DE69210288D1 - Verfahren zur Herstellung von Methanolein und Verfahren zur Herstellung eines Katalysators zur Verwendung in dem Methacrolein-Verfahren - Google Patents

Verfahren zur Herstellung von Methanolein und Verfahren zur Herstellung eines Katalysators zur Verwendung in dem Methacrolein-Verfahren

Info

Publication number
DE69210288D1
DE69210288D1 DE69210288T DE69210288T DE69210288D1 DE 69210288 D1 DE69210288 D1 DE 69210288D1 DE 69210288 T DE69210288 T DE 69210288T DE 69210288 T DE69210288 T DE 69210288T DE 69210288 D1 DE69210288 D1 DE 69210288D1
Authority
DE
Germany
Prior art keywords
processes
producing
methanolein
catalyst
methacrolein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69210288T
Other languages
English (en)
Other versions
DE69210288T2 (de
Inventor
Ikuya Matsuura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Toatsu Chemicals Inc
Original Assignee
Mitsui Toatsu Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc
Publication of DE69210288D1 publication Critical patent/DE69210288D1/de
Application granted granted Critical
Publication of DE69210288T2 publication Critical patent/DE69210288T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69210288T 1991-02-27 1992-02-27 Verfahren zur Herstellung von Methanolein und Verfahren zur Herstellung eines Katalysators zur Verwendung in dem Methacrolein-Verfahren Expired - Fee Related DE69210288T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3271891 1991-02-27

Publications (2)

Publication Number Publication Date
DE69210288D1 true DE69210288D1 (de) 1996-06-05
DE69210288T2 DE69210288T2 (de) 1996-10-10

Family

ID=12366623

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69210288T Expired - Fee Related DE69210288T2 (de) 1991-02-27 1992-02-27 Verfahren zur Herstellung von Methanolein und Verfahren zur Herstellung eines Katalysators zur Verwendung in dem Methacrolein-Verfahren

Country Status (4)

Country Link
US (1) US5245083A (de)
EP (1) EP0501794B1 (de)
KR (1) KR950004031B1 (de)
DE (1) DE69210288T2 (de)

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* Cited by examiner, † Cited by third party
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US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
DE19855913A1 (de) * 1998-12-03 2000-06-08 Basf Ag Multimetalloxidmasse zur gasphasenkatalytischen Oxidation organischer Verbindungen
KR100569632B1 (ko) * 1999-05-13 2006-04-10 가부시키가이샤 닛폰 쇼쿠바이 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법
KR100513664B1 (ko) * 2002-05-16 2005-09-07 주식회사 엘지화학 프로필렌의 부분 산화 반응용 촉매의 제조 방법
US6946422B2 (en) * 2002-12-12 2005-09-20 Saudi Basic Industries Corporation Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes
US7361791B2 (en) * 2003-03-31 2008-04-22 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US20040192973A1 (en) * 2003-03-31 2004-09-30 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
KR100561073B1 (ko) 2004-02-25 2006-03-17 주식회사 엘지화학 기상 부분 산화 반응용 촉매 및 그의 제조방법
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
KR101706851B1 (ko) 2014-06-10 2017-02-27 주식회사 엘지화학 다성분계 복합금속산화물 촉매의 제조방법
EP3219386A1 (de) 2016-03-14 2017-09-20 Evonik Degussa GmbH Verfahren zur hydrothermalen herstellung von molybdän-bismut-cobalt-eisen-mischoxidkatalysatoren
CN111389410A (zh) * 2020-04-17 2020-07-10 中国科学院过程工程研究所 一种复合金属氧化物催化剂及其制备方法
CN112604701B (zh) * 2020-12-29 2022-06-10 上海华谊新材料有限公司 复合氧化物催化剂及其制备方法和用途

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* Cited by examiner, † Cited by third party
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FR1555679A (de) * 1966-11-04 1969-01-31
US3497461A (en) * 1968-02-02 1970-02-24 Du Pont Bismuth molybdate on silica catalysts
US3746657A (en) * 1971-06-28 1973-07-17 Standard Oil Co Catalyst manufacturing process
JPS4852713A (de) * 1971-10-29 1973-07-24
IN142430B (de) * 1975-04-21 1977-07-09 Standard Oil Co
US4049577A (en) * 1975-12-15 1977-09-20 The Dow Chemical Company Catalyst for making acrolein
JPS5945415B2 (ja) * 1976-12-13 1984-11-06 日本ゼオン株式会社 オレフイン酸化用触媒
FR2397229A1 (fr) * 1977-07-01 1979-02-09 Dow Chemical Co Catalyseurs et procede pour preparer l'acide acrylique a partir du propylene
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
JPS5823371B2 (ja) * 1979-07-20 1983-05-14 旭化成株式会社 メタクロレインの製造方法
US4306090A (en) * 1979-10-12 1981-12-15 Rohm And Haas Company Catalyst compositions and their use for the preparation of methacrolein
JPS56166140A (en) * 1980-05-24 1981-12-21 Asahi Chem Ind Co Ltd Preparation of methacrolein
EP0061830B1 (de) * 1981-02-17 1984-08-29 The Standard Oil Company Herstellung von Oxydationskatalysatorgemischen und deren Verwendung zur Herstellung von ungesättigten Aldehyden und Säuren aus Propylen und Isobutylen
US4388223A (en) * 1981-04-06 1983-06-14 Euteco Impianti S.P.A. Catalyst for the conversion of unsaturated hydrocarbons into diolefins or unsaturated aldehydes and nitriles, and process for preparing the same
JPS5946132A (ja) * 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
JPH07116070B2 (ja) * 1987-08-26 1995-12-13 株式会社日本触媒 メチルタ−シャリ−ブチルエ−テルからメタクロレインおよびメタクリル酸の製法
EP0460932B1 (de) * 1990-06-06 1995-05-17 MITSUI TOATSU CHEMICALS, Inc. Verfahren zur Herstellung von Acrolein oder Methacrolein
JP2841324B2 (ja) * 1990-06-06 1998-12-24 三井化学株式会社 メタクロレインの製造方法

Also Published As

Publication number Publication date
KR950004031B1 (ko) 1995-04-22
EP0501794A1 (de) 1992-09-02
US5245083A (en) 1993-09-14
DE69210288T2 (de) 1996-10-10
EP0501794B1 (de) 1996-05-01
KR920016398A (ko) 1992-09-24

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee