ES453887A1 - Un procedimiento de obtencion de acido acrilico o acido me- tacrilico. - Google Patents

Un procedimiento de obtencion de acido acrilico o acido me- tacrilico.

Info

Publication number
ES453887A1
ES453887A1 ES453887A ES453887A ES453887A1 ES 453887 A1 ES453887 A1 ES 453887A1 ES 453887 A ES453887 A ES 453887A ES 453887 A ES453887 A ES 453887A ES 453887 A1 ES453887 A1 ES 453887A1
Authority
ES
Spain
Prior art keywords
acid
catalyst
preparation
acrylic acid
methacrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES453887A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES453887A1 publication Critical patent/ES453887A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un procedimiento de obtención de ácido acrílico o ácido metacrílico a partir de acroleína o metacroleína, respectivamente, que comprende las operaciones de mezclar el aldehído, oxígeno molecular y vapor de agua en una proporción molar dentro del intervalo de 1/0,5 - 5/0 - 20, respectivamente; poner en contacto dicha mezcla con un catalizador a una temperatura de alrededor de 200º a 500ºC, teniendo dicho catalizador una composición representada por la fórmula empírica **(Fórmula)** donde X es un metal seleccionado del grupo que consta de antimonio y germanio, o ambos, y donde a es un número de 6 a alrededor de º18, b, c y d son, individualmente, de alrededor de 0,1 a alrededor de 6, y e es el número de átomos de oxígeno requeridos para satisfacer los requerimientos de valencia de los demás metales presentes; y recuperar el ácido insaturado.
ES453887A 1976-01-02 1976-12-02 Un procedimiento de obtencion de acido acrilico o acido me- tacrilico. Expired ES453887A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/646,224 US4051180A (en) 1976-01-02 1976-01-02 Preparation of acrylic acid and methacrylic acid

Publications (1)

Publication Number Publication Date
ES453887A1 true ES453887A1 (es) 1978-03-16

Family

ID=24592253

Family Applications (1)

Application Number Title Priority Date Filing Date
ES453887A Expired ES453887A1 (es) 1976-01-02 1976-12-02 Un procedimiento de obtencion de acido acrilico o acido me- tacrilico.

Country Status (11)

Country Link
US (2) US4051180A (es)
JP (1) JPS5285091A (es)
AT (1) AT357986B (es)
BE (1) BE849908A (es)
CA (1) CA1068670A (es)
DE (1) DE2654188A1 (es)
ES (1) ES453887A1 (es)
FR (1) FR2336972A1 (es)
GB (1) GB1566882A (es)
IT (1) IT1067287B (es)
NL (1) NL7614499A (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE31088E (en) * 1972-02-09 1982-11-23 Standard Oil Company Process for the manufacture of unsaturated aldehydes and acids from the corresponding olefins
US4169070A (en) * 1978-04-12 1979-09-25 Halcon Research And Development Corporation Catalyst and process for producing unsaturated acids by using same
US4280928A (en) * 1979-10-12 1981-07-28 Rohm And Haas Company Catalyst compositions and their use for the preparation of methacrolein
US4301038A (en) * 1979-12-26 1981-11-17 Standard Oil Company Catalyst for the production of unsaturated aliphatic acids
US4256915A (en) * 1979-12-26 1981-03-17 Standard Oil Company Production of ethylenically unsaturated aliphatic acids
US4560673A (en) * 1983-12-12 1985-12-24 The Standard Oil Company Catalyst for the oxidation of unsaturated aldehydes
US5260250A (en) * 1989-07-05 1993-11-09 Bp Chemicals Limited Catalyst for the production of ethylene and acetic acid
US5210293A (en) * 1989-07-05 1993-05-11 Bp Chemicals Limited Process and catalyst for the production of ethylene and acetic acid
JP3786297B2 (ja) * 1995-03-03 2006-06-14 日本化薬株式会社 触媒の製造方法
JP3537253B2 (ja) * 1996-03-06 2004-06-14 株式会社日本触媒 アクリル酸の製造方法
DE19983250T1 (de) * 1998-08-28 2001-08-09 Asahi Chemical Ind Verfahren zur Herstellung eines Oxidkatalysators für die Verwendung bei der Herstellung von Acrylnitril oder Methacrylnitril aus Propan oder Isobutan
US6762148B2 (en) 1999-09-17 2004-07-13 Nippon Kayaku Kabushiki Kaisha Catalyst process of making
JP3883755B2 (ja) * 1999-09-17 2007-02-21 日本化薬株式会社 触媒の製造方法
JP3744751B2 (ja) * 1999-12-08 2006-02-15 株式会社日本触媒 担体、複合酸化物触媒、およびアクリル酸の製造方法
ZA200200049B (en) 2001-01-25 2002-07-16 Nippon Catalytic Chem Ind Fixed-bed shell-and-tube reactor and its usage.
US6953768B2 (en) * 2002-11-26 2005-10-11 Teck Cominco Metals Ltd. Multi-component catalyst system for the polycondensation manufacture of polyesters
JP4813758B2 (ja) 2003-02-27 2011-11-09 株式会社日本触媒 複合酸化物触媒およびそれを用いたアクリル酸の製造方法
KR100497175B1 (ko) 2003-03-26 2005-06-23 주식회사 엘지화학 프로필렌 및 이소부틸렌 부분산화 반응용 촉매의 제조방법
BRPI0913336A2 (pt) * 2008-06-02 2015-11-24 Nippon Kayaku Kk catalisador e método de produção de aldeído insaturado e ácido carboxílico insaturado
WO2010001732A1 (ja) 2008-06-30 2010-01-07 株式会社日本触媒 固定床多管式反応器への固体粒状物の充填方法
JP2011121048A (ja) * 2009-12-09 2011-06-23 Rohm & Haas Co 固体触媒物質をブレンドし、管状構造物に装填する方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1106648A (en) * 1965-11-10 1968-03-20 Distillers Co Yeast Ltd Improvements in or relating to the production of unsaturated aliphatic acids
NL147411B (nl) * 1968-05-13 1975-10-15 Rikagaku Kenkyusho Werkwijze ter bereiding van acrylzuur door katalytische oxydatie van acrolein in de dampfase.
US3867438A (en) * 1970-10-13 1975-02-18 Degussa Process for the oxidation of {60 ,{62 -unsaturated aldehydes to {60 ,{62 -unsaturated carboxylic acids
JPS4911371B1 (es) * 1970-10-23 1974-03-16 Nippon Catalytic Chem Ind

Also Published As

Publication number Publication date
FR2336972A1 (fr) 1977-07-29
JPS5285091A (en) 1977-07-15
BE849908A (fr) 1977-04-15
US4051180A (en) 1977-09-27
GB1566882A (en) 1980-05-08
ATA893676A (de) 1980-01-15
CA1068670A (en) 1979-12-25
US4082698A (en) 1978-04-04
NL7614499A (nl) 1977-07-05
IT1067287B (it) 1985-03-16
AT357986B (de) 1980-08-11
DE2654188A1 (de) 1977-07-14

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