KR920016398A - 메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법 - Google Patents

메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법 Download PDF

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KR920016398A
KR920016398A KR1019920003000A KR920003000A KR920016398A KR 920016398 A KR920016398 A KR 920016398A KR 1019920003000 A KR1019920003000 A KR 1019920003000A KR 920003000 A KR920003000 A KR 920003000A KR 920016398 A KR920016398 A KR 920016398A
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마쓰우라 이꾸야
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사와무라 하루오
미쓰이도오아쓰가가꾸 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용되는 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 하기 일반식(1)
    (Mo)a(Bi)b(Fe)c(X)d(Z)f(O)g (1)
    [식중, X는 Ni 및 Co로 이루어진 군으로부터 선택된 1종 이상의 원소를 나타내고, Z는 W, Be, Mg, S, Ca, Sr, Ba, Te,Se, Ce, Ge, Mn, Zn, Cr, Ag, Sb, Pb, As. B, P, Nb, Cu, Cd, Sn, Al, Zr 및 Ti로 이루어진 군으로부터 선택된 1종 이상의 원소를 나타내며, a. b, c, d, f 및 g는 각 원소의 원자비율을 나타내고, a를 기준으로하여 a=12로 하였을때에, b=0.1∼10, c=0∼20. d=0∼20. f=0∼4이며, g는 싱기 각 성분의 원자가를 만족시키는데 필요한 원자수이다] 표시되는 조성물(1)과 일반식(2)
    (A)m(Mo)n)(O)p (2)
    [식중, A는 K, Rb 및 Cs로 이루어진 군으로부터 선택된 1종 이상의 원소를 나타내고, m. n 및 p는 각윈소의 원자비율을나타내고, m을 기준으로하여 m=2로 하였을때에, n=1∼9, p=3n+1이다]로 표시되는 조성물(2)와의 혼합물인 촉매의 존재하에서, 이소부틸렌 또는 3급 부탄올을 분자상 산소를 사용하여 기상접촉산화하는 것을 특징으로 하는 메타크롤레인의 제조방법.
  2. 제1항에 있어서, 조성물(1)과 조성물(2)와의 혼합비가 A/Bi의 원자비율로 표시하여 0.02∼1.0인 제조방법.
  3. 제1항 또는 2항에 있어서, 조성물(1)과 조성물(2)를 30℃로부터 300℃의 온도범위에서 가열 혼합하여, 300℃ 이하의 온도에서 증발 건조시켜 굳히고, 300℃로부터 650℃의 온도범위에서 소성하여 얻어진 촉매를 사용하는 제조방법.
  4. 제3항에 있어서, 조성물(1)과 조성물(2)와의 가열 혼합을 물의 존재하에서 실시하여 얻어진 촉매를 사용하는 제조방법.
  5. 하기 일반식(1)
    (Mo)a(Bi)b(Fe)c(X)d(Z)f(O)g (1)
    [식중, X는 Ni 및 Co로, 이루어진 군으로부터 선택된 1종 이상의 원소를 나타내고, Z는 W, Be, Mg, S,Ca, Sr, Ba, Te,Se, Ce, Ge, Mn, Zn, Cr, Ag, Sb, Pb, As, B, P, Nb, Cu, Cd, Sn, Al, Zr 및 Ti로 이루어진 군으로부터 선택된 1종 이상의 원소를 나타내고, a, b, c. d, f 및 g는 각 원소의 윈자비율을 나타내고, a를 기준으로 하여 a=12로 하였을때에,b=0.1∼10, c=0∼20, d=0∼20, f=0∼4이며, g는상기 각 성분의 윈자가를 만족시키는데 필요한 원자수이다]로 표시되는 조성물(1)과, 일반식 (2)
    (A)m(Mo)n)(O)p (2)
    [식중, A는 K. Rb 및 Cs로 이루어진 군으로부터 선택된 1종 이상의 윈소를 나타내고, m. n 및 p는 각윈소의 원자비율을나타내고, m을 기준으로하여 m=2로 하였을때에, n=1∼9, p=3n+1이다]로 표시되는조성물(2)를 가열 혼합하여, 증발 건조시켜 굳히고, 소성하는 것을 특징으로 하는 메타크롤레인의 제조방법에 사용하는 촉매의 제조방법.
  6. 제5항에 있어서, 조성물(1)과 조성물(2)와의 혼합비가 A/Bi의 원자비율로 표시하여 0.02-1.0인 촉매의 제조방법.
  7. 제5항 또는 6항에 있어서, 조성물(1)과 조성물(2)를 30℃로부터 300℃의 온도범위에시 가열 혼합하여, 300℃ 이하의 온도에서 증발 건조시켜 굳히고, 300℃로부터 650℃의 온도범위에서 소성하는 촉매의 제조방법.
  8. 제7항에 있어서, 조성물(1)과 조성물(2)와의 가열 혼합을 물이 존재하에서 실시하는 촉매의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920003000A 1991-02-27 1992-02-26 메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법 KR950004031B1 (ko)

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Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
DE19855913A1 (de) * 1998-12-03 2000-06-08 Basf Ag Multimetalloxidmasse zur gasphasenkatalytischen Oxidation organischer Verbindungen
KR100569632B1 (ko) * 1999-05-13 2006-04-10 가부시키가이샤 닛폰 쇼쿠바이 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법
KR100513664B1 (ko) * 2002-05-16 2005-09-07 주식회사 엘지화학 프로필렌의 부분 산화 반응용 촉매의 제조 방법
US6946422B2 (en) * 2002-12-12 2005-09-20 Saudi Basic Industries Corporation Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes
US20040192973A1 (en) * 2003-03-31 2004-09-30 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7501377B2 (en) * 2003-03-31 2009-03-10 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
KR100561073B1 (ko) * 2004-02-25 2006-03-17 주식회사 엘지화학 기상 부분 산화 반응용 촉매 및 그의 제조방법
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP6303248B2 (ja) 2014-06-10 2018-04-04 エルジー・ケム・リミテッド 多成分系複合金属酸化物触媒の製造方法
EP3219386A1 (de) * 2016-03-14 2017-09-20 Evonik Degussa GmbH Verfahren zur hydrothermalen herstellung von molybdän-bismut-cobalt-eisen-mischoxidkatalysatoren
CN111389410A (zh) * 2020-04-17 2020-07-10 中国科学院过程工程研究所 一种复合金属氧化物催化剂及其制备方法
CN112604701B (zh) * 2020-12-29 2022-06-10 上海华谊新材料有限公司 复合氧化物催化剂及其制备方法和用途

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1555679A (ko) * 1966-11-04 1969-01-31
US3497461A (en) * 1968-02-02 1970-02-24 Du Pont Bismuth molybdate on silica catalysts
US3746657A (en) * 1971-06-28 1973-07-17 Standard Oil Co Catalyst manufacturing process
JPS4852713A (ko) * 1971-10-29 1973-07-24
IN142430B (ko) * 1975-04-21 1977-07-09 Standard Oil Co
US4049577A (en) * 1975-12-15 1977-09-20 The Dow Chemical Company Catalyst for making acrolein
JPS5945415B2 (ja) * 1976-12-13 1984-11-06 日本ゼオン株式会社 オレフイン酸化用触媒
FR2397229A1 (fr) * 1977-07-01 1979-02-09 Dow Chemical Co Catalyseurs et procede pour preparer l'acide acrylique a partir du propylene
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
JPS5823371B2 (ja) * 1979-07-20 1983-05-14 旭化成株式会社 メタクロレインの製造方法
US4306090A (en) * 1979-10-12 1981-12-15 Rohm And Haas Company Catalyst compositions and their use for the preparation of methacrolein
JPS56166140A (en) * 1980-05-24 1981-12-21 Asahi Chem Ind Co Ltd Preparation of methacrolein
DE3260617D1 (en) * 1981-02-17 1984-10-04 Standard Oil Co Ohio Preparation of composite oxidation catalyst and use thereof for the production of unsaturated aldehydes and acids from propylene and isobutylene
US4388223A (en) * 1981-04-06 1983-06-14 Euteco Impianti S.P.A. Catalyst for the conversion of unsaturated hydrocarbons into diolefins or unsaturated aldehydes and nitriles, and process for preparing the same
JPS5946132A (ja) * 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
JPH07116070B2 (ja) * 1987-08-26 1995-12-13 株式会社日本触媒 メチルタ−シャリ−ブチルエ−テルからメタクロレインおよびメタクリル酸の製法
DE69109746T2 (de) * 1990-06-06 1995-10-26 Mitsui Toatsu Chemicals Verfahren zur Herstellung von Acrolein oder Methacrolein.
JP2841324B2 (ja) * 1990-06-06 1998-12-24 三井化学株式会社 メタクロレインの製造方法

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DE69210288D1 (de) 1996-06-05
US5245083A (en) 1993-09-14
KR950004031B1 (ko) 1995-04-22
EP0501794A1 (en) 1992-09-02
DE69210288T2 (de) 1996-10-10
EP0501794B1 (en) 1996-05-01

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