KR910015337A - 메타크릴산 제조용 촉매의 제조방법 - Google Patents

메타크릴산 제조용 촉매의 제조방법 Download PDF

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Publication number
KR910015337A
KR910015337A KR1019910002391A KR910002391A KR910015337A KR 910015337 A KR910015337 A KR 910015337A KR 1019910002391 A KR1019910002391 A KR 1019910002391A KR 910002391 A KR910002391 A KR 910002391A KR 910015337 A KR910015337 A KR 910015337A
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South Korea
Prior art keywords
catalyst
ammonium
group
methacrylic acid
producing
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KR1019910002391A
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English (en)
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KR930005306B1 (ko
Inventor
신지 야마모또
유다까 기노시다
모도무 오오기따
Original Assignee
나가이 야따로오
미쓰비시레이온 가부시끼가이샤
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Publication of KR910015337A publication Critical patent/KR910015337A/ko
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Publication of KR930005306B1 publication Critical patent/KR930005306B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

메타크릴산 제조용 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 촉매 조제시 촉매 구성원소의 원료원으로 산화물, 탄산염, 초산염 및 수산화물로 이루어지는 군으로 부터 선택된 적어도 1종의 원료원을 사용하고, 촉매원료의 수용액 또는 수분산액에 탄산암모늄, 탄산수소암모늄, 황산암모늄 및 황산수소암모늄으로 이루어지는 군으로 부터 선택된 적어도 1종의 화합물을 가한후 물을 제거하고 잔류물을 열처리함을 특징으로 하는 인, 몰리부덴 및 바나듐을 함유하는 다성분계의 메타크릴산 제조용 촉매의 제조방법.
  2. 제1항에 있어서, 메타크릴산 제조용 촉매가 아래 일반식의 것임을 특징으로 하는 메타크릴산 제조용 촉매의 제조방법.
    PaMobVcCudXeYf(NH4)gOh
    (상기식중, P, Mo, V, Cu, NH4및 O는 각각 인, 몰리부덴, 바나듐, 구리, 암모늄기 및 산소이고, X는, 칼륨, 루비듐, 세슘 및 탈륨으로 이루어지는 군으로부터 선택된 적어도 1종의 원소이고, Y는, 은, 마그네슘, 아연, 비소, 계르마늄, 규소, 텅스텐, 붕소, 비스무스, 크롬, 난탄, 바륨, 안티몬, 철, 지르코늄, 텔루루 및 셀륨으로 이루어지는 군으로부터 선택된 적어도 1종의 원소를 나타낸다.
    a, b, c, d, e, f 및 h는 각 원소의 원자비율, g는 암모늄기의 분자수를 나타내고, b=12일때, a=0.5~3, c=0.01~3, d=0.01~2, e=0.01~2, f=0~5이고 h는 전술한 각 성분의 원자가를 만족하는데 필요로되는 산소원자수 이며, g=0.01~2이다.)
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910002391A 1990-02-15 1991-02-13 메타크릴산 제조용 촉매의 제조방법. KR930005306B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP32585 1990-02-15
JP02032585A JP3101821B2 (ja) 1990-02-15 1990-02-15 メタクリル酸製造用触媒の調製法
JP2-32585 1990-02-15

Publications (2)

Publication Number Publication Date
KR910015337A true KR910015337A (ko) 1991-09-30
KR930005306B1 KR930005306B1 (ko) 1993-06-17

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ID=12362944

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KR1019910002391A KR930005306B1 (ko) 1990-02-15 1991-02-13 메타크릴산 제조용 촉매의 제조방법.

Country Status (5)

Country Link
US (1) US5104844A (ko)
EP (1) EP0442517B1 (ko)
JP (1) JP3101821B2 (ko)
KR (1) KR930005306B1 (ko)
DE (1) DE69119925T2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210002576A (ko) * 2018-04-26 2021-01-08 미쯔비시 케미컬 주식회사 메타크릴산 제조용 촉매의 제조 방법, 및 메타크릴산 및 메타크릴산 에스터의 제조 방법

Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
DE4022212A1 (de) * 1990-07-12 1992-01-16 Basf Ag Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts)
US5198579A (en) * 1990-11-14 1993-03-30 Mitsui Toatsu Chemicals, Inc. Catalyst for oxidizing methacrolein and method for preparing methacrylic acid
JP3209778B2 (ja) * 1992-01-22 2001-09-17 三菱レイヨン株式会社 メタクリル酸製造用触媒の調製法
DE4405060A1 (de) * 1994-02-17 1995-08-24 Basf Ag Multimetalloxidmassen
KR0144645B1 (ko) * 1994-12-26 1998-07-15 황선두 메타크릴산 제조용 촉매
JP3765942B2 (ja) * 1999-04-27 2006-04-12 バブコック日立株式会社 排ガス浄化触媒化合物、該化合物を含む触媒、およびその製法
JP4671320B2 (ja) * 2000-09-21 2011-04-13 日本化薬株式会社 メタクリル酸製造用被覆触媒の製法
EP1325780A4 (en) * 2000-09-21 2006-05-03 Nippon Kayaku Kk CATALYST FOR METHACRYLIC ACID PRODUCTION, COATED CATALYST AND METHOD FOR THE PRODUCTION THEREOF
MY144325A (en) * 2003-02-20 2011-08-29 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof
KR100557640B1 (ko) * 2004-01-09 2006-03-10 주식회사 엘지화학 신규한 헤테로폴리산 촉매 및 그의 제조방법
SE543538C2 (sv) 2016-09-15 2021-03-23 Lindvalls Patentbolag Ab Avskrapare för ett ändlöst, rörligt djurhållningsgolv

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US4001316A (en) * 1973-06-15 1977-01-04 Nippon Kayaku Kabushiki Kaisha Method for manufacture of methacrylic acid
US3998876A (en) * 1973-08-16 1976-12-21 Mitsubishi Rayon Co., Ltd. Catalytic process for preparation of unsaturated carboxylic acids
US4000088A (en) * 1974-06-03 1976-12-28 Nippon Kayaku Co., Ltd. Oxidation catalyst for the manufacture of methacrylic acid
JPS5924140B2 (ja) * 1977-10-31 1984-06-07 日本化薬株式会社 メタクリル酸の製造法及び触媒
DD148728A5 (de) * 1978-12-13 1981-06-10 Nippon Kayaku Kk Verfahren zur herstellung eines katalysators mit heteropolysaeurestruktur
US4419270A (en) * 1980-06-26 1983-12-06 Nippon Shokubai Kagaku Kogyo Co. Ltd. Oxidation catalyst
JPH0791212B2 (ja) * 1988-07-11 1995-10-04 三菱レイヨン株式会社 メタクリル酸の製造法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210002576A (ko) * 2018-04-26 2021-01-08 미쯔비시 케미컬 주식회사 메타크릴산 제조용 촉매의 제조 방법, 및 메타크릴산 및 메타크릴산 에스터의 제조 방법

Also Published As

Publication number Publication date
EP0442517B1 (en) 1996-06-05
DE69119925D1 (de) 1996-07-11
EP0442517A1 (en) 1991-08-21
US5104844A (en) 1992-04-14
KR930005306B1 (ko) 1993-06-17
JP3101821B2 (ja) 2000-10-23
JPH03238052A (ja) 1991-10-23
DE69119925T2 (de) 1996-11-28

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