KR920005694A - 메타크릴산 제조용 촉매의 제조방법 - Google Patents

메타크릴산 제조용 촉매의 제조방법

Info

Publication number
KR920005694A
KR920005694A KR1019910006100A KR910006100A KR920005694A KR 920005694 A KR920005694 A KR 920005694A KR 1019910006100 A KR1019910006100 A KR 1019910006100A KR 910006100 A KR910006100 A KR 910006100A KR 920005694 A KR920005694 A KR 920005694A
Authority
KR
South Korea
Prior art keywords
ammonium
group
catalyst
methacrylic acid
thallium
Prior art date
Application number
KR1019910006100A
Other languages
English (en)
Other versions
KR930006683B1 (ko
Inventor
신지 야마모도
모도무 오오기다
Original Assignee
나가이 야다로오
미쯔비시 레이욘 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 나가이 야다로오, 미쯔비시 레이욘 가부시끼가이샤 filed Critical 나가이 야다로오
Publication of KR920005694A publication Critical patent/KR920005694A/ko
Application granted granted Critical
Publication of KR930006683B1 publication Critical patent/KR930006683B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음.

Description

메타크릴산 제조용 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 촉매 제조시 몰리부덴 및 바나듐 성분의 원료로써 산화물을 사용하고, 칼륨, 루비듐, 세슘 및 탈륨 이외의 촉매원료와 물과의 혼합액을 85℃ 이상에서 1~10시간 가열한 후 이 혼합액을 80℃ 이하로 냉각하고, 칼륨, 루비듐, 세슘 및 탈륨으로 이루어지는 군으로부터 선택된 적어도 1종의 원소를 첨가하고 계속하여 혼합액의 온도를 80℃ 이하에서 초산암모늄, 탄산암모늄, 탄산수소암모늄, 황산암모늄 및 황산수소암모늄으로 이루어지는 군으로부터 선택된 적어도 1종 이상의 화합물을 첨가한 후 물을 제거하여 얻은 잔류물을 열처리함을 특징으로 하는 인, 몰리부덴 및 바나듐을 함유하는 다성분계의 메타크릴산 제조용 촉매의 제조방법.
  2. 청구범위 제1항에 있어서, 메타크릴산 제조용 촉매가 아래 일반식으로 표시되는 촉매임을 특징으로 하는 다성분계의 메타크릴산 제조용 촉매의 제조방법.
    PaMobVcCudXeYf(NH4)gOh…………………………………………일반식
    (상기식중, P,Mo,V,Cu,NH4및 O는 각각 인, 몰리부덴, 바나듐, 구리, 암모늄기 및 산소이고, X는 칼륨, 루비듐, 세슘 및 탈륨으로 이루어진 군으로부터 선택된 적어도 1종의 원소이며, Y는 은, 마그네슘, 아연, 비소, 게르마늄, 규소, 텅스텐, 붕소, 비스무트, 크롬, 란탄, 바륨, 안티몬, 철, 지르코늄, 텔루르 및 셀륨으로 이루어진 군으로부터 선택된 적어도 1종의 원소이다. a,b,c,d,e,f,g 및 h는 각 원소의 원자 비율을 나타내며 ; b=12일때 a=0.5~3, c=0.01~3, d=0.01~2, e=0.01~2, f=0~5이고, h는 전기 각 성분의 원자가를 만족하기 위한 산소의 원자수이며, g는 암모늄기의 분자수를 나타내며, g=0.01~2이다)
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019910006100A 1990-04-23 1991-04-16 메타크릴산 제조용 촉매의 제조방법 KR930006683B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2-105338 1990-04-23
JP2105338A JPH047037A (ja) 1990-04-23 1990-04-23 メタクリル酸製造用触媒の調製法
JP105338 1990-04-23

Publications (2)

Publication Number Publication Date
KR920005694A true KR920005694A (ko) 1992-04-03
KR930006683B1 KR930006683B1 (ko) 1993-07-22

Family

ID=14404947

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910006100A KR930006683B1 (ko) 1990-04-23 1991-04-16 메타크릴산 제조용 촉매의 제조방법

Country Status (5)

Country Link
US (1) US5126307A (ko)
EP (1) EP0454376B1 (ko)
JP (1) JPH047037A (ko)
KR (1) KR930006683B1 (ko)
DE (1) DE69112262T2 (ko)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1252093B (it) * 1991-11-26 1995-06-01 Eniricerche Spa Catalizzatore e procedimento per la deidrogenazione ossidativa di etano ad etilene
KR0144645B1 (ko) * 1994-12-26 1998-07-15 황선두 메타크릴산 제조용 촉매
DE19638249A1 (de) * 1996-09-19 1998-03-26 Basf Ag Verfahren zur Herstellung einer katalytisch aktiven Multimetalloxidmasse
FR2811243A1 (fr) * 2000-07-04 2002-01-11 Atofina Compositions solides utiles dans la fabrication de l'acide acrylique par oxydation de l'acroleine
WO2002024328A1 (fr) * 2000-09-21 2002-03-28 Nippon Kayaku Kabushiki Kaisha Catalyseur servant a la production d'acide methacrylique, catalyseur recouvert et procede de fabrication de ce dernier
US7625834B2 (en) * 2002-07-05 2009-12-01 Mitsubishi Rayon Co., Ltd. Process for producing catalysts for the production of methacrylic acid
MY144325A (en) * 2003-02-20 2011-08-29 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof
KR100557640B1 (ko) * 2004-01-09 2006-03-10 주식회사 엘지화학 신규한 헤테로폴리산 촉매 및 그의 제조방법
JP4925415B2 (ja) * 2006-04-19 2012-04-25 三菱レイヨン株式会社 メタクリル酸製造用触媒の製造方法
KR100954049B1 (ko) 2007-06-13 2010-04-20 주식회사 엘지화학 헤테로폴리산계 촉매의 제조방법
JP4920503B2 (ja) * 2007-06-19 2012-04-18 日立アプライアンス株式会社 電気掃除機
CN102105223B (zh) 2008-07-29 2013-07-10 三菱丽阳株式会社 甲基丙烯酸制造用催化剂及其制造方法、以及甲基丙烯酸的制造方法
JP5626583B2 (ja) * 2010-01-28 2014-11-19 三菱レイヨン株式会社 メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4001316A (en) * 1973-06-15 1977-01-04 Nippon Kayaku Kabushiki Kaisha Method for manufacture of methacrylic acid
US3998876A (en) * 1973-08-16 1976-12-21 Mitsubishi Rayon Co., Ltd. Catalytic process for preparation of unsaturated carboxylic acids
JPS5924140B2 (ja) * 1977-10-31 1984-06-07 日本化薬株式会社 メタクリル酸の製造法及び触媒
DD148728A5 (de) * 1978-12-13 1981-06-10 Nippon Kayaku Kk Verfahren zur herstellung eines katalysators mit heteropolysaeurestruktur
US4419270A (en) * 1980-06-26 1983-12-06 Nippon Shokubai Kagaku Kogyo Co. Ltd. Oxidation catalyst
JPH0791212B2 (ja) * 1988-07-11 1995-10-04 三菱レイヨン株式会社 メタクリル酸の製造法

Also Published As

Publication number Publication date
EP0454376A1 (en) 1991-10-30
EP0454376B1 (en) 1995-08-23
US5126307A (en) 1992-06-30
JPH047037A (ja) 1992-01-10
KR930006683B1 (ko) 1993-07-22
DE69112262T2 (de) 1996-02-01
DE69112262D1 (de) 1995-09-28

Similar Documents

Publication Publication Date Title
KR920005694A (ko) 메타크릴산 제조용 촉매의 제조방법
KR830006155A (ko) 메타크틸산의 제조방법
KR920006032A (ko) 철-안티몬-몰리브덴-함유 산화물 촉매 조성물 및 이의 제조 방법
KR930001982A (ko) 메타크롤레인 및 메타크릴산 제조용 촉매의 제조방법
DE245192T1 (de) Keramische verbundformkoerper sowie verfahren zu ihrer herstellung.
KR930701232A (ko) 기계적 강도가 우수한 메타크롤레인 및 메타크릴산 합성용 성형촉매 또는 담지촉매 및 그의 제조방법
ES453887A1 (es) Un procedimiento de obtencion de acido acrilico o acido me- tacrilico.
KR880006160A (ko) 메타클로 레인 및 메티크릴산의 제조방법
MY117568A (en) Method for producing methacrolein
KR830003931A (ko) 개량된 Sb-함유 촉매의 제조방법
KR920000642A (ko) 밀봉용 유리 조성물
KR910015337A (ko) 메타크릴산 제조용 촉매의 제조방법
KR920016398A (ko) 메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법
KR880005063A (ko) 메타크릴산의 제조방법
EP0297392A3 (de) Verfahren zur Herstellung feinteiliger Bariumhexaferritpigmente aus Halogenidschmelzen sowie die Verwendung derartig hergestellter Bariumhexaferritpigmente
KR910007575A (ko) 메타크릴산 제조용 촉매의 제조방법
KR930701231A (ko) 메타크릴산 제조용 촉매의 제조방법
KR850004571A (ko) 불포화 알데히드를 산화시키는 방법
JPS56116041A (en) Binder for photographic toner
Matsuzaki et al. Thermal decomposition process of Bi2 (SO4) 3
JPS5517356A (en) Preparation of methacrylonitrile
KR950002853A (ko) 메타크릴산 제조용 촉매의 제조방법
RU2684087C1 (ru) Применение сложного оксида лантана, молибдена и теллура
KR870004931A (ko) 메타크롤레인 및 메타크릴 산의 제조방법
TH10849B (th) วิธีการผลิตเมธาโครลีอิน

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19990712

Year of fee payment: 7

LAPS Lapse due to unpaid annual fee