-10 | The Standard Oil Company | Antimony-containing C4 oxidation catalysts |
JPS59115750A (ja) * | 1982-12-22 | 1984-07-04 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒 |
WO1987004086A1 (en) * | 1986-01-08 | 1987-07-16 | Mitsubishi Rayon Co., Ltd. | Process for producing methacrylic acid and catalysts for the process |
US5196578A (en) * | 1987-10-09 | 1993-03-23 | Mitsui Toatsu Chemicals, Incorporated | Purification process of methacrylic acid |
EP0415347B2 (en) * | 1989-08-29 | 2002-06-05 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Catalyst for the production of methacrylic acid |
JPH03167152A (ja) * | 1989-11-27 | 1991-07-19 | Mitsubishi Rayon Co Ltd | メタクリル酸の製造法 |
US5221767A (en) * | 1990-07-12 | 1993-06-22 | Basf Aktiengesellschaft | Compositions of the formula Mo12 Pa Vb X1 c X2 d X3 e Sbf Reg Sh On |
DE4022212A1 (de) * | 1990-07-12 | 1992-01-16 | Basf Ag | Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts) |
MXPA03002374A (es) * | 2000-09-21 | 2003-06-30 | Nippon Kayaku Kabushiki Kaisha | Catalizador para produccion de acido metacrilico, catalizador revestido y proceso para produccion del mismo. |
JP4671320B2 (ja) * | 2000-09-21 | 2011-04-13 | 日本化薬株式会社 | メタクリル酸製造用被覆触媒の製法 |
KR100557640B1 (ko) * | 2004-01-09 | 2006-03-10 | 주식회사 엘지화학 | 신규한 헤테로폴리산 촉매 및 그의 제조방법 |
JP5659490B2 (ja) * | 2008-07-29 | 2015-01-28 | 三菱レイヨン株式会社 | メタクリル酸製造用触媒の製造方法、およびメタクリル酸の製造方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1144709B (de) * | 1961-07-12 | 1963-03-07 | Basf Ag | Verfahren zur Herstellung von Phthalsaeureanhydrid durch katalytische Oxydation von o-Xylol |
US4166190A (en) * | 1973-10-11 | 1979-08-28 | The Standard Oil Company | Process for the preparation of methacrylic acid from methacrolein |
US3976688A (en) * | 1973-11-26 | 1976-08-24 | Nippon Zeon Co., Ltd. | Process for preparing unsaturated carboxylic acids |
CA1055468A (en) | 1973-12-26 | 1979-05-29 | Noel J. Bremer | Catalyst compositions especially useful for preparation of unsaturated acids |
US4225466A (en) * | 1973-12-29 | 1980-09-30 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Catalytic oxide composition for preparing methacrylic acid |
GB1489559A (en) * | 1975-03-03 | 1977-10-19 | Mitsubishi Rayon Co | Catalytic process for the preparation of acrylic acid or methacrylic acid |
JPS51115414A (en) * | 1975-04-03 | 1976-10-12 | Mitsubishi Rayon Co Ltd | Process for preparation of unsaturated fatty acids |
US4017423A (en) * | 1975-08-18 | 1977-04-12 | The Standard Oil Company (Ohio) | Process for the preparation of unsaturated acids from unsaturated aldehydes |
JPS5946934B2 (ja) * | 1976-02-09 | 1984-11-15 | 東ソー株式会社 | メタクリル酸の製法 |
US4101448A (en) * | 1976-05-14 | 1978-07-18 | The Standard Oil Company | Catalyst compositions especially useful for preparation of unsaturated acids |
US4042533A (en) * | 1976-06-07 | 1977-08-16 | The Standard Oil Company | Producing unsaturated aliphatic acids |
JPS543008A (en) * | 1977-06-09 | 1979-01-11 | Japan Synthetic Rubber Co Ltd | Preparation of methacrylic acid |
JPS552619A (en) * | 1978-06-21 | 1980-01-10 | Nippon Kayaku Co Ltd | Preparation of methacrylic acid and catalyst |
US4212767A (en) * | 1978-10-17 | 1980-07-15 | Air Products And Chemicals, Inc. | Method of preparing an oxidation catalyst containing a molybdate anion |
YU41495B (en) * | 1979-01-23 | 1987-08-31 | Nippon Kayaku Kk | Process for obtaining methacrolein and methacrylic acid |
JPS55124734A (en) * | 1979-03-22 | 1980-09-26 | Nippon Kayaku Co Ltd | Preparation of methacrylic acid |
JPS5637050A (en) * | 1979-09-04 | 1981-04-10 | Ube Ind Ltd | Preparation of catalyst for preparing unsaturated acid |
-
1980
- 1980-08-05 US US06/175,236 patent/US4301031A/en not_active Expired - Lifetime
-
1981
- 1981-05-26 CA CA000378387A patent/CA1163618A/en not_active Expired
- 1981-06-08 JP JP8799481A patent/JPS5732734A/ja active Granted
- 1981-06-24 MX MX187962A patent/MX159633A/es unknown
- 1981-06-25 DE DE8181302863T patent/DE3169806D1/de not_active Expired
- 1981-06-25 EP EP81302863A patent/EP0051348B1/en not_active Expired
- 1981-08-04 KR KR1019810002828A patent/KR840000986B1/ko active
Also Published As
Publication number | Publication date |
---|---|
JPS5732734A (en) | 1982-02-22 |
MX159633A (es) | 1989-07-20 |
JPH0221859B2 (ko) | 1990-05-16 |
EP0051348A1 (en) | 1982-05-12 |
KR840000986B1 (ko) | 1984-07-13 |
EP0051348B1 (en) | 1985-04-10 |
US4301031A (en) | 1981-11-17 |
DE3169806D1 (en) | 1985-05-15 |
CA1163618A (en) | 1984-03-13 |
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